Advances in the use of observed spatial patterns of catchment hydrological response   总被引：2，自引：0，他引：2  

Rodger B Grayson  Günter Blschl  Andrew W Western  Thomas A McMahon 《Advances in water resources》2002,25(8-12)

Over the past two decades there have been repeated calls for the collection of new data for use in developing hydrological science. The last few years have begun to bear fruit from the seeds sown by these calls, through increases in the availability and utility of remote sensing data, as well as the execution of campaigns in research catchments aimed at providing new data for advancing hydrological understanding and predictive capability. In this paper we discuss some philosophical considerations related to model complexity, data availability and predictive performance, highlighting the potential of observed patterns in moving the science and practice of catchment hydrology forward. We then review advances that have arisen from recent work on spatial patterns, including in the characterisation of spatial structure and heterogeneity, and the use of patterns for developing, calibrating and testing distributed hydrological models. We illustrate progress via examples using observed patterns of snow cover, runoff occurrence and soil moisture. Methods for the comparison of patterns are presented, illustrating how they can be used to assess hydrologically important characteristics of model performance. These methods include point-to-point comparisons, spatial relationships between errors and landscape parameters, transects, and optimal local alignment. It is argued that the progress made to date augers well for future developments, but there is scope for improvements in several areas. These include better quantitative methods for pattern comparisons, better use of pattern information in data assimilation and modelling, and a call for improved archiving of data from field studies to assist in comparative studies for generalising results and developing fundamental understanding.  相似文献   

Geochemical effects of oxidation products and framboidal pyrite oxidation in acid mine drainage prediction techniques   总被引：1，自引：0，他引：1  

P. A. Weber  W. A. Stewart  W. M. Skinner  C. G. Weisener  J. E. Thomas  R. St. C. Smart   《Applied Geochemistry》2004,19(12):1953-1974

Acid mine drainage predictive testwork associated with the Australian Mineral Industries Research Association (AMIRA) P387A Project: Prediction and Kinetic Control of Acid Mine Drainage (AMD) has critically examined static acid assessment and kinetic information from acid–base accounting techniques, including net acid production potential (NAPP), net acid generation (NAG) and column leach tests. This paper compares results on two waste rock samples that were obtained from the Kaltim Prima Coal mine (KPC) containing significant quantities of fine-grained framboidal pyrite. In agreement with other research, the authors' results indicated that framboidal pyrite is more reactive than euhedral forms due to the greater specific surface area of framboidal pyrite. This is evidenced by optical microscopy of reacted samples. Importantly, the results showed that NAPP testing is biased by the rapid acid generating oxidation of framboidal pyrite prior to, and during the acid neutralisation capacity (ANC) test. This can result in negative ANC values for samples containing significant framboidal pyrite (often “corrected” to zero kg H₂SO₄/t) when significant ANC is actually present in the sample. NAG testing using H₂O₂ indicated that samples containing a significant quantity of framboidal pyrite can result in the catalytic decomposition of the H₂O₂ prior to complete oxidation of the sulfide minerals present, requiring sequential addition of H₂O₂ for completion. A benefit of the NAG test, however, is that it assesses the net acid generation capacity of the sample without bias towards acid generation as is observed using NAPP methods. The kinetic NAG test also gives information on the reaction sequence of framboidal and euhedral pyrite. Periodic (kinetic) analysis of sub-samples from column leach tests indicated rapid oxidation of the framboidal pyrite compared to the euhedral pyrite, which was correlated with the greater framboidal pyrite surface area.Calculations to determine the sulfide/sulfate acidity derived from the oxidation of framboidal pyrite prior to; and during the ANC test have been developed to provide a better indication of the actual ANC (ANC_Actual) of the sample. Paste pH values of <pH 4–5 may be one suitable trigger mechanism for the implementation of this new method. This has led to an improved NAPP estimation of total acid production. Together with NAG and column leach testing this improved methodology has resulted in accurate AMD characterisation of samples containing acidic oxidation products and framboidal pyrite.  相似文献   

Constructing motion primitive sets to summarize periodic orbit families and hyperbolic invariant manifolds in a multi-body system     

Smith  Thomas R.  Bosanac  Natasha 《Celestial Mechanics and Dynamical Astronomy》2022,134(1):1-19

Celestial Mechanics and Dynamical Astronomy - The equilibrium figure of an inviscid tidally deformed body is the starting point for the construction of many tidal theories such as Darwinian tidal...  相似文献   

