Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy          下载免费PDF全文

Luke Daly  Phil A. Bland  Svetlana Tessalina  David W. Saxey  Steven M. Reddy  Denis Fougerouse  William D.A. Rickard  Lucy V. Forman  Alexandre La Fontaine  Julie M. Cairney  Simon P. Ringer  Bruce F. Schaefer  Daniel Schwander 《Geostandards and Geoanalytical Research》2018,42(3):279-299

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.  相似文献   

Toxic metals in a highly urbanized industry-impacted estuary (Bahia Blanca Estuary,Argentina): spatio-temporal analysis based on GIS     

Melisa Daiana Fernández Severini  María Elizabeth Carbone  Diana Mariel Villagran  Jorge Eduardo Marcovecchio 《Environmental Earth Sciences》2018,77(10):393

Cadmium, chromium, nickel, and lead were evaluated in the particulate fraction at one of the most industrialized estuaries at the Southwestern Atlantic Ocean, through Geographic Information System (GIS). Concentrations were analyzed at 21 stations during 2008–2010. The highest metal concentrations (Cd: 8,9; Cr: 256,49; Ni: 27,02; Pb: 78,43 µg g^??1 d. w.) were recorded at the stations located near industrial and urban discharges situated along the estuary. In addition, Pb presented a different seasonal and spatial behavior in comparison with Cd, Cr and Ni. Winter and spring presented the higher concentrations of Pb, and the inner stations presented the higher values. The estuary is considered a moderate to strongly polluted and significantly polluted according to the Index of geoaccumulation (I_geo) and the Enrichment Factor of Cd, respectively. The Multidimensional Scaling plot showed three groups of stations: the inner, associated to low levels of metals (G1), middle stations (G2) with intermediate levels and the outer (G3) with the highest ones. In addition, this work reveals the usefulness of the GIS-mapping techniques in the distribution of pollutants along an estuarine environment and the environmental quality assessment of estuarine systems.  相似文献   

The role of social capital,personal networks,and emergency responders in post-disaster recovery and resilience: a study of rural communities in Indiana     

Arif Mohaimin Sadri  Satish V. Ukkusuri  Seungyoon Lee  Rosalee Clawson  Daniel Aldrich  Megan Sapp Nelson  Justin Seipel  Daniel Kelly 《Natural Hazards》2018,90(3):1377-1406

The factors that explain the speed of recovery after disaster remain contested. While many have argued that physical infrastructure, social capital, and disaster damage influence the arc of recovery, empirical studies that test these various factors within a unified modeling framework are few. We conducted a mail survey to collect data on household recovery in four small towns in southern Indiana that were hit by deadly tornadoes in March 2012. The recovery effort is ongoing; while many of the homes, businesses, and community facilities were rebuilt in 2013, some are still under construction. We investigate how households in these communities are recovering from damage that they experienced and the role of social capital, personal networks, and assistance from emergency responders on the overall recovery experience. We used an ordered probit modeling framework to test the combined as well as relative effects of (a) damage to physical infrastructures (houses, vehicles, etc.); (b) recovery assistance from emergency responders (FEMA) as well as friends and neighbors; (c) personal network characteristics (size, network density, proximity, length of relationship); (d) social capital (civic engagement, contact with neighbors, trust); and (e) household characteristics. Results show that while households with higher levels of damage experienced slower recovery, those with recovery assistance from neighbors, stronger personal networks, and higher levels of social capital experienced faster recovery. The insights gained in this study will enable emergency managers and disaster response personnel to implement targeted strategies in facilitating post-disaster recovery and community resilience.  相似文献   

Mapping fractional landscape soils and vegetation components from Hyperion satellite imagery using an unsupervised machine-learning workflow     

Michael J. Friedel  Massimo Buscema  Luiz Eduardo Vicente  Fabio Iwashita  Andréa Koga-Vicente 《International Journal of Digital Earth》2018,11(7):670-690

An unsupervised machine-learning workflow is proposed for estimating fractional landscape soils and vegetation components from remotely sensed hyperspectral imagery. The workflow is applied to EO-1 Hyperion satellite imagery collected near Ibirací, Minas Gerais, Brazil. The proposed workflow includes subset feature selection, learning, and estimation algorithms. Network training with landscape feature class realizations provide a hypersurface from which to estimate mixtures of soil (e.g. 0.5 exceedance for pixels: 75% clay-rich Nitisols, 15% iron-rich Latosols, and 1% quartz-rich Arenosols) and vegetation (e.g. 0.5 exceedance for pixels: 4% Aspen-like trees, 7% Blackberry-like trees, 0% live grass, and 2% dead grass). The process correctly maps forests and iron-rich Latosols as being coincident with existing drainages, and correctly classifies the clay-rich Nitisols and grasses on the intervening hills. These classifications are independently corroborated visually (Google Earth) and quantitatively (random soil samples and crossplots of field spectra). Some mapping challenges are the underestimation of forest fractions and overestimation of soil fractions where steep valley shadows exist, and the under representation of classified grass in some dry areas of the Hyperion image. These preliminary results provide impetus for future hyperspectral studies involving airborne and satellite sensors with higher signal-to-noise and smaller footprints.  相似文献   

