A New Interlaboratory Characterisation of Silicon,Rare Earth Elements and Twenty‐Two Other Trace Element Concentrations in the Natural River Water Certified Reference Material SLRS‐6 (NRC‐CNRC)     

Delphine Yeghicheyan  Dominique Aubert  Martine Bouhnik‐Le Coz  Jrme Chmeleff  Sophie Delpoux  Irina Djouraev  Guy Granier  Franois Lacan  Jean‐Luc Piro  Tristan Rousseau  Christophe Cloquet  Aurlie Marquet  Christophe Menniti  Catherine Pradoux  Rmi Freydier  Emmanoel Vieira da Silva‐Filho  Krzysztof Suchorski 《Geostandards and Geoanalytical Research》2019,43(3):475-496

The natural river water reference material SLRS‐6 (NRC‐CNRC) is the newest batch of a quality control material routinely used in many international environmental laboratories. This work presents a nine‐laboratory compilation of measurements of major and trace element concentrations and their related uncertainties, unavailable in the NRC‐CNRC certificate (B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Y, Zr and REEs). Measurements were mostly made using inductively coupled plasma‐mass spectrometry. The results are compared with equivalent data for the last batch of the material, SLRS‐5, measured simultaneously with SLRS‐6 in this study. In general, very low concentrations, close to the quantification limits, were found in the new batch. The Sr isotopic ratio is also reported.  相似文献   

Paleoeskimo site taphonomy: An assessment of the integrity of the Tayara site,Qikirtaq Island,Nunavik, Canada     

Dominique Todisco  Najat Bhiry  Pierre M. Desrosiers 《Geoarchaeology》2009,24(6):743-791

A detailed taphonomic study was undertaken at the Tayara site in order to determine the impact of natural processes such as surface water flow on spatial patterning and site formation. The study focused on Paleoeskimo level II, which contains many lithics and significant faunal remains. Level II integrity was assessed through spatial analysis and by examining the size distribution of lithic artifacts and bone orientation. Experimental knapping aimed at replicating Paleoeskimo lithic technology was used to assess the possible size sorting of lithics. The study indicates that artifact burial by water‐laid sediments did not result in a selective impoverishment in small‐sized lithics. Statistically significant lithic concentrations and associations suggest that spatial distribution was not significantly modified by site formation processes. However, slight post‐depositional changes were presumably induced by water flows in the form of statistically significant horizontal bone reorientations. These occurred when gently flowing water inundated bone accumulations without inducing significant washing or sorting of smaller lithic debris. The spatial integrity evaluation of the level II assemblage reveals a low degree of spatial disturbance and disorganization of the material (i.e., limited entropy), which is likely related to low‐energy hydraulic forces and rapid burial soon after Paleoeskimo occupation. The grouping and deposition of much of the occupation debris is likely the result of Paleoeskimo activities (e.g., knapping and butchering), and the lithics and fauna specimens are probably at or very near their original location. These results show the behavioral significance of the grouping and deposition of debris in Tayara's level II. © 2009 Wiley Periodicals, Inc.  相似文献   

Flow of ultra-hot orogens: A view from the Precambrian, clues for the Phanerozoic   总被引：1，自引：0，他引：1  

Dominique Chardon  Denis Gapais  Florence Cagnard   《Tectonophysics》2009,477(3-4):105

