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981.
How rock is weathered physically and chemically into transportable material is a fundamental question in critical‐zone science. In addition, the distribution of weathered material (soil and intact regolith) across upland landscapes exerts a first‐order control on the hydrology of watersheds. In this paper we present the results of six shallow seismic‐refraction surveys in the Redondo Mountain region of the Valles Caldera, New Mexico. The P‐wave velocities corresponding to soil (≤ 0.6 km s?1) were inferred from a seventh seismic survey where soil‐thickness data were determined by pit excavation. Using multivariable regression, we quantified the relationships among slope gradient, aspect, and topographic wetness index (TWI) on soil and regolith (soil plus intact regolith) thicknesses. Our results show that both soil and regolith thicknesses vary inversely with TWI in all six survey areas while varying directly with slope aspect (i.e. thicker beneath north‐facing slopes) and inversely with slope gradient (i.e. thinner beneath steep slopes) in the majority of the survey areas. An empirical model based on power‐law relationships between regolith thickness and its correlative variables can fit our inferred thicknesses with R2 ‐values up to 0.880 for soil and 0.831 for regolith in areas with significant topographic variations. These results further demonstrate the efficacy of shallow seismic refraction for mapping and determining how soil and regolith variations correlate with topography across upland landscapes. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
982.
Biostimulation is increasingly used to accelerate microbial remediation of recalcitrant groundwater contaminants. Effective application of biostimulation requires successful emplacement of amendment in the contaminant target zone. Verification of remediation performance requires postemplacement assessment and contaminant monitoring. Sampling‐based approaches are expensive and provide low‐density spatial and temporal information. Time‐lapse electrical resistivity tomography (ERT) is an effective geophysical method for determining temporal changes in subsurface electrical conductivity. Because remedial amendments and biostimulation‐related biogeochemical processes often change subsurface electrical conductivity, ERT can complement and enhance sampling‐based approaches for assessing emplacement and monitoring biostimulation‐based remediation. Field studies demonstrating the ability of time‐lapse ERT to monitor amendment emplacement and behavior were performed during a biostimulation remediation effort conducted at the Department of Defense Reutilization and Marketing Office (DRMO) Yard, in Brandywine, Maryland, United States. Geochemical fluid sampling was used to calibrate a petrophysical relation in order to predict groundwater indicators of amendment distribution. The petrophysical relations were field validated by comparing predictions to sequestered fluid sample results, thus demonstrating the potential of electrical geophysics for quantitative assessment of amendment‐related geochemical properties. Crosshole radar zero‐offset profile and borehole geophysical logging were also performed to augment the data set and validate interpretation. In addition to delineating amendment transport in the first 10 months after emplacement, the time‐lapse ERT results show later changes in bulk electrical properties interpreted as mineral precipitation. Results support the use of more cost‐effective surface‐based ERT in conjunction with limited field sampling to improve spatial and temporal monitoring of amendment emplacement and remediation performance.  相似文献   
983.
Numerical studies of existing buildings demonstrate the effectiveness of nonlinear/inelastic rooftop tuned mass damper frames (NRTMDF) used as a retrofit for reducing seismic response. The technique utilizes a rooftop penthouse as a tuned mass damper with mass incorporated as the roof deck of the penthouse while targeted nonlinearity and energy dissipation are introduced through buckling restrained braces (BRBs) linking the penthouse mass to the structure below. The writers summarize numerical studies of ten existing buildings modified with a specifically tuned NRTMDF. The studies demonstrate the effectiveness of the technique that stems from elastic and transient inelastic period shifts enabled by the damper coupled with targeted energy dissipation in the penthouse BRBs. Numerical simulations using response nonlinear time‐history analysis techniques show that for many structures and sites, the NRTMDF decreases peak transient response and overall seismic demand of the original structure. The technique also reduces seismic demand on nonstructural elements and components, manifested as reductions in floor acceleration spectra. Energy methods show that the approach enables significant reductions in energy demand on the original structure through the complete earthquake acceleration history. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
984.
