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81.
82.
Covered by ultrabasic units for more than a third of its surface,the New Caledonia(South West Pacific)is one of the largest world producers of Ni-ore from lateritic deposits.Almost all outcrops of geological units and open mines contain serpentine and amphibole,also as asbestos varieties.In this geological context,in which weathering processes had a great contribution in the production and dispersion of mineral fibres into the environment,the development of a routinely analytical strategy,able to discriminate an asbestiform fibre from a non-harmful particle,is a pivotal requisite.However,the acquisition of all these parameters is necessary for determining the risk associated to fibres exposition.A multidisciplinary routinely approach,based on the use of complementary simply-to-use but reliable analytical methods is the only possible strategy.In addition,the instrumental apparatus must be easily transportable on the field,directly on the mining site.The employment of specialized tools such as Polarized Light Microscopy associated to Dispersion Staining method(PLM/DS)and portable Raman spectroscopy for identification of environmental asbestos,are proved extremely effective in the improvement of the performance and rapidity of data acquisition and interpretation.Both PLM/DS and handheld Raman devices confirmed to be discriminant in the detection and characterization of asbestos fibres for both serpentine and amphibole.Furthermore,these techniques proved extremely effective even in the presence of strongly fibrous and altered samples.  相似文献   
83.
Analyzing the heterogeneity in metropolitan areas of India utilizing remote sensing data can help to identify more precise patterns of sub-standard residential areas. Earlier work analyzing inequalities in Indian cities employed a constructed index of multiple deprivations (IMDs) utilizing data from the Census of India 2001 (http://censusindia.gov.in). While that index, described in an earlier paper, provided a first approach to identify heterogeneity at the citywide scale, it neither provided information on spatial variations within the geographical boundaries of the Census database, nor about physical characteristics, such as green spaces and the variation in housing density and quality. In this article, we analyze whether different types of sub-standard residential areas can be identified through remote sensing data, combined, where relevant, with ground-truthing and local knowledge. The specific questions address: (1) the extent to which types of residential sub-standard areas can be drawn from remote sensing data, based on patterns of green space, structure of layout, density of built-up areas, size of buildings and other site characteristics; (2) the spatial diversity of these residential types for selected electoral wards; and (3) the correlation between different types of sub-standard residential areas and the results of the index of multiple deprivations utilized at electoral ward level found previously.  相似文献   
84.
Ten-month time series of mean volume backscattering strength (MVBS) and vertical velocity obtained from three moored acoustic Doppler current profilers (ADCPs) deployed from February until December 2005 at 64°S, 66.5°S and 69°S along the Greenwich Meridian were used to analyse the diel vertical zooplankton migration (DVM) and its seasonality and regional variability in the Lazarev Sea. The estimated MVBS exhibited distinct patterns of DVM at all three mooring sites. Between February and October, the timing of the DVM and the residence time of zooplankton at depth were clearly governed by the day–night rhythm. Mean daily cycles of the ADCP-derived vertical velocity were calculated for successive months and showed maximum ascent and descent velocities of 16 and –15 mm s?1. However, a change of the MVBS pattern occurred in late spring/early austral summer (October/November), when the zooplankton communities ceased their synchronous vertical migration at all three mooring sites. Elevated MVBS values were then concentrated in the uppermost layers (<50 m) at 66.5°S. This period coincided with the decay of sea ice coverage at 64°S and 66.5°S between early November and mid-December. Elevated chlorophyll concentrations, which were measured at the end of the deployment, extended from 67°S to 65°S and indicated a phytoplankton bloom in the upper 50 m. Thus, we propose that the increased food supply associated with an ice edge bloom caused the zooplankton communities to cease their DVM in favour of feeding.  相似文献   
85.
