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21.
Jože Kotnik Milena Horvat Emmanuel Tessier Nives Ogrinc Mathilde Monperrus David Amouroux Vesna Fajon Darija Gibičar Suzana Žižek Francesca Sprovieri Nicola Pirrone 《Marine Chemistry》2007
Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg0, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea. 相似文献
22.
Two processes are generally explained as causes of temporal changes in the stoichiometric silicon/nitrogen (Si/N) ratios of
sinking particles and of nutrient consumption in the surface water during the spring diatom bloom: (1) physiological changes
of diatom under the stress of photosynthesis of diatom and (2) differences of regeneration between silicon and nitrogen. We
investigated which process plays an important role in these changes using a one-dimensional ecosystem model that explicitly
represents diatom and the other non-silicious phytoplankton. The model was applied to station A7 (41°30′ N, 145°30′ E) in
the western North Pacific, where diatom regularly blooms in spring. Model simulations show that the Si/N ratios of the flux
exported by the sinking particles at 100 m depth and of nutrient consumptions in the upper 100 m surface water have their
maxima at the end of the spring diatom bloom, the values and timings of which are significantly different from each other.
Analyses of the model results show that the differences of regeneration between silicon and nitrogen mainly cause the temporal
changes of the Si/N ratios. On the other hand, the physiological changes of diatoms under stress can hardly cause these temporal
changes, because the effect of the change in the diatom's uptake ratio of silicon to nitrogen is cancelled by that in its
sinking rate. 相似文献
23.
Several large deployments of neutrally buoyant floats took place within the Antarctic Intermediate (AAIW), North Atlantic Deep Water (NADW), and the Antarctic Bottom Water (AABW) of the South Atlantic in the 1990s and a number of hydrographic sections were occupied as well. Here we use the spatially and temporally averaged velocities measured by these floats, combined with the hydrographic section data and various estimates of regional current transports from moored current meter arrays, to determine the circulation of the three major subthermocline water masses in a zonal strip across the South Atlantic between the latitudes of 19°S and 30°S. We concentrate on this region because the historical literature suggests that it is where the Deep Western Boundary Current containing NADW bifurcates. In support of this notion, we find that a net of about 5 Sv. of the 15–20 Sv that crosses 19°S does continue zonally eastward at least as far as the Mid-Atlantic Ridge. Once across the ridge it takes a circuit to the north along the ridge flanks before returning to the south in the eastern half of the Angola Basin. The data suggest that the NADW then continues on into the Indian Ocean. This scheme is discussed in the context of distributions of dissolved oxygen, silicate and salinity. In spite of the many float-years of data that were collected in the region a surprising result is that their impact on the computed solutions is quite modest. Although the focus is on the NADW we also discuss the circulation for the AAIW and AABW layers. 相似文献
24.
With the development of high-resolution multibeam echosounder systems (MBES) for surveying shallow-water areas a new tool is available to monitor rapid changes in seabed morphology as, e.g., caused by the dumping of dredge spoil in coastal waters. In this study, four data sets of repeated bathymetric surveys with a MBES were processed and analyzed. The data were collected in a 1.94-km2 dumping site in the outer Weser Estuary (German Bight). Between June and December 1998, 2.6 million m3 of dredged sediment were deposited there. The bathymetric maps generated in the course of this study reveal features such as subaqueous dunes, scour holes, and mounds of dumped dredge spoil. The mean water depth decreased by about 1 m during the dumping period. Furthermore, difference grids showing changes in sediment volume allowed a calculation of the sediment budget for the monitored area. After a time period of only 5 months, 0.5 million m3 of the originally dumped 2.6 million m3 of dredge spoil had already been removed from the dumping site. 相似文献
25.