Storm-damaged saline-contaminated boreholes as a means of aquifer contamination   总被引：2，自引：0，他引：2  

Carlson DA  Van Biersel TP  Milner LR 《Ground water》2008,46(1):69-79

Saline water from a storm surge can flow down storm-damaged submerged water supply wells and contaminate boreholes and surrounding aquifers. Using data from conventional purging techniques, aquifer test response analysis, chemical analysis, and regression analysis of chloride/silica (Cl/Si) ratio, equations were derived to estimate the volume of saline water intrusion into a well and a porous media aquifer, the volume of water needed to purge a well shortly following an intrusion event, and the volume of water needed after delay of several or more months, when the saline plume has expanded. Purging time required is a function of volume of water and pumping rate. The study site well is located within a shoreline community of Lake Pontchartrain, St. Tammany Parish, in southeastern Louisiana, United States, which was impacted by two hurricane storm surges and had neither been rehabilitated nor chlorinated prior to our study. Chemical analysis of water samples in fall 2005 and purging of well and aquifer in June 6, 2006, indicated saline water had intruded the well in 2005 and the well and aquifer in 2006. The volume of water needed to purge the study well was approximately 200 casing volumes, which is significantly greater than conventionally used during collection of water samples for water quality analyses.  相似文献   

Discretizing the fracture-matrix interface to simulate solute transport   总被引：1，自引：0，他引：1  

Weatherill D  Graf T  Simmons CT  Cook PG  Therrien R  Reynolds DA 《Ground water》2008,46(4):606-615

This article examines the required spatial discretization perpendicular to the fracture-matrix interface (FMI) for numerical simulation of solute transport in discretely fractured porous media. The discrete-fracture, finite-element model HydroGeoSphere ( Therrien et al. 2005 ) and a discrete-fracture implementation of MT3DMS ( Zheng 1990 ) were used to model solute transport in a single fracture, and the results were compared to the analytical solution of Tang et al. (1981) . To match analytical results on the relatively short timescales simulated in this study, very fine grid spacing perpendicular to the FMI of the scale of the fracture aperture is necessary if advection and/or dispersion in the fracture is high compared to diffusion in the matrix. The requirement of such extremely fine spatial discretization has not been previously reported in the literature. In cases of high matrix diffusion, matching the analytical results is achieved with larger grid spacing at the FMI. Cases where matrix diffusion is lower can employ a larger grid multiplier moving away from the FMI. The very fine spatial discretization identified in this study for cases of low matrix diffusion may limit the applicability of numerical discrete-fracture models in such cases.  相似文献   

The value of subsidence data in ground water model calibration   总被引：2，自引：0，他引：2  

Yan T  Burbey TJ 《Ground water》2008,46(4):538-550

The accurate estimation of aquifer parameters such as transmissivity and specific storage is often an important objective during a ground water modeling investigation or aquifer resource evaluation. Parameter estimation is often accomplished with changes in hydraulic head data as the key and most abundant type of observation. The availability and accessibility of global positioning system and interferometric synthetic aperture radar data in heavily pumped alluvial basins can provide important subsidence observations that can greatly aid parameter estimation. The aim of this investigation is to evaluate the value of spatial and temporal subsidence data for automatically estimating parameters with and without observation error using UCODE-2005 and MODFLOW-2000. A synthetic conceptual model (24 separate cases) containing seven transmissivity zones and three zones each for elastic and inelastic skeletal specific storage was used to simulate subsidence and drawdown in an aquifer with variably thick interbeds with delayed drainage. Five pumping wells of variable rates were used to stress the system for up to 15 years. Calibration results indicate that (1) the inverse of the square of the observation values is a reasonable way to weight the observations, (2) spatially abundant subsidence data typically produce superior parameter estimates under constant pumping even with observation error, (3) only a small number of subsidence observations are required to achieve accurate parameter estimates, and (4) for seasonal pumping, accurate parameter estimates for elastic skeletal specific storage values are largely dependent on the quantity of temporal observational data and less on the quantity of available spatial data.  相似文献   

Assessment of chemical dispersant effectiveness in a wave tank under regular non-breaking and breaking wave conditions     

Li Z  Lee K  King T  Boufadel MC  Venosa AD 《Marine pollution bulletin》2008,56(5):903-912

