Analysis of seawater and different highly saline natural waters by capillary zone electrophoresis     

Andrei R. Timerbaev  Keiichi Fukushi 《Marine Chemistry》2003,82(3-4):221-238

Innovative applications of capillary zone electrophoresis (CZE) to the determination of inorganic ions in environmental aquatic samples of high salinity and, particularly, in seawater are reviewed. Emphasis is placed on advanced approaches utilized for securing separation performance from being degraded by the presence of matrix salts and for simultaneous separation of ions different in natural abundance. Also covered are methodologies of present or possible use to evolve the method's practical utility to trace-level ions. Surveyed procedures are tabulated for the purpose of facilitating the method selection or further development. In addition, brief background information on basic methodological principles of CZE in inorganic ion analysis is given for a better orientation of those intending or just beginning to put CZE to work. Finally, possible future research trends and developments of CZE in the area are briefly discussed.  相似文献   

Nucleosynthesis of ⁵⁶Ni in wind-driven supernova explosions and constraints on the central engine of gamma-ray bursts     

Keiichi Maeda  Nozomu Tominaga 《Monthly notices of the Royal Astronomical Society》2009,394(3):1317-1324

Theoretically expected natures of a supernova (SN) driven by a wind/jet are discussed. Approximate analytical formulations are derived to clarify basic physical processes involved in the wind/jet-driven explosions, and it is shown that the explosion properties are characterized by the energy injection rate     and the mass injection rate     . To explain observations of Supernova 1998bw associated with gamma-ray burst (GRB) 980425, the following conditions are required:     and     (if the wind Lorentz factor  Γ_w∼ 1  ) or     (if  Γ_w≫ 1  ). In Supernova 1998bw, ⁵⁶Ni  (∼0.4 M_⊙)  is probably produced in the shocked stellar mantle, not in the wind. The expected natures of SNe, e.g. ejected ⁵⁶Ni mass and ejecta mass, vary depending on     and     . The sequence of the SN properties from high     and     to low     and     is as follows: Supernova 1998bw-like – intermediate case – low mass ejecta  (≲1 M_⊙)  where ⁵⁶Ni is from the wind – whole collapse. This diversity may explain the diversity of SNe associated with GRBs. Our result can be used to constrain natures of the wind/jet, which are linked to the central engine of GRBs, by studying properties of the associated SNe.  相似文献   

Observational characteristics and possible asphericity of overluminous Type Ia supernovae     

Keiichi Maeda  Koichi Iwamoto 《Monthly notices of the Royal Astronomical Society》2009,394(1):239-249

A few Type Ia supernovae (SNe Ia) have been suggested to be an explosion of a super-Chandrasekhar-mass white dwarf (WD) in order to account for their large luminosities, requiring a large amount of ⁵⁶Ni. However, the candidate overluminous SNe Ia 2003fg, 2006gz and (moderately overluminous) SN 1991T have very different observational features: the characteristic time-scale and velocity are very different. We examine if and how the diversity can be explained, by one-dimensional spherical radiation transport calculations covering a wide range of model parameters (e.g. WD mass). The observations of SN 2006gz are naturally explained by the super-Chandrasekhar-mass model. SN 1991T represents a marginal case, which may either be a Chandrasekhar or a super-Chandrasekhar-mass WD explosion. In contrast, the low velocity and short time-scale seen in SN 2003fg indicate that the ejecta mass is smaller than the Chandrasekhar mass, which is in apparent contradiction to the large luminosity. We suggest that the problem is solved if the progenitor WD, and thus the SN explosion, is aspherical. This may reflect a rapid rotation of the progenitor star, likely a consequence of the super-Chandrasekhar-mass WD progenitor. The observed differences between SNe 2003fg and 2006gz may be attributed to different viewing orientations.  相似文献   

New multiply-lensed galaxies identified in ACS/NIC3 observations of Cl0024+1654 using an improved mass model     

Adi Zitrin  Tom Broadhurst  Keiichi Umetsu  Dan Coe  Narciso Benítez  Begoña Ascaso  Larry Bradley  Holland Ford  James Jee  Elinor Medezinski  Yoel Rephaeli  Wei Zheng 《Monthly notices of the Royal Astronomical Society》2009,396(4):1985-2002

