Unusual sources of fossil micrometeorites deduced from relict chromite in the small size fraction in ~467 Ma old limestone     

Philipp R. Heck  Birger Schmitz  Xenia Ritter  Surya S. Rout  Noriko T. Kita  Céline Defouilloy  Katarina Keating  Kevin Eisenstein  Fredrik Terfelt 《Meteoritics & planetary science》2024,59(3):502-513

Extraterrestrial chrome spinel and chromite extracted from the sedimentary rock record are relicts from coarse micrometeorites and rarely meteorites. They are studied to reconstruct the paleoflux of meteorites to the Earth and the collisional history of the asteroid belt. Minor element concentrations of Ti and V, and oxygen isotopic compositions of these relict minerals were used to classify the meteorite type they stem from, and thus to determine the relative meteorite group abundances through time. While coarse sediment-dispersed extraterrestrial chrome-spinel (SEC) grains from ordinary chondrites dominate through the studied time windows in the Phanerozoic, there are exceptions: We have shown that ~467 Ma ago, 1 Ma before the breakup of the L chondrite parent body (LCPB), more than half of the largest (>63 μm diameter) grains were achondritic and originated from differentiated asteroids in contrast to ordinary chondrites which dominated the meteorite flux throughout most of the past 500 Ma. Here, we present a new data set of oxygen isotopic compositions and elemental compositions of 136 grains of a smaller size fraction (32–63 μm) in ~467 Ma old pre-LCPB limestone from the Lynna River section in western Russia, that was previously studied by elemental analysis. Our study constitutes the most comprehensive oxygen isotopic data set of sediment-dispersed extraterrestrial chrome spinel to date. We also introduce a Raman spectroscopy-based method to identify SEC grains and distinguish them from terrestrial chrome spinel with ~97% reliability. We calibrated the Raman method with the established approach using titanium and vanadium concentrations and oxygen isotopic compositions. We find that ordinary chondrites are approximately three times more abundant in the 32–63 μm fraction than achondrites. While abundances of achondrites compared to ordinary chondrites are lower in the 32–63 μm size fraction than in the >63 μm one, achondrites are approximately three times more abundant in the 32–62 μm fraction than they are in the present flux. We find that the sources of SEC grains vary for different grain sizes, mainly as a result of parent body thermal metamorphism. We conclude that the meteorite flux composition ~467 Ma ago ~1 Ma before the breakup of the LCPB was fundamentally different from today and from other time windows studied in the Phanerozoic, but that in contrast to the large size fraction ordinary chondrites dominated the flux in the small size fraction. The high abundance of ordinary chondrites in the studied samples is consistent with the findings based on coarse extraterrestrial chrome-spinel from other time windows.  相似文献   

The crustal structure of the Guayana Shield, Venezuela, from seismic refraction and gravity data   总被引：1，自引：0，他引：1  

Michael Schmitz  Daniel Chalbaud  Jesús Castillo  Carlos Izarra   《Tectonophysics》2002,345(1-4)

We present results from a seismic refraction experiment on the northern margin of the Guayana Shield performed during June 1998, along nine profiles of up to 320 km length, using the daily blasts of the Cerro Bolívar mines as energy source, as well as from gravimetric measurements. Clear Moho arrivals can be observed on the main E–W profile on the shield, whereas the profiles entering the Oriental Basin to the north are more noisy. The crustal thickness of the shield is unusually high with up to 46 km on the Archean segment in the west and 43 km on the Proterozoic segment in the east. A 20 km thick upper crust with P-wave velocities between 6.0 and 6.3 km/s can be separated from a lower crust with velocities ranging from 6.5 to 7.2 km/s. A lower crustal low velocity zone with a velocity reduction to 6.3 km/s is observed between 25 and 25 km depth. The average crustal velocity is 6.5 km/s. The changes in the Bouguer Anomaly, positive (30 mGal) in the west and negative (−20 mGal) in the east, cannot be explained by the observed seismic crustal features alone. Lateral variations in the crust or in the upper mantle must be responsible for these observations.  相似文献   

Protecting the North-East Atlantic: enhancing synergies by institutional interplay     

