An approach to determination of phenolic compounds in seawater using SPME-GC-MS based on SWCNTs coating   总被引：1，自引：0，他引：1  

ZHU Jia  WANG Ying  ZENG Lin 《中国海洋大学学报(英文版)》2016,15(4):655-659

Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of connections, with many unusual mechanical, chemical and electrical properties. In recent years, with the research of carbon nanotubes and other nano materials, the application prospect is also constantly discussed. In this paper, homemade single-walled carbon nanotubes(SWCNTs) coating was used for establishing an analytical approach to the determination of five kinds of phenolic compounds in seawater using SPME-GC-MS. Optimal conditions: After saturation was conducted with Na Cl, and p H was adjusted to 2.0 with H_2SO_4, the extract was immersed in a water bath at 40 for GC℃-MS determination through 40-min agitating extraction at 500 rmin~(-1) and 3-min desorption at 280℃. The liniearities ranged between 0.01-100 μg L~(-1), and the determination limits ranged between 1.5-10 ngL~(-1). The relative standard deviation(RSD, n = 5) was less than 6.5%. For the phenolic compounds obtained from the spiked recovery test for actual seawater samples, the rates of recovery were 87.5%-101.7%, and the RSDs were less than 8.8%, which met the requirements of determination. Due to its simplicity, high efficiency and low consumption, this approach is suitable for the analysis of trace amounts of phenolic compounds in marine waters.  相似文献   

中国省际人口迁移的多边效应机制分析   总被引：12，自引：6，他引：6  

蒲英霞  韩洪凌  葛莹  孔繁花 《地理学报》2016,71(2):205-176

区际人口迁移不仅与迁出地和目的地的要素特征以及距离有关,而且还受到周边迁移流的影响.基于网络自相关理论,利用"六普"省际人口迁移数据和相关统计资料,在重力模型的基础上考虑迁移流之间可能存在的几种空间依赖形式,构建中国省际迁移流的空间OD模型,初步揭示区域经济社会等因素及其空间溢出效应对省际人口迁移的影响,并就区域要素变化对整个省际人口迁移系统产生的"连锁反应"进行了模拟.结果表明:① 中国省际迁移流之间存在显著的网络自相关效应.目的地和迁出地的自相关效应皆为正,导致迁入和迁出流的空间效仿行为;迁出地和目的地周边则出现负的自相关效应,导致迁移流的空间竞争行为;② 区域经济社会等因素通过网络空间关系对周边地区产生的多边溢出效应导致迁移流在空间上集聚.其中,距离衰减效应位居各要素之首,其溢出效应进一步加剧距离的摩擦作用;对目的地而言,区域工资水平和迁移存量超过GDP的影响并产生正的溢出效应,促进周边地区吸引更多的外来人口;对迁出地而言,人口规模和迁移存量产生正的溢出效应,推动周边地区人口外迁;③ 区域要素变化潜在地对整个省际人口迁移系统产生一系列"连锁反应",震荡中心及其周边区域的迁移流波动较大.江苏省GDP增长5%的模拟结果表明,江苏迁往全国其他省份的人口数量都有不同程度地减少,而其他省份入迁人口均有所增加.相对而言,江苏周边省份的迁入或迁出流受到的波动较大,偏远省份波及较小,这是传统的重力模型所无法解释的.  相似文献   

