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The Sete Cidades volcano (São Miguel, Azores) is situatedat the eastern end of the ultraslow spreading Terceira riftaxis. The volcano comprises several dominantly basaltic pre-calderaeruptions, a trachytic caldera-forming stage and a post-calderastage consisting of alternating trachytic and basaltic eruptions.The post-caldera flank lavas are more primitive (>5 wt %MgO) than the pre-caldera lavas, implying extended fractionalcrystallization and longer crustal residence times for the pre-caldera,shield-building lavas. Thermobarometric estimates show thatthe ascending alkali basaltic magmas stagnated and crystallizedat the crust–mantle boundary (15 km depth), whereas themore evolved magmas mainly fractionated in the upper crust (3km depth). The caldera-forming eruption was triggered by a basalticinjection into a shallow trachytic magma chamber. Lavas fromall stages follow a single, continuous liquid line of descentfrom alkali basalt to trachyte, although slight differencesin incompatible element (e.g. Ba/Nb, La/Nb) and Sr isotope ratiosimply some heterogeneity of the mantle source. Major and traceelement data suggest similar partial melting processes throughoutthe evolution of the volcano. Slight geochemical differencesbetween post- and pre-caldera stage lavas from the Sete Cidadesvolcanic system indicate a variation in the mantle source compositionwith time. The oxygen fugacity increased from the pre-calderato the post-caldera stage lavas, probably as a result of theassimilation of crustal rocks; this is supported by the presenceof crustal xenoliths in the lavas of the flank vents. The lavasfrom the Sete Cidades volcano generally have low Sr isotoperatios; however, rocks from one post-caldera vent on the westernflank indicate mixing with magmas resembling the lavas fromthe neighbouring Agua de Pau volcano, having higher Sr isotoperatios. The different magma sources at Sete Cidades and theadjacent Agua de Pau volcano imply that, despite their closeproximity, there is only limited interaction between them. KEY WORDS: crystallization depth; fractionation; stratigraphy; Terceira rift; volcanic stages 相似文献
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Stable isotopes in a stalagmite from NW Sweden document environmental changes over the past 4000 years 总被引：1，自引：0，他引：1
HANNA S. SUNDQVIST KARIN HOLMGREN ERS MOBERG CHRISTOPH SPÖTL AUGUSTO MANGINI 《Boreas: An International Journal of Quaternary Research》2010,39(1):77-86
Sundqvist, H. S., Holmgren, K., Moberg, A., Spötl, C. & Mangini, A. 2009: Stable isotopes in a stalagmite from NW Sweden document environmental changes over the past 4000 years. Boreas, 10.1111/j.1502‐3885.2009.00099.x. ISSN 0300‐9483. This study of a 4000‐year‐old stalagmite from Korallgrottan in northwestern Sweden highlights the potentials and challenges when using stable isotopes in stalagmites as climate proxies, as well as the fact that the relationship between climate and proxy may change through time. Both the oxygen and the carbon isotopes display an overall trend of enrichment together with decreasing growth rates over the time period covered by the stalagmite, which is considered a generally cooling period according to current palaeoclimate understanding. The stable isotope records show enriched isotopic values during the, for Scandinavia, comparatively cold period AD 1300–1700 and depleted values during the warmer period AD 800–1000. The indication of a negative relationship between measured δ18O and surface temperature concurs with earlier reported stalagmite records from regions with a seasonal snow cover and is further supported by the fact that the stalagmite δ18O record shows general similarities with both regional and hemispheric temperature reconstructions available for the past 500 and 2000 years, respectively. Compared with a stable isotope record of lacustrine carbonates from northern Sweden, however, shifting correlations over time between the two records indicate that a local hydrological change may have taken place at Korallgrottan, or at the lake, compared with around 1000 years ago. The earlier part of the stalagmite δ18O might thus be influenced, to some extent, by another process than the later part, which means that a negative relationship between δ18O and surface temperature might not hold for the entire 4000‐year‐old record. 相似文献
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Climate variability in the SE Alps of Italy over the past 17 000 years reconstructed from a stalagmite record 总被引：1，自引：0，他引：1
SILVIA FRISIA REA BORSATO CHRISTOPH SPÖTL IGOR M. VILLA FRANCO CUCCHI 《Boreas: An International Journal of Quaternary Research》2005,34(4):445-455
Stalagmite SV1 from Grotta Savi, located at the SE margin of the European Alps (Italy), is the first Alpine speleothem that continuously spans the past c . 17kyr. Extension rate and δ18 Oc record for the Lateglacial probably reflect a combination of temperature and rainfall, with rainfall exerting the dominant effect. Low speleothem calcite δ18 Oc values were recorded from c . 14.5 and 12.35 kyr, during GI-1 (Bølling— Allerød) interstadial, which in our interpretation, was warm and wet. The GS-1 (Younger Dryas) was characterized by a shift to heavier δ18 Oc , coinciding with δ13 Cc enrichment and extremely low extension rate (<8 μm/year). These characteristics indicate that GS-1 climate was cool and dry in the SE Alps. Calibration using historical data revealed that there is a positive δ18 Oc /dT relationship. A 1°C rise in mean annual temperature should correspond to c . 2.85% increase of SV-1 δc18 Oc . We reconstructed a slow and steady temperature rise of c . 0.5°C since 10 kyr BP, in broad agreement with reconstructions from pollen data for SE Europe. Stalagmite SV1 indicates that climate variability in the SE Alps has been influenced by the Mediterranean Sea for the past c . 17 kyr. 相似文献
