Effect of incorporation of iron and aluminum on the thermoelastic properties of magnesium silicate perovskite     

Norimasa Nishiyama  Takehiko Yagi  Shigeaki Ono  Hirotada Gotou  Tatsuhiko Harada  Takumi Kikegawa 《Physics and Chemistry of Minerals》2007,34(3):131-143

In situ X-ray diffraction measurements of Fe- and Al-bearing MgSiO₃-rich perovskite (FeAl-Pv), which was synthesized from a natural orthopyroxene, were performed at pressures of 19–32 GPa and temperatures of 300–1,500 K using a combination of a Kawai-type apparatus with eight sintered-diamond anvils and synchrotron radiation. Two runs were performed using a high-pressure cell with two sample chambers, and both MgSiO₃ perovskite (Mg-Pv) and FeAl-Pv were synthesized simultaneously in the same cell. Thus we were able to measure specific volumes (V/V ₀) of Mg-Pv and FeAl-Pv at the same P−T conditions. At all the measurement conditions, values of the specific volume of FeAl-Pv are consistent with those of Mg-Pv within 2 Standard Deviation, strongly suggesting that effect of incorporation of iron and aluminum on the thermoelastic properties of magnesium silicate perovskite is undetectable in this composition, pressure, and temperature range. Two additional runs were performed using a high-pressure cell that has one sample chamber and unit-cell volumes of FeAl-Pv were measured at pressures and temperatures up to 32 GPa and 1,500 K, respectively. All the unit-cell volume data of FeAl-Pv perovskite were fitted to the high temperature Birch–Murnaghan equation of state and a complete set of thermoelastic parameters of this perovskite was determined with an assumption of K′ _300,0 = 4. The determined parameters are K _300,0 = 243(3) GPa, (∂K _T,0/∂T) _P = −0.030(8) GPa/K, a ₀ = 2.78(18) × 10⁻⁵ K⁻¹, and b ₀ = 0.88(28) × 10⁻⁸ K⁻², where a ₀ and b ₀ are the coefficients of the following expression describing the zero-pressure thermal expansion: α _T,0 = a ₀ + b ₀ T. The equation-of-state parameters of FeAl-Pv are in good agreement with those of MgSiO₃ perovskite at the conditions corresponding to the uppermost part of the lower mantle.  相似文献   

Kaolin deposits at Melthonnakkal and Pallipuram within Trivandrum block, southern India     

M. Nakagawa  M. Santosh  S. Yoshikura  M. Miura  T. Fukuda  A. Harada 《Gondwana Research》2006,9(4):530-538

The kaolin deposits at Melthonnakkal and Pallipuram mines form part of the Warkalli Formation belonging to the Tertiary sequence in southern Kerala and occur at the boundary between the Tertiary sequence and Precambrian granulite facies metapelites (khondalites). The sedimentary clays are composed mainly of kaolinite, quartz and gibbsite. XRD and SEM studies have revealed that kaolinite is well-crystallized variety and the platy crystals are scarcely broken in the sedimentary clays. These sedimentary kaolins are considered to have been formed by intense tropical weathering of the khondalites, and subsequently transported and deposited with high organic input into lakes near the weathering crust over the basement rock. Besides, the surficial parts of the sedimentary deposits are extensively lateritized with the formation of goethite and hematite by Quaternary tropical weathering processes.  相似文献   

Temperature variation of elastic constants of quartz across the α - β transition     

Ichiro Ohno  Kazumi Harada  Chihiro Yoshitomi 《Physics and Chemistry of Minerals》2006,33(1):1-9

