Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid     

Tao Wang  Xin Jiang  Congying Wang  Fang Wang  Yongrong Bian  Guifen Yu 《Environmental Earth Sciences》2014,71(2):773-782

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.  相似文献   

The calculation of mine water yield using the non-continuous flow theory     

Liu Peigui  Tao Yuezan  Shang Manting  Yao Mei 《Environmental Earth Sciences》2014,71(2):975-981

Large amounts of groundwater are discharged during underground mining operations. As a result, the drawdown of groundwater, known as aquifer dewatering, is common in mining areas. Because of variability in permeability between different media in mines, mine drainage occurs primarily as non-continuous flow. However, calculations of mine water yield are usually made based on the continuous flow theory, and therefore often produce erroneous results. This study predicts the water yield of a mine using the module MODFLOW and incorporating the non-continuous flow theory into the calculation. Using this method, the predicted water yield of a mine was approximately 50 % lower than that predicted using the continuous flow theory. The model also demonstrates that the rate of mine drainage varies over time; there is initially a decrease in the rate of drainage which gradually approaches a constant value. Double level flow occurs when there is non-continuous flow in continuous media, which can effectively minimize the influence of mine drainage on upper aquifers and relieve the conflict between groundwater supply and drainage in the mining area.  相似文献   

Spatial change detection of glacial lakes in the Koshi River Basin,the Central Himalayas   总被引：2，自引：0，他引：2  

Wang Shijin  Zhang Tao 《Environmental Earth Sciences》2014,72(11):4381-4391

Region warming and the resulting ongoing deglaciation have led to the formation of new glacial lakes and expansion of existing glacial lakes. For giving an overview of the distribution and expansion of glacial lakes in the Koshi River Basin (KRB) between the Central China and Nepal Himalayas in the recent 10 years, this paper aimed to analyze and assess recent spatial variability of glacial lake changes in the KRB, Central Himalayas using two inventory data of glacial lake in 2001 and 2010 in Nepal and Landsat TM/ETM+ data for the 1990s, 2000 and 2009 on the Chinese section of the KRB. The datasets show that there are 1,203 glacial lakes with a total area of 118.54 km² in the KRB in 2009, in which 599 lakes are mapped in the Nepalese section of the KRB with a total of 25.92 km², and 604 lakes in the Chinese section of the KRB with a total area of 92.62 km². From 2000 to 2009, the total number of glacial lakes decreased from 1,668 to 1,203 with a reduction of 45.86 % in the KRB, whereas the total lake areas expanded by 10.60 % (i.e. 0.72 km²/a), from 111.35 to 118.54 km² between 2000, 2001 and 2009, 2010. Especially, 17 lakes are identified as potentially dangerous glacial lakes (PDGLs) by International Centre for Integrated Mountain Development (ICIMOD) on the Nepalese section of the KRB in 2009. In the same period, 23 PDGLs are also identified on the Chinese section of the KRB and the total area increased by 77.46 % (i.e. 0.37 km²/a) from 1990 to 2010 and the expansion rate is significantly higher than 39 % (0.19 km²/a) of non-PDGLs. Therefore, there is a need for promoting the awareness of the hazard potential of glacier lakes to support proper planning of mitigation and adaptation strategies in this context.  相似文献   

河北省尚义县松树沟石墨矿矿床地球化学特征及成因分析          下载免费PDF全文

王广  齐新国  付茂英  田腾飞 《中国地质调查》2014,6(6):29-34

以河北省尚义县松树沟石墨矿的地球化学特征数据为基础,通过与内蒙古兴和石墨矿床进行对比,探究矿床成矿环境,进而分析其矿床成因。岩石学和地球化学分析结果表明: 松树沟石墨矿赋矿层位为集宁岩群下白窑岩组,矿石类型为黑云斜长变粒岩石墨矿石,工业类型为晶质鳞片状石墨; 岩石地球化学特征为高硅、高铝、低碱,具有孔兹岩系特征; 原岩形成在缺氧的弱还原环境,具铕负异常特征; 其变质原岩为富碳质和富铝质的泥质碎屑岩,原岩沉积环境总体为准稳定地理环境,岩石通过区域变质作用形成晶质石墨矿床。对松树沟石墨矿床地质特征和区域成矿规律的研究成果,对区域找矿工作具有重要的参考意义。  相似文献   