Jon Birger Skjærseth 《Marine Policy》2006

This article examines the interplay between three different international institutions on marine pollution in the North Sea and the wider North-East Atlantic: the International North Sea Conferences (INSC), the OSPAR-Convention and preceding conventions as well as the European Union (EU). It argues that interplay between these institutions have proved synergetic in two ways. First, the INSC-process has speeded up decision-making within OSPAR and the EU by means of leadership, change in membership and institutional arrangements. Second, OSPAR and the EU have subsequently facilitated domestic implementation of the North Sea Conference Declarations by means of higher authoritativeness and enforcement competence. These three institutions have fulfilled different functions all of which are needed to make international environmental cooperation effective.  相似文献   

Amplitude versus offset analyses of the deep sedimentary structures at the northern flank of the Porcupine Basin,SW of Ireland     

T. Schmitz  W. Jokat 《International Journal of Earth Sciences》2007,96(1):171-184

This paper represents an attempt of analysing the amplitude versus offset (AVO) behaviour and specific seismic attributes of sedimentary structures from the Porcupine Basin, SW of Ireland. During the last decade, a huge number of carbonate mounds were investigated in this region in water depths of 600–1,000 m, but the genesis and growth of these mounds are still not clearly identified. The aim of this paper is to give a better understanding of the connection between fluid migration pathways in the deeper underground and surface expressions of their fluid expulsions like gas chimneys and pockmarks through which the mounds may generate themselves. The data used in this study to determine boundary conditions for the physical properties of the underlaying strata were gathered from the northern flank of the Porcupine Basin, where a huge amount of fluid and/or gas chimneys covers the seabed. Marine seismic reflection data contain information about the elastic properties of the underlying earth, mainly based on the observed variations in the seismic reflection amplitude at different shot–receiver offsets. To extract elastic parameters from the data, inversion techniques were used, which presume that input amplitudes are proportional to reflection coefficients for plane wave reflection. To calibrate the AVO analyses with the existing stratigraphy in the working area we have used the well logs from several bore holes in the region. The results of this study show clearly that the investigated and identified pockmarks on the seafloor are the surface expression of hydrocarbon seepage in the deeper sedimentary underground.  相似文献   

In situ U-Pb dating and element mapping of three generations of monazite: Unravelling cryptic tectonothermal events in low-grade terranes     

Birger Rasmussen  Ian R. Fletcher 《Geochimica et cosmochimica acta》2007,71(3):670-690

In situ U-Pb dating of monazite and xenotime in sedimentary rocks from the mid-Archean Soanesville Group in the Pilbara Craton, yields ages for provenance, diagenesis and multiple low-grade metamorphic events. Detrital monazite and xenotime grains give dates >3250 Ma, whereas diagenetic xenotime provides a new minimum age of 3190 ± 10 Ma for deposition of the basal Soanesville Group, previously constrained between ∼3235 Ma and ∼2955 Ma. Metamorphic monazite provides evidence for three episodes of growth: at 2.88, 2.16 and 1.65 Ga. Element mapping of monazite for La, Sm, Y and Th reveals distinct cores and rims in some crystals that were used to guide the placement of analytical spots during in situ U-Pb dating by sensitive high-resolution ion microprobe (SHRIMP). Specifically, La and Sm distributions closely correlate with different generations of monazite. The presence of two generations in single monazite crystals highlights the need for characterizing mineral chemistry prior to geochronology. It also shows the importance of using in situ dating techniques rather than methods that rely on the analysis of entire, potentially multi-aged, crystals. The ages recorded by metamorphic monazite span more than one billion years and are interpreted to record cryptic tectonothermal events within the craton. The 2.88 Ga age coincides with a phase of regional deformation, metamorphism and gold mineralization along a major crustal lineament, whereas the most common monazite age population (at 2.16 Ga) corresponds with the migration of a foreland fold-and-thrust belt across the craton. The youngest age (1.65 Ga) coincides with an episode of tectonic reworking in the Capricorn Orogen along the southern Pilbara margin. The prolonged history of monazite growth may, in part, relate to channelized fluid flow during reactivation of long-lived N- to NE-trending crustal structures that transect the craton. Despite repeated episodes of metamorphism, the isotopic system in each generation of monazite remained unperturbed, yielding precise dates. The ability of monazite to record three separate events, and in some instances two events in a single crystal, distinguishes it from most other low-temperature mineral chronometers, which are readily reset during metamorphic overprinting. Low-temperature monazite geochronology can provide a detailed isotopic history of cryptic thermal events and reveal the temporal and spatial patterns of far-field fluid flow related to tectonic processes. The previously unrecognized history of crustal fluid flow in the Pilbara Craton has implications for chemical, mineralogical and isotopic studies seeking to understand conditions on the early Earth.  相似文献   

