The distribution of carbon monoxide in the lower atmosphere of Venus     

Daniel V. Cotton  Jeremy Bailey  D. Crisp  V.S. Meadows 《Icarus》2012,217(2):570-584

We have obtained spatially resolved near-infrared spectroscopy of the Venus nightside on 15 nights over three observing seasons. We use the depth of the CO absorption band at 2.3 μm to map the two-dimensional distribution of CO across both hemispheres. Radiative transfer models are used to relate the measured CO band depth to the volume mixing ratio of CO. The results confirm previous investigations in showing a general trend of increased CO abundances at around 60° latitude north and south as compared with the equatorial regions. Observations taken over a few nights generally show very similar CO distributions, but significant changes are apparent over longer periods. In past studies it has been assumed that the CO latitudinal variation occurs near 35 km altitude, at which K-band sensitivity to CO is greatest. By modeling the detailed spectrum of the excess CO at high latitudes we show that it occurs at altitudes around 45 km, much higher than has previously been assumed, and that there cannot be significant contribution from levels of 36 km or lower. We suggest that this is most likely due to downwelling of CO-rich gas from the upper atmosphere at these latitudes, with the CO being removed by around 40 km through chemical processes such as the reaction with SO₃.  相似文献   

Extending the Capture Map Concept to Estimate Discrete and Risk-Based Streamflow Depletion Potential     

Jeremy T. White  Linzy K. Foster  Michael N. Fienen 《Ground water》2021,59(4):571-580

A popular and contemporary use of numerical groundwater models is to estimate the discrete relation between groundwater extraction and surface-water/groundwater exchange. Previously, the concept of a “capture map” has been put forward as a means to effectively summarize this relation for decision-making consumption. While capture maps have enjoyed success in the environmental simulation industry, they are deterministic, ignoring uncertainty in the underlying model. Furthermore, capture maps are not typically calculated in a manner that facilitates analysis of varying combinations of extraction locations and/or reaches. That is, they are typically constructed with focus on a single reach or group of reaches. The former of these limitations is important for conveying risk to decision makers and stakeholders, while the latter is important for decision-making support related to surface-water management, where future foci may include reaches that were not the focus of the original capture analysis. Herein, we use the concept of a response matrix to generalize the theory of the capture-map approach to estimate spatially discrete streamflow depletion potential. We also use first-order, second-moment uncertainty estimation techniques with the concept of “risk shifting” to place capture maps and streamflow depletion potential in a stochastic, risk-based framework. Our approach is demonstrated for an integrated groundwater/surface-water model of the lower San Antonio River, Texas, USA.  相似文献   

Burial and exhumation of the Hoh Xil Basin,northern Tibetan Plateau: Constraints from detrital (U-Th)/He ages     

Jin-Gen Dai  Matthew Fox  David L. Shuster  Jeremy Hourigan  Xu Han  Ya-Lin Li  Cheng-Shan Wang 《Basin Research》2020,32(5):894-915

The uplift and associated exhumation of the Tibetan Plateau has been widely considered a key control of Cenozoic global cooling. The south-central parts of this plateau experienced rapid exhumation during the Cretaceous–Palaeocene periods. When and how the northern part was exhumed, however, remains controversial. The Hoh Xil Basin (HXB) is the largest late Cretaceous–Cenozoic sedimentary basin in the northern part, and it preserves the archives of the exhumation history. We present detrital apatite and zircon (U-Th)/He data from late Cretaceous–Cenozoic sedimentary rocks of the western and eastern HXB. These data, combined with regional geological constraints and interpreted with inverse and forward model of sediment deposition and burial reheating, suggest that the occurrence of ca. 4–2.7 km and ca. 4–2.3 km of vertical exhumation initiated at ca. 30–25 Ma and 40–35 Ma in the eastern and western HXB respectively. The initial differential exhumation of the eastern HXB and the western HXB might be controlled by the oblique subduction of the Qaidam block beneath the HXB. The initial exhumation timing in the northern Tibetan Plateau is younger than that in the south-central parts. This reveals an episodic exhumation of the Tibetan Plateau compared to models of synchronous Miocene exhumation of the entire plateau and the early Eocene exhumation of the northern Tibetan Plateau shortly after the India–Asia collision. One possible mechanism to account for outward growth is crustal shortening. A simple model of uplift and exhumation would predict a maximum of 0.8 km of surface uplift after upper crustal shortening during 30–27 Ma, which is insufficient to explain the high elevations currently observed. One way to increase elevation without changing exhumation rates and to decouple uplift from upper crustal shortening is through the combined effects of continental subduction, mantle lithosphere removal and magmatic inflation.  相似文献   

Constraining basin thermal history and petroleum generation using palaeoclimate data in the Piceance Basin,Colorado          下载免费PDF全文

Yao Tong  Daniel E. Ibarra  Jeremy K. Caves  Tapan Mukerji  Stephan A. Graham 《Basin Research》2017,29(4):542-553