Rice crop phenology mapping at high spatial and temporal resolution using downscaled MODIS time-series     

Alex O. Onojeghuo  George A. Blackburn  Qunming Wang  Peter M. Atkinson  Daniel Kindred  Yuxin Miao 《地理信息系统科学与遥感》2018,55(5):659-677

Satellite data holds considerable potential as a source of information on rice crop growth which can be used to inform agronomy. However, given the typical field sizes in many rice-growing countries such as China, data from coarse spatial resolution satellite systems such as the Moderate Resolution Imaging Spectroradiometer (MODIS) are inadequate for resolving crop growth variability at the field scale. Nevertheless, systems such as MODIS do provide images with sufficient frequency to be able to capture the detail of rice crop growth trajectories throughout a growing season. In order to generate high spatial and temporal resolution data suitable for mapping rice crop phenology, this study fused MODIS data with lower frequency, higher spatial resolution Landsat data. An overall workflow was developed which began with image preprocessing, calculation of multi-temporal normalized difference vegetation index (NDVI) images, and spatiotemporal fusion of data from the two sensors. The Spatial and Temporal Adaptive Reflectance Fusion Model was used to effectively downscale the MODIS data to deliver a time-series of 30 m spatial resolution NDVI data at 8-day intervals throughout the rice-growing season. Zonal statistical analysis was used to extract NDVI time-series for individual fields and signal filtering was applied to the time-series to generate rice phenology curves. The downscaled MODIS NDVI products were able to characterize the development of paddy rice at fine spatial and temporal resolutions, across wide spatial extents over multiple growing seasons. These data permitted the extraction of key crop seasonality parameters that quantified inter-annual growth variability for a whole agricultural region and enabled mapping of the variability in crop performance between and within fields. Hence, this approach can provide rice crop growth data that is suitable for informing agronomic policy and practice across a wide range of scales.  相似文献   

Design principles for origin-destination flow maps     

Bernhard Jenny  Daniel M. Stephen  Ian Muehlenhaus  Brooke E. Marston  Ritesh Sharma  Eugene Zhang 《制图学和地理信息科学》2018,45(1):62-75

Origin-destination flow maps are often difficult to read due to overlapping flows. Cartographers have developed design principles in manual cartography for origin-destination flow maps to reduce overlaps and increase readability. These design principles are identified and documented using a quantitative content analysis of 97 geographic origin-destination flow maps without branching or merging flows. The effectiveness of selected design principles is verified in a user study with 215 participants. Findings show that (a) curved flows are more effective than straight flows, (b) arrows indicate direction more effectively than tapered line widths, and (c) flows between nodes are more effective than flows between areas. These findings, combined with results from user studies in graph drawing, conclude that effective and efficient origin-destination flow maps should be designed according to the following design principles: overlaps between flows are minimized; symmetric flows are preferred to asymmetric flows; longer flows are curved more than shorter or peripheral flows; acute angles between crossing flows are avoided; sharp bends in flow lines are avoided; flows do not pass under unconnected nodes; flows are radially distributed around nodes; flow direction is indicated with arrowheads; and flow width is scaled with represented quantity.  相似文献   

Opportunities accruing from the application of public private partnerships in down market urban housing in Kenya     

Giti  Daniel Mutegi  KÁkumu  Owiti Abiero  Ondieki  Edwin Oyaro 《GeoJournal》2021,86(6):2957-2974

GeoJournal - The purpose of this study was to investigate the opportunities which accrue from application of PPPs in development of down market urban housing in Kenya, hence attracting private...  相似文献   

Modelling temperature extremes in the Limpopo province: bivariate time-varying threshold excess approach     

Maposa  Daniel  Seimela  Anna M.  Sigauke  Caston  Cochran  James J. 《Natural Hazards》2021,106(3):2227-2249

Natural Hazards - Aiming at the stability of a highway slope reinforced with anti-sliding piles, the mechanical behaviour of the inclined pile-soil arch in a soil slope reinforced with anti-sliding...  相似文献   

The Effect of Key Parameters on the Strength of a Dispersive Soil Stabilized with Sustainable Binders     

Filho  Hugo Carlos Scheuermann  Martins  Carlos Guilherme  Menezes  Ricardo José Wink  Dornelles  Lucas Eduardo  Consoli  Nilo Cesar 《Geotechnical and Geological Engineering》2021,39(7):5395-5404

Geotechnical and Geological Engineering - Dispersive soils are susceptible to phenomena of internal and external erosion when in contact with relatively pure water due to its particle’s...  相似文献   

Evaluating property buyouts and disaster recovery assistance (Rebuild) options in Canada: A comparative analysis of Constance Bay,Ontario and Pointe Gatineau,Quebec     

Cottar  Shaieree  Doberstein  Brent  Henstra  Daniel  Wandel  Johanna 《Natural Hazards》2021,109(1):201-220

Natural Hazards - How have property buyouts and disaster recovery assistance programs been implemented in Canadian communities? This paper compares contrasting policies and programs in two Canadian...  相似文献