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91.
REE mineralogy was characterized at the micrometer scale (using scanning electron microscopy) in the four tectono-metamorphic units of the Beni Mzala window, Sebtide Complex, Internal Rif, Morocco, which sample a HP-LT metamorphic gradient from subgreenschist to blueschist/eclogite facies. These tectonic units are composed of garnet-free metapelites (and associated synmetamorphic veins) from the same homogeneous aluminium-rich and calcium-poor protolith. In that context, mineralogical differences between units are assumed to result from contrasted pressure and temperature histories. Light REE-bearing Al-phosphates of the crandallite group with florencite-rich composition and variable goyazite content are the dominant LREE minerals in the lowest-grade units, Tizgarine (300 °C, 3 kbar as peak conditions) and Boquete de Anjera (350 °C, 10 kbar). In the latter unit, metamorphic florencite is associated with MREE-rich monazite. In the schist of the highest-grade units, Beni Mzala 2 (420–450 °C, 12 kbar) and Beni Mzala 1 (550 °C, 16 kbar), associations of allanite-rich epidote and synchisite (a LREE-fluorocarbonate) are found whereas florencite and monazite are no longer observed. At the wall of the quartz–kyanite veins, retrograde monazite-(Ce) with grain size of 20 to 50 μm is the only LREE-bearing mineral. Th–Pb and U–Pb SIMS data on some of these grains yield ages of 21.3 ± 1.7 Ma and 20.9 ± 2.1 Ma, respectively, consistent with previous K–Ar ages obtained on retrograde clay–mica mixtures in rocks from the same locality. The identification of a stability field for monazite in high-pressure aluminous metapelites with an upper thermal-limit below 450 °C as well as the derivation of meaningful U–Pb and Th–Pb SIMS ages demonstrates the monazite potential for dating HP-LT metapelites. However, since, under these conditions, monazite growth occurs below its admitted closure-temperature, these ages must be interpreted on the basis of monazite textural relationships.  相似文献   
92.
Extensive mapping of relict lateritic landsurfaces over the 1600 m of relief of mainland New Caledonia is used to evaluate long-term morphogenesis of the island since its emergence in the Oligocene. The results support the interpretation of the lateritic levels as abandoned, stepped remnant landsurfaces that may be grouped into eight island-scale erosion levels recording episodic lowering of base level. The separation of the erosion levels results from the combination of positive epeirogenic movements of the New Caledonia continental ridge and long-term Neogene climate variability, which is recorded by the contrasted erosion and weathering patterns of the three youngest levels and tentatively correlated with known global and regional paleoclimatic events.  相似文献   
93.
In order to quantify Al transfer in response to fluid-mineral equilibration under evolving metamorphic conditions, isobaric (0.7 GPa) experiments were conducted in the 350-550 °C range. Disequilibrium was induced (1) by holding initially pure water and natural minerals (kyanite + quartz ± muscovite enclosed in a perforated inner capsule) under isothermal conditions and (2) by stepwise temperature variations. In all experiments, secondary Al-bearing phases crystallized in the external tube of a “tube-in-tube” setup (SEM characterization); they are interpreted as witnesses of the evolution of the fluid composition (fluid reaction path). These reaction paths and the subsequent amount of secondary crystallizations were modeled using thermodynamic data from SUPCRT92 and estimates of both starting-mineral dissolution rates and elemental diffusion coefficients from the literature. A major result is that the amount of aluminum transferred to secondary phases is a thousand times larger than the calculated Al concentration in the fluid. Although the crystallization of Al-bearing phases was expected as a response to a temperature decrease, the stepwise temperature increase (20 °C/day) also led to aluminum transfer towards secondary phases. In the course of re-equilibration, the fluid first becomes saturated with respect to aluminosilicates and then reaches silica saturation, due to the low solubility of Al-minerals. Consequently, aluminosilicates partly recrystallize in response to a temperature increase. Crystallization of secondary Al-phases in the external tube implies that aqueous aluminum was efficiently transported from the inner capsule, even in the pure Al2O3-SiO2-H2O system. Therefore, mass balance calculations considering a constant Al reference frame, i.e., postulating Al immobility, should be regarded with caution.  相似文献   
94.
