蒸发岩中硫同位素的地球化学特征及其沉积学意义——以思茅盆地MZK- 3井为例   总被引：2，自引：0，他引：2  

苗忠英  郑绵平  张雪飞  张震  高运志 《地质学报》2019,93(5):1166-1179

思茅盆地目前是中国唯一的含古代固体钾盐矿床的沉积盆地,其钾盐形成时代、物源特征、海侵方向等多年来一直存在争议。本文依据海相硬石膏的形成条件、存在形式、同位素分馏机理,重点分析了盆地内MZK-3井蒸发岩硫同位素的地球化学特征。结果表明:①岩盐中的硬石膏在蒸发盆地析岩盐阶段即可形成,单独成层的硬石膏是由原始沉积的石膏经历了沉积埋藏升温进而脱水而成;②岩盐中硬石膏的硫同位素值具有"双峰"特征,分别为14‰～16‰和8‰～10‰或6‰～8‰,这体现了硫酸盐的双重来源——原始海水中的硫酸盐和陆源淡水输入的硫酸盐或火山活动提供的硫源;③硬石膏层的硫同位素在区域上具有对比性,结合~(87)Sr/~(86)Sr值的特征,认为其代表了海相的沉积环境;④硬石膏层的硫同位素值平面上由南向北降低,可能反映了在此方向陆源淡水或火山活动对蒸发岩盆地的影响逐渐增强,进而说明这可能也是海侵的方向。可见对硬石膏硫同位素的研究,不仅在沉积学上能揭示物源、沉积环境、海侵方向等信息,更能对研究区钾盐矿床勘查提供有益的参考。  相似文献   

高原季节性冻土区砂土液化探讨——以阿克陶MS6.7地震为例     

姚远  陈杰  李涛  付博  王浩然  李跃华 《第四纪研究》2019,39(2):381-390

2016年11月25日新疆阿克陶县木吉乡发生MS6.7地震,发震构造为公格尔山拉张系北端的木吉断裂,断裂总长度超过100 km,以右旋走滑为主兼有一定的拉张分量。文章在对震区进行了初步的地震地质灾害调查,总结砂土液化和地裂缝在高原季节性冻土地区的分布及发育特点的基础上,发现:1)在研究区Ⅰ维日麻村的砂土液化主要沿原有泉眼或沿地裂缝发育,沿泉眼形成的砂土液化其喷砂锥的覆盖面积达36.1 m2,占总液化面积的60%,研究区Ⅱ布拉克村的砂土液化则主要是沿草甸的根系喷出,在地表形成大面积的最新涌水结冻特征;2)对研究区Ⅱ布拉克村地裂缝的深度进行统计,反演出区域冻土层厚度,结合探槽揭露的地层剖面,推断冻土层发生大面积地裂缝是因为地震引起冻土层下部融土层发生砂土液化导致土层变形失稳,从而使冻土层发生形变产生一系列规律性的地裂缝。  相似文献   

水库水体二氧化碳分压研究进展     

姚玲  高全洲  陶贞  邓浩俊  冯雍  李银花 《第四纪研究》2019,39(5):1264-1275

天然水体中存在同化二氧化碳(CO2)的光合作用,也存在释放CO2的微生物呼吸过程。地球表层水体与大气之间的CO2交换构成全球碳循环的一个重要环节。水-气之间CO2交换的方向和通量主要受大气圈和水体表层CO2分压(pCO2)的制约。水体pCO2值可以通过对近水面气体成分变化过程的现场仪器检测或者根据测定的水体化学参数运用经验公式计算求得。迄今对陆地水体,尤其河流筑坝形成的"蓄水河流"(下称水库)水体CO2动态研究中,由于水域及其近表层大气成分的时空多变,一般采用水化学参数计算方法求得水体的pCO2值。全球约70.97%的水库表层水体pCO2高于大气pCO2。全球尺度上水库表层水体pCO2自热带向寒温带逐渐递减;单个水库水体的pCO2一般呈现"出库>入库>库中"、pCO2随深度而增加的变化规律。水库表层水体pCO2的时间变化一般表现为"冬季>夏季、消融期>冰冻期、黑夜>白天"。水库水体的pCO2是其水化学平衡的结果,受水温、水体pH、水生生物活动以及外来水体的混合等多种因素影响,变化较为复杂。为精确量化水库水-气界面CO2交换通量,水文学、湖沼学、生态学和地球化学等领域的学者有必要合作,共同努力进行水库流域尺度的实地观测,完善水体溶解无机碳计算模型,深入探讨水库水体碳动力学机制,为全球碳循环研究和气候变化预测提供可靠的基础数据。  相似文献   

