Intra-oceanic island arc origin for Iratsu eclogites of the Sanbagawa belt,central Shikoku,southwest Japan     

Atsushi Utsunomiya  Bor-ming Jahn  Kazuaki Okamoto  Tsutomu Ota  Hironao Shinjoe 《Chemical Geology》2011,280(1-2):97-114

New geochemical and Sr–Nd isotopic data for the Iratsu eclogite and surrounding metamorphic rocks of the Sanbagawa belt, Japan, show that, while the protoliths of the metamorphic rocks formed in a variety of tectonic settings, the Iratsu body represents a deeply subducted and accreted island arc. The igneous protoliths of eclogites and garnet amphibolites were probably generated from a mantle source that had components of both a depleted mantle modified by slab-released fluid (as seen in a negative Nb anomaly) and an enriched mantle, similar to that of ocean island basalts (OIB). Fractional crystallization modeling indicates that the protoliths of some garnet clinopyroxenites from the Iratsu body are cumulates from a basaltic magma that crystallized under high O₂ and H₂O fugacities in the middle to lower crust. The source characteristics and crystallization conditions suggest that the protoliths of the Iratsu rocks formed in an oceanic island arc. Quartz eclogites from the marginal zone of the Iratsu body have geochemical signatures similar to turbidites from the Izu–Bonin island arc (as seen in a negative Nb anomaly and a concave REE pattern). The protoliths might be volcaniclastic turbidites that formed in a setting proximal to the oceanic island arc. Geochemical and isotopic signatures of the surrounding mafic schists are similar to normal (N-) and enriched (E-) mid-ocean-ridge basalt (MORB), and distinct from the rocks from the Iratsu body. The protoliths of the mafic schists likely formed in a plume-influenced mid-ocean ridge or back-arc basin. Pelitic schists from the surrounding rocks and pelitic gneisses from the marginal zone of the Iratsu body have evolved, continental geochemical signatures (as seen in a negative ε_Nd(t) value (~?5)), consistent with their origin as continent-derived trench-fill turbidites.  相似文献   

Empirical ocean-color algorithms to retrieve chlorophyll-a, total suspended matter, and colored dissolved organic matter absorption coefficient in the Yellow and East China Seas   总被引：4，自引：1，他引：3  

Eko Siswanto  Junwu Tang  Hisashi Yamaguchi  Yu-Hwan Ahn  Joji Ishizaka  Sinjae Yoo  Sang-Woo Kim  Yoko Kiyomoto  Keiko Yamada  Connie Chiang  Hiroshi Kawamura 《Journal of Oceanography》2011,67(5):627-650

A bio-optical dataset collected during the 1998?C2007 period in the Yellow and East China Seas (YECS) was used to provide alternative empirical ocean-color algorithms in the retrieval of chlorophyll-a (Chl-a), total suspended matter (TSM), and colored dissolved organic matter (CDOM) absorption coefficients at 440 nm (ag₄₄₀). Assuming that remote-sensing reflectance (Rrs) could be retrieved accurately, empirical algorithms for T_Chl (regionally tuned Tassan??s Chl-a algorithm) in case-1 waters (T_Chl2i in case-2 waters), T_TSM (regionally tuned Tassan??s TSM algorithm), and T_ag440 or C_ag440 (regionally tuned Tassan??s or Carder??s ag₄₄₀ algorithm) were able to retrieve Chl-a, TSM, and ag₄₄₀ with uncertainties as high as 35, 46, and 35%, respectively. Applying the standard SeaWiFS Rrs, T_Chl was not viable in the eastern part of the YECS, which was associated with an inaccurate SeaWiFS Rrs retrieval because of improper atmospheric correction. T_Chl behaved better than other algorithms in the turbid case-2 waters, although overestimation was still observed. To retrieve more reliable Chl-a estimates with standard SeaWiFS Rrs in turbid water (a proxy for case-2 waters), we modified T_Chl for data with SeaWiFS normalized water-leaving radiance at 555 nm (nLw₅₅₅) > 2 mW cm^?2 ??m^?1 sr^?1 (T_Chl2s). Finally, with standard SeaWiFS Rrs, we recommend switching algorithms from T_Chl2s (for case-2 waters) to MOC_Chl (SeaWiFS-modified NASA OC4v4 standard algorithm for case-1 waters) for retrieving Chl-a, which resulted in uncertainties as high as 49%. To retrieve TSM and ag₄₄₀ using SeaWiFS Rrs, we recommend empirical algorithms for T_TSM (pre-SeaWiFS-modified form) and MT_ag440 or MC_ag440 (SeaWiFS Rrs-modified forms of T_ag440 or C_ag440). These could retrieve with uncertainties as high as 82 and 52%, respectively.  相似文献   

