Geochemical Characteristics and Genetic Significance of Datangpo‐Type Manganese Ore Deposits during the Cryogenian Period     

Jiafei Xiao  Jingyang He  Haiying Yang  Chengquan Wu  Jianbin Xu  Yantao Li 《Resource Geology》2019,69(3):227-248

The Datangpo‐type manganese ore deposits, which formed during the Nanhuan (Cryogenian) period and are located in northeastern Guizhou and adjacent areas, are one of the most important manganese resources in China, showing good prospecting potential. Many middle‐to‐large deposits, and even super‐large mineral deposits, have been discovered. However, the genesis of manganese ore deposits is still controversial and remains a long‐standing source of debate; there are several viewpoints including biogenesis, hydrothermal sedimentation, gravity flows, cold‐spring carbonates, etc. Geochemical data from several manganese ore deposits show that there are positive correlations between Al₂O₃ and TiO₂, SiO₂, K₂O, and Na₂O, and strong negative correlations between Al₂O₃ and CaO, MgO, and MnO in black shales and manganese ores. U, Mo, and V show distinct enrichment in black shales and inconspicuous enrichment in Mn ores. Ba and Rb show strong positive correlations with K₂O in manganese ores. Cu, Ni, and Zn show clear correlations with total iron in both manganese ores and black shales. ∑REE of manganese ores has a large range with evident positive Ce anomalies and positive Eu anomalies. The Post Archean Australian Shale (PAAS) normalized rare earth element (REE) distribution patterns of manganese ores present pronounced middle rare earth element (MREE) enrichment, producing “hat‐shaped” REE plots. ∑REE of black shales is more variable compared with PAAS, and the PAAS‐normalized REE distribution patterns appear as “flat‐shaped” REE plots, lacking evident anomaly characteristics. δ¹³C values of carbonate in both manganese ores and the black shales show observable negative excursions. The comprehensive analysis suggests that the black shales formed in a reducing and quiet water column, while the manganese ores formed in oxic muddy seawater, which resulted from periodic transgressions. There was an oxidation–reduction cycle of manganese between the top water body and the bottom water body caused by the transgressions during the early Datangpo, which resulted in the dissolution of manganese. Through the exchange of the euphotic zone water and the bottom water, and episodic inflow of oxygenated water, the manganese in the bottom water was oxidized to Mn‐oxyhydroxides and rapidly buried along with algae. In the early diagenetic stage, Mn‐oxyhydroxides were reduced and dissolved in the anoxic pore water and then transformed into Mn‐carbonates by reacting with HCO₃^? from the degradation of organic matter or from seawater. In the intervals between transgressions, continuous supplies of terrigenous clastics and the high productive rates of organic matter in the euphotic zone resulted in the deposition of the black shales enriched in organic matter.  相似文献   

鄂尔多斯盆地渭北地区上三叠统延长组长7油层组碳酸盐结核中自生碳酸盐矿物的特征          下载免费PDF全文

李云  胡作维  刘灿  董杰  贺静  袁效奇  魏杨 《古地理学报》2019,21(4):577-588

早期形成的碳酸盐结核在埋藏期间会经历多种碳酸盐矿物相沉淀的复杂胶结作用,岩石学研究是探究结核成因的关键。通过野外剖面观察、岩石学观察和阴极发光技术,分析了鄂尔多斯盆地渭北地区上三叠统延长组长7油层组泥页岩中各种形状的方解石和白云石结核中自生碳酸盐矿物的特征。这些结核为成岩早期的产物,构成结核的自生碳酸盐矿物特征显著:(1)球粒方解石结核中,方解石呈纤维状或刃片状,球粒间充填晶粒方解石或因压实呈贴面结合,纤维状方解石发桔红色和暗红色2种光,刃片状方解石发暗红色光;(2)粉晶方解石结核中,方解石呈他形粒状,含有机质包裹体或纤维状晶形残余,晶间含沥青和纤维状方解石残余,主要发暗红色光;(3)白云石结核有泥晶和粉晶2种晶体类型,粉晶白云石结核含较多泥质,泥质条带或有机质条带处常见纤柱状白云石;(4)沿裂缝充填的方解石和白云石常呈纤维状或纤柱状结构,发暗红色光或不发光。研究区长7油层组碳酸盐结核中的方解石和白云石具有不同的成因类型和复杂的胶结作用:球粒方解石和泥晶白云石代表了结核开始形成时的胶结作用,可以准确地反映结核的成因;粉晶方解石、粉晶白云石反映了交代成因;裂缝中纤维状、纤柱状方解石和白云石集合体则为结核经历了较强压实作用之后充填裂缝而成。  相似文献   