Nonaqueous phase liquid (NAPL)‐impacted lower permeability layers in heterogeneous media are difficult to fully remediate and can act as persistent sources of groundwater contamination through diffusive emissions to transmissive aquifer zones. This work investigated the benefits of partial remediation involving treatment focused near the high‐low permeability interface, with the performance metric being emissions reduction. A sequential base‐activated persulfate (S2O8 2?) delivery treatment strategy was studied in this work, involving 13–14 d deliveries of 10% w/w sodium persulfate (Na2S2O8) and 14–28 d deliveries of 19 g/L sodium hydroxide (NaOH). Treatment and control experiments were conducted in 1.2‐m wide × 1.2‐m tall × 5‐cm thick physical model tanks containing two soil layers differing in hydraulic conductivity by three orders of magnitude. The top 10 cm of the lower permeability layers contained 7400–7800 mg‐NAPL/kg‐soil; the NAPL was comprised of benzene, toluene, ethylbenzene, p‐xylene, o‐xylene, n‐propylbenzene, and 1,3,5‐trimethylbenzene (TMB) mixed in octane. Approximately 0.1 g‐Na2S2O8 was delivered per cm2‐interface area over 13–14 d. The S2O8 2? and SO4 2? concentration profiles suggest higher oxidant reaction rates when NaOH is delivered prior to, rather than after Na2S2O8. After 264 d and two treatments, hydrocarbon emissions from the NAPL source were reduced by 60% to 73% compared to a no‐treatment control tank. The incremental benefit of the second treatment was only about 10% of the effect of the first treatment.  相似文献   
985.
We exploit a natural experiment in Boulder Creek, a ~ 30 km2 drainage in the Santa Cruz mountains, CA, USA to explore how an abrupt increase in the caliber of bedload sediment along a bedrock channel influences channel morphology in an actively uplifting landscape. Boulder Creek's bedrock channel, which is entirely developed on weak sedimentary rock, has a high flow shear stress that is about 3.5 times greater where it transports coarse (~ 22 cm D50) diorite in the lower reaches in comparison with the upstream section of the creek that transports only relatively finer bedload (~2 cm D50) derived from weak sedimentary rocks. In addition, Boulder Creek's channel abruptly widens and shallows downstream and transitions from partial to nearly continuous alluvial cover where it begins transporting coarse diorite. Boulder Creek's tributary channels are also about three times steeper where they transport diorite bedload, and within the Santa Cruz mountains channels in sedimentary bedrock are systematically steeper when >50% of their catchment area is within crystalline basement rocks. Despite this clear control of coarse sediment size on channel slopes, the threshold of motion stress for bedload, alone, does not appear to control channel profile slopes here. Upper Boulder Creek, which is starved of coarse sediment, maintains high flow shear stresses well in excess of the threshold for motion. In contrast, lower Boulder Creek, with a greater coarse sediment supply, exerts high flow stresses much closer to the threshold for motion. We speculate that upper Boulder Creek has evolved to sustain partial alluvial cover and transfer greater energy to the bed via bedload impacts to compensate for its low coarse sediment supply. Thus bedload supply, bedrock erosion efficiency, and grain size all appear to influence channel slopes here. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
986.
The RadioAstron ground-space interferometer provides the highest angular resolution achieved now in astronomy. The detection of interferometric fringes from quasars with this angular resolution on baselines of 100–200 thousand km suggests the brightness temperatures which exceed the Compton limit by two orders of magnitude. Polarimetric measurements on ground-space baselines have revealed fine structure testifying to recollimation shocks on scales of 100–250 μas and a helical magnetic field near the base of radio emission in BL Lacertae. Substructure within a the scattering disk of pulsar emission on interferometer baselines (from 60000 to 250000 km) was discovered. This substructure is produced by action of the interstellar interferometer with an effective baseline of about 1 AU and the effective angular resolution of better than 1 μas. Diameters of scattering disks were measured for several pulsars, and distances to diffusing screens were evaluated. The ground-space observations of sources of the maser radiation in lines of water and hydroxyl have shown that the maser sources in star-forming regions remain unresolved on baselines, which considerably exceed the Earth diameter. These very compact and bright features with angular sizes of about 20–60 μas correspond to linear sizes of about 5–10 million km (several solar diameters).  相似文献   
987.
