Formation process of pyrite polyframboid based on the heavy-metal analysis by micro-PIXE     

Hisanari Sugawara  Masayuki Sakakibara  David Belton  Tetsuya Suzuki 《Environmental Earth Sciences》2013,69(3):811-819

Pyrite framboid in sedimentary rocks could be concerned with arsenic contamination in groundwater of acidic environment and has been studied for the formation process of its unique morphology. However, not much has been discussed about the formation process based on the heavy-metal distribution in pyrite framboids and their aggregates. To reveal the formation process of pyrite framboids and their aggregates, mudstone from the Late Cretaceous Hakobuchi Group, central Hokkaido, Japan, are investigated for mode, petrographical, mineralogical, and micro-PIXE (particle-induced X-ray emission) analysis in this study. Spherical and sub-spherical pyrite framboids observed in polyframboids can be divided into two types based on the diameter of framboids (D) and the average diameter of microcrystals (d) within framboids: type 1, ranging from 2 to 9 μm and from 0.4 to 0.9 μm, respectively, and type 2, ranging from 8 to 50 μm and from 0.5 to 1.8 μm, respectively. Based on the quantitative traverse analyses and 2-D elemental mapping results by micro-PIXE, heterogeneities in the concentrations of heavy metals within the analyzed aggregations of pyrite are exhibited. On the basis of the As and Pb zoning patterns, the time range and chronological stages of pyrite-aggregation growth are revealed.  相似文献   

Evaluation of ionic pollutants in cloud droplets at a mountain ridge in northern Japan using constrained oblique rotational factor analysis     

Nobuaki Ogawa  Ryoei Kikuchi  Tomoko Okamura  Junko Inotsume  Tetsuya Adzuhata  Toru Ozeki  Masahiro Kajikawa 《Atmospheric Research》2000,54(4)

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Molecular Identification and Expression Analysis of Carbonic Anhydrase VII in Pufferfish (Takifugu rubripes)     

Sumi  Kanij Rukshana  Kim  Soo Cheol  Howlader  Jewel  Sharker  Md Rajib  Choi  Kap Seong  Choi  Sang Ki  Park  Jong-In  Nou  Ill-Sup  Kho  Kang Hee 《Ocean Science Journal》2019,54(3):363-374

Ocean Science Journal - A carbonic anhydrase VII gene, encoding 277 amino acids, was identified in the intestinal tissue of pufferfish (Takifugu rubripes). The translated protein with an 833-bp...  相似文献   

Re-Os isotope systematics and fractionation of siderophile elements in metal phases from CBa chondrites     

Nao Nakanishi  Tetsuya Yokoyama  Satoki Okabayashi  Tomohiro Usui  Hikaru Iwamori 《Meteoritics & planetary science》2018,53(5):1051-1065

We report Os isotope compositions of metal grains in two CB_a chondrites (Bencubbin and Gujba) determined using a micromilling sampling coupled with thermal ionization mass spectrometry, together with the abundances of major and trace siderophile elements obtained by electron probe microanalysis and femtosecond laser ablation inductively coupled plasma–mass spectrometry. The CB_a metal grains presented ¹⁸⁷Os/¹⁸⁸Os ratios akin to carbonaceous chondrites with limited variations (0.1257–0.1270). Most of the CB_a metal grains were scattered along a ¹⁸⁷Re-¹⁸⁷Os reference isochron of IIIAB iron meteorites, indicating that the CB_a metals experienced limited Re-Os fractionation at the time of their formation. The Re/Os ratios of sampling spots for the CB_a metals, recast from the observed ¹⁸⁷Os/¹⁸⁸Os ratios, had a positive correlation with their Os/Ir ratios. In addition, the metal grains showed a positive correlation in a Pd/Fe versus Ni/Fe diagram. These correlations suggest that the CB_a metal grains have formed via equilibrium condensation or evaporation from a gaseous reservoir at ~10⁻⁴ bar with enhanced metal abundances. Compared to the Bencubbin metals, the Gujba metals are characterized by having systematically lower Pd/Fe and Ni/Fe ratios that span subchondritic values. Such a difference was most likely induced by the compositionally heterogeneous impact plume from which the metals were condensed.  相似文献   