南海边缘海多金属结核与大洋多金属结核对比     

殷征欣  王海峰  韩金生  吕修亚  沈泽中  陈静  贺惠忠  谢安远  关瑶  董超 《吉林大学学报(地球科学版)》2019,49(1):261-277

本文通过系统对比分析前人研究成果,研究了南海边缘海多金属结核的成矿特征,结果表明：南海边缘海结核的矿物组成与大洋结核相似,均主要由锰相矿物和铁相矿物组成,其中锰相矿物主要为水羟锰矿和钡镁锰矿,铁相矿物主要以无定型铁氧化/氢氧化物形式存在,另外南海边缘海结核中含有大量硅酸盐矿物,表明在南海结核成矿过程中受到大量的陆源碎屑矿物混杂;相对于大洋主要经济成矿区的多金属结核,南海边缘海多金属结核中主要的经济元素如Mn、Cu、Co、Ni和Zn质量分数较低,而亲陆源性元素如Fe、Ti、P、Nb、Pb、Rb、Sc、Ta、Sr、Th和REY（REE和Y）等质量分数较高;南海边缘海多金属结核的元素地球化学特征和REE配分模式显示其为水成成因,并呈现更低的Mn/Fe值;同时南海边缘海结核也具有较快的平均生长速率及较高的δCe正异常,表明其生长在更为氧化的海水环境。虽然较快的沉积物沉积速率和动荡的海水环境影响了南海边缘海结核的成矿,但大量陆源物质进入海洋也为南海边缘海结核提供了丰富的成矿物质来源,便于南海边缘海结核的快速生长成矿。南海边缘海结核富集有Fe、Ti、Pb、Rb、Th和REY等金属元素,同样可以作为极具潜力的海洋矿产资源。南海边缘海多金属结核具有其独特的地球化学特征,与大洋多金属结核存在着明显差异。  相似文献   

龙门山断层破裂的频率非平稳特性     

李启成  郭雷  何书耕  齐庆杰 《吉林大学学报(地球科学版)》2019,49(3):865-871

为研究地震过程中的频率非平稳特性,对近年来龙门山断层发生的两次大地震:汶川大地震和芦山大地震的近断层地震记录进行频谱分析。结果表明:相对于芦山地震有较大走向滑动分量的汶川地震,大多数位于汶川地震断层滑动前方的台站接收到更高的频率成分,位于断层滑动后方的台站接收到的地震波频率较低;尽管芦山地震断层相对汶川地震有较小的走向滑动分量,但仍然可以得出与汶川地震相同的结论,不同的是虽然芦山地震沿断层面向上方向分量大,但是其同一台站东西、南北、竖直三方向分量记录幅值相当。把芦山地震三分量记录变换到走向和沿断层面向上方向,证实了沿断层面向上方向高频成分更丰富。在断层滑动前方接收到的地震波频率较高,在断层滑动后方接收到的频率较低,这正是多普勒效应影响的结果。由于多普勒效应的客观存在,其对频率非平稳特性的影响与震源、传播路径和场地效应一样具有普遍性;所以,工程场地接收到的地震波的频率不仅取决于震源、传播路径、场地效应,还取决于断层滑动速度(多普勒效应)。  相似文献   