Intercomparison of Two Hydroxyl Radical Measurement Techniques at the Atmosphere Simulation Chamber SAPHIR     

Eric Schlosser  Birger Bohn  Theo Brauers  Hans-Peter Dorn  Hendrik Fuchs  Rolf Häseler  Andreas Hofzumahaus  Frank Holland  Franz Rohrer  Lutz Olaf Rupp  Manfred Siese  Ralf Tillmann  Andreas Wahner 《Journal of Atmospheric Chemistry》2007,56(2):187-205

At the atmosphere simulation chamber SAPHIR in Jülich both Laser-Induced Fluorescence Spectroscopy (LIF) and Long-Path Differential Optical Laser Absorption Spectroscopy (DOAS) are operational for the detection of OH radicals at tropospheric levels. The two different spectroscopic techniques were compared within the controlled environment of SAPHIR based on all simultaneous measurements acquired in 2003 (13 days). Hydroxyl radicals were scavenged by added CO during four of these days in order to experimentally check the calculated precisions at the detection limit. LIF measurements have a higher precision (σ= 0.88×10⁶ cm^–3) and better time resolution (Δt = 60 s), but the DOAS method (σ= 1.24×10⁶ cm^–3, Δt = 135 s) is regarded as primary standard for comparisons because of its good accuracy. A high correlation coefficient of r = 0.95 was found for the whole data set highlighting the advantage of using a simulation chamber. The data set consists of two groups. The first one includes 3 days, where the LIF measurements yield (1 – 2) ×10⁶ cm^–3 higher OH concentrations than observed by the DOAS instrument. The experimental conditions during these days are characterized by increased NO_x concentration and a small dynamic range in OH. Excellent agreement is found within the other group of 6 days. The regression to the combined data of this large group yields unity slope without a significant offset.  相似文献   

Rheological anisotropy of the Earth’s mantle and attenuation of seismic waves     

B. I. Birger 《Izvestiya Physics of the Solid Earth》2006,42(11):877-889

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A new approach to interpreting Rock-Eval S₂ and TOC data for kerogen quality assessment     

Birger Dahl  Jrgen Bojesen-Koefoed  Anders Holm  Holger Justwan  Egil Rasmussen  Erik Thomsen 《Organic Geochemistry》2004,35(11-12):1461

A simple method for application in source potential mapping is used to assess the original oil and gas potentials in source rock horizons based upon Rock-Eval potential (S₂) and total organic carbon (TOC) values. The method assumes that kerogens consist of mixtures of end-members with assigned hydrogen index values. Based on suggested algorithms, the average amounts of oil-prone, gas-prone and inert organic material over source rock intervals are determined in TOC units. The method uses regression lines from plots of remaining hydrocarbon potentials (S₂) versus total organic carbon (TOC), and “quick-look” transparent overlays are used to read the appropriate kerogen mixture.Mineral matrix effects during pyrolysis, when strong, can cause erroneous results. This effect which occurs for oil-prone kerogens and adsorptive minerals can cause problems particularly for lean samples (S₂ = 0–3 mg HC/g rock) whilst the errors for richer samples are less.The method is applied on three sections of Upper Jurassic organic-rich rocks from the Danish North Sea sector, which are at different maturity stages. One of these sections is dominated by gas-prone material, one is dominated by oil-prone material and the third section contains a mixture of oil- and gas-prone material.The method has been compared with other methods that split kerogens in oil and gas generating potential and has given reasonable results.Experience using the method and a presented example suggest that sedimentological, system tract information may be derived from S₂ to TOC cross-plots. A constructed modelling example suggests that the end-member concept used in this approach may be used in forward type source rock prediction models when combined with sedimentological models. The resulting S₂–TOC plots can be used in order to check the forward modelling results against observed values.  相似文献   

