Hydrogen isotopes in volcanic plumes: Tracers for remote temperature sensing of fumaroles     

Urumu Tsunogai  Kanae Kamimura  Saya Anzai  Fumiko Nakagawa  Daisuke D. Komatsu 《Geochimica et cosmochimica acta》2011,75(16):4531-4546

In high-temperature volcanic fumaroles (>400 °C), the isotopic composition of molecular hydrogen (H₂) reaches equilibrium with that of the fumarolic H₂O. In this study, we used this hydrogen isotope exchange equilibrium of fumarolic H₂ as a tracer for the remote temperature at volcanic fumaroles. In this remote sensing, we deduced the hydrogen isotopic composition (δD value) of fumarolic H₂ from those in the volcanic plume. To ascertain that we can estimate the δD value of fumarolic H₂ from those in a volcanic plume, we estimated the values in three fumaroles with outlet temperatures of 630 °C (Tarumae), 203 °C (Kuju), and 107 °C (E-san). For this we measured the concentration and δD value of H₂ in each volcanic plume, along with those determined directly at each fumarole. The average and maximum mixing ratios of fumarolic H₂ within a plume’s total H₂ were 97% and 99% (at Tarumae), 89% and 96% (at Kuju), and 97% and 99% (at E-san). We found a linear relationship between the depletion in the δD values of H₂, with the reciprocal of H₂ concentration. Furthermore, the estimated end-member δD value for each H₂-enriched component (−260 ± 30‰ vs. VSMOW in Tarumae, −509 ± 23‰ in Kuju, and −437 ± 14‰ in E-san) coincided well with those observed at each fumarole (−247.0 ± 0.6‰ in Tarumae, −527.7 ± 10.1‰ in Kuju, and −432.1 ± 2.5‰ in E-san). Moreover, the calculated isotopic temperatures at the fumaroles agreed to within 20 °C with the observed outlet temperature at Tarumae and Kuju. We deduced that the δD value of the fumarolic H₂ was quenched within the volcanic plume. This enabled us to remotely estimate these in the fumarole, and thus the outlet temperature of fumaroles, at least for those having the outlet temperatures more than 400 °C. By applying this methodology to the volcanic plume emitted from the Crater 1 of Mt. Naka-dake (the volcano Aso) where direct measurement on fumaroles was impractical, we estimated that the δD value of the fumarolic H₂ to be −172 ± 16‰ and the outlet temperature to be 868 ± 97 °C. The remote temperature sensing using hydrogen isotopes developed in this study is widely applicable to many volcanic systems.  相似文献   

Compressibility of strontium orthophosphate Sr<Subscript>3</Subscript>(PO<Subscript>4</Subscript>)<Subscript>2</Subscript> at high pressure     

Shuangmeng Zhai  Weihong Xue  Daisuke Yamazaki  Shuangming Shan  Eiji Ito  Naotaka Tomioka  Akira Shimojuku  Ken-ichi Funakoshi 《Physics and Chemistry of Minerals》2011,38(5):357-361

High pressure in situ synchrotron X-ray diffraction experiment of strontium orthophosphate Sr₃(PO₄)₂ has been carried out to 20.0 GPa at room temperature using multianvil apparatus. Fitting a third-order Birch–Murnaghan equation of state to the P–V data yields a volume of V ₀ = 498.0 ± 0.1 Å³, an isothermal bulk modulus of K _T  = 89.5 ± 1.7 GPa, and first pressure derivative of K _T ′ = 6.57 ± 0.34. If K _T ′ is fixed at 4, K _T is obtained as 104.4 ± 1.2 GPa. Analysis of axial compressible modulus shows that the a-axis (K _a  = 79.6 ± 3.2 GPa) is more compressible than the c-axis (K _c  = 116.4 ± 4.3 GPa). Based on the high pressure Raman spectroscopic results, the mode Grüneisen parameters are determined and the average mode Grüneisen parameter of PO₄ vibrations of Sr₃(PO₄)₂ is calculated to be 0.30(2).  相似文献   

http://www.sciencedirect.com/science/article/pii/S167498711200062X     

Tetsuya Tokiwa  Kimikazu Tsusaka  Makoto Matsubara  Taiki Ishikawa  Daisuke Ogawa 《地学前缘(英文版)》2013,4(1):105-111

This paper focuses on the formation mechanism of fractures induced by excavation of a gallery in soft sedimentary rocks in the Horonobe area of Japan.Detailed fracture mapping of the gallery indicates that the fractures consist of both pre-existing shear fractures and excavation damaged zone(EDZ) fractures. EDZ fractures correspond to weak planes associated with bedding planes or transgranular cracks.The EDZ fractures terminate against pre-existing shear fractures.Therefore,even for excavations in soft sedimentary rocks,formation of the EDZ fractures are controlled by pre-existing fractures and earlier weak planes.  相似文献   

