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41.
Lidong Dai Yuki Kudo Kei Hirose Motohiko Murakami Yuki Asahara Haruka Ozawa Yasuo Ohishi Naohisa Hirao 《Physics and Chemistry of Minerals》2013,40(3):195-201
The sound velocities of two aluminum-rich phases in the lower mantle, hexagonal new Al-rich phase (NAL) and its corresponding high-pressure polymorph orthorhombic Ca-ferrite-type phase (CF), were determined with the Brillouin scattering method in a pressure range from 9 to 73 GPa at room temperature. Both NAL and CF samples have identical chemical composition of Na0.4Mg0.6Al1.6Si0.4O4 (40 % NaAlSiO4–60 % MgAl2O4). Infrared laser annealing in the diamond anvil cell was performed to minimize the stress state of the sample and obtain the high-quality Brillouin spectra. The results show shear modulus at zero pressure G 0 = 121.960 ± 0.087 GPa and its pressure derivative G’ = 1.961 ± 0.009 for the NAL phase, and G 0 = 129.653 ± 0.059 GPa and G’ = 2.340 ± 0.004 for the CF phase. The zero-pressure shear velocities of the NAL and CF phases are obtained to be 5.601 ± 0.005 km/sec and 5.741 ± 0.001 km/sec, respectively. We also found that shear velocity increases by 2.5 % upon phase transition from NAL to CF at around 40 GPa. 相似文献
42.
Arnold Gucsik Taro Endo Hirotsugu Nishido Kiyotaka Ninagawa Masahiro Kayama Szaniszló Bérczi Szabolcs Nagy Péter Ábrahám Yuki Kimura Hitoshi Miura Ildikó Gyollai Irakli Simonia Péter Rózsa József Posta Dániel Apai Krisztián Mihályi Mihály Nagy Ulrich Ott 《Meteoritics & planetary science》2013,48(12):2577-2596
Highly forsteritic olivine (Fo: 99.2–99.7) in the Kaba meteorite emits bright cathodoluminescence (CL). CL spectra of red luminescent forsterite grains have two broad emission bands at approximately 630 nm (impurity center of divalent Mn ions) in the red region and above 700 nm (trivalent Cr ions) in the red–IR region. The cores of the grains show CL blue luminescence giving a characteristic broad band emission at 400 nm, also associated with minor red emissions related to Mn and Cr ions. CL color variation of Kaba forsterite is attributed to structural defects. Electron probe microanalyzer (EPMA) analysis shows concentrations of Ca, Al, and Ti in the center of the forsterite grain. The migration of diffusible ions of Mn, Cr, and Fe to the rim of the Kaba meteoritic forsterite was controlled by the hydrothermal alteration at relatively low temperature (estimated at about 250 °C), while Ca and Al ions might still lie in the core. A very unusual phase of FeO (wüstite) was also observed, which may be a terrestrial alteration product of FeNi‐metal. 相似文献
43.
Geochemical characteristics of deposits from the 2011 Tohoku‐oki tsunami at Hasunuma,Kujukuri coastal plain,Japan 
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下载免费PDF全文 Tetsuya Shinozaki Yuki Sawai Junko Hara Minoru Ikehara Dan Matsumoto Koichiro Tanigawa 《Island Arc》2016,25(5):350-368
We examined the geochemical characteristics and temporal changes of deposits associated with the 2011 Tohoku‐oki tsunami. Stable carbon isotope ratios, biomarkers, and water‐leachable ions were measured in a sandy tsunami deposit and associated soils sampled at Hasunuma, Kujukuri coastal plain, Japan, in 2011 and 2014. At this site, the 2011 tsunami formed a 10–30 cm ‐thick layer of very fine to medium sand. The tsunami deposit was organic‐poor, and no samples contained any detectable biomarkers of either terrigenous or marine origin. In the underlying soil, we identified hydrocarbons and sterols derived from terrestrial plants, but detected no biomarkers of marine origin. In the samples collected in 2011, concentrations of tsunami‐derived water‐leachable ions were highest in the soil immediately beneath the tsunami deposit and then decreased gradually with depth. Because of its finer texture and higher organic content, the soil has a higher water‐holding capacity than the sandy tsunami deposit. This distribution suggests that ions derived from the tsunami quickly penetrated the sand layer and became concentrated in the underlying soil. In the samples collected in 2014, concentrations of water‐leachable ions were very low in both soil and sand. We attribute the decrease in ion concentrations to post‐tsunami rainfall, seepage, and seasonal changes in groundwater level. Although water‐leachable ions derived from seawater were concentrated in the soil beneath the tsunami deposit following the tsunami inundation, they were not retained for more than a few years. To elucidate the behavior of geochemical characteristics associated with tsunamis, further research on organic‐rich muddy deposits (muddy tsunami deposits and soils beneath sandy tsunami deposits) as well as sandy tsunami deposits is required. 相似文献
44.
