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71.
“Buffer capacities” has been defined in ecology as a holistic concept (e.g., Integration of Ecosystem Theories: A Pattern, second ed. Kluwer, Dordrecht, 1997, 388pp), but we show that it can also be worked out in mechanistic studies. Our mechanistic approach highlights that “buffering capacities” can be depleted progressively, and, therefore, we make a distinction between current and potential “buffering capacities”. We have applied this concept to understand the limited “local stability” in seagrass ecosystems and their vulnerability towards structural changes into macro-algal dominated communities. We explored the following processes and studied how they confer buffering capacities to the seagrass ecosystem: (i) net autotrophy is persistent in Zostera noltii meadows where plant assimilation acts as a sink for nutrients, this contrasted with the Ulva system that shifted back and forth between net autotrophy and net heterotrophy; (ii) the Z. noltii ecosystem possesses a certain albeit rather limited capacity to modify the balance between nitrogen fixation and denitrification, i.e., it was found that in situ nitrogen fixation always exceeded denitrification; (iii) the nitrogen demand of organoheterotrophic bacteria in the sediment results in nitrogen retention of N in the sediment and hence a buffer against release of nitrogen compounds from sediments, (iv) habitat diversification in seagrass meadows provides shelter for meiofauna and hence buffering against adverse conditions, (v) sedimentary iron provides a buffer against noxious sulfide (note: bacterial sulfide production is enhanced in anoxic sediment niches by increased organic matter loading). On the other hand, in the coastal system we studied, sedimentary iron appears less important as a redox-coupled buffer system against phosphate loading. This is because most inorganic phosphate is bound to calcium rather than to iron. In addition, our studies have highlighted the importance of plant–microbe interactions in the seagrass meadows.  相似文献   
72.
Females of Donax trunculus L. show higher concentrations of Mn and Zn than males. Differences are very high for Mn which also shows very large monthly fluctuations. Both the metals present higher contents during the period of gonadic maturation. Some high values of manganese found in the period when gonads are resting suggest the influence of sharp environmental variations in the area where bivalves have been collected.  相似文献   
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74.
Thin levels of amphibolites from the Canigou, Albères and Cap de Creus massifs have been studied in order to investigate their pressure and temperature evolution during time. P and T values have been calculated using the amphibole–plagioclase–quartz thermo-barometer. Si, Al, Mg and Fe of zoned amphiboles have been analysed from core to rim by microprobe. By combining the results obtained from several (or different) crystals, PTt paths have been determined using the amphibole-plagioclase-quartz equilibriums. In the Canigou Massif, the amphibolites have recorded anti-clockwise PTt paths around a peak of metamorphism located at about 650?°C–6.1 kbar, whereas in the Albères Massif, the calculated PTt paths of amphibolites near the paragneisses are retrograde only, from 600?°C–5 kbar to 450?°C–2.5 kbar, but one cummingtonite-bearing amphibolite has also recorded an anti-clockwise evolution around 650?°C–4.5 kbar. The retrograde PTt paths recorded for amphibolites from the ‘Cap de Creus’ Massif are retrograde only, from 650?°C–6 kbar and 400?°C–1 kbar. To cite this article: C. Triboulet et al., C. R. Geoscience 337 (2005).  相似文献   
75.
We present a model of the subducting Cocos slab beneath Central Mexico, that provides an explanation for stresses causing the occurrence of the majority of the intraslab earthquakes which are concentrated in a long flat segment. Based on the recently developed thermal models for the Central Mexico subduction zone, the thermal stresses due to non-uniform temperature contrast in the subducting slab are calculated using a finite element approach. The slab is considered purely elastic but due to high temperature at its bottom the behavior is considered as ductile creep. The calculation results show a  20 km slab core characterized by a tensional state of stress with stresses up to 70 MPa. On the other hand, the top of the slab experiences high compressive thermal stresses up to 110 MPa, depending on the elastic constants used and location along the flat part of the subducting plate. These compressive stresses at the top of the slab are not consistent with the exclusive normal fault intraslab earthquakes, and two different sources of stress are proposed.

The trenchward migration of the Mexican volcanic arc for the last 7 Ma indicates an increase of the slab dip through time. This observation suggests that the gravity torque might exceed the suction torque. Considering the flat slab as an embedded plate subject to an applied clockwise net torque of 0.5 × 1016–1.5 × 1016 N m, the upper half would exhibit tensional stresses of 40–110 MPa that can actually balance the compressive thermally induced stresses.

An alternative stress source might come from the slab pull force caused by the slab positive density anomaly. Based on our density anomaly estimations (75 ± 20 kg/m3), a 350 km slab length, dipping at 20° into the asthenosphere, induces a slab pull force of 1.7 × 1012–4.6 × 1012 N m. This force produces a tensional stress of 41–114 MPa, sufficient to balance the compressive thermal stresses at the top of the flat slab.

The linear superposition of the thermally and torque or slab pull induced stresses shows tensile stresses up to 60–180 MPa inside the flat slab core. Also, our results suggest that the majority of the intraslab earthquakes inside the flat slab are situated where the resultant stresses are larger than 40–80 MPa.