The α − β transition of quartz was successfully observed with using a single sample by means of the rectangular parallelepiped resonance (RPR) method. An oriented rectangular parallelepiped of α-quartz single crystal was prepared and the resonant frequencies of 30–11 vibrational modes were measured from room temperature to 700°C. The softening of quartz crystal was observed as the significant reduction of resonant frequencies near the α–β transition. The present study is the first application of the RPR method to the study of phase transition. The complete set of elastic constants of α- and β-quartz were determined as a function of temperature by the least-squares inversion of the measured frequency data obtained by a single run. This is a merit yielded by the RPR method. It is shown near the α − β transition in both α- and β-quartz that the elastic parameters decrease proportionally to |T−T ₀|⁻ⁿ , where T is temperature and T ₀ is the transition temperature, 573.0°C for α-quartz and 574.3°C for β-quartz. It was also seen that linear incompressibilities K ₁ = (C ₁₁ +C ₁₂ +C ₁₃)/3 and K ₃ = (C ₃₃ +2C ₁₃)/3 decrease rapidly toward the transition, whereas, shear moduli C ₄₄, C _S1 = (C ₁₁ +C ₃₃ -2C ₁₃)/4 and C _S3 = (C ₁₁ -C ₁₂)/2 = C ₆₆ decrease only slightly. The shear modulus C _S3 = C ₆₆ increased slightly in α-quartz. The elastic properties of isotropic aggregate of quartz were calculated, and it is shown that the longitudinal wave velocity significantly decreases at the α − β transition, whereas, the shear wave velocity decreases only slightly.  相似文献   

Hybridization of a Shallow 'I-type' Granitoid Pluton and its Host Migmatite by Magma-Chamber Wall Collapse: the Tokuwa Pluton, Central Japan   总被引：1，自引：0，他引：1  

Saito  Satoshi; Arima  Makoto; Nakajima  Takashi 《Journal of Petrology》2007,48(1):79-111

The Miocene Tokuwa pluton of ‘I-type’ granitoidaffinity was emplaced discordantly into a Cretaceous to Paleogeneaccretionary complex and induced a contact aureole in whichvarious thermally metamorphosed rocks were developed, includinghornfels, metatexite, diatexite and cordierite-bearing tonalite(Crd-tonalite) of ‘S-type’ granite affinity. Thethermally metamorphosed rocks show low-pressure reaction texturesculminating in partial melting. Peak P–T conditions of3 kbar at 780°C are estimated on the basis of the TWQ thermobarometerfor the garnet-bearing rocks. The rocks in the contact aureoleexhibit a gradual transition from hornfels, through metatexiteand diatexite to Crd-tonalite. The Sr-isotopic composition atthe time of Tokuwa pluton emplacement at 12 Ma decreases systematicallyfrom metatexite (0·7100–0·7112) throughdiatexite (0·7078–0·7094) to Crd-tonalite(0·7067–0·7068); this trend is interpretedin terms of mixing between the Tokuwa magma and the aureolemigmatites. The field relationships, geochemical data, and isotopicdata collectively suggest that the emplacement of the Tokuwapluton triggered partial melting of the surrounding metasedimentaryrocks. Subsequent hybridization of the Tokuwa magma with themetatexite in variable proportions produced the Crd-tonaliteand diatexite. The hybridization was caused by invasion of theTokuwa magma into the migmatite zone, accompanied by gravitationalcollapse of the previously crystallized wall of the magma chamber.The data presented demonstrate that even a relatively low-temperature,shallow, ‘I-type’ granitoid pluton can induce contactanatexis and hybrid ‘S-type’ granitoid formationat the intrusive contact. KEY WORDS: contact metamorphism; hybridization; magma–host-rock interaction; migmatite; ‘S-type’ granitoid  相似文献   

Molecular and isotopic composition of hydrate-bound and dissolved gases in the southern basin of Lake Baikal, based on an improved headspace gas method   总被引：1，自引：1，他引：0  

Hirotoshi Sakagami  Nobuo Takahashi  Akihiro Hachikubo  Hirotsugu Minami  Satoshi Yamashita  Hitoshi Shoji  Oleg Khlystov  Gennadiy Kalmychkov  Mikhail Grachev  Marc De Batist 《Geo-Marine Letters》2012,32(5-6):465-472

Assessments of the molecular and isotopic composition of hydrate-bound and dissolved gases in pore water were conducted during the multi-phase gas hydrate project (MHP-09) cruise VER09-03 to the southern basin of Lake Baikal in September 2009. To avoid changes in gas composition during core sampling and transport, various headspace methods were investigated aimed at preserving the dissolved gases in pore water. When distilled water was added to the sediment samples, the concentrations of carbon dioxide and oxygen decreased because of dissolution into the water and/or microbial consumption. When the headspace was not flushed with inert gases, trace levels of hydrogen and ethylene were detected. The findings suggest that best preparation is achieved by flushing the headspace with helium, and adding a saturated aqueous solution of sodium chloride. This improved headspace method served to examine the molecular and isotopic compositions of gas samples retrieved at several new sites in the southern basin. Methane was the major component, and the proportion of ethane ranged widely from 0.0009 to 1.67?mol% of the total hydrocarbon gases. The proportions of propane and higher hydrocarbons were small or less than their detection limits. The carbon isotope signatures suggest that microbial-sourced methane and ethane were dominant in the Peschanka study area, whereas ethane was of thermogenic origin at all other study sites in the southern basin of Lake Baikal.  相似文献   