We present an improved strong-lensing analysis of Cl0024+1654  ( z = 0.39)  using deep Hubble Space Telescope ( HST )/Advanced Camera for Surveys (ACS)/NIC3 images, based on 33 multiply-lensed images of 11 background galaxies. These are found with a model that assumes mass approximately traces light, with a low-order expansion to allow for flexibility on large scales. The model is constrained initially by the well-known five-image system  ( z = 1.675)  and refined as new multiply-lensed systems are identified using the model. Photometric redshifts of these new systems are then used to constrain better the mass profile by adopting the standard cosmological relation between redshift and lensing distance. Our model requires only six free parameters to describe well all positional and redshift data. The resulting inner mass profile has a slope of  d log  M /d log  r ≃−0.55  , consistent with new weak-lensing measurements where the data overlap, at   r ≃ 200 kpc/ h ₇₀  . The combined profile is well fitted by a high-concentration Navarro, Frenk & White (NFW) mass profile,   C _vir∼ 8.6 ± 1.6  , similar to other well-studied clusters, but larger than predicted with standard Λ cold dark matter (ΛCDM). A well-defined radial critical curve is generated by the model and is clearly observed at   r ≃ 12  arcsec, outlined by elongated images pointing towards the centre of mass. The relative fluxes of the multiply-lensed images are found to agree well with the modelled magnifications, providing an independent consistency check.  相似文献   

Modeling the Contemporary Stress Field and Deformation Pattern of Eastern Mediterranean     

S K Dwivedi  D Hayashi 《中国地质大学学报(英文版)》2010,(4)

The contemporary stress field in the earth's crust is important and provides insights into mechanisms that drive plate motions.In this study,elastic plane stress finite element modeling incorporating realistic rock parameters was used to calculate the stress field,displacement field,and deformation of the plate interactions in the eastern Mediterranean.Modeled stress data for the African-Arabian-Anatolian plate interactions with fixed European platform correlate well with observed contemporary stress indica...  相似文献   

Interstadial coral reef terraces and relative sea-level changes during marine oxygen isotope stages 3–4, Kikai Island, central Ryukyus, Japan     

Keiichi Sasaki  Akio Omura  Kazuo Murakami  Natsume Sagawa  Toru Nakamori 《Quaternary International》2004,120(1):51

Coral reef terraces are one of the best recorders of relative sea-level changes during the last glacial cycle. Thus far, knowledge of relative sea-level record based on coral reefs during the marine Oxygen Isotope Stage (OIS) 3 has been limited to studies of the Huon Peninsula, Papua New Guinea. High-precision a α-spectrometric ²³⁰Th/²³⁴U dating demonstrated an offlapping sequence of five coral reef complexes, ages of which are 66, 64, 62, 55 and 52 ka, in the northern part of Kikai Island, central Ryukyus of Japan. Interstadial reefs, characterized by deepening-upward sequences of coral assemblages, recorded three hemicycles from transgression to highstand at 52, 62, and 66 ka, during which these reefs were drowned. These highstands in the relative sea-level record can be correlated with the eustatic record reconstructed from the Huon reef terraces and with the interstadials 14, 18, and 19 of the GISP 2 oxygen isotope record. This consistency confirms the Huon sea-level record of OIS 3 and implies that the eustatic sea level responded to the millennial-scale climate changes even during the glacial period of OIS 4.  相似文献   

Damage detection of base‐isolated buildings using multi‐input multi‐output subspace identification     

Reiki Yoshimoto  Akira Mita  Keiichi Okada 《地震工程与结构动力学》2005,34(3):307-324

A damage detection algorithm of structural health monitoring systems for base‐isolated buildings is proposed. The algorithm consists of the multiple‐input multiple‐output subspace identification method and the complex modal analysis. The algorithm is applicable to linear and non‐linear systems. The story stiffness and damping as damage indices of a shear structure are identified by the algorithm. The algorithm is further tuned for base‐isolated buildings considering their unique dynamic characteristics by simplifying the systems to single‐degree‐of‐freedom systems. The isolation layer and the superstructure of a base‐isolated building are treated as separate substructures as they are distinctly different in their dynamic properties. The effectiveness of the algorithm is evaluated through the numerical analysis and experiment. Finally, the algorithm is applied to the existing 7‐story base‐isolated building that is equipped with an Internet‐based monitoring system. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Experimental study of migration of potassium ion through a two-layer soil system     

