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31.
When GNSS receivers capable of collecting dual-frequency data are available, it is possible to eliminate the first-order ionospheric effect in the data processing through the ionosphere-free linear combination. However, the second- and third-order ionospheric effects still remain. The first-, second- and third-order ionospheric effects are directly proportional to the total electron content (TEC), although the second- and third-order effects are influenced, respectively, by the geomagnetic field and the maximum electron density. In recent years, the international scientific community has given more attention to these kinds of effects and some works have shown that for high precision GNSS positioning these effects have to be taken into consideration. We present a software tool called RINEX_HO that was developed to correct GPS observables for second- and third-order ionosphere effects. RINEX_HO requires as input a RINEX observation file, then computes the second- and third-order ionospheric effects, and applies the corrections to the original GPS observables, creating a corrected RINEX file. The mathematical models implemented to compute these effects are presented, as well as the transformations involving the earth’s magnetic field. The use of TEC from global ionospheric maps and TEC calculated from raw pseudorange measurements or pseudoranges smoothed by phase is also investigated.  相似文献   
32.
The mechanism by which olivine grains became embedded within iron‐nickel alloy in pallasite meteorites continues to be a matter of scientific debate. Geochemical and textural observations have failed to fully elucidate the origin and history of the olivine crystals; however, little research attention has been devoted to their crystallographic orientations within the metal matrix. Using electron backscatter diffraction, we have collected crystallographic orientation data for 296 crystals within ~65 cm2 sample surface from Springwater. Though no global crystallographic preferred orientation exists, very low misorientations are observed among [100] axes of olivine crystals within specific texturally defined domains. Combined with a thorough characterization of large‐scale Springwater textures, the definitively nonrandom spatial distribution of olivine orientations provides clues regarding the nature of the olivine's initial formation environment as well as the sequence of events subsequent to metal incorporation.  相似文献   
33.
The efficacy of water quality policies aiming to reduce or prevent nitrate contamination of waterbodies may be constrained by the inherent delay or “time lag” of water and solute transport through unsaturated (soil) and saturated (groundwater) pathways. These delays must be quantified in order to establish realistic deadlines, thresholds and policy expectations, and to design effective best management practices. The objective of this review is to synthesise the current state of research on nitrate-related time lags in both the European and North American environmental and legislative contexts. The durations of time lags have been found to differ according to climatic, pedological, landscape and management scenarios. Elucidation of these driving factors at a watershed scale is essential where water quality is impaired or at risk. Finally, the existence of time lags is increasingly being acknowledged at a policy level and incorporated into the development of environmental legislation. However, the full impact of these time lags is not yet fully understood or appreciated, and continued outreach and education in scientific, public and policy venues is still required.  相似文献   
34.
We measured the effects of a plant invasion (Phragmites australis) on resident fish (Fundulus heteroclitus) in New England salt marshes by assessing diet quality at the food web base and by quantifying the importance of primary producers to secondary production using a recently developed Bayesian mixing model (Stable Isotope Analysis in R, “SIAR”). Spartina alterniflora, the dominant native plant, exhibited significantly greater leaf toughness and higher C/N ratios relative to P. australis. Benthic microalgae and phytoplankton (as suspended particulate matter) exhibited the lowest C/N indicating higher diet quality. We conducted a sensitivity analysis in SIAR by modeling F. heteroclitus at three separate trophic levels (1.5, 2.0, and 2.5) using species-specific discrimination factors to determine basal resource contributions. Overall, the best-fitting models include those that assume F. heteroclitus resides approximately 2.0 trophic levels above primary producers. Using discrimination factors from a range of data sources reported in the literature, our analyses revealed that consumers rely less on benthic microalgae and phytoplankton in restricted marshes (7–23 % and 11–44 %, respectively) relative to reference marshes (5–34 % and 23–48 %, respectively), resulting in a shift in diet toward invasive plant consumption (0–27 %). This is likely due to increased P. australis cover and marsh surface shading leading to decreased microalgal biomass, combined with reduced flooding of the marsh surface that favors terrestrial invertebrate assemblages. Restoration decreased the quantity of P. australis in the food web (0–15 %) and increased the importance of microalgae (1–30 %), phytoplankton (19–48 %), and native plants (23–63 %), indicating a shift in ecological recovery toward reference conditions.  相似文献   
35.
