Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy          下载免费PDF全文

Atsuyuki Ohta  Ran Kubota 《Geostandards and Geoanalytical Research》2016,40(1):117-134

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).  相似文献   

Variation on PAR to global solar radiation ratio along altitude gradient in Naeba Mountain     

Q. Wang  Y. Kakubari  M. Kubota  J. Tenhunen 《Theoretical and Applied Climatology》2007,87(1-4):239-253

Summary We investigated the ratio of photosynthetically active photon flux (Q _p ) to global solar radiation (R _s ) at three sites along different altitudes in Naeba Mountain, Japan at various temporal scales based on 3 years measurement data (1999–2001). The lowest values of the ratio ever reported were found for all sites on both an hourly and a daily scale. A similar slight diurnal pattern was found for all sites based on the monthly mean hourly values of the ratio. However, different sites exhibited different seasonal courses. Statistically significant altitude dependencies were found for the hourly Q _p /R _s under both clear and cloudy weather conditions (t-test, P < 0.001). For clear weather conditions, the hourly Q _p /R _s exhibited an increasing trend with altitude at an average rate of 3.6% per km. The increasing rate was more noticeable below 900 m (8.8% per km) than above (0.7% per km). The inverse trend was found for hourly Q _p /R _s with the altitude under cloudy weather conditions. The hourly Q _p /R _s decreased from 550 m to 1500 m at a rate of 1.8% per km. Again, a major decrease occurred below 900 m, which had the rate of 4.2% per km, compared with 0.2% per km over 900 m. Although the same tendencies were noted for daily Q _p /R _s , under clear sky conditions, they were not as statistically significant as the hourly counterpart (t-test, P < 0.021). The increasing rate of Q _p /R _s at this scale under clear weather conditions was near that of the hourly rate, but below the 900 m rate was reduced to near half of the hourly rate (4.7% per km). And the rate over 900 m increased to 2.7% per km. On the other hand, statistically significant altitude effect was noted for the daily under cloudy weather conditions (t-test, P < 0.002). A rapidly decreasing rate was found for it along the altitude gradient. The reason was due to the large decreasing rate below 900 m (12.4% per km). But again similar to the hourly Q _p /R _s , a very small decreasing rate of daily Q _p /R _s was found over 900 m under cloudy weather conditions. These results suggest the necessity of considering the altitude dependency of Q _p /R _s in future studies.  相似文献   

Effects of land‐use changes on hydrological processes in the middle basin of the Heihe River,northwest China     

Genxu Wang  Jingqi Liu  Jumpei Kubota  Ling Chen 《水文研究》2007,21(10):1370-1382

The effects of land‐use changes on the runoff process in the midstream plain of this arid inland river basin are a key factor in the rational allocation of water resources to the middle and lower reaches. The question is whether and by how much increasingly heavy land use impacts the hydrological processes in such an arid inland river basin. The catchment of the Heihe River, one of the largest inland rivers in the arid region of northwest China, was chosen to investigate the hydrological responses to land‐use change. Flow duration curves were used to detect trends and variations in runoff between the upper and lower reaches. Relationships among precipitation, upstream runoff, and hydrological variables were identified to distinguish the effects of climatic changes and upstream runoff changes on middle and downstream runoff processes. The quantitative relation between midstream cultivated land use and various parameters of downstream runoff processes were analysed using the four periods of land‐use data since 1956. The Volterra numerical function relation of the hydrological non‐linear system response was utilized to develop a multifactor hydrological response simulation model based on the three factors of precipitation, upstream runoff, and cultivated land area. The results showed that, since 1967, the medium‐ and high‐coverage natural grassland area in the midstream region has decreased by 80·1%, and the downstream runoff has declined by 27·32% due to the continuous expansion of the cultivated land area. The contribution of cultivated land expansion to the impact on the annual total runoff is 14–31%, on the annual, spring and winter base flow it is 44–75%, and on spring and winter discharge it is 23–64%. Once the water conservation plan dominated by land‐use structural adjustments is implemented over the next 5 years, the mean annual discharge in the lower reach could increase by 8·98% and the spring discharge by 26·28%. This will significantly alleviate the imbalance between water supply and demand in both its quantity and temporal distribution in the middle and lower reaches. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Relations between load and settlement of circular foundations on or in a dense sand expressed by a function of diameter and depth     

Hiroaki Nagaoka  Masahiro Yamazaki  Naoto Kubota  Takashi Okamoto 《国际地质力学数值与分析法杂志》2005,29(6):551-576

When load acts on a circular foundation on or in a dense sand, average contact pressure on the lower surface of the foundation is q and settlement of the foundation is s. Diameter and depth of the foundation are B and D_f. When the sand, B and D_f are given, we can know the relation between q and s/B by, e.g. a loading test, i.e. the relation is determined by B and D_f for the sand. Using the results of numerical analyses, we express a relation between q and s/B up to s=0.1B by functions of a single variable which is a linear combination of B and D_f. Consequently when two foundations have different B's and different D_f's but have the same value of the variable, the relations are the same. Then we examine whether the functions can express the results of eleven tests of model foundations of wide range of B and/or D_f. In all the tests, the relations are expressed with sufficient accuracy. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Arsenic accumulation and distribution in tissues of black-footed albatrosses     