Current chemical dispersant effectiveness tests for product selection are commonly performed with bench-scale testing apparatus. However, for the assessment of oil dispersant effectiveness under real sea state conditions, test protocols are required to have hydrodynamic conditions closer to the natural environment, including transport and dilution effects. To achieve this goal, Fisheries and Oceans Canada and the US Environmental Protection Agency (EPA) designed and constructed a wave tank system to study chemical dispersant effectiveness under controlled mixing energy conditions (regular non-breaking, spilling breaking, and plunging breaking waves). Quantification of oil dispersant effectiveness was based on observed changes in dispersed oil concentrations and oil-droplet size distribution. The study results quantitatively demonstrated that total dispersed oil concentration and breakup kinetics of oil droplets in the water column were strongly dependent on the presence of chemical dispersants and the influence of breaking waves. These data on the effectiveness of dispersants as a function of sea state will have significant implications in the drafting of future operational guidelines for dispersant use at sea.  相似文献   

Characterization of Damage in Sandstones along the Mojave Section of the San Andreas Fault: Implications for the Shallow Extent of Damage Generation     

Ory Dor  Judith S. Chester  Yehuda Ben-Zion  James N. Brune  Thomas K. Rockwell 《Pure and Applied Geophysics》2009,166(10-11):1747-1773

Following theoretical calculations that suggest shallow generation of rock damage during an earthquake rupture, we measure the degree of fracture damage in young sedimentary rocks from the Juniper Hills Formation (JHF) that were displaced 21 km along the Mojave section of San Andreas Fault (SAF) and were not exhumed significantly during their displacement. In exposures adjacent to the fault, the JHF typically displays original sedimentary fabrics and little evidence of bulk shear strain at the mesoscopic scale. The formation is, however, pervasively fractured at the microscopic scale over a zone that is about a 100 m wide on the southwest side of the SAF near Little Rock. The abundance of open fractures, the poor consolidation, and the shallow inferred burial depth imply that the damage was generated close to the surface of the Earth. The spatial correlation of this damage with a seismically active trace of the SAF suggests that it was generated by SAF slip events that by assumption were of a seismic nature throughout the displacement history of the JHF. Thus the JHF provides a very shallow upper bound for the generation of brittle damage in a seismic fault zone. The fracture fabric is characterized by preferred orientations of fractures that split grains between contact points and is consistent with overall deformation under directed compression. However, the available results cannot be used to distinguish between proposed off-fault damage mechanisms. Fracture orientations are compatible with a maximum compressive stress oriented at a high angle to the fault at about 10 m, and at a lower, more variable angle farther away from the fault. The fracture distribution and fabric are consistent with observations made of the microscale damage characteristics of the Hungry Valley Formation in the northwestern section of the SAF in the Mojave, and with previous observations of exhumed, ancestral strands of the SAF.  相似文献   

Kinematic transformations for planar multi‐directional pseudodynamic testing     

Oya Mercan  James M. Ricles  Richard Sause  Thomas Marullo 《地震工程与结构动力学》2009,38(9):1093-1119

The pseudodynamic (PSD) test method imposes command displacements to a test structure for a given time step. The measured restoring forces and displaced position achieved in the test structure are then used to integrate the equations of motion to determine the command displacements for the next time step. Multi‐directional displacements of the test structure can introduce error in the measured restoring forces and displaced position. The subsequently determined command displacements will not be correct unless the effects of the multi‐directional displacements are considered. This paper presents two approaches for correcting kinematic errors in planar multi‐directional PSD testing, where the test structure is loaded through a rigid loading block. The first approach, referred to as the incremental kinematic transformation method, employs linear displacement transformations within each time step. The second method, referred to as the total kinematic transformation method, is based on accurate nonlinear displacement transformations. Using three displacement sensors and the trigonometric law of cosines, this second method enables the simultaneous nonlinear equations that express the motion of the loading block to be solved without using iteration. The formulation and example applications for each method are given. Results from numerical simulations and laboratory experiments show that the total transformation method maintains accuracy, while the incremental transformation method may accumulate error if the incremental rotation of the loading block is not small over the time step. A procedure for estimating the incremental error in the incremental kinematic transformation method is presented as a means to predict and possibly control the error. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

MODFLOW-CFP: A New Conduit Flow Process for MODFLOW–2005     

reviewed by Thomas Reimann  and Melissa E. Hill 《Ground water》2009,47(3):321-325

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