Ductile deformation and development of andalusite microstructures in the Hongusan area: Constraints on the metamorphism and tectonics of the Ryoke Belt     

Yoko  Adachi  Simon  Wallis 《Island Arc》2008,17(1):41-56

Abstract   The main mesoscopic features of the ductile deformation in the Hongusan region of the Ryoke Belt can be explained in terms of a single deformation phase, Dm . The associated stretching lineation is roughly east–west and has an associated top-to-the-west sense of shear. This information fills an important gap in our knowledge about the deformational history of the Ryoke metamorphic belt. Andalusite porphyroblasts are well-developed in the Hongusan area and their microstructure can be used to link the deformational history with the metamorphism. However, the andalusite porphyroblasts show both intertectonic and post-tectonic microstructures. Some porphyroblasts have an intertectonic core and post-tectonic rim. Analysis of associated metamorphic minerals and bulk-rock chemistry suggests that the distinct types of microstructure can be explained in terms of distinct formation reactions related to regional and contact metamorphism. The intertectonic microstructure shows the presence of a deformation pre-dating Dm , referred to as Dc . These two deformation stages are sufficient to account for all the main deformation features. The distribution of post-tectonic andalusite growth shows a very broad thermal effect around an intrusion in the area. This can help place constraints on the thermal history of the Ryoke metamorphic belt.  相似文献   

Thermobaric structure of the Kokchetav ultrahigh-pressure–high-pressure massif deduced from a north–south transect in the Kulet and Saldat–Kol regions, northern Kazakhstan     

Tsutomu Ota  Masaru Terabayashi  Christopher D. Parkinson and  Hideki Masago 《Island Arc》2000,9(3):328-357

Abstract To investigate the regional thermobaric structure of the diamondiferous Kokchetav ultrahigh‐pressure and high‐pressure (UHP–HP) massif and adjacent units, eclogite and other metabasites in the Kulet and Saldat–Kol regions, northern Kazakhstan, were examined. The UHP–HP massif is subdivided into four units, bounded by subhorizontal faults. Unit I is situated at the lowest level of the massif and consists of garnet–amphibolite and acidic gneiss with minor pelitic schist and orthogneiss. Unit II, which structurally overlies Unit I, is composed mainly of pelitic schist and gneiss, and whiteschist locally with abundant eclogite blocks. The primary minerals observed in Kulet and Saldat–Kol eclogites are omphacite, sodic augite, garnet, quartz, rutile and minor barroisite, hornblende, zoisite, clinozoisite and phengite. Rare kyanite occurs as inclusions in garnet. Coesite inclusions occur in garnet porphyroblasts in whiteschist from Kulet, which are closely associated with eclogite masses. Unit III consists of alternating orthogneiss and amphibolite with local eclogite masses. The structurally highest unit, Unit IV, is composed of quartzitic schist with minor pelitic, calcareous, and basic schist intercalations. Mineral assemblages and compositions, and occurrences of polymorphs of SiO₂ (quartz or coesite) in metabasites and associated rocks in the Kulet and Saldat–Kol regions indicate that the metamorphic grades correspond to epidote–amphibolite, through high‐pressure amphibolite and quartz–eclogite, to coesite–eclogite facies conditions. Based on estimations by several geothermobarometers, eclogite from Unit II yielded the highest peak pressure and temperature conditions in the UHP–HP massif, with metamorphic pressure and temperature decreasing towards the upper and lower structural units. The observed thermobaric structure is subhorizontal. The UHP–HP massif is overlain by a weakly metamorphosed unit to the north and is underlain by the low‐pressure Daulet Suite to the south; boundaries are subhorizontal faults. There is a distinct pressure gap across these boundaries. These suggest that the highest grade unit, Unit II, has been selectively extruded from the greatest depths within the UHP–HP unit during the exhumation process, and that all of the UHP–HP unit has been tectonically intruded and juxtaposed into the adjacent lower grade units at shallower depths of about 10 km.  相似文献   