内蒙古八大关斑岩型铜钼矿床成岩成矿年代学研究   总被引：4，自引：1，他引：3  

康永建  王亚君  黄光杰  佘宏全  向安平  田京  郭志军  董旭舟 《矿床地质》2014,33(4):795-806

八大关斑岩铜钼矿床是中国内蒙大兴安岭地区典型的斑岩型铜钼矿床之一。对矿区Ⅱ号岩体不同位置的2件岩石样品采用高精度的LA_ICP_MS锆石U_Pb测年,获得的锆石U_Pb年龄分别为(230.6±2.8)Ma和(230.5±4.4)Ma,两者在误差范围内非常一致,由此确认花岗闪长斑岩体的形成年龄约为230 Ma;对矿区7件辉钼矿样品采用Re_Os同位素测年,获得的Re_Os等时线年龄为(228.7±3.1)Ma,指示了八大关铜钼矿床辉钼矿的沉淀时间约为228.7 Ma。结合矿区岩相学、矿物学特征,辉钼矿呈浸染状分布于花岗闪长斑岩体内,且辉钼矿与黄铜矿密切共生,以及上述2种精确方法获得的年龄在误差范围内的一致性,说明花岗闪长斑岩即为成矿岩体,成岩与成矿大致同时或成矿略晚于成岩,表明八大关铜钼矿床形成于中三叠世,属于印支期成矿。  相似文献   

南秦岭构造带内早古生代碱基性岩浆活动：古特提斯洋裂解的证据   总被引：2，自引：0，他引：2  

陈虹  田蜜  武国利  胡健民 《地质论评》2014,60(6):1437-1452

位于南秦岭构造带南缘的勉略(勉县—略阳)洋是东古特提斯洋的北侧分支洋盆,在勉县—略阳地区发育有典型的蛇绿岩组合。然而,由于中三叠世晚期开始的碰撞造山作用以及之后陆内变形作用的改造,对于勉略洋盆在构造带东段的裂解和演化过程并不清晰。本文对发育于东南秦岭构造带内的基性岩墙群进行了岩石学、岩石地球化学、同位素年代学等方面的研究。结果表明,基性岩脉以辉长岩、辉绿岩等基性岩为主,其SiO 2含量为41.89%~49.75%,属基性—超基性岩类,并具有富钠、高钛的碱性岩特征。岩石的稀土、微量元素和Sr—Nd同位素特征与板内洋岛玄武岩(OIB)特征一致,岩浆源于具有地壳混染的板内洋岛玄武岩型地幔源区。该类基性岩脉顺层侵入到早古生代早期地层中,通过基性岩脉中的锆石SHRIMP测年获得岩脉顺层侵位的时代为晚志留世早期(约422 Ma)。这种岩浆作用很可能与古特提斯洋初始裂解有关,并导致南秦岭构造带内地壳伸展、基性岩浆侵位,该过程与南秦岭构造带北缘的商丹(商南—丹凤)原特提斯洋的消减和陆内俯冲可能相关。  相似文献   

塔中地区奥陶系喜马拉雅山期S干气充注的证据          下载免费PDF全文

何宏  李红霞  张科  陶小晚  蔡春芳 《地质科学》2014,49(4):1327-1336

塔中地区奥陶系天然气成因多样;Ⅰ号坡折带中东部奥陶系天然气以高干燥系数、 甲烷同位素值重为特征;与塔深1井寒武系原油裂解气接近;应主要来自寒武系原油裂解气成因。寒武系贫H₂S、 高成熟原油裂解气在喜马拉雅山期时;气侵奥陶系油气藏;得到了以下主要证据的支持: 1）天然气甲烷δ¹³C值大多比Chung et al.（1988）天然气模式甲烷δ¹³C值计算值高3‰以上;2）干燥系数与甲烷δ¹³C值大体上具有正相关关系;3）天然气干燥系数与H₂S含量大体上具有负相关关系。这些特征表明;存在贫H₂S、 相对富¹³C甲烷为主的干气与富H₂S、 相对贫¹³C甲烷的湿气混合作用。奥陶系中H₂S-δ³⁴S 值为14‰～20‰;远低于中深1井寒武系原地热化学硫酸盐还原作用（TSR）成因的H₂S（33‰）;支持了奥陶系中H₂S并不是来源于寒武系古油气藏。于是提出;来自寒武系贫H₂S的干气在喜马拉雅山期对良里塔格组和鹰山组油气藏发生了气洗;油气藏的气/油比值增大、 导致了原油蜡含量增高、 甲烷δ¹³C值发生正偏移。  相似文献   