羌塘盆地中央隆起带的抬升演化:构造-热年代学约束     

赵珍  陆露  吴珍汉 《地学前缘》2019,26(2):249-263

本文综合磷灰石裂变径迹年龄(113~43 Ma)、锆石裂变径迹年龄(169~103 Ma)、锆石U-Pb年龄(215~206 Ma)、黑云母K-Ar年龄(186~178 Ma),通过磷灰石热史模拟,TASC图谱分析和矿物封闭温度年龄等手段,获得了中央隆起晚三叠世至今较为完整的冷却抬升历史。中央隆起主要经历了早侏罗世、晚侏罗世-早白垩世、晚白垩世-中新世早期和中新世晚期至今四期冷却事件,与南北羌塘板块后碰撞伸展、拉萨羌塘板块碰撞、新特提斯洋板片俯冲、印度欧亚板块碰撞以及中新世南北向走滑伸展存在动力学联系,造成11.4 km、2.85 km、4.3~5 km和0.85 km的抬升量。中央隆起在侏罗纪相对两侧盆地抬升,随着两侧盆地经历了侏罗纪的沉积增厚,与两侧盆地高差减小,在早白垩世早期可能位于海平面附近,随后快速抬升至2~2.5 km,统一接受晚白垩世红层沉积,并经历长期持续的逆冲推覆构造活动,进一步抬升至5 km,随后受到中新世古大湖夷平和南北向伸展作用影响,中央隆起相对盆地发生差异抬升。  相似文献   

盐亭县崩塌稳定性分析与防治     

李振 《地质灾害与环境保护》2019,(2):27-34

对盐亭县危岩带进行现场地质调查,在此基础上对四处典型危岩体特征进行分析,采用赤平投影法、稳定性计算、坠落轨迹及冲击能计算对危岩体的稳定性进行评估。结果表明:(1)四处危岩体在天然和暴雨工况下均处于不稳定或欠稳定状态;(2)W1、W2、W3三处危岩体的水平崩落距离和末动能较大,对附近居民和公共设施安全造成威胁,有必要采取防治措施;(3)根据现场调查和计算分析,对4处危岩体采取针对性整治措施。  相似文献   

Magmatic‐Hydrothermal Mineralization Sequence in Xinlu Ore Field,Guangxi, South China: Constraints from Zircon U‐Pb,Molybdenite Re‐Os,and Muscovite Ar‐Ar Dating     

Yangyang Feng  Zuohai Feng  Wei Fu  Zhiqiang Kang  Jian Jiang  Along Guo  Xi Wang  Meng Feng  Chunzeng Wang 《Resource Geology》2019,69(4):430-447

The Xinlu Sn‐polymetallic ore field is located in the western Nanling Polymetallic Belt in northeastern Guangxi, South China, where a number of typical skarn‐, hydrothermal vein‐type tin deposits have developed. There are two types of Sn deposits: skarn‐type and sulfide‐quartz vein‐type. The tin mineralizations mainly occur on the south side of the Guposhan granitic complex pluton and within its outer contact zone. To constrain the Sn mineralization age and further understand its genetic links to the Guposhan granitic complex, a series of geochronological works has been conducted at the Liuheao deposit of the ore field using high‐precision zircon SHRIMP U‐Pb, molybdenite Re‐Os, and muscovite Ar‐Ar dating methods. The results show that the biotite‐monzogranite, which is part of the Xinlu intrusive unit of the Guposhan complex pluton, has a SHRIMP U‐Pb zircon age of 161.0 ± 1.5 Ma. The skarn‐type ore has a ⁴⁰Ar‐³⁹Ar muscovite plateau age of 160 ± 2 Ma (same as its isochron age), and the sulfide‐quartz vein‐type ore yields an Re‐Os molybdenite isochron age of 154.4 ± 3.5 Ma. The magmatic‐hydrothermal geochronological sequence demonstrated that the hydrothermal mineralization took place immediately following the emplacement of the monzogranite, with the skarn metasomatic mineralization stage predating the sulfide mineralization stage. Geochronologically, we have compared this ore field with 26 typical Sn deposits distributed along the Nanling Polymetallic Belt, leading to the suggestion of the magmatic‐metallogenic processes in the Xinlu ore field (ca. 161–154 Ma) as a component of the Early Yanshanian large‐scale Sn‐polymetallic mineralization event (peaked at 160–150 Ma) in the Nanling Range of South China. Petrogenesis of Sn‐producing granite and Sn‐polymetallic mineralization were probably caused by crust–mantle interaction as a result of significant lithospheric extension and thinning in South China in the Late Jurassic.  相似文献   

In Situ U‐Th‐Pb Dating and Sr‐Nd Isotope Analysis of Bastnäsite by LA‐(MC)‐ICP‐MS     

Yue‐Heng Yang  Fu‐Yuan Wu  Qiu‐Li Li  Yamirka Rojas‐Agramonte  Jin‐Hui Yang  Yang Li  Qian Ma  Lie‐Wen Xie  Chao Huang  Hong‐Rui Fan  Zi‐Fu Zhao  Cheng Xu 《Geostandards and Geoanalytical Research》2019,43(4):543-565

