The behaviour of platinum-group elements (PGE) in the exogenic cycle was examined in profiles of oxidized Main Sulfide Zone (MSZ) ores, in which the general metal distribution patterns of the pristine MSZ are grossly preserved. However, at similar Pt grades, significant proportions of Pd have been lost from the system. This indicates that Pd is more mobile than Pt and is dispersed in the supergene environment. Sperrylite and cooperite/braggite are stable in the oxidized MSZ. In contrast, the (Pt,Pd)-bismuthotellurides, common in pristine MSZ ores, have disintegrated, and ill-defined (Pt,Pd)-oxides or (Pt,Pd)-hydroxides have formed. The assemblage of detrital PGM present in the Makwiro River close to the Hartley Platinum Mine indicates further mineralogical changes. Sperrylite largely remains stable whereas most cooperite/braggite grains have been partly altered or completely destroyed. Grains of Pt-Fe alloy are ubiquitous in the alluvial sediments. Most likely, these grains are neo-formations that formed either from pre-existing, unstable PGM or via a solution stage under low-temperature conditions. 相似文献
The traditional method used in the water quality classification of Finnish lakes includes the collection of water samples from lakes and their analysis in laboratory conditions. The classification is based on statistical analysis of water quality parameter values and on expert opinion. It is possible to acquire similar information by using radiance values measured with the Earth Observing System Terra/Aqua Moderate Resolution Imaging Spectroradiometer (MODIS). In this letter, the classification accuracy with MODIS data is about 80%. Only about 0.2% of the 20 391 pixels were misclassified by two or more classes, as a four-class classification system is used. 相似文献
Ambient concentrations of polycyclic aromatic hydrocarbons (PAHs) were measured in Helsinki (Finland). Particle mass size
distributions were obtained with a cascade impactor (12 stages) with glass fibre filters as substrates. Simultaneously with
the impactor measurements, particulate and gaseous PAHs were collected on a quartz filter and XAD-2 adsorbent, respectively,
for evaluation of gas-partition coefficients. Samples were analysed for PAHs by on-line coupled supercritical fluid extraction
— liquid chromatography — gas chromatography — mass spectrometry. The impactor results showed that most of the PAHs in Helsinki
urban area were concentrated in fine particles (<2.5 μm diameter) with unimode peak at about 1 μm. The results were comparable
with the number distribution measured with a differential mobility particle sizer. Total amounts of PAHs (gas + particle)
varied from 15 (acenaphthylene) to 1990 (fluorene) pg/m3. The PAHs lighter than 202 amu (pyrene and fluoranthene) were exclusively in gas phase, whereas those heavier than 202 amu
were mostly associated with particles. A plot of the partition coefficients (logKp) versus the temperature dependent sub-cooled
vapour pressures (logp
L0
) showed a gradient of −0.66, which deviated from equilibrium state (gradient = −1). 相似文献
Multiple-scattering computations are carried out to explain the variation of the observed brightness of the A and B rings of Saturn with declination of the Earth and Sun. These computations are performed by a doubling scheme for a homogeneous plane-parallel scattering medium. We test a range of choices for the phase function, albedo for single scattering, and optical depth of both the rings. Isotropic scattering and several other simple phase functions are ruled out, and we find that the phase function must be moderately peaked in both the forward and backward directions. The tilt effect can be explained by multiple scattering in a homogeneous layer, but, for ring B, this requires a single-scattering albedo in excess of 0.8. The brightest part of ring B must have an optical depth greater than 0.9. We find that the tilt effect for ring A can be reproduced by particles having the same properties as those in ring B with the optical depth for the A ring in the range 0.4 to 0.6. 相似文献