Fall,classification, and exposure history of the Mifflin L5 chondrite     

Noriko T. Kita  Kees C. Welten  John W. Valley  Michael J. Spicuzza  Daisuke Nakashima  Travis J. Tenner  Takayuki Ushikubo  Glenn J. MacPherson  Linda Welzenbach  Philipp R. Heck  Andrew M. Davis  Matthias M. M. Meier  Rainer Wieler  Marc W. Caffee  Matthias Laubenstein  Kunihiko Nishiizumi 《Meteoritics & planetary science》2013,48(4):641-655

The Mifflin meteorite fell on the night of April 14, 2010, in southwestern Wisconsin. A bright fireball was observed throughout a wide area of the midwestern United States. The petrography, mineral compositions, and oxygen isotope ratios indicate that the meteorite is a L5 chondrite fragmental breccia with light/dark structure. The meteorite shows a low shock stage of S2, although some shock‐melted veins are present. The U,Th‐He age is 0.7 Ga, and the K‐Ar age is 1.8 Ga, indicating that Mifflin might have been heated at the time of the 470 Ma L‐chondrite parent body breakup and that U, Th‐He, and K‐Ar ages were partially reset. The cosmogenic radionuclide data indicate that Mifflin was exposed to cosmic rays while its radius was 30–65 cm. Assuming this exposure geometry, a cosmic‐ray exposure age of 25 ± 3 Ma is calculated from cosmogenic noble gas concentrations. The low ²²Ne/²¹Ne ratio may, however, indicate a two‐stage exposure with a longer first‐stage exposure at high shielding. Mifflin is unusual in having a low radiogenic gas content combined with a low shock stage and no evidence of late stage annealing; this inconsistency remains unexplained.  相似文献   

Detection of small earthquakes along the Pacific-Antarctic Ridge from T-waves recorded by abyssal ocean-bottom observatories     

Aki Ito  Hiroko Sugioka  Daisuke Suetsugu  Hajime Shiobara  Toshihiko Kanazawa  Yoshio Fukao 《Marine Geophysical Researches》2012,33(3):229-238

A number of seismoacoustic T-wave events were observed between January 2003 and January 2004 by broadband ocean-bottom seismometers installed on the French Polynesia seafloor at depths of 4,000?C5,000?m, well below the conjugate depth of the SOFAR channel. Using T-wave arrival times, we located 89 T-wave events along the Pacific-Antarctic Ridge. Among these, 63 events were not detected by land-based seismic observations of the United States Geological Survey (USGS), which was nearly twice the number of earthquakes reported by the USGS in the area during the observation period. We used a simple method to estimate earthquake magnitude from T-wave energy. The magnitudes of the events unidentified by the USGS ranged from 2.3 to 5.5, whereas magnitudes of the earthquakes reported by the USGS ranged from 4.1 to 6.2. Our study suggests that T-wave observations with abyssal ocean-bottom seismometers can improve the detection of small earthquakes and help our understanding of the seismotectonics of remote oceanic areas.  相似文献   

Eutrophication-induced changes in Lake Nakaumi,southwest Japan     

Kota Katsuki  Yasushi Miyamoto  Kazuyoshi Yamada  Hiroyuki Takata  Keiko Yamaguchi  Daisuke Nakayama  Hugo Coops  Hidenobu Kunii  Ritsuo Nomura  Boo-Keun Khim 《Journal of Paleolimnology》2008,40(4):1115-1125

Lake Nakaumi, southwest Japan, is an enclosed lagoon characterized by polyhaline and halocline conditions. Since the last century, its ecological state has been altered by eutrophication. We used a paleolimnological approach and studied multiple proxies, including chemical compounds, diatoms, foraminifera and molluscs, to infer the eutrophication history of the ecosystem. Eutrophication in Lake Nakaumi was associated with several factors, including increased nutrient loading, input of herbicides, and dike building since the 1920s. The ecological condition of this lake was divided into several stages that reflect the eutrophication process after the 1940s. A catastrophic “regime shift” from a clear state with aquatic vegetation to a turbid one with phytoplankton occurred in the early 1950s. Environmental degradation in the Honjo area, a part of Lake Nakaumi, was attributed primarily to physical changes caused by the construction of an enclosing dike. Eutrophication occurred almost simultaneously with the physical changes to the Honjo area in the 1970s. Until recently, no regime shift was observed in this area, though the core-top sediments show possible symptoms of incipient change.  相似文献   

Contributions of slab fluid and sediment melt components to magmatism in the Mariana Arc–Trough system: Evidence from geochemical compositions and Sr,Nd, and noble gas isotope systematics          下载免费PDF全文