36.
We investigated cloud properties of warm clouds in a tropical montane cloud forest at Pico del Este (1,051 m a.s.l.) in the northeastern part of Puerto Rico to address the question of whether cloud properties in the Caribbean could potentially be affected by African dust transported across the Atlantic Ocean. We analyzed data collected during 12 days in July 2011. Cloud droplet size spectra were measured using the FM-100 fog droplet spectrometer that measured droplet size distributions in the range from 2 to 49 µm, primarily during fog events. The droplet size spectra revealed a bimodal structure, with the first peak (D < 6 µm) being more pronounced in terms of droplet number concentrations, whereas the second peak (10 µm < D < 20 µm) was found to be the one relevant for total liquid water content (LWC) of the cloud. We identified three major clusters of characteristic droplet size spectra by means of hierarchical clustering. All clusters differed significantly from each other in droplet number concentration ( \(N_{\rm tot}\) ), effective diameter (ED), and median volume diameter (MVD). For the cluster comprising the largest droplets and the lowest droplet number concentrations, we found evidence of inhomogeneous mixing in the cloud. Contrastingly, the other two clusters revealed microphysical behavior, which could be expected under homogeneous mixing conditions. For those conditions, an increase in cloud condensation nuclei—e.g., from processed African dust transported to the site—is supposed to lead to an increased droplet concentration. In fact, one of these two clusters showed a clear shift of cloud droplet size spectra towards smaller droplet diameters. Since this cluster occurred during periods with strong evidence for the presence of long-range transported African dust, we hypothesize a link between the observed dust episodes and cloud characteristics in the Caribbean at our site, which is similar to the anthropogenic aerosol indirect effect.  相似文献   
37.
Explosive activity at Lathrop Wells volcano, Nevada, U.S.A. originated with weak Strombolian (WS) eruptions along a short fissure, and transitioned to violent Strombolian (VS) activity from a central vent, with lava effusion during both stages. The cause for this transition is unknown; it does not reflect a compositional change, as evidenced by the consistent bulk geochemistry of all the eruptive products. However, comparison of agglutinate samples from the early, WS events with samples of scoria from the later, VS events reveal differences in the abundance and morphology of groundmass phases and variable textures in the rims of olivine phenocrysts. Scanning electron microscope (SEM) examination of thin sections from the WS samples show euhedral magnetite microlites in the groundmass glass and olivine phenocrysts show symplectite lamellae in their rims. Secondary ion mass spectrometry (SIMS) depth profiles of these symplectites indicate they are diffusion-controlled. The calculated DFe-Mg allows an estimation of the oxygen fugacity (fO2) and indicates an increased fO2 during eruption of the WS products. Conversely, the VS samples show virtually no magnetite microlites in the groundmass glass, a lack of symplectites in the olivines, and a lower calculated fO2. These microtextural features suggest that the Lathrop Wells trachybasalt experienced increased oxidation during WS activity. As magma ascended through the original fissure, exsolved bubbles were concentrated in the wider part(s) (the protoconduit) and this bubble flux drove convective circulation that oxidized the magma through exposure to atmosphere and recirculation. This oxidation resulted in groundmass crystallization of magnetite within the melt and formation of symplectites within the olivine phenocrysts. Bubble-driven convection mixed magma vertically within the protoconduit, keeping it fluid and driving Strombolian bursts, while microlite crystallization in narrower parts of the fissure helped to focus flow. Development of a central conduit increased the magma ascent velocity (due to a greater product volume in the later eruptive stages) and caused the shift in eruption intensity. Consequently, variations in microtextures of the Lathrop Wells products reveal how a combination of fluid dynamic and crystallization processes in the ascending magma resulted in different styles of activity while the products maintained a consistent bulk composition.  相似文献   
38.
Turbulent wall pressure data acquired during tests of a full-scale experimental towed array over a range of tow speeds in straight tows and turns is presented. The experimental towed array contained a linear array of sensors mounted at the fluid–solid interface to measure the spectra of the wall pressure fluctuations due to the cylindrical turbulent boundary layer. The physics are dominated by the growth of a thick, high Reynolds number turbulent boundary layer at arc length Reynolds numbers as high as 9×108. The measured wavenumber-frequency spectra, autospectra, cross-spectral decay and convection velocities are presented. A well-defined convective ridge exists in the wavenumber-frequency spectra obtained during straight tows and turns. Turns give rise to a complicated fluid–structure interaction problem, but do not lead to the separation of the turbulent boundary layer. As the array moves through a turn, flow-induced vibrations of the array are shown to dominate the spectra at low frequencies, with more rapid decay in the measured coherence occurring at higher frequencies. The use of tow speed as a velocity scale is shown to collapse autospectra and convection velocities.  相似文献   
39.