The issue addressed in this paper is the objective selection of appropriate ground motion models for seismic hazard assessment in the Pyrenees. The method of Scherbaum et al. (2004a) is applied in order to rank eight published ground motion models relevant to intraplate or to low deformation rate contexts. This method is based on a transparent and data-driven process which quantifies the model fit and also measures how well the underlying model assumptions are met. The method is applied to 15 accelerometric records obtained in the Pyrenees for events of local magnitude between 4.8 and 5.1, corresponding to moment magnitudes ranging from 3.7 to 3.9. Only stations at rock sites are considered. A total of 720 spectral amplitudes are used to rank the selected ground motion models. Some control parameters of these models, such as magnitude and distance definitions, may vary from one model to the other. It is thus important to correct the selected models for their difference with respect to the magnitude and distance definitions used for the Pyrenean data. Our analysis shows that, with these corrections, some of the ground motion models successfully fit the data. These are the Lussou et al. (2001) and the Berge-Thierry et al. (2003) models. According to the selected ground motion models, a possible scenario of a magnitude 6 event is proposed; it predicts response spectra accelerations of 0.08–0.1 g at 1 Hz at a hypocentral distance of 10 km.  相似文献   
95.
Recent studies show that SouthEast Indian Ocean (SEIO) SSTs are a highly significant precursor of transitions of the whole monsoon-El Niño-Southern Oscillation (ENSO) system during recent decades. However, the reasons for this specific interannual variability have not yet been identified unequivocally from the observations. Among these, the possibility of SEIO SST-driven variability in the monsoon-ENSO system is investigated here by inserting positive/negative SEIO temperature anomalies in the February’s restart files of a state-of-the-art coupled General Circulation Model (GCM) for 49 years of a control simulation. For each year of the control simulation, the model was then integrated for a 1-year period in fully coupled mode. These experiments show that Indian Summer Monsoon (ISM) and tropical Indian Ocean Dipole Mode (IODM) events are significantly influenced by the SEIO temperature perturbations inserted in the mixed layer of the coupled GCM several months before. A warm SEIO perturbation, inserted in late boreal winter, slowly propagates northward during the following seasons, implies enhanced ISM rainfall and finally triggers a negative IODM pattern during boreal fall in agreement with observations. A reversed evolution is simulated for a cold SEIO perturbation. It is shown that the life cycle of the simulated SEIO signal is driven by the positive wind-evaporation-SST, coastal upwelling and wind-thermocline-SST feedbacks. Further diagnosis of the sensitivity experiments suggests that stronger ISM and IODM variabilities are generated by excluding the El Niño years of the control simulation or when the initial background state in the SEIO is warmer. This finding confirms that IODM events may be triggered by multiple factors, other than ENSO, including subtropical SEIO SST anomalies. However, the ENSO mode does not react significantly to the SEIO temperature perturbation in the perturbed runs even though the simulated Pacific pattern agrees with the observations during boreal fall. These discrepancies with the observations may be linked to model biases in the Pacific and to the too strong ENSO simulated by this coupled GCM. These modeling evidences confirm that subtropical Indian Ocean SST anomalies generated by Mascarene high pulses during austral summer are a significant precursor of both ISM and IODM events occuring several months later.  相似文献   
96.
We have hindcast the wind and wave conditions in the Mediterranean Sea for two one month periods. Four different meteorological models and three different wave models have been used. The results have been compared with satellite and buoy wind and wave observations.Several conclusions concerning both the instruments and the models have been derived. The quality of both wind and wave results has been assessed. Close to the coasts high resolution, nested wave models are required for sufficient reliability.A wave threshold analysis suggests a sufficient reliability only off the coast, with a substantial decrease for low wave heights.  相似文献   
97.
The mid-term safety of deep geological nuclear waste repositories is based in part on the presence of a buffer, the main role of which is to isolate the environment from radionuclides. A design evaluation of such a repository is necessary to assess the potential vertical canister movement inside the drift that could reduce the buffer efficiency. A thermo-hydro-mechanical (THM) simulation is performed in a vertical cross-section of the drift. The THM couplings are described, and their influences on the mid-term (300 years) response of the engineered barrier system (EBS) are revealed. This study uses an advanced constitutive model to simulate the THM processes that occur in a specific EBS design case. The near-field simulations of the nuclear waste canister are performed in a two-dimensional finite element configuration that considers the effect of gravity. The focus of this study is on the mechanical behaviour of the buffer, which consists of two different forms of bentonite. Such an approach allows realistic consideration of the effect of the wetting and drying of the buffer material in non-isothermal conditions. Due to a specific design that includes bentonite blocks and pellets, the canister is observed to heave slightly during the re-saturation period, which extends up to 100 years.  相似文献   
98.