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Estimating regional carbon exchange in New England and Quebec by combining atmospheric, ground-based and satellite data 总被引：1，自引：0，他引：1
DANIEL M. MATROSS ARLYN ANDREWS MAHADEVAN PATHMATHEVAN CHRISTOPH GERBIG JOHN C. LIN STEVEN C. WOFSY BRUCE C. DAUBE ELAINE W. GOTTLIEB VICTORIA Y. CHOW JOHN T. LEE CONGLONG ZHAO PETER S. BAKWIN J. WILLIAM MUNGER DAVID Y. HOLLINGER 《Tellus. Series B, Chemical and physical meteorology》2006,58(5):344-358
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RAFFAELE DI CUIA ALBERTO RIVA ANDREA SCIFONI ALESSANDRO MORETTI CHRISTOPH SPÖTL BRUNO CALINE 《Sedimentology》2011,58(6):1347-1369
A multidisciplinary study, conducted over the carbonate platform deposits of the Liassic Calcari Grigi Group (Southern Alps), highlighted how the use of outcrop analogues can contribute to better define the distribution of dolomitic bodies related to fault networks, to characterize the petrophysical properties of the dolomitic sequence and unravel a complex diagenetic history. This study was carried out in the Asiago Plateau (southernmost part of the eastern Southern Alps, northern Italy) which provides excellent outcrops of the Jurassic Calcari Grigi Group. The dolomitization of the Jurassic sequence is variable in terms of stratigraphic extension and geographic distribution. In the studied localities the dolomitization is generally limited to the Mount Zugna Formation and is characterized by an undulatory front, with ‘sub‐vertical dolomitic chimneys’ along the major faults. Within this unit, and often associated with faults, stacked high‐porosity and permeability bed‐parallel dolomitic bodies are developed that show excellent petrophysical properties. The dolomitic intervals are characterized by pervasive unimodal and patchy polymodal dolomite crystals. Thin section, cathodoluminescence, isotopic and fluid inclusion analyses were used to constrain the paragenetic evolution of the sequence which is similar in all the studied localities. The first dolomitization stage is marked by zoned dolomite crystals with a dull luminescent core. The porosity is thought to have increased after this stage, with dark blue luminescent dolomite accompanied by the corrosion of older crystals. The appearance of saddle dolomite marks the onset of the porosity reduction stage, ending with the infilling of vugs and the remaining open pores with calcite cement. The diagenetic evolution locally stopped at the saddle dolomite stage with the complete occlusion of the remaining pores. Paragenetic and fluid‐inclusion data suggest an evolutionary trend of increasing temperatures and decreasing salinity toward brackish fluids responsible for dolomite and calcite precipitation. The integration of the available data seem to indicate that the diagenetic evolution of the study area is related to: (i) the interplay between evolving fluids (from marine to brackish); (ii) the burial of the sequence (increasing temperature); and (iii) the evolution of the hydrogeological system (fault and fracture network, fluid mixing). This complex paragenetic evolution is strongly linked to the evolution of the porosity framework that evolved from a good, widespread network in the early stages of the burial history to a confined system in the later stages due to reduction of porosity by the deposition of late calcite and dolomite cements. 相似文献
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JOCHEN KNIES JENS MATTHIESSEN CHRISTOPH VOGT RUEDIGER STEIN 《Boreas: An International Journal of Quaternary Research》2002,31(1):82-93
A multiproxy analysis of Hole 911A (Ocean Drilling Program (ODP) Leg 151) drilled on the Yermak Plateau (eastern Arctic Ocean) is used to investigate the behaviour of the Svalbard/Barents Sea ice sheet (SBIS) during late Pliocene and early Pleistocene (~3.0-1.7 Ma) climate changes. Contemporary with the 'Mid-Pliocene (~3 Ma) global warmth' (MPGW), a warmer period lasting ~300 kyr with seasonally ice-free conditions in the marginal eastern Arctic Ocean is assumed to be an important regional moisture source, and possibly one decisive trigger for intensification of the Northern Hemisphere glaciation in the Svalbard/Barents Sea area at ~2.7 Ma. An abrupt pulse of ice-rafted debris (IRD) to the Yermak Plateau at ~2.7 Ma reflects distinct melting of sediment-laden icebergs derived from the SBIS and may indicate the protruding advance of the ice sheet onto the outer shelf. Spectral analysis of the total organic carbon (TOC) record being predominantly of terrigenous/fossil-reworked origin indicates SBIS and possibly Scandinavian Ice Sheet response to incoming solar radiation at obliquity and precession periodicities. The strong variance in frequencies near the 41 kyr obliquity cycle between 2.7 and 1.7 Ma indicates, for the first time in the Arctic Ocean, a close relationship of SBIS growth and decay patterns to the Earth's orbital obliquity amplitudes, which dominated global ice volume variations during late Pliocene/early Pleistocene climate changes. 相似文献