This study provides a reasonable explanation for the existence of exclusively normal fault intraslab earthquakes in the flat slab beneath Central Mexico, and also it shows that thermal stresses due to non-uniform reheating of subducting slabs play a considerable role in the total stress field.  相似文献   

76.
The distribution of gold in high-temperature fumarole gases of the Kudryavy volcano (Kurile Islands) was measured for gas, gas condensate, natural fumarolic sublimates, and precipitates in silica tubes from vents with outlet temperatures ranging from 380 to 870°C. Gold abundance in condensates ranges from 0.3 to 2.4 ppb, which is significantly lower than the abundances of transition metals. Gold contents in zoned precipitates from silica tubes increase gradually with a decrease in temperature to a maximum of 8 ppm in the oxychloride zone at a temperature of approximately 300°C. Total Au content in moderate-temperature sulfide and oxychloride zones is mainly a result of Au inclusions in the abundant Fe–Cu and Zn sulfide minerals as determined by instrumental neutron activation analysis. Most Au occurs as a Cu–Au–Ag triple alloy. Single grains of native gold and binary Au–Ag alloys were also identified among sublimates, but aggregates and crystals of Cu–Au–Ag alloy were found in all fumarolic fields, both in silica tube precipitates and in natural fumarolic crusts. Although the Au triple alloy is homogeneous on the scale of microns and has a composition close to (Cu,Ni,Zn)3(Au,Ag)2, transmission electron microscopy (TEM) shows that these alloy solid solutions consist of monocrystal domains of Au–Ag, Au–Cu, and possibly Cu2O. Gold occurs in oxide assemblages due to the decomposition of its halogenide complexes under high-temperature conditions (650–870°C). In lower temperature zones (<650°C), Au behavior is related to sulfur compounds whose evolution is strongly controlled by redox state. Other minerals that formed from gas transport and precipitation at Kudryavy volcano include garnet, aegirine, diopside, magnetite, anhydrite, molybdenite, multivalent molybdenum oxides (molybdite, tugarinovite, and ilsemannite), powellite, scheelite, wolframite, Na–K chlorides, pyrrhotite, wurtzite, greenockite, pyrite, galena, cubanite, rare native metals (including Fe, Cr, Mo, Sn, Ag, and Al), Cu–Zn–Fe–In sulfides, In-bearing Pb–Bi sulfosalts, cannizzarite, rheniite, cadmoindite, and kudriavite. Although most of these minerals are fine-grained, they are strongly idiomorphic with textures such as gas channels and lamellar, banded, skeletal, and dendrite-like crystals, characteristic of precipitation from a gas phase. The identified textures and mineral assemblages at Kudryavy volcano can be used to interpret geochemical origins of both ancient and modern ore deposits, particularly gold-rich porphyry and related epithermal systems.  相似文献   
77.
78.
The 8-10 May 1997 eruption of Bezymianny volcano began with extrusion of a crystallized plug from the vent in the upper part of the dome. Progressive gravitational collapses of the plug caused decompression of highly crystalline magma in the upper conduit, leading at 13:12 local time on 9 May to a powerful, vertical Vulcanian explosion. The dense pyroclastic mixture collapsed in boil-over style to generate a pyroclastic surge which was focused toward the southeast by the steep-walled, 1956 horseshoe-shaped crater. This surge, with a temperature <200 °C, covered an elliptical area >30 km2 with deposits as much as 30 cm thick and extending 7 km from the vent. The surge deposits comprised massive to vaguely laminated, gravelly sand (Md -1.2 to 3.7J sorting 1.2 to 3J) of poorly vesiculated andesite (mean density 1.82 g cm-3; vesicularity 30 vol%; SiO2 content ~58.0 wt%). The deposits, with a volume of 5-15᎒6 m3, became finer grained and better sorted with distance; the maximal diameter of juvenile clasts decreased from 46 to 4 cm. The transport and deposition of the surge over a snowy landscape generated extensive lahars which traveled >30 km. Immediately following the surge, semi-vesiculated block-and-ash flows were emplaced as far as 4.7 km from the vent. Over time the juvenile lava in clasts of these flows became progressively less crystallized, apparently more silicic (59.0 to 59.9 wt% SiO2) and more vesiculated (density 1.64 to 1.12 g cm-3; vesicularity 37 to 57 vol%). At this stage the eruption showed transitional behavior, with mass divided between collapsing fountain and buoyant column. The youngest pumice-and-ash flows were accompanied by a sustained sub-Plinian eruption column ~14 km high, from which platy fallout clasts were deposited (~59.7% SiO2; density 1.09 g cm-3; vesicularity 58 vol%). The explosive activity lasted about 37 min and produced a total of ~0.026 km3 dense rock equivalent of magma, with an average discharge of ~1.2᎒4 m3 s-1. A lava flow ~200 m long terminated the eruption. The evolutionary succession of different eruptive styles during the explosive eruption was caused by vertical gradients in crystallization and volatile content of the conduit magma, which produced significant changes in the properties of the erupting mixture.  相似文献   
79.
80.
Shales play an important role in many engineering applications such as nuclear waste, CO2 storage and oil or gas production. Shales are often utilized as an impermeable seal or an unconventional reservoir. For both situations, shales are often studied using seismic waves. Elastic properties of shales strongly depend on their hydration, which can lead to substantial structural changes. Thus, in order to explore shaly formations with seismic methods, it is necessary to understand the dependency of shale elastic properties on variations in hydration. In this work, we investigate structural changes in Opalinus shale at different hydration states using laboratory measurements and X-ray micro-computed tomography. We show that the shale swells with hydration and shrinks with drying with no visible damage. The pore space of the shale deforms, exhibiting a reduction in the total porosity with drying and an increase in the total porosity with hydration. We study the elastic properties of the shale at different hydration states using ultrasonic velocities measurements. The elastic moduli of the shale show substantial changes with variations in hydration, which cannot be explained with a single driving mechanism. We suggest that changes of the elastic moduli with variations in hydration are driven by multiple competing factors: (1) variations in total porosity, (2) substitution of pore-filling fluid, (3) change in stiffness of contacts between clay particles and (4) chemical hardening/softening of clay particles. We qualitatively and quantitatively analyse and discuss the influence of each of these factors on the elastic moduli. We conclude that depending on the microstructure and composition of a particular shale, some of the factors dominate over the others, resulting in different dependencies of the elastic moduli on hydration.  相似文献   
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