Accelerometric data from the well-studied valley EUROSEISTEST are used to investigate ground motion uncertainty and variability. We define a simple local ground motion prediction equation (GMPE) and investigate changes in standard deviation (σ) and its components, the between-event variability (τ) and within-event variability (φ). Improving seismological metadata significantly reduces τ (30–50%), which in turn reduces the total σ. Improving site information reduces the systematic site-to-site variability, φ S2S (20–30%), in turn reducing φ, and ultimately, σ. Our values of standard deviations are lower than global values from literature, and closer to path-specific than site-specific values. However, our data have insufficient azimuthal coverage for single-path analysis. Certain stations have higher ground-motion variability, possibly due to topography, basin edge or downgoing wave effects. Sensitivity checks show that 3 recordings per event is a sufficient data selection criterion, however, one of the dataset’s advantages is the large number of recordings per station (9–90) that yields good site term estimates. We examine uncertainty components binning our data with magnitude from 0.01 to 2 s; at smaller magnitudes, τ decreases and φ SS increases, possibly due to κ and source-site trade-offs Finally, we investigate the alternative approach of computing φ SS using existing GMPEs instead of creating an ad hoc local GMPE. This is important where data are insufficient to create one, or when site-specific PSHA is performed. We show that global GMPEs may still capture φ SS , provided that: (1) the magnitude scaling errors are accommodated by the event terms; (2) there are no distance scaling errors (use of a regionally applicable model). Site terms (φ S2S ) computed by different global GMPEs (using different site-proxies) vary significantly, especially for hard-rock sites. This indicates that GMPEs may be poorly constrained where they are sometimes most needed, i.e., for hard rock.  相似文献   
99.
Altimetry missions such as Topex/Poseidon, Jason-1, GFO and ENVISAT have been widely used in the continental domain over lakes, rivers and wetland although they were mostly dedicated to oceanic studies. Knowledge of the instrumental biases is a key issue. Numerous sites have been dedicated to calibration purposes, either in the oceanic domain (Harvest offshore platform in California, Corsica, Bass Strait in Australia) or over lakes (Lake Erie in United States). A new site (Lake Issykkul in Kirghizstan) is proposed for calibration in the continental domain. This lake is covered by past (T/P) and current radar altimetry satellites (Jason-1, T/P, GFO, and ENVISAT). Several in situ water levels and local meteorological variables are available at the site. Located in a mountainous area, it offers an opportunity for calibration far away from all other existing sites and very different environment contexts. Two GPS campaigns have been conducted on the lake in 2004 and in 2005. They consisted of cruises with stations installed onboard a boat following the satellite ground tracks, and onshore settings. This enabled estimating a bias for each altimeter and each tracking algorithm available. Biases obtained for Envisat, GFO, T/P and Jason-1 using the default ocean tracker (respectively, 48.1 ± 6.6, 7.5 ± 4.0, 0 ± 4.3 and 7.0 ± 5.5 cm) agree with biases published at the other calibration sites. For Jason-1, there is a significant disagreement with results obtained in the ocean field (7 cm instead of 13 cm) but is coherent with bias obtained on the Lake Erie site. Erroneous estimates of the sea state bias correction from non-oceanic-like waveforms is discussed as a possible explanation. Errors in the ionospheric, wet and dry tropospheric corrections for the continental domain are also highlighted and quantified.  相似文献   
100.
The mechanical efficiency of the biocementation process is directly related to the microstructural properties of the biocemented sand, such as the volume fraction of calcite, its distribution within the pore space, coordination number, contact surface area, and types of contact. In the present work, some of these microscopic properties are computed, from 3D images obtained by X-ray tomography of biocemented sand. These properties are then used as an input in current analytical models to estimate the elastic properties (Young and shear moduli) and the strength properties (Coulomb cohesion). For the elastic properties, the analytical estimates (contact cement theory model) are compared with classical bounds, self-consistent estimate and numerical results obtained by direct computation (FEM computation) on the same 3D images. Concerning the cohesion, an analytical model initially developed to estimate the cohesion due to suction in unsaturated soils is modified to evaluate the macroscopic cohesion of biocemented sands. Such analytical model is calibrated on experimental data obtained from triaxial tests performed on the same biocemented sand. In overall, the presented results point out the important role of some microstructural parameters, notably those related to the contact, on such effective parameters.  相似文献   
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