Control of Phosphate Concentration through Adsorption and Desorption Processes in Groundwater and Seawater Mixing at Sandy Beaches in Tokyo Bay, Japan     

Masahiro Suzumura  Shingo Ueda  Eiichi Sumi 《Journal of Oceanography》2000,56(6):667-673

Field observation was conducted to monitor phosphate concentrations in groundwater and seawater mixing at two sandy beaches in Futtsu and Miura in Tokyo Bay, Japan. Dissolved phosphate concentrations were measured along transects from fresh groundwater aquifer to seawater adjacent the beaches. The concentrations were often high (up to 46 µM) in fresh groundwater samples (Cl^– < 0.2). Coastal seawater, on the other hand, exhibited low phosphate concentrations (1.5 µM or less). Along the transects, phosphate generally displayed non-conservative behavior during mixing of fresh and saline waters in the aquifer; concentrations as high as 100 µM were found around the upper limit of seawater intrusion (Cl^– = 2). Laboratory experiments were executed to identify the processes that control the phosphate behavior in the mixing processes. The results revealed that adsorption-desorption processes by the aquifer sand particles could significantly control the phosphate concentrations in the groundwater. Furthermore, the adsorption and/or desorption was found to be a function of salinity; the equilibrium concentration of dissolved phosphate in slurry of sand and water was the highest in freshwater and decreased considerably in saline water. The extreme concentration of phosphate may be caused by release from sand particles coinciding with the rapid change in salinity with tide.  相似文献   

Accelerated continental-scale snowmelt and ecohydrological impacts in the four largest Siberian river basins in response to spring warming     

Kazuyoshi Suzuki  Tetsuya Hiyama  Koji Matsuo  Kazuhito Ichii  Yoshihiro Iijima  Dai Yamazaki 《水文研究》2020,34(19):3867-3881

River runoff from the four largest Siberian river basins (the Ob, Yenisei, Lena, and Kolyma) considerably contributes to freshwater flux into the Arctic Ocean from the Eurasian continent. However, the effects of variation in snow cover fraction on the ecohydrological variations in these basins are not well understood. In this study, we analysed the spatiotemporal variability of the maximum snow cover fraction (SCF_max) in the four Siberian river basins. We compared the SCF_max from 2000 to 2016 with data in terms of monthly temperature and precipitation, night-time surface temperatures, the terrestrial water storage anomaly (TWSA), the normalised difference vegetation index (NDVI), and river runoff. Our results exhibit a decreasing trend in the April SCF_max values since 2000, largely in response to warming air temperatures in April. We identified snowmelt water as the dominant control on the observed increase in the runoff contribution in May across all four Siberian river basins. In addition, we detected that the interannual river runoff was predominantly controlled by interannual variations in the TWSA. The NDVI in June was strongly controlled by the timing of the snowmelt along with the surface air temperature and TWSA in June. The rate of increase in the freshwater flux from the four Siberian rivers decreased from 2000 to 2016, exhibiting large interannual variations corresponding to interannual variations in the TWSA. However, we identified a clear increase trend in the freshwater flux of ~4 km³/year when analysing the long-term 39-year historical record (1978–2016). Our results suggest that continued global warming will accelerate the transition towards the earlier timing of snowmelt and spring freshwater flux into the Arctic Ocean. Our findings also highlight the effects of earlier snowmelt on ecohydrological changes in the Northern Hemisphere.  相似文献   

Near-field beam pattern measurement of qualification model of ALMA band 8 (385–500 GHz) cartridge receiver     

Masato Naruse  Tetsuya Ito  Yutaro Sekimoto  Hiroyuki Toba  Naohisa Satou  Masahiro Sugimoto  Wenlei Shan  Yoshizou Iizuka  Toshiaki Kamba  Mamoru Kamikura  Yasutaka Serizawa 《Experimental Astronomy》2009,24(1-3):89-107