溶液和温度作用下膨润土防水毯的渗透性能     

何俊  王小琦  颜兴  万娟  朱志政 《吉林大学学报(地球科学版)》2019,49(3):807-816

以颗粒状和粉末状膨润土防水毯(GCLs)为对象,运用GDS (global digital systems)全自动渗透仪开展渗透试验,研究CaCl_2溶液作用下GCLs渗透性能的温度效应,初步探讨其机理。试验表明:当水化液为0.05mol/L的CaCl_2溶液时,两种GCLs渗透系数随温度升高呈现增大趋势;当水化液为去离子水时,颗粒状GCL渗透系数随温度升高而减小,粉末状GCL渗透系数随温度升高而增大。去离子水情况下,膨润土吸附结合水量随温度升高而减小;CaCl_2溶液作用下,吸附结合水量较去离子水情况大幅降低。当CaCl_2溶液浓度一定时,膨润土膨胀指数随温度升高而略有增大;当温度一定时,膨润土膨胀指数随CaCl_2溶液浓度升高而显著减小。以去离子水进行试验时:颗粒状和粉末状GCLs渗透系数随温度的变化主要影响因素为凝胶态蒙脱石数量,其次为流体黏滞系数和吸附结合水量;颗粒状GCLs膨润土孔隙结构越不均匀,凝胶态蒙脱石数量的影响就越显著,导致渗透系数随温度升高而减小、固有渗透率随温度升高显著降低。以CaCl_2溶液进行试验时,两种GCLs渗透系数随温度变化的主要受流体黏滞系数和吸附结合水量的影响,而受凝胶态蒙脱石数量的影响较小。孔隙溶液性质、温度和膨润土类型均对GCLs的防渗性能具有重要影响。  相似文献   

平庄盆地六家立井地区找铀目标层岩石学特征及其找矿意义     

殷榕蔚  霍超  吕永华  赵岳  赵明  张恒利  贺军 《中国煤炭地质》2019,(3):39-44

六家立井地区位于平庄盆地北缘,白垩系下统阜新组上段是该区砂岩型铀矿床目标层位,具有较好找铀前景。为深入了解该区砂体的岩石学特征,通过野外钻探工作、岩心编录、样品采集及岩矿测试方法,详细研究了目标层碎屑岩类型、碎屑岩成分、结构构造等岩石学方面特征。结果表明目标层碎屑岩成分成熟度和结构成熟度均较低,具有搬运距离短、沉积速度快的特点,其物源较单一,初步判断物源来自盆地东北部和西北部隆起带酸性花岗岩,同时也为铀成矿提供了良好的铀源。  相似文献   

矿山环境治理过程中资金运作模式探索与实践     

田招龙  张雄邦  陈仕涛  何钰 《中国煤炭地质》2019,(2):77-81

矿山环境治理恢复基金制度之所以取代矿山地质环境治理恢复保证金制度,目的之一是通过基金的合理运营,为矿山环境治理提供长效稳定的资金保障。通过对矿山地质环境治理恢复保证金制度中的资金问题进行剖析,从基金来源、基金运营、基金投入三个方面提出矿山环境治理过程中新的商业运作模式,并从市场化角度对社会资本进入矿山复绿和综合利用进行了探索,以期对矿山环境治理恢复基金制度的建立提供一定的指导和参考。  相似文献   

胜利东二号露天矿6煤层直接液化性能评价     

韩晓宙  霍超  赵岳  张建强  张恒利  贺军 《中国煤炭地质》2019,(3):19-22

基于褐煤直接液化特性与煤性质的关系,从煤岩组分和煤质基本性质出发,结合前人对与褐煤直接液化相关的煤岩组分和煤质指标研究成果,通过采样测试与收集数据,探讨了胜利煤田东二号露天矿6煤层煤岩组分、灰分、挥发分、H/C原子比对其直接液化的影响,提出了褐煤作为直接液化的指标要求范围。结果表明:该煤层活性组分(腐植组和稳定组)含量较高,挥发分含量大于35%、H/C原子大部分大于0. 70、浮煤灰分大部分小于10%,符合液化指标要求,可作为较理想的直接液化原料煤。  相似文献   

Paleoproterozoic volcanic rocks in the southern margin of the North China Craton,central China:Implications for the Columbia supercontinent   总被引：1，自引：0，他引：1  