Bastnäsite is the end member of a large group of carbonate–fluoride minerals with the common formula (REE) CO₃F·CaCO₃. This group is generally widespread and, despite never occurring in large quantities, represents the major economic light rare earth element (LREE) mineral in deposits related to carbonatite and alkaline intrusions. Since bastnäsite is easily altered and commonly contains inclusions of earlier‐crystallised minerals, in situ analysis is considered the most suitable method to measure its U‐Th‐Pb and Sr‐Nd isotopic compositions. Electron probe microanalysis and laser ablation (multi‐collector) inductively coupled plasma‐mass spectrometry of forty‐six bastnäsite samples from LREE deposits in China, Pakistan, Sweden, Mongolia, USA, Malawi and Madagascar indicate that this mineral typically has high Th and LREE and moderate U and Sr contents. Analysis of an in‐house bastnäsite reference material (K‐9) demonstrated that precise and accurate U‐Th‐Pb ages could be obtained after common Pb correction. Moreover, the Th‐Pb age with its high precision is preferable to the U‐Pb age because most bastnäsites have relatively high Th rather than U contents. These results will have significant implications for understanding the genesis of endogenous ore deposits and formation processes related to metallogenic geochronology research.  相似文献   

Basaltic and Solution Reference Materials for Iron,Copper and Zinc Isotope Measurements     

Jin Li  Suo‐han Tang  Xiang‐kun Zhu  Zhi‐hong Li  Shi‐Zhen Li  Bin Yan  Yue Wang  Jian Sun  Yao Shi  Aiguo Dong  Nick S. Belshaw  Xingchao Zhang  Sheng‐ao Liu  Ji‐hua Liu  Deli Wang  Shao‐yong Jiang  KeJun Hou  Anthony S. Cohen 《Geostandards and Geoanalytical Research》2019,43(1):163-175

Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ⁵⁶Fe = 0.83 ± 0.07 and δ⁵⁷Fe = 1.20 ± 0.13, δ⁶⁵Cu = 0.57 ± 0.06, and δ⁶⁶Zn = ?0.79 ± 0.12 and δ⁶⁸Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ⁵⁶Fe = 0.15 ± 0.07, δ⁵⁷Fe = 0.22 ± 0.10, δ⁶⁵Cu = 0.12 ± 0.08, δ⁶⁶Zn = 0.17 ± 0.13, and δ⁶⁸Zn = 0.34 ± 0.26 (2s).  相似文献   

雄安新区蓟县系雾迷山组岩溶热储特征、主控因素及有利区预测^*          下载免费PDF全文

鲁锴  鲍志东  季汉成  刘金侠  王贵玲  马峰  郭瑞婧  曹瑛倬  杨飞  符勇  李潇博  华盈鑫  阙宜娟  李宗峰  许西挺  胡先才 《古地理学报》2019,21(6):885-900

雄安新区蓟县系雾迷山组中赋存丰富的地热资源,研究雾迷山组岩溶热储特征及优质储集层发育的主控因素是地热资源勘探的基础。综合运用野外剖面、岩心、薄片、钻井、测井、录井等地质与地球物理资料,对雾迷山组岩溶热储特征和演化过程进行了深入研究,明确了优质储集层形成的控制因素,预测了有利靶区。结果表明,雾迷山组岩溶热储主要岩性为晶粒白云岩、颗粒白云岩、微生物白云岩、硅质白云岩和角砾白云岩等,溶蚀孔洞、裂缝及其组合为主要的储集空间类型。雾迷山组热储平均孔隙度为3.18%,平均渗透率为91.48×10^-3 μm²;其中角砾白云岩物性最好。雾迷山组岩溶热储经历了沉积—准同生期成孔(雾迷山沉积期)、Ⅰ期表生增孔(雾迷山沉积期后至青白口纪前)、Ⅰ期埋藏减孔(青白口纪前至三叠纪)、Ⅱ期表生增孔(三叠纪—古近纪)、Ⅱ期埋藏减孔(新近纪—第四纪)5个阶段,岩性及岩相、成岩作用和构造应力是雾迷山组有利热储形成的主控因素。藻云坪—云坪相、表生岩溶、埋藏溶蚀、准同生岩溶、岩溶高地—斜坡和地层裂缝段比率大于0.4的6项叠合区是研究区最有利的岩溶热储发育区。  相似文献   

饶河杂岩中枕状玄武岩的锆石U-Pb年代学、地球化学及其地质意义     

曾振  孙雷  张兴洲  崔维龙  蒋力 《地质与资源》2019,28(2):119-127

那丹哈达增生杂岩为中国东部古太平洋板块俯冲最为可靠的地质记录之一,对限定古大洋板块的西向俯冲具有重要的理论意义.饶河杂岩位于那丹哈达增生杂岩的核心位置,发育典型的增生杂岩组合,其中玄武岩类多呈构造透镜体状产出于超镁铁质-镁铁质杂岩带,变形轻微,没有遭受变质.对饶河杂岩中枕状玄武岩样品进行的同位素年代学和地球化学研究结果表明：饶河杂岩中枕状玄武岩锆石LA-ICP-MS U-Pb年龄为中侏罗世（168±2 Ma）,枕状玄武岩大离子亲石元素Rb、Sr亏损,高场强元素Nb、Ta富集,Th元素丰度较高,形成于洋岛（OIB型）环境.饶河杂岩中枕状玄武岩的形成时代和成因环境,对于该区侏罗纪时期构造动力学背景研究具有意义.  相似文献