where k (M− 2 s− 1) can be determined from the
in the pH range 2 to 5, from 5 to 40 °C and 0.01 to 1 M.The effect of pH and ionic strength on the reaction suggest that the rates are due to
where H2A = H2CrO4, HA = HCrO4, H2B = H2SO3 and HB = HSO3. The overall rate expression over the investigated pH range can be determined from
k=kH2A–H2B(αH2A)(αH2B)2+kHA–H2B(αHA)(αH2B)2+kH2A–HB(αH2A)(αHB)2
with kH2A−H2B = 5.0 × 107, kHA–H2B = 1.5 × 106 and kH2A–HB = 6.7 × 107.Fe(III) in the range 1.5 to 20 μM exerts a small catalytic effect on the reaction and significantly lowers the initial concentration of Cr(VI) compared to the nominal value. Contrary to Fe(III), formaldehyde (20 to 200 μM) reacts with S(IV) to form the hydroxymethanesulfonate adduct (CH2OHSO3), which does not react with Cr(VI). Major cations Mg2+ and some minor elements such as Ba2+ and Cu2+ did not affect the rates. The application of this rate law to environmental conditions suggest that this reaction may have a role in acidic solutions (aerosols and fog droplets). This reaction becomes more important in the presence of high Fe(III) and low HMS concentrations, contributing to affect the atmospheric transport of chromium species and the distribution of redox species of chromium, which reach surface water from atmospheric depositions.  相似文献   
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41.
Multiridge Euler deconvolution   总被引:1,自引:0,他引:1  
Potential field interpretation can be carried out using multiscale methods. This class of methods analyses a multiscale data set, which is built by upward continuation of the original data to a number of altitudes conveniently chosen. Euler deconvolution can be cast into this multiscale environment by analysing data along ridges of potential fields, e.g., at those points along lines across scales where the field or its horizontal or vertical derivative respectively is zero. Previous work has shown that Euler equations are notably simplified along any of these ridges. Since a given anomaly may generate one or more ridges we describe in this paper how Euler deconvolution may be used to jointly invert data along all of them, so performing a multiridge Euler deconvolution. The method enjoys the stable and high‐resolution properties of multiscale methods, due to the composite upward continuation/vertical differentiation filter used. Such a physically‐based field transformation can have a positive effect on reducing both high‐wavenumber noise and interference or regional field effects. Multiridge Euler deconvolution can also be applied to the modulus of an analytic signal, gravity/magnetic gradient tensor components or Hilbert transform components. The advantages of using multiridge Euler deconvolution compared to single ridge Euler deconvolution include improved solution clustering, increased number of solutions, improvement of accuracy of the results obtainable from some types of ridges and greater ease in the selection of ridges to invert. The multiscale approach is particularly well suited to deal with non‐ideal sources. In these cases, our strategy is to find the optimal combination of upward continuation altitude range and data differentiation order, such that the field could be sensed as approximately homogeneous and then characterized by a structural index close to an integer value. This allows us to estimate depths related to the top or the centre of the structure.  相似文献   
42.
This paper investigates the dynamic behavior and the seismic effectiveness of a non‐conventional Tuned Mass Damper (TMD) with large mass ratio. Compared with conventional TMD, the device mass is increased up to be comparable with the mass of the structure to be protected, aiming at a better control performance. In order to avoid the introduction of an excessive additional weight, masses already present on the structure are converted into tuned masses, retaining structural or architectural functions beyond the mere control function. A reduced order model is introduced for design purposes and the optimal design of a large mass ratio TMD for seismic applications is then formulated. The design method is specifically developed to implement High‐Damping Rubber Bearings (HDRB) to connect the device mass to the main structure, taking advantage of combining stiffness and noticeable damping characteristics. Ground acceleration is modeled as a Gaussian random process with white noise power spectral density. A numerical searching technique is used to obtain the optimal design parameter, the frequency ratio alpha, which minimizes the root‐mean‐square displacement response of the main structure. The study finally comprises shaking table tests on a 1:5 scale model under a wide selection of accelerograms, both artificial and natural, to assess the seismic effectiveness of the proposed large mass ratio TMD. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
43.
Mineralogy and Petrology - Limestone represents the main raw material for ordinary Portland cement clinker production. In this study eight natural limestones from different geological environments...  相似文献   
44.
A 1-D General Ocean Turbulence Model that includes the effects of sediment-induced stratification is shown to simulate the observed onshore and offshore migration of a nearshore sandbar. The only two free parameters of the model, the bed reference concentration and the sediment diffusivity, are taken from the literature, rather than tuned to the data used here. The model results suggest that predictions of onshore bar migration, in which wave-induced sediment transport confined to within a few centimeters of the bottom dominates, are not greatly affected by accounting for buoyancy effects. The model results also suggest that both mean flows and waves transport sediment during offshore bar migration, with different components of transport dominating at different cross-shore locations across the bar-trough bathymetry. Neglecting the effects of sediment-induced stratification results in higher model skill during the largest waves, likely because the excess turbulence production simulated by the non-stratified model is counterbalanced by neglected breaking-wave-generated turbulence. Considering both onshore and offshore migration, the model that includes sediment-induced stratification has higher skill than the model without stratification.  相似文献   
45.