Changming Wang  Xinyu He  Emmanuel John M.Carranza  Chengmin Cui 《地学前缘(英文版)》2019,10(4):1543-1560

The volcanic rocks of the Xiong'er Group are situated in the southern margin of the North China Craton(NCC).Research on the Xiong er Group is important to understand the tectonic evolution of the NCC and the Columbia supercontinent during the Paleoproterozoic.In this study,to constrain the age of the Xiong'er volcanic rocks and identify its tectonic environment,we report zircon LA-ICP-MS data with Hf isotope,whole-rock major and trace element compositions and Sr-Nd-Pb-Hf isotopes of the volcanic rocks of the Xiong'er Group.The Xiong'er volcanic rocks mainly consist of basaltic andesite,andesite.dacite and rhyolite,with minor basalt.Our new sets of data combined with those from previous studies indicate that Xiong'er volcanism should have lasted from 1827 Ma to 1746 Ma as the major phase of the volcanism.These volcanics have extremely low MgO.Cr and Ni contents,are enriched in LREEs and LILEs but depleted in HFSEs(Nb,Ta,and Ti),similar to arc-related volcanic rocks.They are characterized by negative zircon ε_(Hf)_(t) values of-17.4 to 8.8,whole-rock initial ~(87)Sr/~(86)Sr values of 0.7023 to 0.7177 andε_(Nd)(t) values of-10.9 to 6.4.and Pb isotopes(~(206)Pb/~(204)Pb =14.366-16.431,~(207)Pb/~(204)Pb =15.106-15.371,~(208)Pb/~(204)Pb= 32.455-37.422).The available elemental and Sr-Nd-Pb-Hf isotope data suggest that the Xiong'er volcanic rocks were sourced from a mantle contaminated by continental crust.The volcanic rocks of the Xiong'er Group might have been generated by high-degree partial melting of a lithospheric mantle that was originally modified by oceanic subduction in the Archean.Thus,we suggest that the subduction-modified lithospheric mantle occurred in an extensional setting during the breakup of the Columbia supercontinent in the Late Paleoproterozoic,rather than in an arc setting.  相似文献   

Seasonal variation of airborne fungi of the Tiantishan Grottoes and Western Xia Museum,Wuwei, China     

YuLong Duan  FaSi Wu  DongPeng He  RuiHong Xu  HuYuan Feng  Tuo Chen  GuangXiu Liu  WanFu Wang 《寒旱区科学》2021,13(6):522-532

In this study, a systematic survey of cultural airborne fungi was carried out in the occurrence environments of wall paintings that are preserved in the Tiantishan Grottoes and the Western Xia Museum, China. A bio-aerosol sampler was used for sampling in four seasons in 2016. Culture-dependent and -independent methods were taken to acquire airborne fungal concentration and purified strains; by the extraction of genomic DNA, amplification of fungal ITS rRNA gene region, sequencing, and phylogenetic analysis, thereafter the fungal community composition and distribution characteristics of different study sites were clarified. We disclosure the main environmental factors which may be responsible for dynamic changes of airborne fungi at the sampling sites. The concentration of cultural airborne fungi was in a range from 13 to 1,576 CFU/m³, no significant difference between the two sites at the Tiantishan Grottoes, with obvious characteristics of seasonal variation, in winter and spring were higher than in summer and autumn. Also, there was a significant difference in fungal concentration between the inside and outside of the Western Xia Museum, the outside of the museum was far more than the inside of the museum in the four seasons, particularly in the winter. Eight fungal genera were detected, including Cladosporium, Penicillium, Alternaria, and Filobasidium as the dominant groups. The airborne fungal community structures of the Tiantishan Grottoes show a distinct characteristic of seasonal variation and spatial distribution. Relative humidity, temperature and seasonal rainfall influence airborne fungal distribution. Some of the isolated strains have the potential to cause biodeterioration of ancient wall paintings. This study provides supporting information for the pre-warning conservation of cultural relics that are preserved at local sites and inside museums.  相似文献