Horizontal and vertical distributions of <Superscript>137</Superscript>Cs in seabed sediments around the river mouth near Fukushima Daiichi Nuclear Power Plant     

Tadahiko Tsuruta  Hisaya Harada  Toshiharu Misonou  Toshiyuki Matsuoka  Yasuyuki Hodotsuka 《Journal of Oceanography》2017,73(5):547-558

Investigations including a bathymetric survey, sonic prospecting, and vibrocoring were performed to understand the horizontal and vertical distribution of ¹³⁷Cs in seabed sediments in shallow seas with depths less than 30 m near the Fukushima Daiichi Nuclear Power Plant. Especially, features of ¹³⁷Cs distributions in deeper sections of the seabed sediments were studied to evaluate the vertical heterogeneity of ¹³⁷Cs distribution in the seabed sediments in shallow seas. The distribution area of the seabed sediments was less than half of the investigation area, and the locations of the seabed sediments were divided into flat and terrace-like seafloors based on their topographical features. The thicknesses of the seabed sediment layers were mostly <2 m. The ¹³⁷Cs inventories in the seabed sediments varied from 13 ± 1 to 3,510 ± 26 kBq m^?2, and continuous distributions of ¹³⁷Cs at depths greater than 81 cm were observed. The ¹³⁷Cs distributions were not uniform; however, the ¹³⁷Cs inventories tended to be larger near the base of the steeper ascending slopes than in the terrace-like seafloors themselves. Based on the relationship between the ¹³⁷Cs inventories and mean shear stress, features of the seafloor topography were inferred to be significant control factors governing the horizontal and vertical distribution of ¹³⁷Cs in the seabed sediments. Rapid changes and multiple peaks in the vertical profile of the ¹³⁷Cs distributions suggest that they are related to pulse input caused by heavy-rain events. Change in the ¹³⁷Cs inventories with depth in this study are larger than those reported in previous studies, indicating earlier results of ¹³⁷Cs inventories per unit in seabed sediments in shallow seas, especially near the river mouth, which drains a radiologically highly-contaminated basin, were underestimated.  相似文献   

Detection and accuracy of landslide movement by InSAR analysis using PALSAR-2 data     

Takaki Nishiguchi  Satoshi Tsuchiya  Fumitoshi Imaizumi 《Landslides》2017,14(4):1483-1490

Interferometric synthetic aperture radar (InSAR) analysis is a radar technique for generating large-area maps of ground deformation using differences in the phase of microwaves returning to a satellite. In recent years, high-resolution SAR sensors have been developed that enable small-scale slope deformation to be detected, such as the partial block movement of a landslide. The L-band SAR (PALSAR-2) is mounted on Advanced Land Observing Satellite-2 (ALOS-2), which was launched on 24 Mar. 2014. Its main improvements compared with ALOS are enhanced resolution of as high as 3 m with a high-frequency recurrence period (14 days). Owing to its high resolution and the use of the L-band, PALSAR-2 can obtain reflective data passing through a tree canopy surface, unlike the other synthetic aperture radars. Therefore, the coherence of InSAR in mountainous forest areas is less likely to decrease, making it advantageous for the extraction of slope movement. In this study, to verify the accuracy of InSAR analysis using PALSAR-2 data, we compared the results of InSAR analysis and the measurement of the displacement in a landslide by global navigation satellite system (GNSS) observation. It was found that the average difference between the displacements obtained by InSAR analysis and the field measurements by GNSS was only 15.1 mm in the slant range direction, indicating the high accuracy of InSAR analysis. Many of the areas detected by InSAR analysis corresponded to the locations of surface changes due to landslide activity. Additionally, in the areas detected by InSAR analysis using multiple datasets, the ground changes due to landslide movement were confirmed by site investigation.  相似文献   

Combined electromagnetic, geochemical and thermal surveys of Taal volcano (Philippines) during the period 2005–2006     