We describe the petrography and mineralogy of six CV3 carbonaceous chondrites. LAP02206, LAP02228, LAP04843, and GRA06101 are classified as oxidized Allende-like chondrites (CV3oxA). RBT04143 and QUE97186 are classified as members of the reduced subtype (CV3red). Chondrules in the CV3oxA chondrites show extensive Fe–Mg zoning. Fe-rich olivine in the rims of the CV3oxA chondrules are 16O-poor relative to Mg-rich olivine in the cores, suggesting that in addition to Fe and Mg, oxygen was exchanged between chondrules and matrix during weak thermal metamorphism. The CV3red chondrites appear to have formed through various processes. QUE97186 shows chondrule flattening with a preferred orientation, which is interpreted to have resulted from shock impact at a pressure of ～20 GPa. The post-shock residual heat (～1000 °C) is likely to be responsible for the restricted Fe/Mg ratios of matrix olivine. Based on the degree of Fe–Mg homogenization of matrix olivines, we estimate the spatial scale of the shock-heated region to be ～1 m. RBT04143 is a breccia containing many clasts of two types of lithologies: reduced-type material and very weakly altered material. 相似文献
45.
Coupling fluvial processes and landslide distribution toward geomorphological hazard assessment: a case study in a transient landscape in Japan 总被引：1，自引：0，他引：1
Ching-Ying Tsou Masahiro Chigira Yuki Matsushi Narumi Hiraishi Noriyuki Arai 《Landslides》2017,14(6):1901-1914
This study quantified the relationship among deep-seated gravitational slope deformations (DGSDs), landslides, and river rejuvenation in the upper reaches of the Kumano River in the Kii Mountains of Japan, an area of frequent bedrock landslides. River profiles and hillslope landforms were examined, and high-resolution digital elevation models (DEMs) were used to identify DGSDs and landslides. Many of the deep-seated landslides were associated with rainstorms in 1889 and 2011. Landslide volumes were related to landslide areas on the basis of 52 deep-seated landslides that failed during the 2011 rainfall, providing basic data for landscape denudation and sediment yield. River rejuvenation occurred stepwise, incising moderate relief paleosurfaces and forming two series of knickpoints and V-shaped inner gorges that are up to 400-m deep. More than 65% of DGSDs and 75% of the landslides were located in association with the incised inner gorges along the peripheries of the paleosurfaces or were entirely contained within the inner gorges. DGSDs and landslides associated with the incised inner valley slopes tended to be larger than those developed within the paleosurfaces and may be long-term transient hillslope responses to river incision. Hillslope undercutting caused by rejuvenated river incision may play an important role in long-term slope stability and distribution of mass movements, and could serve as an indicator of landslide hazard. 相似文献
46.
Konstantin Frisch Silke Voigt Thomas Voigt Alexandra Hellwig Verena Verestek Yuki Weber 《Sedimentology》2019,66(5):1716-1745
Central Asia witnessed progressive aridification during the Miocene, commonly related to mountain uplift, the Paratethys retreat and global climate cooling. However, the formation of Miocene lakes in Central Asia seems to oppose drier conditions, suggesting that the precise timing, extent and forcing of the aridification is still not well constrained. This study presents a facies model for the alluvial–lacustrine part of the Middle to Late Miocene of the Ili Basin, obtained from two successions. The model enables the semi‐quantitative assessment of regional water level and salinity, and characterizes the control of water level on evaporite formation and diagenesis. Both the proximal Kendyrlisai and the distal Aktau successions show an overall increase in water availability from dry mudflat deposits to lacustrine sedimentation with a transitional playa phase. Increasing evaporation rates outpaced the water supply and caused groundwater salinization. Subsequent lake expansion coincided with a basin‐wide desalinization and required a shift to a positive water budget. A climatic control of the hydrological evolution is inferred due to abrupt salinization and a minor tectonic influence. The long‐term water accumulation is probably related to the hydrological closure of the basin in the early Middle Miocene (15·3 Ma). Starting at 14·3 Ma, the step‐wise salinization occurred simultaneously with the global cooling of the Miocene Climate Transition. The Miocene Climate Transition led to extreme aridity in the Ili Basin, highlighted by the early diagenetic formation of displacive anhydrite in the basin centre. The expansion of the freshwater lake (12·7 to 11·5 Ma) was possibly promoted by lower evaporation rates due to decreasing air temperatures in the Ili Basin after the Miocene Climate Transition. The extreme aridity in the Ili Basin is interpreted as a continental counterpart to the Badenian Salinity Crisis in the Central Paratethys. This emphasizes the role of atmospheric forcing on evaporite sedimentation across Eurasia during the Middle Miocene. 相似文献
47.