Effect of biogeochemical diagenesis on sediment fabric in shallow marine carbonate sediments near the Dry Tortugas, Florida     

Yoko Furukawa  Dawn Lavoie  Kevin Stephens 《Geo-Marine Letters》1997,17(4):283-290

 Shallow marine carbonate sediments near the Dry Tortugas undergo extensive biogeochemical diagenesis upon deposition, resulting in postdepositional fabric comprised of micritic aggregates of clay-sized particles, a matrix of peloidal mud, and intraparticular cementation. Freshly deposited primary skeletons, mostly Halimeda fragments, yield micritic aggregates of clay-sized particles, which then form peloidal mud fabric upon compaction. The cryptocrystalline particles produced by micritization are later replaced by high magnesian calcite. Cementation is observed in the intra-particular microenvironment. However, no inter-particular, grain-binding cement was detected throughout the gravity core samples investigated.  相似文献   

Interdecadal changes of the Indian Ocean subtropical dipole mode     

Yoko Yamagami  Tomoki Tozuka 《Climate Dynamics》2015,44(11-12):3057-3066

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Rapid contamination during storage of carbonaceous chondrites prepared for micro FTIR measurements     

Yoko KEBUKAWA  Satoru NAKASHIMA  Takahiro OTSUKA  Keiko NAKAMURA‐MESSENGER  Michael E. ZOLENSKY 《Meteoritics & planetary science》2009,44(4):545-557

Abstract— Organic contamination (?2965 and ?1260 cm^?1peaks) was found on Tagish Lake (C2) and Murchison (CM2) carbonaceous chondrites containing abundant hydrous minerals by Fourier transform infrared (FTIR) microspectroscopy on the samples pressed on Al plates. On the other hand, anhydrous chondrite (Moss, CO3) was not contaminated. This contamination occurred within one day of storage, when the samples pressed on Al were stored within containers including silicone rubber mats. Volatile molecules having similar peaks to the contaminants were detected by long‐path gas cell FTIR measurements for the silicone rubber mat. Rapid adsorption of the volatile contaminants also occurred when silica gel and hydrous minerals such as serpentine were stored in containers including silicone rubber, silicone grease, or adhesive tape. However, they did not show any contamination when stored in glass and polystyrene containers without these compounds. Therefore, precious astronomical samples such as meteorites, interplanetary dust particles (IDPs), and mission‐returned samples from comets, asteroids, and Mars, should be measured by micro FTIR within one day of storage in glass containers without silicone rubber, silicone grease, or adhesive tape.  相似文献   

Kinetics of organic matter degradation in the Murchison meteorite for the evaluation of parent‐body temperature history     

Yoko KEBUKAWA  Satoru NAKASHIMA  Michael E. ZOLENSKY 《Meteoritics & planetary science》2010,45(1):99-113