To gain new insights into the variability of particulate organic carbon (POC) fluxes and to better understand the factors controlling the POC/234Th ratios in suspended and sinking particulate matter, we investigated the relationships between POC/234Th ratios and biochemical composition (uronic acids, URA; total carbohydrates, TCHO; acid polysaccharides, APS; and POC) of suspended and sinking matter from the Gulf of Mexico in 2005 and 2006. Our data show that URA/POC in sediment traps (STs), APS/POC in the suspended particles, and turnover times of particulate 234Th in the water column and those of bacteria in STs inside eddies usually increased with depth, whereas particulate POC/234Th (10–50 μm) and the sediment-trap parameters (POC flux, POC/234Th ratio, bacterial biomass, and bacterial production) decreased with depth. However, this trend was not the case for most biological parameters (e.g., phytoplankton and bacterial biomass) or for the other parameters at the edges of eddies or at coastal-upwelling sites.In general, the following relationships were observed: 1) 234Th/POC ratios in STs were correlated with APS flux, and these ratios in the 10–50 μm suspended particles also correlated with URA/POC ratios; 2) neither URA fluxes nor URA/POC ratios were significantly related to bacterial biomass; 3) the sum of two uronic acids (G2, glucuronic, and galacturonic acid, which composed most of the URA pool) was positively related to bacterial biomass; and 4) the POC/234Th ratios in intermediate-sized particles (10–50 μm) were close to those in sinking particles but much lower than those in > 50 μm particles. The results indicate that acid polysaccharides, though a minor fraction (~ 1%) of the organic carbon, act more likely as proxy compound classes that might contain the more refractory 234Th-binding biopolymer, rather than acting as the original 234Th “scavenger” compound. Moreover, these acid polysaccharides, which might first be produced by phytoplankton and then modified by bacteria, also influence the on-and-off “piggy-back” processes of organic matter and 234Th, thus causing additional variability of the POC/234Th in particles of different sizes.  相似文献   
40.
Seagrasses are clonal plants that grow submerged in dynamic sedimentary environments where burial is a common occurrence. Clonal organisms may respond to burial in very different ways depending on how strongly integrated they are through horizontal rhizomes, but the effect of clonal integration under conditions of stress such as burial is poorly studied for seagrasses. We test the effect of burial on tropical seagrasses that occur in multispecific meadows by subjecting plants in mixed stands to burial of 0, 2, 4, 8 and 16 cm for 27 days. Treatments were divided into those where rhizomes were severed and those where rhizomes were left intact. We hypothesize that species withstand burial better if clonal integration is maintained (intact rhizomes). Results showed that all species tolerated burial of up to 4 cm without adverse effects but significant reductions in shoot density and biomass become evident at 8 cm of burial. Furthermore, Cymodocea serrulata and Syringodium isoetifolium were strong integrators, i.e. they provide support for buried shoots, whereas Halophila ovalis and Halodule uninervis were weak integrators that did not show evidence of subsidizing buried shoots. Vertical elongation was observed for C. serrulata and H. uninervis as a response to burial only when rhizomes were severed, leading us to speculate on whether species rely on vertical elongation as an escape strategy only in the absence of resource translocation. Our distinction between the responses of treatments with intact rhizomes from those with severed rhizomes may be extended to an interpretation of burial scale (intact rhizomes=broad spatial?scale burial; severed rhizomes=fine spatial?scale burial). We concluded that broad spatial?scale burial exceeding 4 cm leads to rapid loss or reduction of all species. However, fine spatial–scale burial exceeding 4 cm, such as those caused by shrimp mounds (bioturbation), is expected to favor C. serrulata and S. isoetifolium, while H. ovalis and H. uninervis are disadvantaged. Clonal integration is an important trait in moderating the response of seagrasses to sediment burial and in this way, helps them to cope in high-stress habitats.  相似文献   
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