J. Zlotnicki  Y. Sasai  J. P. Toutain  E. U. Villacorte  A. Bernard  Julio P. Sabit  Juan M. Gordon Jr  Ernesto G. Corpuz  M. Harada  J. T. Punongbayan  H. Hase  T. Nagao 《Bulletin of Volcanology》2009,71(1):29-47

Since 1572, 33 phreatic to phreatomagmatic eruptions have occurred on Taal volcano (Philippines), some of them causing several hundred casualties. Considering the time delay between two consecutive eruptions, there is an 88% probability that Taal volcano should have already erupted. Since 1992, several phases of seismic activity have been recorded accompanied by ground deformation, opening of fissures, and surface activity. The volcanic activity of Taal appears to be controlled by dike injections and magma supply, buffered by a hydrothermal system that releases fluids and heat through boiling and subsequent steaming. In early 2005, a multidisciplinary project was launched for studying the hydrothermal activity. To map the hydrothermal system, combined surveys were carried out to investigate self-potential, total magnetic field, ground temperature and carbon dioxide soil degassing, along with satellite thermal imaging of the Main Crater Lake. The elevated temperatures and high concentrations of carbon dioxide, as well as electromagnetic anomalies, indicate large-scale hydrothermal degassing. This process is enhanced along the tectonic features (e.g., crater rim and faults) of the volcano, while active fissures opened along the E–W northern flank during the 1992–1994 seismic activity. Heat and fluids from the hydrothermal system are essentially released in the northern part of the crater, which is bounded to the South by a suspected NW–SE fault along which seismicity seems to take place, and dikes are thought to be intruded. During the January 2005 surveys, a new seismic crisis started, and the felt earthquakes prompted spontaneous evacuation of hundreds of inhabitants living on the volcano. Repeated surveys show changes of self-potential, total magnetic field, and ground temperature with time, without any noticeable spatial enlargement. These observations suggest that the northern flank located between the crater rim and the 1992–1994 fissures is connected with a deep thermal source in Main crater and is reactivated during seismic crises. This sector could be subjected to flank failure.  相似文献   

Phytoplankton community reorganization driven by eutrophication and warming in Lake Biwa   总被引：1，自引：0，他引：1  

Chih Hao Hsieh  Kanako Ishikawa  Yoichiro Sakai  Toshiyuki Ishikawa  Satoshi Ichise  Yoshimasa Yamamoto  Ting Chun Kuo  Ho Dong Park  Norio Yamamura  Michio Kumagai 《Aquatic Sciences - Research Across Boundaries》2010,72(4):467-483

We compiled and analyzed long-term data, including chemical, physical and phytoplankton community data, for the Lake Biwa ecosystem from 1962 to 2003. Analyses on environmental data indicate that Lake Biwa had experienced intensified eutrophication (according to total phosphorus concentration) in the late 1960s and returned to a less eutrophic status around 1985, and then exhibited rapid warming and thus increased water column stability since 1990. Total phytoplankton cell volume largely followed the trend of total phosphorus concentration, albeit short-term fluctuations existed. However, phytoplankton community shifted dramatically in response to those changes of environmental states. These shifts were cause by changes in trophic status driven by phosphorus loadings and physical properties in the water column driven by warming. Moreover, most phytoplankton species did not show a strong linear correlation with environmental variables, suggesting nonlinear transitions among different states.  相似文献   

Continuous Observation of Groundwater and Crustal Deformation for Forecasting Tonankai and Nankai Earthquakes in Japan     

Satoshi Itaba  Naoji Koizumi  Norio Matsumoto  Ryu Ohtani 《Pure and Applied Geophysics》2010,167(8-9):1105-1114

In 2006, we started construction of an observation network of 12 stations in and around Shikoku and the Kii Peninsula to conduct research for forecasting Tonankai and Nankai earthquakes. The purpose of the network is to clarify the mechanism of past preseismic groundwater changes and crustal deformation related to Tonankai and Nankai earthquakes. Construction of the network of 12 stations was completed in January 2009. Work on two stations, Hongu-Mikoshi (HGM) and Ichiura (ICU), was finished earlier and they began observations in 2007. These two stations detected strain changes caused by the slow-slip events on the plate boundary in June 2008, although related changes in groundwater levels were not clearly recognized.  相似文献