Erdal Dolu Erkan Gökaşan Engin Meriç Mustafa Ergin Tolga Görüm Hüseyin Tur Berkan Ecevitoğlu Niyazi Avşar Muhittin Görmüş Fatmagül Batuk Buğser Tok Oktay Çetin 《Geo-Marine Letters》2007,27(6):355-381
The Quaternary evolution of the Gulf of İzmit, situated on the tectonically active North Anatolian Fault Zone (NAFZ), was
investigated using seismic reflection, paleontologic, and sediment textural data. On the basis of seismic stratigraphic and
sedimentologic-paleontologic interpretations, four depositional units were distinguished within the Plio-Quaternary sequence
of the Gulf of İzmit. According to these data, Plio-Quaternary deposits supplied from the northern terrestrial area started
to accumulate during a progradational phase, in a south-facing half-graben. A coarse-grained sedimentary unit prograding into
the gulf from the south since 200 ka b.p. indicates a dramatic variation in the evolution of the gulf, with the initiation of a new strike-slip fault of the NAFZ
and a corresponding uplift of the Armutlu Peninsula in the south of the gulf. During the evolution of this fault from a wide
shear zone consisting of right-stepped strike-slip faults and pull-apart basins to a localized principal fault zone, sediments
were deposited under the influence of northerly prograding terrestrial and shallow-marine conditions due to relative sea-level
fluctuations in the Marmara Sea. During this period, the Gulf of İzmit was invaded mainly by Mediterranean and partly by Black
Sea waters. In the latest glacial period, shallow areas in the gulf became subaerially exposed, whereas the central and western
sub-basins of the gulf turned into lakes. The present evolution of the Gulf of İzmit is controlled by the after effects of
the new rupture of the NAFZ and the estuarine nature of the gulf environment. 相似文献
26.
Size-Fractionated Primary Production Estimated by a Two-Phytoplankton Community Model Applicable to Ocean Color Remote Sensing 总被引:3,自引:0,他引:3
In order to estimate primary production from ocean color satellite data using the Vertical Generalized Production Model (VGPM; Behrenfeld and Falkowski, 1997), we propose a two-phytoplankton community model. This model is based on the two assumptions that changes in chlorophyll concentration result from changes of large-sized phytoplankton abundance, and chlorophyll specific productivity of phytoplankton tends to be inversely proportional to phytoplankton size. Based on the analysis of primary production data, P
opt
B
, which was one parameter in the VGPM, was modeled as a function of sea surface temperature and sea surface chlorophyll concentration. The two-phytoplankton community model incorporated into the VGPM gave good estimates in a relatively high productive area. Size-fractionated primary production was estimated by the two-phytoplankton community model, and P
opt
B
of small-sized phytoplankton was 4.5 times that of large-sized phytoplankton. This result fell into the ranges observed during field studies. 相似文献
27.
Long-term Sensor Drift Found in Recovered Argo Profiling Floats 总被引:5,自引:0,他引:5
We recovered three Argo profiling floats after 2 to 2.5 years of operation, and recalibrated their temperature, conductivity, and pressure sensors. The results demonstrate that these floats exhibited a significant drift in salinity of −0.0074 to −0.0125, primarily due to the conductivity sensor drift. Combined with the recalibration result for another previously recovered float, the indication is that the negative salinity drift increases nearly in proportion to the operating period of floats. The increasing rate is −0.0041 (±0.0015) year−1, which yields a salinity drift of −0.016 (±0.006) for the expected float lifetime of four years. The present result suggests that reducing the float surfacing time would improve the accuracy of the salinity measurements. 相似文献
28.
Takushi?NikiEmail author Taiki?Fujinaga Mariyo?F.?Watanabe Junji?Kinoshita 《Journal of Oceanography》2004,60(5):913-917
Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide
(DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity
(minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation
≤7%) and linearity (r
2 > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample
to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity. 相似文献
29.
Eddy Shedding from the Kuroshio Bend at Luzon Strait 总被引:16,自引:1,他引:16
TOPEX/POSEDIENT-ERS satellite altimeter data along with the mean state from the Parallel Ocean Climate Model result have been used to investigate the variation of Kuroshio intrusion and eddy shedding at Luzon Strait during 1992–2001. The Kuroshio penetrates into the South China Sea and forms a bend. The Kuroshio bend varies with time, periodically shedding anticyclonic eddies. Criteria of eddy shedding are identified: 1) When the shedding event occurs, there are usually two centers of high Sea Surface Height (SSH) together with negative geostrophic vorticity in the Kuroshio Bend (KB) area. 2) Between the two centers of high SSH there usually exists positive geostrophic vorticity. These criteria have been used to determine the eddy shedding times and locations. The most frequent eddy shedding intervals are 70, 80 and 90 days. In both the winter and summer monsoon period, the most frequent locations are 119.5°E and 120°E, which means that the seasonal variation of eddy shedding location is unclear. 相似文献
30.
In this paper we analyze seismic regime and earthquake depth distribution and correlation of seismicity and mud volcanism in the Azerbaijan and the Caspian Sea region. For the present region we have calculated accurate source locations, seismic activity, earthquake repetition and released earthquake energy parameters. It is shown that the active tectonic processes in the region are concentrated within the thick sedimentary cover that we consider as a general source of contemporary stress and a main structural element responsible for the origin of regional earthquakes. The correlation of seismicity and mud volcanism is of paragenetic character. 相似文献