This paper investigates the hydrothermal fluid circulation that was linked to the extensional evolution of the Adriatic rifted margin during the Jurassic opening of the Alpine Tethys. Remnants of this rifted margin are spectacularly preserved in SE Switzerland and N Italy. Five study areas were chosen ranging from the former proximal to the most distal part of the margin. We demonstrate an intimate link between Jurassic extensional tectonics and fluid activity affecting the pre- to early post-rift sedimentary sequences. Nature, composition and origin of fluids are constrained by a multidisciplinary approach based on field observations and including geochemical (O-C, Sr, He isotopes, U-Pb datings, fluid inclusion microthermometry) and petrological methods. Several fluid-related diagenetic products and processes such as dolomitization, veining, hydraulic brecciation, and silicification can be recognized. It appears that different paleogeographic settings and different stratigraphic levels document distinct phases of fluid activity. The fluids reached temperatures of up to 150°C near paleo-seafloor. They were enriched in 18O, had high 87Sr/86Sr and low 3He/4He ratios, documenting a strong interaction between seawater and a granitic basement. Many lines of evidence point to the occurrence of over-pressured fluids and long-lasting fluid circulation due to fault-valve mechanisms and high thermal gradients. Two main stages with different fluid chemistry can be recognized: (1) a carbonate-rich stage that developed during the stretching phases and was linked to high-angle normal faulting, and (2) a silica-rich stage occurring during late rift exhumation of crustal and mantle rocks in the distal domains in the presence of detachment faults and high thermal gradients. This paper provides, for the first time, a large and robust characterization of fluid–rock interactions occurring during rifting along an almost complete section across a magma-poor rifted margin.  相似文献   
988.
Mass-transport complexes (MTCs) dominate the stratigraphic record of many salt-influenced sedimentary basins. Commonly in such settings, halokinesis is invoked as a primary trigger for MTC emplacement, although the link between specific phases of salt movement, and related minibasin dynamics, remains unclear. Here, we use high-quality 3D seismic reflection and well data to constrain the composition, geometry and distribution (in time and space) of six MTCs preserved in a salt-confined, supra-canopy minibasin in the northern Gulf of Mexico, and to assess how their emplacement relate to regional and local controls. We define three main tectono-sedimentary phases in the development of the minibasin: (a) initial minibasin subsidence and passive diapirism, during which time deposition was dominated by relatively large-volume MTCs (c. 25 km3) derived from the shelf-edge or upper slope; (b) minibasin margin uplift and steepening, during which time small-volume MTCs (c. 20 km3) derived from the shelf-edge or upper slope were emplaced; and (c) active diapirism, during which time very small volume MTCs (c. 1 km3) were emplaced, locally derived from the diapir flanks or roofs. We present a generic model that emphasizes the dynamic nature of minibasin evolution, and how MTC emplacement relates to halokinetic sequence development. Although based on a single data-rich case study, our model may be applicable to other MTC-rich, salt-influenced sedimentary basins.  相似文献   
989.
990.
We used space-for-time substitution, correlation, and regression analyses to study the effects of urbanization age on stream channel variables from 19 low-order urban watersheds in the southern Piedmont of the United States. The results are used to address questions regarding which variables are most responsive to urbanization age, the duration of response relative to system size, and changes in adjustment rate over time. Few morphological variables were found to be well correlated with metrics of urbanization age. The maximum-width/maximum-depth ratio (Wmax/Dmax) exhibited the best correlations to multiple metrics of urbanization age, with all correlations positive. A dearth of young urbanization ages in our dataset makes mathematically derived response times and end states for Wmax/Dmax highly uncertain. Inferences from the age range that is better represented suggest that the period of major response has occurred within the first three decades following urbanization. Subsequently, gradual increase in Wmax/Dmax appears to continue over 40 or more years. Response of channel form to urbanization and time elapsed in these low-order Piedmont streams is constrained by the presence of resistant bedrock below streambeds, a circumstance addressed by recent channel evolution models.  相似文献   
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