新疆东准乌须克劳格岩体LA-ICP-MS锆石U-Pb年龄、Hf同位素特征及其地质意义     

李高峰  孟贵祥  吴建  姜彦勇  雷印祥  童英 《地质通报》2016,35(7):1170-1183

新疆东准噶尔琼河坝地区近年来找矿获得重大突破,发现了一系列重要的矿产,这些矿产基本上围绕该地区出露面积最大的乌须克劳格岩体分布。该岩体组成比较复杂,主要岩性为二长花岗岩和花岗闪长岩。采用LA-ICP-MS技术测得花岗闪长岩和二长花岗岩锆石~(206)Pb/~(238)U年龄分别为428.9±1.9Ma和427.2±1.7Ma,被解释为岩石的结晶年龄。2类岩石都属于过铝质-钙碱性系列花岗岩,具有较高的铝、钙含量,K_2O/Na_2O值普遍偏低,介于0.15~0.40之间;稀土元素配分曲线呈现右倾特征,稀土元素总量较低,轻稀土元素相对富集,负Eu异常不明显;在微量元素原始地幔标准化蛛网图上,高场强元素Th、Nb、Ta、P、Ti等相对亏损,大离子亲石元素Rb、Ba、U、K、Sr等相对富集,具有高Ba、Sr含量和高(La/Yb)_N、Sr/Y值,显示出高Ba-Sr花岗岩的特征;同时岩体具有高正ε_(Hf)(t)值和年轻的模式年龄。这些地球化学和同位素特征表明,晚志留世乌须克劳格岩体是大陆边缘弧环境下大洋板片熔融的产物。  相似文献   

专题地质填图及有关问题讨论   总被引：2，自引：1，他引：1  

王涛  计文化  胡建民  李建星  胡道功  童英 《地质通报》2016,35(5):633-641

面积性地质调查及填图是今后地质调查的主要工作,如何做好这个工作,并实现地质调查和科研一体化,特别是在已有填图基础上,如何部署和开展新的填图工作,是一个亟待回答的新问题。专题地质填图是针对存在的重要地质或资源、环境问题,或是针对特定目标地质体等,以解决特定问题或满足社会特定需求为主要目的、填图与研究融为一体的地质填图,填图的范围和比例尺依据解决问题和目标地质体而定。专题地质填图是以问题和需求为驱动,是对已有的综合地质填图的补充和提高,是高效实现地调科研一体化的一种方式。论述了专题填图的内涵、必要性,以及开展专题填图的方式和方法。  相似文献   

Identifications of aquifer group classification by using environmental isotope and hydrogeochemistry method: a case study of Huabei plain,China     

Jiang Chen  Ying Wang  Zongyu Chen 《Environmental Earth Sciences》2016,75(19):1314

  相似文献   

Characteristics of deuterium excess parameters for geothermal water in Beijing     

Kai Liu  Xiaojuan Qiao  Baoling Li  Ying Sun  Zhiping Li  Conglin Pu 《Environmental Earth Sciences》2016,75(23):1485

This study investigates the characteristics of geothermal water in 10 geothermal fields in Beijing. The relationships between the deuterium excess parameter (d) and temperature, depth, age of geothermal groundwater, groundwater flow field, and Eh were investigated using geothermal groundwater samples. Results showed that (1) the average d value of geothermal water is 5.4, whereas that of the groundwater in normal temperature is 6.04. The differences are induced by the oxygen isotope exchange during the water–rock interaction, which may be more easily completed in geothermal water than in cold groundwater. (2) The d value increases remarkably with the age of the geothermal groundwater. The d value increases from 11.2 to 14.6 when the age of the geothermal water is 12,760 ± 130 a and 38,960 ± 630 a, respectively. Moreover, the isotope heat exchange for composition of the hydrogen and oxygen isotopes in the geothermal groundwater proceeds sufficiently with time. (3) The d value decreases from 5.72 to 3.03 when the depth increases from 125.13 to 3221 m. Generally, in the same area, the d value decreases with depth because the temperature is increasing. (4) The d value of the groundwater gradually reduces from the northern recharge area to the southern discharge area. The average d value is 7.31 in the northern recharge area and 5.68 in the middle Beijing Depression, whereas the d value in the southern area of Fengheying is ?9.20. The larger difference in d values between the recharge and discharge areas is due to the slower velocity of underwater flow, which induces longer time for oxygen exchange. (5) The relationship between the d and Eh is complex. When Eh is <200 mV, the d value of the geothermal water decreases with the decrease in Eh. When Eh is higher than 200 mV, the d value increases slightly with the decrease in Eh. The study of the characteristics of deuterium excess parameters for geothermal water could provide a scientific isotopic evidence for assessment and exploitation measures in geothermal groundwater systems.  相似文献   

Numerical Analysis of Gravity Coring Using Coupled Eulerian-Lagrangian Method and a New Corer     

Huawei Qin  Zhen Cai  Jianjun Wang  Wei Ye  Ying Chen 《Marine Georesources & Geotechnology》2016,34(5):403-408

