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11.
Mussels are used as sentinel organisms and bioindicators to evaluate the toxic effects of chemical pollutants in marine organisms, especially heavy metals, representing an important tool for biomonitoring environmental pollution in coastal areas. Antioxidant defence enzymes play an important role in cellular antioxidant defence systems and protect from oxidative damage by reactive oxygen species (ROS). Indigenous mussels Mytilus galloprovincialis of the Saronikos Gulf of Greece were used for monitoring heavy metal pollution in three polluted sites in the area and in one unpolluted site. Seasonal variations of the activity of antioxidant defence enzymes, superoxide dismutase (SOD) and catalase (CAT), as well as lipid peroxidation (LP) were measured as biomarkers in a period of three years in relation to concentrations of trace metals in their gills and mantle and compared to mussels from an unpolluted sampling site. SOD activity increased at least 2 fold at the polluted sites when compared to the control site (the high activity was recorded in the spring time). CAT activity was increased 2-3 times at the polluted sites, with high activity in the winter and spring time, compared to the control site. LP concentration was twice higher at the polluted sites, following the same seasonal pattern. Trace metals contents in mussels collected at polluted sites were 3-4 fold higher compared to the control site and showed moderate variations along the months, with a winter maximum followed by a summer pre-spawning minimum matching the seasonal trends of temperature and salinity. Our results showed that metal pollution in the Elefsis Bay (the most polluted coastal area) causes relatively medium levels of oxidative stress in tissues of mussels due to cellular oxy-radical generation. This study, which is the first in the area, showed that seasonal variations of the activity of antioxidant defence enzymes and LP concentrations in mussels can be used as potential biomarkers of toxicity for long-term monitoring in marine coastal ecosystems.  相似文献   
12.
A computationally efficient and rigorous thermodynamic model that predicts the physical state and composition of inorganic atmospheric aerosol is presented. One of the main features of the model is the implementation of mutual deliquescence of multicomponent salt particles, which lowers the deliquescence point of the aerosol phase.The model is used to examine the behavior of four types of tropospheric aerosol (marine, urban, remote continental and non-urban continental), and the results are compared with the predictions of two other models currently in use. The results of all three models were generally in good agreement. Differences were found primarily in the mutual deliquescence humidity regions, where the new model predicted the existence of water, and the other two did not. Differences in the behavior (speciation and water absorbing properties) between the aerosol types are pointed out. The new model also needed considerably less CPU time, and always shows stability and robust convergence.  相似文献   
13.
In recent years, the additional risk posed to the built environment due to aftershock sequences and triggered events has been brought to attention, and several efforts have been directed towards developing fragility functions for structures in damaged conditions. Despite this rise of interest, a rather fundamental component for such tasks, namely that of aftershock ground motion record selection, has remained under-scrutinized. Herein, we propose a pragmatic procedure that can be applied for the selection of mainshock-aftershock ground motion pairs using consistent causal parameters and accounting for the correlation between their spectral accelerations. In addition, a structural analysis strategy that can be employed for the analytical derivation of damage-dependent fragility functions is outlined and presented through a case study. A more conventional back-to-back IDA analysis is also carried out in order to compare the derived damage-dependent fragility functions with the ones obtained with the proposed procedure. The results indicate that record selection remains a crucial factor even when assessing the structural vulnerability of damaged buildings, and should thus be treated cautiously.  相似文献   
14.
The paper studies the performance of a typical overpass bridge, with continuous deck and monolithic pier-deck connections, subjected to strike-slip faulting. A three-dimensional (3D) finite element (FE) model of the entire bridge–foundation–abutment–soil system is developed, accounting for soil, structure and geometric nonlinearities. Soil behaviour is simulated with a thoroughly validated strain softening constitutive model. The concrete damaged plasticity (CDP) model is implemented for piers, accounting for the interaction between axial force N , bending moment M , shear force Q and torsion T (NMQT ); the model is validated against experimental results from the literature. The location of the fault rupture is parametrically investigated, confirming the vulnerability of indeterminate structural systems to large tectonic deformation. The deck is shown to sustain both in-plane and out-of-plane bending moments, as well as torsion; the piers are subjected to biaxial bending, shear and torsion. The response is highly dependent on the location of the fault rupture, emphasizing the need to develop cost-effective modelling techniques. Four such techniques are developed (with and without decoupling) and comparatively assessed using the detailed 3D FE model as benchmark. The best prediction is achieved by a coupled model, which includes the bridge superstructure, detailed 3D modelling of the soil-foundation system only for the pier directly affected by the fault, and nonlinear springs representing the foundations of all other piers. The proposed technique offers a computationally efficient means to parametrically analyse long multispan bridges subjected to faulting, for which full 3D FE modelling is impractical.  相似文献   
15.