The Irpinia Seismic Network (ISNet) is deployed in Southern Apennines along the active fault system responsible for the 1980, November 23, M s 6.9 Campania–Lucania earthquake. It is set up by 28 stations and covers an area of about 100 × 70 km2. Each site is equipped with a 1-g full-scale accelerometer and a short-period velocimeter. Due to its design characteristics, i.e., the wide dynamic range and the high density of stations, the ISNet network is mainly devoted to estimating in real-time the earthquake location and magnitude from low- to high- magnitude events, and to providing ground-motion parameters values so to get some insights about the ground shaking expected. Moreover, the availability of high-quality of data allows studying the source processes related to the seismogenetic structures in the area. The network layout, the data communication system and protocols and the main instrumental features are described in the paper. The data analysis is managed by Earthworm software package that also provides the earthquake location while custom software has been developed for real-time computation of the source parameters and shaking maps. Technical details about these procedures are given in the article. The data collected at the ISNet stations are available upon request.  相似文献   
46.
A set of raw industrial materials, that is, pure quartz and quartz-rich mixtures, were investigated through electron paramagnetic resonance and electron spin echo-envelope modulation spectroscopies, with the aim of evaluating the effective role played by defect centres and of assessing whether they can be used to monitor changes in the physical properties of quartz powders with reference to their health effects. The obtained results point to two interactions of the Al defect centres with H+, hosted in sites within the channels parallel and perpendicular to the c axis of quartz, respectively. These two Al/H+ (hAl) centres exhibit a weak chemical bond, and their relative amounts appear to be modified/controlled by the thermo-mechanical processes underwent by powders. Indeed, a mechanically promoted inter-conversion between the two kinds of site is suggested. As a consequence, the hAl centres are effective in monitoring even modest activations of powders, through thermal or mechanical processes, and they are also supposed to play a specific, relevant role in quartz reactivity during the considered industrial processes.  相似文献   
47.
An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu3SnS4, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu3SnS4 crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)2Cu(II)SnS4 and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites.  相似文献   
48.
Geotechnical characterization of a landslide in a Blue Clay slope   总被引:1,自引:1,他引:0  
This paper describes the results of an experimental, as well as theoretical, analysis of a landslide in a clay slope at the margin of a small town of Southern Italy, whose reactivation of 1998 caused severe damages to some structures. To protect the upslope urban area, an anchored diaphragm wall and a drainage system were constructed in 2001. In the meantime, in order to understand the processes which caused the reactivation, a Department of the Basilicata Administrative Region provided financial support to a geotechnical investigation. Laboratory tests on undisturbed and reconstituted specimens, in situ pore pressure and deep displacement measurements were carried out. Both experimental and theoretical in situ water content (and porosity) profiles were determined. Theoretical analyses of pore pressure distribution and stability analyses were carried out. The influence of the drainage system on the slope safety factor was evaluated. Experimental and theoretical data suggest that a first time process occurred in the lower part of the landslide system. The upper part moved on pre-existing surfaces on which an average shear strength close to the residual strength was available. Noticeable water content increase was found around some of these surfaces. Erosion at the toe of the landslide was the probable cause of reactivation. The analysis of the drain system effectiveness suggests that drainage has not significantly influenced pore pressures on the considered slip surfaces yet, mainly because of the very low permeability of the clay.  相似文献   
49.
 The study proposes a model by which a thick succession of volcanic tuffs can be zeolitized by alteration of pyroclastic material in the presence of sufficient eruptive water and at temperatures close to water vapour condensation. In the case of phreatomagmatic products, the model simplifies interpretation of problematic deposits that exhibit pronounced vertical and lateral variation in lithification grade. A major feature of the model is that thick zeolitized tuffs can be formed during emplacement of pyroclastic products, in marked contrast to later alteration in an open hydrologic system. Geological, volcanological and mineralogical data for the Neapolitan Yellow Tuff, a widespread trachytic pyroclastic deposit outcropping around Campi Flegrei (Southern Italy), have been used to infer the physico-chemical conditions that determined mineral genesis. This tuff shows a reduction in lithification grade towards the base, top and with distance from the vent and very variable zeolitization within the lithified portion. We suggest that during initial emplacement the erupted products chilled against the ground, inhibiting zeolite crystallization. During rapid deposition of the thick, wet succession thermal insulation allowed the persistence of elevated temperatures for a time sufficient for enhancement of hydration-dissolution processes in the volcanic glass. The highly reactive alkali-trachytic glass quickly buffered the acid pH of the system, favouring phillipsite crystallization followed by chabazite nucleation. The variable zeolite content reflects fluctuating emplacement conditions (e.g. changes in water content and temperature). Cooling of the upper and relatively thin distal deposits inhibited the zeolitization process, thereby preserving the primary unlithified deposit. Received: 25 May 1999 / Accepted: 28 October 1999  相似文献   
50.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2
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