The shortcomings of gravity corers in sampling marine sediments have been observed extensively in various field tests. In order to optimize the coring, this article provides an alternative numerical way to model the gravity coring and analyze the sampling effect. Based on this analysis, a new hydraulic hammer corer is devised. A coupled Eulerian-Lagrangian method with capability of simulating the problem involving extreme deformation, penetration is used to simulate the coring process. The results show that the hydrostatic pressure and deviator stress increase and reach their peak when the pile tip is slightly above or at the level of the observation point and then drop rapidly when the pile tip slides below the observation point. In addition, the stress path indicates that the soil element sustains plastic compression before yielding and then expands until recovering to the original state. The obvious “under-sampling” phenomenon is also well-captured by the finite element model.  相似文献   

Antioxidant system responses in two co-occurring green-tide algae under stress conditions     

王影  赵新宇  唐学玺 《中国海洋湖沼学报》2016,34(1):102-108

Green tides have occurred every year from 2007 to 2014 in the Yellow Sea. Ulva prolifera(Müller) J. Agardh has been identified as the bloom-forming alga,co-occurring with U. intestinalis. We observed distinct strategies for both algal species during green tides. U. prolifera exhibited a high abundance initially and then decreased dramatically,while U. intestinalis persisted throughout. The antioxidant system responses of these two macroalgae were compared in the late phase of a green tide(in-situ) and after laboratory acclimation. Lipid peroxidation and antioxidant system responses differed significantly between the two. Malondialdehyde and hydrogen peroxide contents increased significantly in-situ in U. prolifera,but not in U. intestinalis. In U. prolifera,we observed a significant decrease in total antioxidant ability(T-AOC),antioxidant enzymes(SOD and Apx),and non-enzyme antioxidants(GSH and As A) in-situ. U. intestinalis showed the same pattern of T-AOC and SOD,but its Gpx,Apx,and GSH responses did not differ significantly. The results suggest that U. prolifera was more susceptible than U. intestinalis to the harsh environmental changes during the late phase of a Yellow Sea green tide. The boom and bust strategy exhibited by U. prolifera and the persistence of U. intestinalis can be explained by differences in enzyme activity and antioxidant systems.  相似文献   

岷江上游槽谷曲流段大型古滑坡成因与复活性分析——以松潘县元坝子古滑坡为例   总被引：1，自引：1，他引：0       下载免费PDF全文

魏昌利  张瑛  冯文凯  杨志华  陈亮 《水文地质工程地质》2018,(6):141-141

岷江上游靠近分水岭部位的槽谷曲流河段,由于地壳抬升缓慢,河谷宽、岸坡缓,降雨量相对偏少,通常被认为发生大型滑坡的可能性较小。但通过笔者近年来的调查发现,在岷江上游红桥关至西宁关的槽谷曲流段两岸大型滑坡密集发育,且大多具有地震滑坡的特征,同时个别滑坡受后期江水冲刷、工程开挖等因素影响复活。文章选取其中较为典型的元坝子滑坡为例进行解剖,元坝子滑坡位于岷江曲流凹岸,长780 m,宽480 m,体积293×104 m3。通过地质分析、测年鉴定和数值模拟,认为该滑坡是历史地震引发的大型岩质古滑坡,其发展经历了斜坡裂缝、地震滑坡、河流下切和前缘复活等阶段。稳定性计算结果显示,目前滑坡整体天然工况下稳定性好,极端暴雨工况下欠稳定,受江水冲刷、降雨、融雪等因素影响,出现局部变形复活。建议应加强滑坡变形监测,避免整体滑动造成堵江、威胁成兰铁路安全。  相似文献   

FLAC3D在边坡数值分析及位移监测中应用     

张颖  孙兆涛  裴仲文 《探矿工程》2018,45(3):57-61

以辽宁省岫岩县某山头边坡为例,通过槽探、钻探、大型剪切试验等多种手段,找出合理潜在滑动面。利用FLAC3D软件对该边坡进行三维数值模拟,分析应力应变关系,得出变形较大及应力集中区域,同时利用强度折减法得出边坡的安全系数,评价其稳定性。将从边坡后缘张拉裂隙上布设的位移监测点采集到的数据,与数值模拟结果进行对比分析,验证数值模拟的可靠性,为边坡抗滑设计提供依据。  相似文献