Yan Jun Du  Shigenori Hayashi  Song Yu Liu 《Environmental Geology》2005,48(8):1096-1106

A barrier system based on the hydraulic trap design concept for a landfill was proposed. To study the field scenario in which a clay liner is underlain by a granular layer functioning as a secondary leachate drain layer, a laboratory advection–diffusion test was performed to investigate factors controlling the transport of contaminants in a two-layer soil system. The soils used for this study were Ariake clay and, the underlying layer, Shirasu soil from the Kyushu region of Japan. Potassium (K⁺) was selected as the target chemical species with an initial concentration of 905 mg L⁻¹. The effective diffusion coefficients (D _e) of K⁺ for Ariake clay and Shirasu soil were back-calculated using an available computer program, Pollute V 6.3. Values of D _e derived from this experiment are consistent with previously published ones. The Ariake clay has lower D _e than the Shirasu soil. The hypothesis that mechanical dispersion can be considered negligible is reasonable based on both the observation that the predicted values well fit the experimental data and the analyses of two dimensionless parameters. Parametric analyses show that transport of K⁺ through soils is controlled by advection–diffusion rather than diffusion only, whereas at low Darcy velocity (i.e., ≤10⁻⁹ m s⁻¹), transport of K⁺ will be controlled by diffusion. Applications of the test results and parametric analysis results in practical situations were reviewed.  相似文献   

Uranium and Thorium Isotope Distribution in an Offshore Bottom Sediment Core of the Selenga Delta, Lake Baikal, Siberia     

Aya Sakaguchi  Masayoshi Yamamoto  Keiichi Sasaki  Kenji Kashiwaya 《Journal of Paleolimnology》2006,35(4):807-818

Distribution of uranium and thorium isotopes in a short sediment core obtained offshore of the Selenga Delta in Lake Baikal, Siberia, was investigated to establish their sedimentary behaviors and to look for a linkage to paleoenvironmental changes. The sediments were composed of dominantly fine detrital materials (70–85%) and a relatively high sedimentation rate (ca. 0.03 cm y⁻¹). The depth profile of ²³⁸U content in bulk sediment samples showed a large variation of 70–123 Bq kg⁻¹, while ²³²Th profile showed a relatively narrow range from 36 to 56 Bq kg⁻¹. The observed ²³⁴U/²³⁸U activity ratios revealed a marked disequilibrium ranging from 1.53 to 1.84 with a mean value of 1.71 ± 0.07, demonstrating the presence of 50–80% authigenic ²³⁸U in the bulk sediments. The distribution of this authigenic ²³⁸U did not display any clear correlation with variations in sediment composition (organic, carbonate, Bio-SiO₂ and mineral contents) including grain size median. The profile of terrigenous ²³⁸U showed a relatively similar pattern to that of ²³²Th. Results of sequential leaching indicate that ²³⁸U in Fe–Mn oxyhydroxides fractions were responsible for the distribution of authigenic ²³⁸U rather than in Bio-SiO₂ fraction. The distribution of authigenic ²³⁸U in the bottom sediments may be explained by the fluctuation of U adsorption capacity on particles including organic matter and Fe–Mn oxyhydroxides before they entered the lake. This study highlights the potential use of authigenic and terrigenous U (Th) signatures in sediments to trace the behavior of U (Th) and to reconstruct environmental (e.g., hydrological) changes in the lake catchment area.  相似文献   

²³⁰Th/²³⁴U and ¹⁴C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan     

Keiichi  Sasaki  Akio  Omura  Tetsuo  Miwa  Yoshihiro  Tsuji  Hiroki  Matsuda  Toru  Nakamori  Yasufumi  Iryu  Tsutomu  Yamada  Yuri  Sato  Hiroshi  Nakagawa 《Island Arc》2006,15(4):455-467

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.  相似文献