Reliable dating of glaciomarine sediments deposited on the Antarctic shelf since the Last Glacial Maximum (LGM) is challenging because of the rarity of calcareous (micro‐) fossils and the recycling of fossil organic matter. Consequently, radiocarbon (14C) ages of the acid‐insoluble organic fraction (AIO) of the sediments bear uncertainties that are difficult to quantify. Here we present the results of three different methods to date a sedimentary unit consisting of diatomaceous ooze and diatomaceous mud that was deposited following the last deglaciation at five core sites on the inner shelf in the western Amundsen Sea (West Antarctica). In three cores conventional 14C dating of the AIO in bulk samples yielded age reversals down‐core, but at all sites the AIO 14C ages obtained from diatomaceous ooze within the diatom‐rich unit yielded similar uncorrected 14C ages between 13 517 ± 56 and 11 543 ± 47 years before present (a BP). Correction of these ages by subtracting the core‐top ages, which probably reflect present‐day deposition (as indicated by 210Pb dating of the sediment surface at one core site), yielded ages between ca. 10 500 and 8400 cal. a BP. Correction of the AIO ages of the diatomaceous ooze by only subtracting the marine reservoir effect (MRE) of 1300 a indicated deposition of the diatom‐rich sediments between 14 100 and 11 900 cal. a BP. Most of these ages are consistent with age constraints between 13.0 and 8.0 ka for the diatom‐rich unit, which we obtained by correlating the relative palaeomagnetic intensity (RPI) records of three of the sediment cores with global and regional reference curves. As a third dating technique we applied conventional radiocarbon dating of the AIO included in acid‐cleaned diatom hard parts extracted from the diatomaceous ooze. This method yielded uncorrected 14C ages of only 5111 ± 38 and 5106 ± 38 a BP, respectively. We reject these young ages, because they are likely to be overprinted by the adsorption of modern atmospheric carbon dioxide onto the surfaces of the diatom hard parts prior to sample graphitisation and combustion for 14C dating. The deposition of the diatom‐rich unit in the western Amundsen Sea suggests deglaciation of the inner shelf before ca. 13 ka BP. The deposition of diatomaceous oozes elsewhere on the Antarctic shelf around the same time, however, seems to be coincidental rather than directly related. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
86.
Polarized optical absorption spectra of natural olivine, Fa10Fo90, were measured before and after annealing/quenching experiments performed at 650, 800, 1,000 and 1,200°C under controlled oxygen fugacity. It was found that the annealing induces weak but definite changes in the olivine spectra. The intensity of the spin-allowed Z > X-polarized band at 9,560 cm?1 and shoulder at ~8,300 cm?1 attributed to Fe2+(M2), continuously decreases with annealing temperature, whereas a weaker band at ~11,600 cm?1 assigned to electronic spin-allowed transitions of Fe2+(M1), increases. This evidently shows that annealing treatments cause a redistribution of Fe2+ from M2 to M1. The fractionation increases with increasing temperature. This observation is in good correspondence with many diffraction structural studies of natural and synthetic olivines, as well as with recent Raman and Mössbauer investigations by Kolesov and Geiger (Mitt Österr Mineral Ges 149:48, 2004) and Morozov et al. (Eur J Mineral 17:495–500, 2005) evidencing a weak tendency of Fe to order into the M1 site with increasing temperature. However, this deduction is incompatible with the results of the in situ neutron power diffraction study of synthetic FeMgSiO4 by Redfern et al. (Phys Chem Minerals 27:630–637, 2000). Polarization properties of the UV absorption edge, attributed to ligand-to-metal charge-transfer transitions in Fe3+, changes from Y > X ? Z in natural samples to a weak Y ≥ X ≥ Z-pleochroism in annealed ones. This may be due to redistribution of a small content of Fe3+ among M1 and M2 structural sites.  相似文献   
87.
88.
It appears that there is a genuine shortage of radio pulsars with surface magnetic fields significantly smaller than ∼108 G. We propose that the pulsars with very low magnetic fields are actually strange stars locked in a state of minimum free energy and therefore at a limiting value of the magnetic field which cannot be lowered by the system spontaneously.  相似文献   
89.
90.
Zooplankton are an important trophic link and a key food source for many larval fish species in estuarine ecosystems. The present study documents temporal and spatial zooplankton dynamics in Suisun Bay and the Sacramento–San Joaquin Delta—the landward portion of the San Francisco Estuary (California, USA)—over a 37-year period (1972–2008). The zooplankton community experienced major changes in species composition, largely associated with direct and indirect effects of introductions of non-native bivalve and zooplankton species. A major clam invasion and many subsequent changes in zooplankton abundance and composition coincided with an extended drought and accompanying low-flow/high-salinity conditions during 1987–1994. In the downstream mesohaline region, the historically abundant calanoid copepods and rotifers have declined significantly, but their biomass has been compensated to some extent by the introduced cyclopoid Limnothoina tetraspina. The more upstream estuary has also experienced long-term declining biomass trends, particularly of cladocerans and rotifers, although calanoid copepods have increased since the early 1990s due to the introduced Pseudodiaptomus spp. In addition, mysid biomass has dropped significantly throughout the estuary. Shifts in zooplankton species composition have also been accompanied by an observed decrease in mean zooplankton size and an inferred decrease in zooplankton food quality. These changes in the biomass, size, and possibly chemical composition of the zooplankton community imply major alterations in pelagic food web processes, including a drop in prey quantity and quality for foraging fish and an increase in the importance of the microbial food web for higher trophic levels.  相似文献   
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