A comparative study of the modelling of cement hydration and cement-rock laboratory experiments     

David Savage  Josep M. SolerKohei Yamaguchi  Colin WalkerAkira Honda  Manabu InagakiClaire Watson  James WilsonSteven Benbow  Irina GausJoerg Rueedi 《Applied Geochemistry》2011,26(7):1138-1152

The use of cement and concrete as fracture grouting or as tunnel seals in a geological disposal facility for radioactive wastes creates potential issues concerning chemical reactivity. From a long-term safety perspective, it is desirable to be able model these interactions and changes quantitatively. The ‘Long-term Cement Studies’ (LCS) project was formulated with an emphasis on in situ field experiments with more realistic boundary conditions and longer time scales compared with former experiments. As part of the project programme, a modelling inter-comparison has been conducted, involving the modelling of two experiments describing cement hydration on one hand and cement-rock reaction on the other, with teams representing the NDA (UK), Posiva (Finland), and JAEA (Japan).This modelling exercise showed that the dominant reaction pathways in the two experiments are fairly well understood and are consistent between the different modelling teams, although significant differences existed amongst the precise parameterisation (e.g. reactive surface areas, dependences of rate upon pH, types of secondary minerals), and in some instances, processes (e.g. partition of alkali elements between solids and liquid during cement hydration; kinetic models of cement hydration). It was not conclusive if certain processes such as surface complexation (preferred by some modellers, but not by others) played a role in the cement-rock experiment or not. These processes appear to be more relevant at early times in the experiment and the evolution at longer timescales was not affected. The observed permeability profile with time could not be matched. The fact that no secondary minerals could be observed and that the precipitated mass calculated during the simulations is minor might suggest that the permeability reduction does not have a chemical origin, although a small amount of precipitates at pore throats could have a large impact on permeability.The modelling exercises showed that there is an interest in keeping the numerical models as simple as possible and trying to obtain a reasonable fit with a minimum of processes, minerals and parameters. However, up-scaling processes and model parameterisation to the timescales appropriate to repository safety assessment are of considerable concern. Future modelling exercises of this type should focus on a suitable natural or industrial analogue that might aid assessing mineral-fluid reactions at these longer timescales.  相似文献   

Short-term residence and movement patterns of the annular seabream Diplodus annularis in a temperate marine reserve     

David March  Josep Als  Amlia Grau  Miquel Palmer 《Estuarine, Coastal and Shelf Science》2011,92(4):251-587

The short-term movements of a small temperate fish, the annular seabream Diplodus annularis (Linnaeus 1758), were examined using standard tag-recapture and passive acoustic telemetry in Palma Bay (NW Mediterranean), a marine protected area (MPA). The study aimed to provide valuable information for assessing the recreational fishery and its results suggest that MPAs can be used to protect the adult stock of D. annularis. All the fish tagged with standard tags were recaptured near the release locations, with a maximum distance of ∼300 m. The maximum time between release and recapture was 185 d. Two different arrays of acoustic receivers were deployed, one in 2008 and another in 2009, within the MPA. Twenty adults were surgically tagged with acoustic transmitters. Fish monitored in 2008 (n = 12) were translocated from the point of capture to analyse the movement behaviour after artificial displacement. Upon release at displaced locations, 67% of the fish moved towards the original capture location using a time of return that ranged from 0.75 to 15.25 h. Fish monitored in 2009 (n = 8) were released at the point of capture. They showed high site fidelity with a maximum period of 27 d between the first time and the last time they were detected.  相似文献   

Growth and grazing rate dynamics of major phytoplankton groups in an oligotrophic coastal site   总被引：1，自引：0，他引：1  

Andrés Gutiérrez-Rodríguez  Mikel Latasa  Renate Scharek  Ramon Massana  Gemma Vila  Josep M. Gasol 《Estuarine, Coastal and Shelf Science》2011