This contribution emphasizes first-order structural and metamorphic characters of Precambrian accretionary orogens to understand the kinematics and thermomechanical state of the continental lithosphere in convergent settings involving massive juvenile magmatism. We define a new class of orogens, called ultra-hot orogens (UHO), in which the weakest type of lithosphere on Earth is deformed. UHO are characterized by (1) distributed shortening and orogen-scale flow combining vertical and horizontal longitudinal advection, under long-lasting convergence, (2) homogeneous thickening by combined downward movements of supracrustal units and three-dimensional mass redistribution in the viscous lower crust, and (3) steady-state, negligible topography and relief leveled by syn-shortening erosion and near-field sedimentation. The flow analysis of UHO provides clues to understanding crustal kinematics beneath high plateaus and suggests that the seismic reflectivity pattern of hot orogens is an image of the layering produced by lateral flow of the lower crust and associated syn-kinematic plutonism.In between the UHO and the modern cold orogens (CO), developed by shortening of lithosphere bearing a stiff upper mantle, two classes of orogens are defined. Hot orogens (HO, representative of Cordilleran and wide mature collisional belts) share flow pattern characteristics with UHO, but involve a less intense magmatic activity and develop high topographies driving their collapse. Mixed-hot orogens (MHO, representative of magmatic arcs and Proterozoic collisional belts) are orogens made of UHO-type juvenile crust and display CO-like structure and kinematics. This classification points to the fundamental link between the presence of a stiff lithospheric mantle and strain localization along major thrusts in convergent settings. A high Moho temperature (> 900 °C), implying thinning of the lithospheric mantle, enhances three-dimensional flow of the lithosphere in response to convergence. Overall, this classification of orogens emphasizes the space and time variability of uppermost mantle temperature in controlling plate interactions and continental growth.  相似文献   

Thermal anomalies and paleoclimatic diffusive and advective phenomena: example of the Anglo-Paris Basin,northern France     

Jacques Dentzer  Sophie Violette  Simon Lopez  Dominique Bruel 《Hydrogeology Journal》2017,25(7):1951-1965

This study is the first quantification of the combined impact of diffusive and advective paleoclimatic phenomena to explain the weak vertical thermal flux anomaly in the upper part of the Anglo-Paris intracratonic sedimentary basin in northern France. The aim of the research is to understand the mechanisms at the origin of the thermal flux anomaly at the level of the Meso-Cenozoic sediment pile. Based on a temperature profile representative of the basin, transient thermo-hydraulic simulations were performed along a representative vertical cross-section of about 400 km within the Lower Cretaceous multi-layer aquifer. Four paleoclimatic scenarios are the combination of two paleotemperature climatic forcings and two hydrodynamic regimes, one of them taking into account the interruption of the recharge linked to permafrost development. The simulation results clearly show the transient nature of the basin’s thermal regime. Then, for the reference well, the majority of the thermal flux anomaly can be explained by advective and paleoclimatic mechanisms with a decrease in geothermal flux simulated up to a little over 30 mW/m², depending on the scenarios. Decrease in heat flux because of basin-scale subsurface flows in the Lower Cretaceous is around 15 mW/m². There are several ways forward from this first simple model, including simulation of development of permafrost and also the integration of vertical flows in the basin by use of a three-dimensional model to better explain the data.  相似文献   

Compositional dual mesh method for single phase flow in heterogeneous porous media—application to CO<Subscript>2</Subscript> storage     

Dominique Guérillot  Jérémie Bruyelle 《Computational Geosciences》2017,21(5-6):949-961

Numerical simulation of fluid flow coupled with chemical reactions has been an active field in the hydrogeology community and many formulations have been programmed into different software. In recent years, this subject has attracted increasing interest in the reservoir simulation community, partly for the application of chemical methods for hydrocarbon extraction but also for research on the geological sequestration of CO₂. In this paper, an extension to the concept of dual mesh for reactive transport modeling is presented. This approach involves two meshes, a low-resolution mesh to resolve the pressure equation and a high-resolution mesh to transport the species and to calculate the geochemical equilibrium. The main objective is to preserve the fine scale heterogeneities to reach a more accurate field behavior simulation than conventional approach which consist in performing simulations on a coarser mesh. The method is applied to a simulation of CO₂ storage in the SPE10 model that keep a high resolution of the heterogeneities.  相似文献   

Hydrodynamic behaviour of coarse bioclastic sand from shelly cheniers     

Pierre Weill  Dominique Mouazé  Bernadette Tessier  Jean‐Claude Brun‐Cottan 《地球表面变化过程与地形》2010,35(14):1642-1654