Yasuo Ikeda  Keisuke Nagao  Teruaki Ishii  Daisuke Matsumoto  Robert J. Stern  Hiroo Kagami  Makoto Arima  Sherman H. Bloomer 《Island Arc》2016,25(4):253-273

This study presents new major and trace element, mineral, and Sr, Nd, and noble gas isotope geochemical analyses of basalts, gabbro, and clinopyroxenite from the Mariana Arc (Central Islands and Southern Seamount provinces) including the forearc, and the Mariana Trough (Central Graben and Spreading Ridge). Mantle source compositions beneath the Mariana Arc and the Mariana Trough indicate a mantle source that is depleted in high field strength elements relative to MORB (mid‐oceanic ridge basalt). Samples from the Mariana Arc, characterized by high ratios of Ba/Th, U/Th, ⁸⁴Kr/⁴He and ¹³²Xe/⁴He, are explained by addition of fluid from the subducted slab to the mantle wedge. Correlations of noble gas data, as well as large ion lithophile elements, indicate that heavy noble gases (Ar, Kr, and Xe) provide evidence for fluid fluxing into the mantle wedge. On the other hand, major elements and Sr, Nd, He, and Ne isotopic data of basalts from the Mariana Trough are geochemically indistinguishable from MORB. Correlations of ³He/⁴He and ⁴⁰Ar/³⁶Ar in the Mariana Trough samples are explained by mixing between MORB and atmosphere. One sample from the Central Graben indicates extreme enrichment in ²⁰Ne/²²Ne and ²¹Ne/²²Ne, suggesting incorporation of solar‐type Ne in the magma source. Excess ¹²⁹Xe is also observed in this sample suggesting primordial noble gases in the mantle source. The Mariana Trough basalts indicate that both fluid and sediment components contributed to the basalts, with slab‐derived fluids dominating beneath the Spreading Ridge, and that sediment melts, characterized by high La/Sm and relatively low U/Th and Zr/Nb, dominate in the source region of basalts from the Central Graben.  相似文献   

Trace element composition in tuite decomposed from natural apatite in high-pressure and high-temperature experiments     

ZHAI ShuangMeng  XUE WeiHong  Daisuke YAMAZAKI  MA Fang 《中国科学:地球科学(英文版)》2014,(12)

Tuite has been suggested as a potential reservoir for trace elements in the deep mantle,but no evidence confirms this supposition.By using a natural apatite as starting material,the trace-element-bearing tuite large crystals were obtained under highpressure and high-temperature conditions(15 GPa and 1800 K).X-ray diffraction pattern and Micro-Raman spectrum of the run product confirm that tuite was synthesized.The concentrations of trace elements in tuite crystals were analyzed by laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS).The rare earth element patterns of tuite show enrichment of light rare earth elements relative to heavy rare earth elements.Tuite shows high concentrations of Th and Sr,and negative anomalies of Rb,Nb,and Hf.The results show that tuite can accommodate a large amount of trace elements.Tuite might be an important host to accommodate trace elements if there is much apatite subducted into the deep mantle.  相似文献   

Scientific role of ACA for low-mass star-formation study     

Shigehisa Takakuwa  Daisuke Iono  Baltasar Vila-Vilaro  Tomohiko Sekiguchi  Ryohei Kawabe 《Astrophysics and Space Science》2008,313(1-3):169-173

We discuss the scientific role of the Atacama Compact Array (ACA), the Japanese contribution to the ALMA project, for low-mass star-formation study. Our recent observations of several low-mass protostellar envelopes in the submillimeter CS (J=7–6) and HCN (J=4–3) lines with the SMA and ASTE have revealed that these submillimeter emissions are more extended than ∼2000 AU and show different velocity structures from those traced by millimeter lines. These results suggest the importance of taking short-spacing informations the ACA can offer. Our comprehensive imaging simulations of these protostellar envelopes, as well as prestellar cores and debris disks, unprecedentedly demonstrate the scientific importance of ACA.  相似文献   

A newly devised infra-red ground scanner and its application to geothermal research in volcanoes     

Daisuke Shimozuru  Tsuneomi Kagiyama 《Journal of Volcanology and Geothermal Research》1978,4(3-4)

A new infra-red radiometer for volcanological purposes consists of a commercially available infra-red optical unit (IR camera), mounted on a balloon-tracking theodolite in place of the telescope. The device has a motor-driven horizontal scan at two speeds, and the output signal is fed to a portable recorder. Thus, it is possible to obtain the horizontal temperature profile of an objective area. With successive scanning with different vertical angles of the camera, the spatial temperature distribution can be obtained.The IR ground scanner was successfully utilized at two volcanoes — Kusatsu-shirane and Mihara-yama, O-shima. Repeated IR surveys were made after minor eruptive events. Variations of the surface temperature with time were detected for both volcanoes. The IR scanner is also suitable for monitoring the time and temperature of eruptions from active vents.  相似文献