High altitude and latitude findings of subfossil peatland pine trees were unearthed from the region of NW Finnish Lapland and dated by 14C and tree-ring methods. The depositional history of the trees illustrated two distinct peatland pine phases dated to Middle Holocene intervals 4900–4400 and 4100–3400 cal. a BC. It seems evident that both thermal and hydroclimatic fluctuations have played roles of varying importance in the establishment of this pine population and its demise. The presence of these pines, from a site ~60 km north of the coniferous timberline and conditions ~1 °C and 100 degree-days colder than those at the present-day timberline, concurs with previous studies demonstrating the association between the high-latitude summer-temperature cooling and circumpolar timberline retreat since the Middle Holocene due to Milankovitch forcing. On the other hand, the peatland pine recruitment was made possible by drier than present surface conditions during the previously reconstructed Middle Holocene drought anomaly (Hyvärinen-Alhonen event). Our data suggest this event was not continuous but reached its two-phase climax during the peatland pine phases, with an interruption of several centuries with moister surface conditions between 4400 and 4100 cal. a BC. The findings highlight the sensitivity of well-dated peatland tree assemblages in terms of recording past climatic evolution and events and the need for new collections from north and south Fennoscandia and the Baltic region, for more detailed analyses over extended time intervals and regions. 相似文献
We present a Holocene record of floristic diversity and environmental change for the central Varanger Peninsula, Finnmark, based on ancient DNA extracted from the sediments of a small lake (sedaDNA). The record covers the period c. 10 700 to 3300 cal. a BP and is complemented by pollen data. Measures of species richness, sample evenness and beta diversity were calculated based on sedaDNA sampling intervals and 1000‐year time windows. We identified 101 vascular plant and 17 bryophyte taxa, a high proportion (86%) of which are still growing within the region today. The high species richness (>60 taxa) observed in the Early Holocene, including representatives from all important plant functional groups, shows that modern shrub‐tundra communities, and much of their species complement, were in place as early as c. 10 700 cal. a BP. We infer that postglacial colonization of the area occurred prior to the full Holocene, during the Pleistocene‐Holocene transition, Younger Dryas stadial or earlier. Abundant DNA of the extra‐limital aquatic plant Callitriche hermaphroditica suggests it expanded its range northward between c. 10 200 and 9600 cal. a BP, when summers were warmer than present. High values of Pinus DNA occur throughout the record, but we cannot say with certainty if they represent prior local presence; however, pollen influx values >500 grains cm?2 a?1 between c. 8000 and 7300 cal. a BP strongly suggest the presence of pine woodland during this period. As the site lies beyond the modern tree limit of pine, it is likely that this expansion also reflects a response to warmer Early Holocene summers. 相似文献
The Diavik Diamond Mine in the NWT of Canada has produced in excess of 100 million carats from 3 kimberlite pipes since mining commenced in 2002. Here, we present new findings from deep (>400 m below surface) mining, sampling and drilling work in the A154N kimberlite volcano that require a revision of previous geological and emplacement models and provide a window into how the sub-continental lithospheric mantle (SCLM) below Diavik was sampled by kimberlite magmas through time. Updated internal geological models feature two volcanic packages interpreted to represent two successive cycles of explosive eruption followed by active and passive sedimentation from a presumed crater-rim, both preceded and followed by intrusions of coherent kimberlite. Contact relationships apparent among the geological units allow for a sequential organization of as many as five temporally-discrete emplacement events. Representative populations of mantle minerals extracted from geological units corresponding to four of the emplacement events at A154N are analyzed for major and trace elements, and provide insights into the whether or not kimberlites randomly sample from the mantle. Two independent geothermometers using clinopyroxene and garnet data indicate similar source depths for clinopyroxenes and G9 garnets (130–160 km), and suggest deeper sampling with time for both clinopyroxene and garnets. Harzburgite is limited to 110–160 km, and appears more prevalent in early, low-volume events. Variable ratios of garnet parageneses from the same depth horizons suggest random sampling by passing magmas, but deeper garnet sampling through time suggests early preferential sampling of shallow/depleted SCLM. Evaluations of Ti, Zr, Y and Ga over the range of estimated depths support models of the SCLM underlying the central Slave terrane.