Cheniers from Mont‐Saint‐Michel bay (France) are coarse shelly sand ridges migrating on the mudflat up to the salt marshes where they accumulate and merge in a littoral barrier. In this macrotidal setting and low wave forcing, the cheniers are rarely submerged. However, they are found to move up to several metres during coincidence of spring tide and wave activity. Their processes of migration, morphology and internal structure (composition of the beddings, grain size, sorting and grain arrangement) are thought to be closely related to the hydrodynamic behaviour of the coarse and shelly sediment. This paper focuses on the hydrodynamic behaviour of bioclastic sand sampled from the cheniers: settling velocities of the shell fragments were measured using a 2 m long sedimentation tube. Thresholds of motion under unidirectional current, velocity and turbulence vertical profiles were characterized in a small recirculating flume using Laser Doppler Anemometry (LDA). The flat‐shaped bioclastic particles feature low settling velocities and reveal a good resistance to the re‐suspension effect of the flow when imbricated in a sediment bed. The shear stress in the bottom boundary layer has been measured in the viscous and log sub‐layers. Nikuradse roughness heights (k_s) for shell debris beds of different sizes have been quantified. It is found that k_s ≈ 2·56d₅₀. This value is close to the ones used for classic rounded sand grains despite their major differences of shape. The dual behaviour of the shell fragments (low settling velocity, good resistance to unidirectional flow) should be considered as a key to understanding how this coarse material is transported across the tidal flat, and finally accumulated as cheniers. Further flume experiments including wave activity and tidal fluctuations are necessary to better quantify these complex processes. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Evolution of calc-alkaline to alkaline magmatism through Carboniferous convergence to Permian transcurrent tectonics,western Chinese Tianshan   总被引：7，自引：0，他引：7  

Bo Wang  Dominique Cluzel  Liangshu Shu  Michel Faure  Jacques Charvet  Yan Chen  Sebastien Meffre  Koen de Jong 《International Journal of Earth Sciences》2009,98(6):1275-1298

Continuous magmatic activity occurred in the western Chinese Tianshan, Central Asia, from the Carboniferous to the Permian, i.e. before and after the Late Carboniferous amalgamation of Junggar and the Yili Blocks. Zircon U–Pb LA-ICPMS and Ar–Ar data reveal a coincidence in time between regional wrench faulting and granitoid emplacement. Permian post-collisional granitoids crop out within or at the margins of large-scale dextral strike-slip shear zones, some of them show synkinematic fabrics. The whole rock geochemical features of the Early-Middle Permian granitoids indicate an evolution from high-K calc-alkaline towards alkaline series. In other places of the North Tianshan, alkaline magmatism occurred together with deep marine sedimentation within elongated troughs controlled by wrench faults. Therefore, in contrast with previous interpretations that forwarded continental rift or mantle plume hypotheses, the coexistence of diverse magmatic sources during the same tectonic episode suggests that post-collisional lithosphere-scale transcurrent shearing tightly controlled the magmatic activity during the transition from convergent margin to intraplate anorogenic processes.  相似文献   

Comment on “Comparison of the composition of the Tempel 1 ejecta to the dust in Comet C/Hale-Bopp 1995 O1 and YSO HD 100546” by C.M. Lisse, K.E. Kraemer, J.A. Nuth III, A. Li, D. Joswiak [2007. Icarus 187, 69-86]     

Jacques Crovisier  Dominique Bockelée-Morvan 《Icarus》2008,195(2):938-940

Lisse et al. [Lisse, C.M., Kraemer, K.E., Nuth III, J.A., Li, A., Joswiak, D., 2007. Icarus 187, 69-86] recently presented a new analysis of an ISO spectrum of Comet C/1995 O1 (Hale-Bopp), from which they claimed the identification of many new dust species. Among them are PAHs, which were not found in our first analysis of the ISO spectra. We present here a re-examination of the ISO observations of Comet Hale-Bopp. From the absence of PAHs features in the 5.25-8.5 μm region, we infer that PAHs are at least twice less abundant than derived by Lisse et al. The carbonate feature at 7.00 μm is marginally present, but lower by a factor 2 to 3 than predicted by the model of Lisse et al.  相似文献   

Hydrodynamics of suspended particulate matter in the tidal freshwater zone of a macrotidal estuary (the Seine Estuary, France)     

Loïc Guézennec  Robert Lafite  Jean-Paul Dupont  Robert Meyer  Dominique Boust 《Estuaries and Coasts》1999,22(3):717-727