Abstract– To evaluate kinetic parameters for thermal degradation of organic matter, in situ heating experiments of insoluble organic matter (IOM) and bulk of Murchison (CM2) meteorite were conducted under Fourier transform infrared micro‐spectroscopy combined with a heating stage. Decreases of aliphatic C–H band area under Ar flow were well fitted with Ginstling‐Brounshtein three‐dimensional diffusion model, and the rate constants for decreases of aliphatic C–H were determined. Activation energies E_a and frequency factors A obtained from these rate constants at different temperatures using the Arrhenius equation were E_a = 109 ± 3 kJ mol^?1 and A = 8.7 × 10⁴ s^?1 for IOM, and E_a = 61 ± 6 kJ mol^?1 and A = 3.8 s^?1 for bulk, respectively. Activation energy values of aliphatic C–H decrease are larger for IOM than bulk. Hence, the mineral assemblage of the Murchison meteorite might have catalytic effects for the organic matter degradation. Using obtained kinetic expressions, the time scale for metamorphism can be estimated for a given temperature with aliphatic C–H band area, or the temperature of metamorphism can be estimated for a given time scale. For example, using the obtained kinetic parameters of IOM, aliphatic C–H is lost approximately within 200 years at 100 °C and 100 Myr at 0 °C. Assuming alteration period of 7.5 Myr, alteration temperatures could be calculated to be <15 ± 12 °C. Aliphatic C–H decrease profiles in a parent body can be estimated using time–temperature history model. The kinetic expression obtained by the infrared spectral band of aliphatic C–H could be used as an alternative method to evaluate thermal processes of organic matter in carbonaceous chondrites.  相似文献   

Silicon flux and distribution of biogenic silica in deep-sea sediments in the western North Pacific Ocean     

Yoko Shibamoto  Koh Harada 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(2):163-174

We investigated biogenic silica, several biological components, and silicate in pore-water in the abyssal sediment to determine silicon flux of western North Pacific during several cruises. The surficial sediment biogenic silica content was high at high latitudes with the boundary running along the Kuroshio Extension, and maximum values (exceeding 20%) were found in the Oyashio region. In the subtropical region to the south, most stations showed less than 5% biogenic silica content. This distribution pattern reflected primary production and ocean currents in the surface layer very well. Pore-water samples were collected from 4 stations along the east coast of Japan. The highest asymptotic silicic acid concentration (670 μmol L^?1) in pore-water was observed at the junction of Kuroshio and Oyashio, followed by samples from the Oyashio region. It is at the southern station that the lowest value (450 μmol L^?1) was observed, and the primary production is low under the influence of Kuroshio there. The diffusive flux followed the same geographic trend as the asymptotic silicic acid concentrations did, ranging 77–389 mmol m^?2 yr ^?1. Multiple sampling of pore-water was conducted throughout the year at one station at high latitude. The average annual biogenic silica rain flux observed using sediment traps was 373 mmol m^?2 yr^?1; the diffusive flux and burial flux at the sediment–water interface were 305 and 9 mmol m^?2 yr^?1, respectively. We concluded that most of the settling silica particles dissolved and diffused at the sediment–water interface and approximately 3% only were preserved in this area. In addition, the obvious time lag observed between the peak rain flux and the maximum diffusive flux suggested that primary production in the surface layer has a great influence on the sedimentation environment of abyssal western North Pacific. These transitions of Si flux at the sediment–water interface were considerably greater in northwestern North Pacific than in southwestern North Pacific. In addition, a station in the Philippine Sea indicated high biogenic silica content because of Ethmodiscus ooze, which are scattered randomly on the sea floor in the subtropical region.  相似文献   

Source parameters of some presumed Semipalatinsk underground nuclear explosions     

Ota Kulhánek 《Pure and Applied Geophysics》1973,102(1):51-66

Summary Short-period vertical-componentP-wave spectra of seven presumed Semipalatinsk underground nuclear explosions, recorded by the Swedish seismic station network, are investigated. The events considered have closely spaced foci and cover the magnitude range fromm _b=5.5 tom _b=6.6. Spectra of six of these explosions show pronounced minima, varying from about 1.5 to 1.8 cps, which could be explained as principle minima due toP-pP interference. Supposing a nearsurfaceP-wave velocity at the test area of 4 km/sec, the shot depths are estimated to vary roughly from 750 to 1350 m. In order to obtain an estimate of the yield, the observed spectra are compared withHaskell's theoretical source spectra. For four events, relative yield estimates fit well the predicted values for explosions fired in a granitic medium. The behaviour of the remaining three explosions is discussed in detail.  相似文献