There has been more attention to phytoplankton dynamics in nutrient-rich waters than in oligotrophic ones thus requiring the need to study the dynamics and responses in oligotrophic waters. Accordingly, phytoplankton community in Blanes Bay was overall dominated by Prymnesiophyceae, remarkably constant throughout the year (31 ± 13% Total chlorophyll a, Tchl a) and Bacillariophyta with a more episodic appearance (20 ± 23% Tchl a). Prasinophyceae and Synechococcus contribution became substantial in winter (Prasinophyceae = 30% Tchl a) and summer (Synechococcus = 35% Tchl a). Phytoplankton growth and grazing mortality rates for major groups were estimated by dilution experiments in combination with high pressure liquid chromatography and flow cytometry carried out monthly over two years. Growth rates of total phytoplankton (range = 0.30–1.91 d⁻¹) were significantly higher in spring and summer (μ > 1.3 d⁻¹) than in autumn and winter (μ ∼ 0.65 d⁻¹) and showed a weak dependence on temperature but a significant positive correlation with day length. Microzooplankton grazing (range = 0.03–1.4 d⁻¹) was closely coupled to phytoplankton growth. Grazing represented the main process for loss of phytoplankton, removing 60 ± 34% (±SD) of daily primary production and 70 ± 48% of Tchl a stock. Chla synthesis was highest during the Bacillarophyceae-dominated spring bloom (Chl a_synt = 2.3 ± 1.6 μg Chl a L⁻¹ d⁻¹) and lowest during the following post-bloom conditions dominated by Prymnesiophyceae (Chl a_synt = 0.23 ± 0.08 μg Chl a L⁻¹ d⁻¹). This variability was smoothed when expressed in carbon equivalents mainly due to the opposite dynamics of C:chl a (range = 11–135) and chl a concentration (range = 0.07–2.0 μg chl a L⁻¹). Bacillariophyta and Synechococcus contribution to C fluxes was higher than to biomass because of their fast-growth rate. The opposite was true for Prymnesiophyceae.  相似文献   

Spatial and temporal variability of deep-water algal assemblages in the Northwestern Mediterranean: The effects of an exceptional storm     

Laura Navarro  Enric Ballesteros  Cristina Linares  Bernat Hereu 《Estuarine, Coastal and Shelf Science》2011

There are deep-water populations of the endemic and threatened Mediterranean brown alga Cystoseira zosteroides in the Medes Islands Marine Reserve (NW Mediterranean). Here, the distribution, population structure, individual growth, mortality and recruitment rates of this species over two years are described in relation to the effects of an exceptional storm. We found a high spatial variability in the structure and dynamics of C. zosteroides populations at small geographical scales, suggesting that environmental factors acting at the population level display a key role in population size structure, mortality and recruitment. The elevated mortality rates recorded at some locations (almost 80%) is amongst the highest recorded for perennial algae as a consequence of a single storm, emphasizing the importance of episodic catastrophic events in the maintenance of these deep-water, slow-growing populations. These findings are of particular importance not only to fully understand the ecology of C. zosteroides, but also for its conservation.  相似文献   

Water and nutrient fluxes off Northwest Africa     

Maria V. Pastor  Josep L. Pelegrí  Alonso Hernández-Guerra  Jordi Font  Jordi Salat  Mikhail Emelianov 《Continental Shelf Research》2008

A historical data set is used to describe the coastal transition zone off Northwest Africa during spring 1973 and fall 1975, from 17° to 26°N, with special emphasis on the interaction between subtropical (North Atlantic Central Waters) and tropical (South Atlantic Central Waters) gyres. The near-surface geostrophic circulation, relative to 300 m, is quite complex. Major features are a large cyclonic pattern north of Cape Blanc (21°N) and offshore flow at the Cape Verde front. The large cyclone occurs in the region of most intense winds, and resembles a large meander of the baroclinic southward upwelling jet. The Cape Verde frontal system displays substantial interleaving that may partly originate as mesoscale features at the coastal upwelling front. Property–property diagrams show that the front is an effective barrier to all properties except temperature. The analysis of the Turner angle suggests that the frontal system is characterized by large heat horizontal diffusion as a result of intense double diffusion, which results in the smoothing of the temperature horizontal gradients. Nine cross-shore sections are used to calculate along-shore geostrophic water-mass and nutrient transports and to infer exchanges between the coastal transition zone and the deep ocean (import: deep ocean to transition zone; export: transition zone to deep ocean). These exchanges compare well with mean wind-induced transports and actual geostrophic cross-shore transport estimates. The region is divided into three areas: southern (18–21°N), central (21–23.5°N), and northern (23.5–26°N). In the northern area geostrophic import is roughly compensated with wind-induced export during both seasons. In the central area geostrophic import is greater than wind-induced export during spring, resulting in net import of both water (0.8 Sv) and nitrate (14 kmol s⁻¹), but during fall both factors again roughly cancel. In the southern area geostrophy and wind join to export water and nutrients during both seasons, they increase from 0.6 Sv and 3 kmol s⁻¹ during fall to 2.9 Sv and 53 kmol s⁻¹ during spring.  相似文献   