Yuki Hibiya Tsuyoshi Iizuka Katsuyuki Yamashita Shigekazu Yoneda Akane Yamakawa 《Geostandards and Geoanalytical Research》2019,43(1):133-145
Combined determination of Cr and Ti isotopes of planetary materials offers a means with which to investigate their genetic relationship and the evolution of the protoplanetary disk. Here, we report the new sequential chemical separation procedure for combined Cr and Ti isotope ratio measurements. It comprises three steps: (a) Fe removal using AG1‐X8 anion exchange resin, (b) Ti separation using TODGA resin and (c) Cr separation using AG50W‐X8 cation exchange resin (with one additional step of Ti purification using AG1‐X8 anion exchange resin for samples having high Cr/Ti and Ca/Ti ratios). We applied the proposed procedure to terrestrial and meteorite samples with various compositions. Typical recovery rates of 90–100% were achieved with total procedural Cr and Ti blanks of 3–5 and 2–3 ng, respectively. We measured the Cr and Ti isotope compositions of the separated samples using thermal ionisation mass spectrometry and multiple collector‐inductively coupled plasma‐mass spectrometry, respectively. Our Cr and Ti isotope data were found to be consistent with those of previous studies of individual Cr and Ti isotopic compositions of the meteorites. These results demonstrate the capability of our separation method when applied to combined high‐precision Cr and Ti isotope analyses for single digests of planetary materials. 相似文献
48.
A series of in-situ high temperature infrared (IR) measurements of water in an agate sample and in a milky quartz has been conducted in order to understand the nature of water in silica at high temperatures (50–700?°C) and the dehydration behavior. IR absorption bands of water molecules trapped in the milky quartz showed a systematic decrease in intensities and a shift from 3425?cm?1 at 50?°C toward 3590?cm?1 at 700?°C without any loss of water. This indicates a change in IR absorption coefficients corresponding to different polymeric states of water at different temperatures. The broad 3430?cm?1 band in the agate sample also showed a systematic decrease in IR intensity and a band shift toward higher frequency with increasing temperature (～700?°C). This indicates that the agate sample also contains fluid inclusion-like water. For this agate sample, a dehydration of loosely hydrogen-bonded molecular water occurred at lower temperatures (<200?°C). At higher temperatures (>400?°C), sharp bands around 3660 and 3725?cm?1 (3740?cm?1 at 50?°C) due to surface silanols, appeared. This indicates dehydration of H2O molecules that are hydrogen bonded to surface silanols. SiOH species in the agate are divided into three groups, namely SiOH group located at structural defects, surface silanols hydrogen bonded to each other and free surface silanols. Former two dehydrate below 700?°C and the dehydration rate of the SiOH at structural defects is faster than the other. IR spectra show that SiOH species decrease continuously even after the dehydration of most of H2O molecules. All these results provide realistic bases for the change in physicochemical states of different OH species in silica at high temperatures. 相似文献
49.
We conducted a seismic tomographic analysis to estimate the crustal structure beneath the Shikoku and Chugoku regions in Japan. The Philippine Sea slab (PHS slab) subducts continuously in a SE–NW direction beneath this region, and the crustal structure is complex. Furthermore, the Median Tectonic Line (MTL), one of the longest and most active arc-parallel fault systems in Japan (hereafter, the MTL active fault system), is located in this area, and the right-lateral strike–slip movement of this fault system is related to the oblique subduction of the PHS slab. The MTL active fault system has ruptured repeatedly during the last 10 000 years, and has high seismic potential. Our tomographic analysis clarified the heterogeneous crustal structure along the MTL active fault system. This fault system in Shikoku can be divided into two segments, an east segment and a west segment, on the basis of the velocity structure. This segmentation model is consistent with other such models that have been determined from geological and geomorphological data such as fault geometry, slip rate, and faulting history. This consistency suggests that the surface characteristics of the MTL active fault system are related to structural properties of the crust. In particular, a prominent low-velocity (low-V) zone is present in the lower crust beneath the east segment. Our tomographic images show that the lower crust structure beneath the east segment is obviously different from that of the other segment. Furthermore, this low-V zone may indicate the presence of fluid, possibly related to dehydration of the PHS slab. As the presence of fluid in the lower crust affects the activity of the fault, stress accumulation and the fault failure mechanism may differ between the two segments of the MTL active fault system. 相似文献
50.
Tsushima Island is one of the oldest zinc-lead mining areas in Japan. River water and sediment samples were collected mainly from Taishu area to determine the contamination level of Zn and to clarify its behaviour in the natural system. Among the water samples analysed, 64% exceeded the standard environmental limit of 0.03 µg ml− 1 for Zn. In most cases, Zn concentration in sediment samples also exceeded the standard value, and the concentration varied from 86.75–7490.07 µg g− 1. The mineralogical constituents in sediments were almost similar and quartz had the strongest peak, but the interior part of the ores had many minerals, with galena having the highest proportion. Considering the enrichment factor values (EFc), 12 samples have values of more than 50, indicating a high pollution load for Zn. This study revealed that the sulphide ores, and contaminated sediments, are the possible contamination sources of Shiine River, and Zn dissolution occurred by reactions, such as desorption and ion exchange. 相似文献