五河杂岩的变质岩石学及P-T条件分析钻孔的研究   总被引：1，自引：0，他引：1       下载免费PDF全文

王娟  盛勇  卜香萍  康涛  石永红 《地质科学》2014,(2):556-575

五河杂岩是华北克拉通东部陆块东南缘最重要的岩石单元。然而,直至今日,人们对于该组杂岩一直缺乏足够的研究,特别是对于其形成的变质条件分歧较大。本文通过对蒙城南ZK02钻孔中五河杂岩的构成和地质特征详细研究表明五河杂岩分为上、下两段。上段主要为一套由云母片岩、大理岩和花岗片麻岩组成的变质表壳岩系,下段为一套基性变质岩,主要岩性为斜长角闪岩、角闪岩、石榴斜长角闪岩和少量的混合岩。同时,针对下段特征岩石（石榴斜长角闪岩）,进行了较为详细的岩相学和矿物化学分析,并应用不同的温压计进行P-T条件评价和比较,结合岩相学限定和前人的研究成果,认为五河杂岩的主体普遍经历了高压角闪岩相变质作用,其温压范围为：T=671 ℃～700 ℃和P=0.82～0.95 GPa,地温梯度约为25～28 ℃/km,与典型陆壳地温梯度类似。与同邻区主要岩石单元的变质级别相比,五河杂岩应当形成于板内变质环境,并不具备造山带变质特征。  相似文献   

Spatio-temporal distributions of climate disasters and the response of wheat yields in China from 1983 to 2008   总被引：1，自引：0，他引：1  

Wenjiao Shi  Fulu Tao 《Natural Hazards》2014,74(2):569-583

Climate disasters are now on the rise and more likely to increase in frequency and/or severity under climate change in the future. To clearly illustrate spatial–temporal distributions of climate disasters and the response of wheat yields to disasters over the past three decades, several disaster indices including the impact of climate disasters, the sensitivity to climate disasters and the response index of wheat yield losses to climate disasters were defined and calculated. The impact and sensitivity indices were examined by the agricultural production losses due to climate disasters, and the response of wheat yields to climate disasters was assessed by wheat yield loss compared with the 5-year moving average. The results showed that the indices of climate disaster impacts and sensitivities as well as response index of wheat yields to climate disasters could represent the spatial–temporal distributions of climate disasters well in the whole China. Droughts in northern China had higher impacts and sensitivities than those in southern China during the period 1983–2008, but the impacts of floods were opposite. In northern China, although impacted area by drought was larger than that by flood, the flood sensitivities were larger than drought sensitivities when flood happened. Although drought significantly affected wheat yields in most of the regions with drier conditions during 1983–2008 in major wheat-producing regions, better management practices like irrigation and drought-tolerant cultivars applied in the Huang-Huai-Hai Plain can adapt to climate disasters especially droughts. To ensure the stability of agricultural production, future food security will need to be achieved through quantifying the relative effects of climate disasters and effective adaptation to increasingly frequent extreme climate events.  相似文献   

云南中甸红牛-红山矽卡岩型铜矿床矿物学特征与成矿作用   总被引：8，自引：5，他引：3  

彭惠娟  李洪英  裴荣富  张长青  周云满  田广  李建新  龙飞 《岩石学报》2014,30(1):237-256

红牛-红山矿床位于西南三江成矿带的中甸岛弧,是形成于晚燕山期的矽卡岩型铜矿床。矿区与成矿作用密切相关的石英二长斑岩中角闪石和黑云母斑晶的出现以及较高的含F量(分别为1.49%和2.62%),表明其岩浆为富H2O富挥发分熔体;石英斑晶具有港湾状、浑圆状的溶蚀表面和钾长石细晶外壳,并且显示了典型的骸晶状结构指示了其岩浆经历了快速上升侵位过程和岩浆热液的自交代作用;钻孔中岩浆热液角砾岩和大量石英细脉的出现暗示了岩浆在快速上侵过程中发生了隐爆作用,形成并出溶了含有大量F、Cl等组分的高盐度超临界流体。矽卡岩阶段石榴子石和透辉石具有明显的三个期次:早期细粒的钙铝榴石(And22-57)和角岩中的透辉石(Hd7-27)形成于少量高温气液岩浆流体与围岩的扩散交代作用;中期粗粒的钙铁榴石(And75-98)和次透辉石-钙铁辉石(Hd10-99)形成于大量高温、低氧逸度的岩浆流体与围岩的渗滤交代作用;晚期的钙铝榴石脉(And14-60)和钙铁辉石脉(Hd31-58)形成于低温、高氧逸度的早期交代残留溶液。矽卡岩矿物的生成,使碳酸盐围岩丢失CO2,矿物体积减少,孔隙度和渗透性增加,为成矿提供了条件。退化变质阶段的透闪石、阳起石、绿帘石、绿泥石等交代早期矽卡岩矿物,消耗了成矿流体中大量的CO2和H2O,生成含水矿物以及石英、方解石,使围岩裂隙愈合,孔隙流体压力增加,导致成矿流体沸腾,形成大量黄铜矿、磁黄铁矿、黄铁矿、辉钼矿化。石英-硫化物阶段,由于成矿流体超压→流体沸腾,裂隙生成→减压排泄,裂隙愈合→流体超压的循环,在此过程中围岩经历了多次破裂和裂隙的愈合,直至整个成矿体系完全开放,并与大气水发生混合,使成矿流体中剩余金属最终沉淀。  相似文献