Determining the groundwater contribution of nonpoint source pollution at a watershed scale is a challenging issue. In this study, we utilized a top‐down approach to characterize representative groundwater response units (GRUs) based on land use and landscape position (e.g., upland, sideslope, or floodplain) in the 275‐km2 Clear Creek Watershed, Iowa. Groundwater monitoring wells were then established along downslope transects in representative GRUs. This unique combination of top‐down/bottom‐up approaches allowed us to estimate groundwater pollutant loads at the watershed scale with minimal monitoring. For the 2015 study period, results indicated that more groundwater recharge occurred in the floodplain (404 mm) compared to the uplands or sideslopes (281 and 165 mm, respectively), irrespective of land use. Recharge in the floodplains consisted of 37% of the annual precipitation, whereas upland wells averaged 26% and sideslopes averaged 15% of the annual precipitation. Less recharge was found to occur beneath perennial grass compared to row crop and urbanized areas. Baseflow discharge accounted for 69% of the total NO3‐N exported from the Clear Creek Watershed, with row crop areas contributing approximately 95% of the annual load. Orthophosphorus (OP) yields were approximately 0.72 kg/ha beneath urban and suburban areas, three times higher than those in row crop or perennial areas. Urban and suburban areas accounted for 21.4% of groundwater orthophosphorus and chloride loads in the watershed compared to only 8.5% of the land area. Overall, the groundwater load allocation model for baseflow nutrient discharge to Clear Creek can be used to target future nonpoint source load reduction strategies at the watershed scale. The use of GRUs can pinpoint better areas of concern for controlling nutrient loads.  相似文献   
16.
17.
The seismic behaviour of caisson foundations supporting typical bridge piers is analysed with 3D finite elements, with due consideration to soil and interface nonlinearities. Single-degree-of freedom oscillators of varying mass and height, simulating heavily and lightly loaded bridge piers, founded on similar caissons are studied. Four different combinations of the static ( $\text{ FS }_\mathrm{V}$ FS V ) and seismic ( $\text{ FS }_\mathrm{E}$ FS E ) factors of safety are examined: (1) a lightly loaded ( $\text{ FS }_\mathrm{V}= 5$ FS V = 5 ) seismically under-designed ( $\text{ FS }_\mathrm{E} < 1$ FS E < 1 ) caisson, (2) a lightly loaded seismically over-designed ( $\text{ FS }_\mathrm{E} >1$ FS E > 1 ) caisson, (3) a heavily loaded ( $\text{ FS }_\mathrm{V} = 2.5$ FS V = 2.5 ) seismically under-designed ( $\text{ FS }_\mathrm{E} < 1$ FS E < 1 ) caisson and (4) a heavily loaded seismically over-designed caisson. The analysis is performed with use of seismic records appropriately modified so that the effective response periods (due to soil-structure-interaction effects) of the studied systems correspond to the same spectral acceleration, thus allowing their inelastic seismic performance to be compared on a fair basis. Key performance measures of the systems are then contrasted, such as: accelerations, displacements, rotations and settlements. It is shown that the performance of the lightly loaded seismically under-designed caisson is advantageous: not only does it reduce significantly the seismic load to the superstructure, but it also produces minimal residual displacements of the foundation. For heavily loaded foundations, however ( $\text{ FS }_{V} = 2.5$ FS V = 2.5 ), the performance of the two systems (over and under designed) is similar.  相似文献   
18.
The possibility of using the species Silene compacta Fischer (Caryophyllaceae) as a plant indicator for Zn, Fe and Cu is discussed in this paper. Rock and plant samples were collected from an area near Essimi, north-eastern Greece, which is known for its Cu–Pb–Zn mineralization and analyzed for their content in 14 elements (Fe, Mn, Ag, As, Cd, Co, Cu, Mo, Ni, Pb, Sb, Sn, Zn and V). The data illustrate positive linear correlation between the concentrations of Zn, Fe and Cu in plant ash and rock samples. In particular, these correlations are 0.99 for Zn, 0.97 for Fe and 0.97 for Cu and are significant at the 99.9% confidence level. Therefore, S. compacta could be used as a plant indicator for Zn, Fe and Cu mineralization.  相似文献   
19.