Fujihara J  Kunito T  Kubota R  Tanaka H  Tanabe S 《Marine pollution bulletin》2004,48(11-12):1153-1160

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Concentration and subcellular distribution of trace elements in liver of small cetaceans incidentally caught along the Brazilian coast     

Kunito T  Nakamura S  Ikemoto T  Anan Y  Kubota R  Tanabe S  Rosas FC  Fillmann G  Readman JW 《Marine pollution bulletin》2004,49(7-8):574-587

Concentrations of trace elements (V, Cr, Mn, Fe, Co, Cu, Zn, Ga, As, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, T-Hg, Org-Hg, Tl and Pb) were determined in liver samples of estuarine dolphin (Sotalia guianensis; n = 20), Franciscana dolphin (Pontoporia blainvillei; n = 23), Atlantic spotted dolphin (Stenella frontalis; n = 2), common dolphin (Delphinus capensis; n = 1) and striped dolphin (Stenella coeruleoalba; n = 1) incidentally caught along the coast of Sao Paulo State and Parana State, Brazil, from 1997 to 1999. The hepatic concentrations of trace elements in the Brazilian cetaceans were comparable to the data available in literature on marine mammals from Northern Hemisphere. Concentrations of V, Se, Mo, Cd, T-Hg and Org-Hg increased with increasing age in liver of both estuarine and Franciscana dolphins. Very high concentrations of Cu (range, 262-1970 microg/g dry wt.) and Zn (range, 242-369 microg/g dry wt.) were observed in liver of sucklings of estuarine dolphin. Hepatic concentrations of V, Se, T-Hg, Org-Hg and Pb were significantly higher in estuarine dolphin, whereas Franciscana dolphin showed higher concentrations of Mn, Co, As and Rb. Ratio of Org-Hg to T-Hg in liver was significantly higher in Franciscana dolphin than estuarine dolphin, suggesting that demethylation ability of methyl Hg might be lower in liver of Franciscana than estuarine dolphins. High hepatic concentrations of Ag were found in some specimens of Franciscana dolphin (maximum, 20 microg/g dry wt.), and 17% of Franciscana showed higher concentrations of Ag than Hg. These samples with high Ag concentration also exhibited elevated hepatic Se concentration, implying that Ag might be detoxified by Se in the liver. Higher correlation coefficient between (Hg+0.5 Ag) and Se than between Hg and Se and the large distribution of Ag in non-soluble fraction in nuclear and mitochondrial fraction of the liver also suggests that Ag might be detoxified by Se via formation of Ag2Se in the liver of Franciscana dolphin.  相似文献   

Long-term precipitation and stream discharge records at seven forested experimental watersheds along a latitudinal transect in Japan: Jozankei,Kamabuchi, Takaragawa,Tsukuba, Tatsunokuchi-yama,Kahoku and Sarukawa     

Takanori Shimizu  Koji Tamai  Ikuhiro Hosoda  Shoji Noguchi  Yuji Kominami  Toshio Abe  Kenzo Kitamura  Ushio Kurokawa  Delphis F. Levia  Tayoko Kubota  Naoki Kabeya  Shin'ichi Iida  Tatsuhiko Nobuhiro  Shinji Sawano  Sho Iwagami  Akira Shimizu  Yoshio Tsuboyama 《水文研究》2021,35(10):e14376

This data note introduces a database of long-term daily total precipitation and stream discharge data for seven forested watersheds in Japan that have been continuously monitored by the Forestry and Forest Products Research Institute. Three of the watersheds started data collection in the 1930s. Forest cover across the sites ranges from cool to warm temperate regions with the latitude spanning from 31 to 44° N and annual precipitation ranging from 1200 to 3000 mm yr⁻¹. The effects of vegetation change via clearcutting, thinning and forest fire (among other stressors) on stream discharge can be analysed from the long-term observation sites. Moreover, this multi-site dataset allows for inter- and intra-site comparisons of annual water loss (difference of annual precipitation and stream discharge). These long-term datasets can provide comprehensive insights into the effects of climate change and other stressors on forested ecosystems, not only in Japan but across a spectrum of forest types, if combined with other long-term records from other forested watersheds across the world.  相似文献   

Effects of plant roots on the soil erosion rate under simulated rainfall with high kinetic energy     

Yoshinori Shinohara  Sohei Otani  Tetsuya Kubota  Kyoichi Otsuki  Kazuki Nanko 《水文科学杂志》2013,58(13):2435-2442

ABSTRACT

This study examined the effects of herbaceous plant roots on interrill erosion using two herbaceous species: clover (Trifolium repens) and oats (Avena sativa). We developed a simple rainfall simulator with relatively high normalized kinetic energy (KE; 23.2 J m^?2 mm^?1). Under simulated rainfall, we measured eroded soil for 42 boxes with various amounts of aboveground and belowground biomass. Aboveground vegetation had a significant effect on the soil erosion rate (SER). We found a clear negative relationship between the percent vegetation cover (c) and the SER. In contrast, plant roots showed no effects on the SER. The SER was not significantly different between the boxes with and without plant roots under similar c conditions. Thus, plant roots could have less of an effect on the SER under higher KE conditions.