The effects of fortnightly, semidiurnal, and quaterdiurnal lunar tidal cycles on suspended particle concentrations in the tidal freshwater zone of the Seine macrotidal estuary were studied during periods of medium to low freshwater flow. Long-term records of turbidity show semidiurnal and spring-neap erosion-sedimentation cycles. During spring tide, the rise in low tide levels in the upper estuary leads to storage of water in the upper estuary. This increases residence time of water and suspended particulate matter (SPM). During spring tide periods, significant tidal pumping, measured by flux calculations, prevents SPM transit to the middle estuary which is characterized by the turbidity maximum zone. On a long-term basis, this tidal pumping allows marine particles to move upstream for several tens of kilometers into the upper estuary. At the end of the spring tide period, when the concentrations of suspended particulate matter are at their peak values and the low-tide level drops, the transport of suspended particulate matter to the middle estuary reaches its highest point. This period of maximum turbidity is of short duration because a significant amount of the SPM settles during neap tide. The particles, which settle under these conditions, are trapped in the upper estuary and cannot be moved to the zone of maximum turbidity until the next spring tide. From the upper estuary to the zone of maximum turbidity, particulate transport is generated by pulses at the start of the spring-neap tide transition period.  相似文献   

The planktonic food web of the Bizerte lagoon (south-western Mediterranean) during summer: I. Spatial distribution under different anthropogenic pressures     

Asma Sakka Hlaili  Boutheina Grami  Nathalie Niquil  Michel Gosselin  Dominique Hamel  Marc Troussellier  Hassine Hadj Mabrouk 《Estuarine, Coastal and Shelf Science》2008

The structure and the trophic interactions of the planktonic food web were investigated during summer 2004 in a coastal lagoon of south-western Mediterranean Sea. Biomasses of planktonic components as well as bacterial and phytoplankton production and grazing by microzooplankton were quantified at four stations (MA, MB, MJ and R) inside the lagoon. Station MA was impacted by urban discharge, station MB was influenced by industrial activity, station MJ was located in a shellfish farming sector, while station R represented the lagoon central area. Biomasses and production rates of bacteria (7–33 mg C m⁻³; 17.5–35 mg C m⁻³ d⁻¹) and phytoplankton (80–299 mg C m⁻³; 34–210 mg C m⁻³ d⁻¹) showed high values at station MJ, where substantial concentrations of nutrients (NO₃⁻ and Si(OH)₄) were found. Microphytoplankton, which dominated the total algal biomass and production (>82%), were characterized by the proliferation of several chain-forming diatoms. Microzooplankton was mainly composed of dinoflagellates (Torodinium, Protoperidinium and Dinophysis) and aloricate (Lohmaniellea and Strombidium) and tintinnid (Tintinnopsis, Tintinnus, Favella and Eutintinnus) ciliates. Higher biomass of these protozoa (359 mg C m⁻³) was observed at station MB, where large tintinnids were encountered. Mesozooplankton mainly represented by Calanoida (Acartia, Temora, Calanus, Eucalanus, Paracalanus and Centropages) and Cyclopoida (Oithona) copepods, exhibited higher and lower biomasses at stations MA/MJ and MB, respectively. Bacterivory represented only 35% of bacterial production at stations MB and R, but higher fractions (65–70%) were observed at stations MA and MJ. Small heterotrophic flagellates and aloricate ciliates seemed to be the main controllers of bacteria. Pico- and nanophytoplankton represented a significant alternative carbon pool for micrograzers, which grazing represented 67–90% of pico- and nano-algal production in all stations. Microzooplankton has, however, a relatively low impact on microphytoplankton, as ≤45% of microalgal production was consumed in all stations. This implies that an important fraction of diatom production would be channelled by herbivorous meso-grazers to higher consumers at stations MA and MJ where copepods were numerous. Most of the microalgal production would, however, sink particularly at station MB where copepods were scare. These different trophic interactions suggest different food web structures between stations. A multivorous food web seemed to prevail in stations MJ and MA, whereas microbial web was dominant in the other stations.  相似文献