Lateral variations of the local magnitude at Ebre station,Northeastern Iberian Peninsula     

Josep Vila  Josep Batllo  Antoni M. Correig 《Pure and Applied Geophysics》1996,147(1):131-146

Since 1984, a seismic surveillance at the Baix Ebre Region (NE of the Iberian Peninsula) has been carried out from a seismic network consisting of two digital and one analog stations. Large discrepancies between the recorded amplitudes and the magnitude estimates given by different agencies have been observed. To explain these discrepancies, that consist of a large reduction of amplitude and a strong dependence of the azimuth, a local magnitude formula for the area has been computed, using the analog records obtained at EBR short-period station. Global results show an average station correction factor between the computed local magnitude and the reported magnitude of the order of 1, presenting large variations around the mean value with a clear dependence on the azimuth. A detailed analysis of this variation around the mean value reveals that earthquakes can be classified according to their location in different geological units, thus obtaining for each zone a distinct station correction factor that can fluctuate as much as 0.6 around the average. These large lateral variations of the magnitude are in good agreement with previous studies of coda-Q attenuation.  相似文献   

Cloud cover climatologies in the Mediterranean obtained from satellites,surface observations,reanalyses, and CMIP5 simulations: validation and future scenarios     

Aaron Enriquez-Alonso  Arturo Sanchez-Lorenzo  Josep Calbó  Josep-Abel González  Joel R. Norris 《Climate Dynamics》2016,47(1-2):249-269

  相似文献   

Improving wave predictions with artificial neural networks, by O. Makarynskyy     

Josep R. Medina 《Ocean Engineering》2005,32(1):379

  相似文献   

Water Flow, Trophic Depletion, and Benthic Macrofauna Impoverishment in a Submarine Cave from the Western Mediterranean   总被引：1，自引：0，他引：1  

Mikel Zabala  Tecla Riera  Josep Maria Gili  Manel Barange  Agustin Lobo  Josep Peñuelas 《Marine Ecology》1989,10(3):271-287

Abstract. Biotic zonation and severe impoverishment of benthic macrofauna are two of the most conspicuous features of submarine caves. The prevailing explanation assumes trophic depletion caused by reduction of water flow. However, no isolation of water was found in the studied Catalan submarine cave, even in the wall microlayer. Fluorescein diffusion was so fast that it was detectable everywhere in the cave already only a few minutes after the injection. The rate of dissolution of plaster spheres was even greater in the cave than in a nearby tunnel – without benthic macrofauna impoverishment – showing a considerable water flow. The oxygen concentration of water in dialysis bags placed at varying distances from the cave walls showed that no wall microlayer gradients were present.
Biochemical gradients did not indicate any decrease in food supply. Although photosynthetic pigment concentration generally decreased inside the cave, and although the gradients were not linear but formed different patterns throughout the cave, the BOD₅, the POM, the C:N ratio, the [³H]-thymidine incorporation rate, and the ETS activity were higher in the inner part of the cave. There was an accumulation of detritic material and bacteria in the inner parts that constitute a plausible food supply for benthic macrofauna.
If neither water motion nor food supply can be invoked, research into the causes of zonation and disappearence of benthic macrofauna is proposed to be carried out on biotic interactions and behavioural processes.  相似文献   

Comparative analysis of a new assessment of the seismic risk of residential buildings of two districts of Barcelona     

Aguilar-Meléndez  Armando  Pujades  Lluis G.  Barbat  Alex H.  Monterrubio-Velasco  Marisol  de la Puente  Josep  Lantada  Nieves 《Natural Hazards》2022,110(3):1649-1691

Natural Hazards - There are personal and institutional decisions that can increase the seismic resilience of the buildings in a city. However, some of these decisions are possible if we have basic...  相似文献