Climatological Ertel’s potential-vorticity flux and mean meridional circulation in the extratropical troposphere – lower stratosphere     

J. Bartels  D. Peters  G. Schmitz 《Annales Geophysicae》1998,16(2):250-265

We investigated to what extent the isentropic, non-geostrophic formulation of zonally averaged circulation derived for stratospheric conditions is applicable to climatological transport in the extratropical troposphere and lower stratosphere. The study is based on 10 years of daily data of ECMWF analysis and on the ECHAM3 climate model of the German Climate Computing Centre. The main result is a scalar isentropic mixing coefficient, K_yy, and a mean meridional transport circulation consistently derived from the same data base. For both data sources, isentropic mean meridional circulation is derived from horizontal mass flow rate for 4 representative months. Alternatively, a mean meridional circulation is calculated from total diabatic heating rates of the ECHAM3 model. It is shown that only the latter is in good agreement with the ECMWF mean meridional circulation. Isentropic analysis also comprises the seasonal cycle of the climatological meridional gradient and flux of Ertels potential vorticity (PV). Application of Tungs flux-gradient relation yields that for all seasons K_yy is positive in height-latitude regions where statistical significance is reached. Large K_yy values, marking regions of more efficient mixing, have been found in the subtropical vertical band of weak westerly wind and in mid-latitudes in regions of upward-propagating baroclinic wave activity in the middle and upper troposphere. Based on the ECMWF data and results of baroclinic-wave behaviour, strong indications are presented that positive zonally averaged PV flux polewards of the jet core in the NH is strengthened by stationary waves and nonlinear effects. Reduced eddy transport is apparent in winter and spring slightly below the subtropical tropopause jet. The seasonal cycle of K_yy from ECHAM3 data is to a great extent in agreement with the result based on ECMWF analysis. In the model, reduced interannual variability enlarges the height-latitude range where sign of K_yy is significant.  相似文献   

Quality Assurance of Hydrocarbon Measurements for the German Tropospheric Research Focus (TFS)     

A. Volz-Thomas  J. Slemr  S. Konrad  Th. Schmitz  E. C. Apel  V. A. Mohnen 《Journal of Atmospheric Chemistry》2002,42(1):255-279

In the German Focus on Tropospheric Research (TFS) independent quality assurance procedures were implemented in order to obtain information on data quality and comparability of the different measurements made in the different field campaigns. This paper describes the results for measurements of hydrocarbons using in-situ gas chromatographictechniques and off line analysis of samples collected in canisters (analysed by two central laboratories CL-1 and CL-2) and samples collected on adsorption tubes. The QA-procedures included comparisons with synthetic standards (prepared by EN 45001 certified laboratories), absolute calibration with a diffusion source, and an instrument/methodology comparison in ambient air. Harmonisation of the ambient measurements was achieved with a complex mixture (NCAR/BERLIOZ) containing 70 commonly observed hydrocarbons at mixing ratios of 0.2 to 10 ppb (mole fraction) in nitrogen, which was calibrated by referencing to hydrocarbon standards of the National Institute for Standards and Technology (NIST).For the certified synthetic standards, the experienced groups agreed to within ± 20% for most compounds. Much larger discrepancies were observed for the new Airmotec HC2010 instruments due to problems with identification, co-elution and blanks/memory effects. The results in ambient air were similar: Reasonable agreement was found for the results from the experienced groups with well characterised in situ instruments andfor the charcoal tubes, whereas larger discrepancies were observed for the results from new groups and instruments. For the latter, only selected compounds met the data quality objectives (DQO). The canister samples analysed by CL-2 were in good agreement with the reference instrument, whereas large deviations were found for a number of compounds in the analysis of the same canisters by CL-1. The results of the comparison provided the final basis for flagging and harmonising the data from all participants prior to their submission to the TFS central data bank.  相似文献