Twenty-four years of AVHRR-derived sea surface temperature (SST) data (1985–2008) and 35 years of NOCS (V.2) in situ-based SST data (1973–2008) were used to investigate the decadal scale variability of this parameter in the Mediterranean Sea in relation to local air–sea interaction and large-scale atmospheric variability. Satellite and in situ-derived data indicate a strong eastward increasing sea surface warming trend from the early 1990s onwards. The satellite-derived mean annual warming rate is about 0.037°C year–1 for the whole basin, about 0.026°C year–1 for the western sub-basin and about 0.042°C year–1 for the eastern sub-basin over 1985–2008. NOCS-derived data indicate similar variability but with lower warming trends for both sub-basins over the same period. The long-term Mediterranean SST spatiotemporal variability is mainly associated with horizontal heat advection variations and an increasing warming of the Atlantic inflow. Analysis of SST and net heat flux inter-annual variations indicates a negative correlation, with the long-term SST increase, driving a net air–sea heat flux decrease in the Mediterranean Sea through a large increase in the latent heat loss. Empirical orthogonal function (EOF) analysis of the monthly average anomaly satellite-derived time series showed that the first EOF mode is associated with a long-term warming trend throughout the whole Mediterranean surface and it is highly correlated with both the Eastern Atlantic (EA) pattern and the Atlantic Multidecadal Oscillation (AMO) index. On the other hand, SST basin-average yearly anomaly and NAO variations show low and not statistically significant correlations of opposite sign for the eastern (negative correlation) and western (positive correlation) sub-basins. However, there seems to be a link between NAO and SST decadal-scale variations that is particularly evidenced in the second EOF mode of SST anomalies. NOCS SST time series show a significant SST rise in the western basin from 1973 to the late 1980s following a large warming of the inflowing surface Atlantic waters and a long-term increase of the NAO index, whereas SST slowly increased in the eastern basin. In the early 1990s, there is an abrupt change from a very high positive to a low NAO phase which coincides with a large change in the SST spatiotemporal variability pattern. This pronounced variability shift is followed by an acceleration of the warming rate in the Mediterranean Sea and a change in the direction (from westward to eastward) of its spatial increasing tendency.  相似文献   
20.
The best known model for numerically simulating the hysteretic behavior of various structural components is the bilinear hysteretic system. There are two possible mechanical formulations that correspond to the same bilinear model from a mathematical viewpoint. The first one consists of a linear elastic spring connected in series with a parallel system comprising a plastic slider and a linear elastic spring, while the second one comprises a linear elastic spring connected in parallel with an elastic-perfectly plastic system. However, the bilinear hysteretic model is unable to describe either softening or hardening effects in these components. In order to account for this, the bilinear model is extended to a trilinear one. Thus, two trilinear hysteretic models are developed and numerically tested, and the analysis shows that both exhibit three plastic phases. More specifically, the first system exhibits one elastic phase, while the second one exhibits two elastic phases according to the level of strain amplitude. Next, the change of slope between the plastic phases in unloading does not occur at the same displacement level in the two models. Furthermore, the dissipated energy per cycle in the first trilinear model, as proven mathematically and explained physically, decreases in the case of hardening and increases in the case of softening, while in the second trilinear model the dissipated energy per cycle remains unchanged, as is the case with the bilinear model. Numerical examples are presented to quantify the aforementioned observations made in reference to the mechanical behavior of the two trilinear hysteretic models. Finally, a set of cyclic shear tests over a wide range of strain amplitudes on a high damping rubber bearing is used in the parameter identification of the two different systems, namely (a) trilinear hysteretic models of the first type connected in parallel, and (b) trilinear hysteretic models of the second type also connected in parallel. The results show that the complex nonlinear shear behavior of high damping rubber bearings can be correctly simulated by a parallel system which consists of only one component, namely the trilinear hysteretic system of the first type. The second parallel system was not able to describe the enlargement of the dissipated hysteresis area for large strain amplitudes.  相似文献   
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