Careful assessment of basin thermal history is critical to modelling petroleum generation in sedimentary basins. In this paper, we propose a novel approach to constraining basin thermal history using palaeoclimate temperature reconstructions and study its impact on estimating source rock maturation and hydrocarbon generation in a terrestrial sedimentary basin. We compile mean annual temperature (MAT) estimates from macroflora assemblage data to capture past surface temperature variation for the Piceance Basin, a high‐elevation, intermontane, sedimentary basin in Colorado, USA. We use macroflora assemblage data to constrain the temporal evolution of the upper thermal boundary condition and to capture the temperature change with basin uplift. We compare these results with the case where the upper thermal boundary condition is based solely upon a simplified latitudinal temperature estimate with no elevation effect. For illustrative purposes, 2 one‐dimensional (1‐D) basin models are constructed using these two different upper thermal boundary condition scenarios and additional geological and geochemical input data in order to investigate the impact of the upper thermal boundary condition on petroleum source rock maturation and kerogen transformation processes. The basin model predictions indicate that the source rock maturation is very sensitive to the upper thermal boundary condition for terrestrial basins with variable elevation histories. The models show substantial differences in source rock maturation histories and kerogen transformation ratio over geologic time. Vitrinite reflectance decreases by 0.21%Ro, source rock transformation ratio decreases 10.5% and hydrocarbon mass generation decreases by 16% using the macroflora assemblage data. In addition, we find that by using the macroflora assemblage data, the modelled depth profiles of vitrinite reflectance better matches present‐day measurements. These differences demonstrate the importance of constraining thermal boundary conditions, which can be addressed by palaeotemperature reconstructions from palaeoclimate and palaeo‐elevation data for many terrestrial basins. Although the palaeotemperature reconstruction compiled for this study is region specific, the approach presented here is generally applicable for other terrestrial basin settings, particularly basins which have undergone substantial subaerial elevation change over time.  相似文献   

Decadal Changes in Water Quality and Net Productivity of a Shallow Danish Estuary Following Significant Nutrient Reductions     

Peter A. Staehr  Jeremy Testa  Jacob Carstensen 《Estuaries and Coasts》2017,40(1):63-79

We utilized an extensive data set (1977–2013) from a water quality monitoring program to investigate the recovery of a Danish estuary following large reductions in total phosphorus (TP) and total nitrogen (TN) loading. Monthly rates of net transport and biogeochemical transformation of dissolved inorganic nitrogen (DIN) and phosphorus (DIP) were computed in two basins of the estuary using a box model approach, and oxygen-based rates of net ecosystem production (NEP) were determined. Since 1990, nutrient loading was reduced by 58 % for nitrogen and 80 % for phosphorus, causing significant decreases in DIN (60 %) and DIP (85 %) concentrations. Reductions in nutrient loadings and concentrations reduced annual chlorophyll levels by 50 % in the inner estuary and improved Secchi depth by approximately 1 m during the same period, particularly in the summer period. In the outer, deeper region of the estuary trends in water quality was less evident. Improvements in the inner estuary were strongly coupled to declines in DIN. Thresholds of DIN and DIP concentrations limiting phytoplankton growth indicated that both regions of the estuary were nitrogen limited. NEP rates indicated the development of more net autotrophic conditions over time that were likely associated with higher benthic primary production stimulated by improved light conditions. Box model computations revealed a modest reduction in summer net production of DIP over time, despite the persistence of elevated fluxes for several years after external loads were reduced. Since the mid-1990s, nutrient loading and transformation were stable while nutrient concentrations continued to decline and water quality improved in the inner estuary. The oligotrophication trajectory involved an initial fast transformation and modest retention of nutrients followed by a gradual decline in the rate of improvement towards a new stable condition.  相似文献   

A service-based framework for the OAIS model for earth science data management     

Edward Flathers  Jeremy Kenyon  Paul E Gessler 《Earth Science Informatics》2017,10(3):383-393

The Consultative Committee for Space Data Systems (CCSDS), in 2002, released their first version of a Reference Model for an Open Archival Information System (OAIS). In 2003, the model was adopted by the International Standards Organization (ISO) as ISO 14721:2003. The CCSDS document was updated in 2012 with additional focus on verifying the authenticity of data and developing concepts of access rights and a security model. The OAIS model is the basis of research data management systems across institutions and disciplines around the world. The Organization for the Advancement of Structured Information Standards (OASIS), in 2006, released their first version of a Reference Model for Service Oriented Architecture (SOA). OASIS defines the SOA as “a paradigm for organizing and utilizing distributed capabilities that may be under the control of different ownership domains.” Systems designed around the SOA model benefit from improved scalability, flexibility, and agility. This paper applies the SOA model to the OAIS repository to describe how repositories can be implemented and extended through the use of services that may be internal or external to the host institution, including the consumption of network- or cloud-based services and resources. We use the Service Oriented Architecture (SOA) design paradigm to describe a set of potential extensions to OAIS Reference Model: purpose and justification for each extension, where and how each extension connects to the model, and an example of a specific service that meets the purpose.  相似文献   

Seismic and Petrophysical Relationships from UK Continental Shelf Rocks at Elevated Pressures     

Solomon Assefa  Clive Mc Cann  Jeremy Sothcott 《Marine Georesources & Geotechnology》2013,31(2):119-140

Abstract

There are few published seismic (P- and S-waves) properties for seafloor bedrocks. At low pressures (1 to 10 MPa), velocities and attenuations are determined mainly by open microcracks. At higher pressures, the microcracks close, and the velocities and attenuations depend primarily on the matrix porosity. We have investigated both the relationships between the acoustic, petrophysical, and geological properties of the rocks at 40 MPa pressure and the effect of microcracks on the acoustic properties at 10 MPa pressure. In this paper we discuss the former; the latter will be discussed separately.