The nature of compositional heterogeneity within large silicic magma bodies has important implications for how silicic reservoirs are assembled and evolve through time. We examine compositional heterogeneity in the youngest (~170 to 70 ka) post-caldera volcanism at Yellowstone caldera, the Central Plateau Member (CPM) rhyolites, as a case study. We compare 238U–230Th age, trace-element, and Hf isotopic data from zircons, and major-element, Ba, and Pb isotopic data from sanidines hosted in two CPM rhyolites (Hayden Valley and Solfatara Plateau flows) and one extracaldera rhyolite (Gibbon River flow), all of which erupted near the caldera margin ca. 100 ka. The Hayden Valley flow hosts two zircon populations and one sanidine population that are consistent with residence in the CPM reservoir. The Gibbon River flow hosts one zircon population that is compositionally distinct from Hayden Valley flow zircons. The Solfatara Plateau flow contains multiple sanidine populations and all three zircon populations found in the Hayden Valley and Gibbon River flows, demonstrating that the Solfatara Plateau flow formed by mixing extracaldera magma with the margin of the CPM reservoir. This process highlights the dynamic nature of magmatic interactions at the margins of large silicic reservoirs. More generally, Hf isotopic data from the CPM zircons provide the first direct evidence for isotopically juvenile magmas contributing mass to the youngest post-caldera magmatic system and demonstrate that the sources contributing magma to the CPM reservoir were heterogeneous in 176Hf/177Hf at ca. 100 ka. Thus, the limited compositional variability of CPM glasses reflects homogenization occurring within the CPM reservoir, not a homogeneous source. 相似文献
Holocene climate variability is punctuated by episodic climatic events such as the Little Ice Age (LIA) predating the industrial-era warming. Their dating and forcing mechanisms have however remained controversial. Even more crucially, it is uncertain whether earlier events represent climatic regimes similar to the LIA. Here we produce and analyse a new 7500-year long palaeoclimate record tailored to detect LIA-like climatic regimes from northern European tree-ring data. In addition to the actual LIA, we identify LIA-like ca. 100–800 year periods with cold temperatures combined with clear sky conditions from 540 CE, 1670 BCE, 3240 BCE and 5450 BCE onwards, these LIA-like regimes covering 20% of the study period. Consistent with climate modelling, the LIA-like regimes originate from a coupled atmosphere–ocean–sea ice North Atlantic-Arctic system and were amplified by volcanic activity (multiple eruptions closely spaced in time), tree-ring evidence pointing to similarly enhanced LIA-like regimes starting after the eruptions recorded in 1627 BCE, 536/540 CE and 1809/1815 CE. Conversely, the ongoing decline in Arctic sea-ice extent is mirrored in our data which shows reversal of the LIA-like conditions since the late nineteenth century, our record also correlating highly with the instrumentally recorded Northern Hemisphere and global temperatures over the same period. Our results bridge the gaps between low- and high-resolution, precisely dated proxies and demonstrate the efficacy of slow and fast components of the climate system to generate LIA-like climate regimes.
We present initial results from the first community-wide effort to compare global plasma interaction model results for Mars. Seven modeling groups participated in this activity, using MHD, multi-fluid, and hybrid assumptions in their simulations. Moderate solar wind and solar EUV conditions were chosen, and the conditions were implemented in the models and run to steady state. Model output was compared in three ways to determine how pressure was partitioned and conserved in each model, the location and asymmetry of plasma boundaries and pathways for planetary ion escape, and the total escape flux of planetary oxygen ions. The two participating MHD models provided similar results, while the five sets of multi-fluid and hybrid results were different in many ways. All hybrid results, however, showed two main channels for oxygen ion escape (a pickup ion ‘plume’ in the hemisphere toward which the solar wind convection electric field is directed, and a channel in the opposite hemisphere of the central magnetotail), while the MHD models showed one (a roughly symmetric channel in the central magnetotail). Most models showed a transition from an upstream region dominated by plasma dynamic pressure to a magnetosheath region dominated by thermal pressure to a low altitude region dominated by magnetic pressure. However, calculated escape rates for a single ion species varied by roughly an order of magnitude for similar input conditions, suggesting that the uncertainties in both the current and integrated escape over martian history as determined by models are large. These uncertainties are in addition to those associated with the evolution of the Sun, the martian dynamo, and the early atmosphere, highlighting the challenges we face in constructing Mars’ past using models. 相似文献