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Origin and palaeoenvironmental significance of lamination in stalagmites from Katerloch Cave,Austria
The origin and environmental dependencies of lamination in stalagmites from Katerloch, common in speleothems from other cave sites, are examined in detail. Petrographic observations and chemical analyses (including isotopes) of stalagmites and modern calcite were combined with multi‐annual cave monitoring. All investigated stalagmites are composed of low‐Mg calcite and show white, porous laminae and typically thinner, translucent dense laminae. The binary lamination pattern results from changes in the calcite fabric: white, porous laminae are characterized by a high porosity and abundant fluid inclusions and also by enhanced vertical growth and thinning towards the flanks. Translucent, dense laminae exhibit a compact fabric and constant thickness of individual growth layers. U‐Th dating supports an annual origin of the lamination and the seasonally changing intensity of cave ventilation provides a robust explanation for the observed relationships between lamination, stable C isotopic compositions and trace elements (Mg, Sr and Ba). The seasonally variable air exchange, driven by temperature contrasts between the cave interior and outside atmosphere, modulates the rate and amount of CO2 degassing from the drip water and affects the hydrochemistry and consequently the fabric of the precipitating calcite. Although cave air composition and drip rate are both major variables in controlling CO2 degassing from the drip water, the seasonally changing ventilation in Katerloch exerts the primary control and the results suggest a secondary (amplifying/attenuating) influence of the drip rate. Drip rate, however, might be the controlling parameter for lamina development at cave sites experiencing only small seasonal cave air exchange. Importantly, the seasonally variable composition of drip water does not reflect the seasonal cycle of processes in the soil zone, but results from exchange with the cave atmosphere. The alternating porous and dense calcite fabric is the expression of a variable degree of lateral coalescence of smaller crystallites forming large columnar crystals. The white, porous laminae represent partial coalescence and form during the warm season: low calcite δ13C values are linked to low δ13C values of cave air and drip water during that time. This observation corresponds to times of reduced cave ventilation, high pCO2 of cave air, low drip water pH, lower calcite supersaturation and typically high drip rates. In contrast, the translucent, dense laminae represent more or less complete lateral coalescence (inclusion‐free) during the cold season (high calcite, drip water and cave air δ13C values), i.e. times of enhanced cave ventilation, low cave air pCO2, increased drip water pH, relatively high calcite supersaturation and typically low drip rates. In essence, the relative development of the two lamina types reflects changes in the seasonality of external air temperature and precipitation, with a strong control of the winter air temperature on the intensity of cave‐air exchange. Thick translucent, dense laminae are favoured by long, cold and wet winters and such conditions may be related closely to the North Atlantic Oscillation mode (weak westerlies) and enhanced Mediterranean cyclone activity during the cold season. Studies of speleothem lamination can thus help to better understand (and quantify) the role of seasonality changes, for example, during rapid climate events. 相似文献
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PRABIR K. PATRA SHYAM LAL VARUN SHEEL B. H. SUBBARAYA CHRISTOPH BR&#;HL REINHARD BORCHERS PETER FABIAN 《Tellus. Series B, Chemical and physical meteorology》2000,52(3):934-946
Balloon‐borne cryogenic air sampler experiments have been conducted from a tropical (Hyderabad, 17.5°N) and a midlatitude (GAP, southern France, 44°N) station since 1987 in the altitude range of about 8‐35 km. Air samples are analysed at the Max Planck Institute for Aeronomy (MPAE) and Physical Research Laboratory (PRL) using various gas chromatographic techniques to obtain the vertical distributions of several halogenated source gases and long‐lived dynamical tracers. These observations are used to determine the stratospheric partitioning of the chlorine species into their organic and inorganic forms for the altitude range of 20 to 35 km. Distributions of inorganic chlorine indicate increase in their abundances with altitude, latitude and time. Mixing ratio correlations of organic and inorganic chlorine with N2 O have been obtained which also suggest that the rate of increase in inorganic halogens component in the stratosphere is larger than the increase rate of total organic halogen. This supports previous assessments that halogen‐induced ozone depletion will continue to be observed for a few more years, despite the decrease of halocarbon loading into the stratosphere since 1994. 相似文献