P- and S-wave velocity and attenuation measurements were carried out on a suite of seabed sedimentary and igneous rocks at effective pressures from 10 to 40 MPa at ultrasonic frequencies. The porosities and permeabilities of the rocks ranged from 0% to 32% and 0 to 110 mDarcy, respectively. Characterization of the rocks revealed that most of the sandstones have a substantial clay content (kaolinite, illite, and chlorite) and fractures. Most of the igneous rocks are chloritized.

The seismic properties of the rocks are markedly lower than those of similar continental rocks because of the microporosity formed by the alteration of feldspars, micas, and mafic minerals to clays (e.g., chloritization of pyroxenes) and the corresponding reduction of the elastic moduli. The results of this study suggest that the values of velocities and quality factors used for ocean acoustic propagation models are lower than normally assumed.  相似文献   

Copper in the sediment and sea surface microlayer near a fallowed, open-net fish farm     

Loucks RH  Smith RE  Fisher CV  Brian Fisher E 《Marine pollution bulletin》2012,64(9):1970-1973

Sediment and sea surface microlayer samples near an open-net salmon farm in Nova Scotia, were analysed for copper. Copper is a constituent of the feed and is an active ingredient of anti-foulants. The salmon farm was placed in fallow after 15years of production. Sampling was pursued over 27months. Elevated copper concentrations in the sediments indicated the farm site as a source. Bubble flotation due to gas-emitting sediments from eutrophication is a likely process for accumulating copper in the sea surface microlayer at enriched concentrations. Elevated and enriched concentrations in the sea surface microlayer over distance from the farm site led, as a result of wind-drift, to an enlarged farm footprint. The levels of copper in both sediments and sea surface microlayer exceeded guidelines for protection of marine life. Over the 27months period, copper levels persisted in the sediments and decreased gradually in the sea surface microlayer.  相似文献   

Adoption of the arctic search and rescue agreement: A shift of the arctic regime toward a hard law basis?     

Shih-Ming Kao Nathaniel S. Pearre  Jeremy Firestone 《Marine Policy》2012,36(3):832-838

This paper examines the Arctic Search and Rescue Agreement—the first legally-binding instrument negotiated and adopted under the auspices of the Arctic Council—and analyzes its implications for the current Arctic regime. Led by the Arctic Council, the Arctic regime was established in a soft law format. However, the soft law nature and restricted mandates of the Arctic Council have limited its capacity to respond to new issues emerging from climate change, particularly those related to the exploitation of oil and gas reserves, commercial shipping through the region, effects on wildlife, and impacts on indigenous peoples' homelands and culture. The adoption of the Agreement represents a new approach for the Arctic States to respond to these new challenges. At the same time, it does not imply that a legally-binding instrument is necessarily preferable for every issue, and importantly, the new Arctic Agreement does not establish new institutional relationships, suggesting satisfaction among the Arctic States with the existing arrangements. Thus, although the Arctic regime is undoubtedly changing, this change should not be treated today as a shift from soft to hard law. What is more certain is that the Arctic Council will continue to function as a cooperative forum where the Arctic States can address these challenges, and its importance will only increase in coming years.  相似文献   

First steps towards a quota allocation system in the Indian Ocean     

Jeremy Noye  Kwame Mfodwo 《Marine Policy》2012,36(4):882-894

In response to recommendations made by a recent performance review, the Indian Ocean Tuna Commission (IOTC) is attempting to develop a quota allocation system (QAS) for management of the tuna and tuna-like species of the Indian Ocean. As “first-movers” in the process, Indonesia, the Seychelles, the European Union, Iran, and the Republic of Korea made contrasting proposals to the IOTC in March 2011 on possible QAS form and structure. Structure (the factors to be taken into account in determining allocation) is critical as it will determine on a long term basis the share accruing to each IOTC member state of the estimated USD 2-3 billion worth of tuna caught in the Indian Ocean each year. This article records and discusses the content of these first steps towards QAS formulation by placing them in the context of rights-based management as applied to the offshore areas falling under tuna RFMO management. The options proposed in March (which the IOTC is still considering) all have a similar architecture but result in sharply divergent allocation outcomes. Despite the sophistication of some of the proposals, the recent IOTC review suggests that the regulatory and management capacity of the IOTC does not match the science and enforcement requirements appropriate to these recent proposals. Perhaps efforts to improve IOTC performance need to be made in parallel with discussions on QAS definition and implementation. To further advance the debate and also concretely demonstrate likely economic outcomes, the article provides indicative monetary valuations of quota allocations proposed. It uses a range of potential historical reference periods (5, 10, 15, and 20 years).  相似文献