We have developed a near-field vector beam measurement system covering the range of frequencies from 385 to 500 GHz. The measurement set-up is capable of measurements with dynamic range exceeding 50 dB and amplitude and phase stability respectively of 0.1 dB/h and 1 degree/5 min at room temperature. Beam patterns of the ALMA band 8 corrugated horns and receiver optics block were measured at room temperature and lately compared with physical optics calculations obtained in the far-field. Both co-polar and cross-polar beam patterns of a qualification model of the ALMA band 8 cartridge cooled in a cartridge-test-cryostat have also been measured in the near-field as a detector of a submillimeter vector network analyzer. The measurements presented in this work refer to the lowest, middle and upper frequencies of band 8. The comparisons between software model and experimental measurements at these frequencies show good agreement down to ?30 dB for the main polarization component. The cross-polarization level of the beam propagating through the receiver optics block was also characterized. We found that a cross-polarization level better than ?28 dB can be achieved at all measured frequencies. The measured beam pattern of this receiver corresponds to efficiency of greater than 92% at the sub reflector (diameter of 750 mm) of the ALMA 12 m optics.  相似文献   

Westward rotation of the atmospheric angular momentum vector of Titan by thermal tides     

Tetsuya Tokano 《Planetary and Space Science》2010,58(5):814-829

The orientation of the atmospheric angular momentum vector of Titan and its temporal variation predicted by a general circulation model are analysed and interpreted. The atmospheric angular momentum vector is tilted by a few degrees from the polar axis and the vector rotates (precesses) westward with a constant period of 1 Titan day. The fast westward rotation is likely to be caused by migrating diurnal thermal tides. The tilt is almost cancelled out in the troposphere by the wavenumber 2 pattern of Saturn's gravitational tide, but is more pronounced in the stratosphere, where thermal tides are significant. The predicted tilt angle and the equatorial angular momentum vary with season and maximize when the hemispheric asymmetry of the axial angular momentum or superrotation attains its peak.  相似文献   

Preface     

Roussos Dimitrakopoulos  Richard B. McCammon  Tetsuya Shoji 《Mathematical Geosciences》1994,26(8):877-878

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Aircraft Observations of the Development of Thermal Internal Boundary Layers and Scaling of the Convective Boundary Layer Over Non-Homogeneous Land Surfaces   总被引：1，自引：0，他引：1  

Michail A. Strunin  Tetsuya Hiyama  Jun Asanuma  Tetsuo Ohata 《Boundary-Layer Meteorology》2004,111(3):491-522

This study investigates the convective boundary layer (CBL) that develops over anon-homogeneous surface under different thermal and dynamic conditions. Analysesare based on data obtained from a Russian research aircraft equipped with turbulentsensors during the GAME-Siberia experiment over Yakutsk in Siberia, from April to June 2000.Mesoscale thermal internal boundary layers (MTIBLs) that radically modified CBLdevelopment were observed under unstable atmospheric conditions. It was found thatMTIBLs strongly influenced the vertical and horizontal structures of virtual potentialtemperature, specific humidity and, most notably, the vertical sensible and latent heatfluxes. MTIBLs in the vicinity of the Lena River lowlands were confirmed by clouddistributions in satellite pictures.MTIBLs spread through the entire CBL and radically modify its structure if the CBL isunstable, and strong thermal features on the underlying surface have horizontal scalesexceeding 10 km. MTIBL detection is facilitated through the use of special parameterslinking shear stress and convective motion.The turbulent structure of the CBL with and without MTIBLs was scaled usingthe mosaic or flux aggregate approach. A non-dimensional parameterL_Rau/L_hetero (where L_Rau is Raupach's length and L_hetero is the horizontal scale of the surface heterogeneity)estimates the application limit of similarity and local similarity scaling models forthe mosaic parts over the surface. Normalized vertical profiles of wind speed, airtemperature, turbulent sensible and latent heat fluxes for the mosaic parts withL_RauL_hetero < 1 could be estimated by typical scalingcurves for the homogeneous CBL. Traditional similarity scaling models for the CBLcould not be applied for the mosaic parts with L_Rau/L_hetero > 1.For some horizontally non-homogeneous CBLs, horizontal sensible heat fluxes werecomparable with the vertical fluxes. The largest horizontal sensible heat fluxes occurred at the top of the surface layer and below the top of the CBL.Formerly affiliated to the Frontier Observational Research System for Global ChangeFormerly affiliated to the Frontier Observational Research System for Global Change  相似文献