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111.
International Journal of Earth Sciences - The Western Sierras Pampeanas (WSP) of Argentina record a protracted geological history from the Mesoproterozoic assembly of the Rodinia supercontinent to...  相似文献   
112.
Mount Bulusan, the Philippines’ fourth most active volcano, erupted in February 21, 2011, sending volcanic ash and pyroclastic materials to its surrounding rivers. The waters drained into the estuary of harmful algal blooms plagued Sorsogon Bay. We aim to determine the impact of the 2011 volcanic eruption and the preceding volcanic ash emissions to the dissolved silica concentration of rivers draining the flanks of Mt. Bulusan and its possible implications to the phytoplankton assemblage of the bay. Six river water sampling periods from August 2010 to October 2012 overlapped with Mt. Bulusan’s active phase of volcanism. Our data shows that mean river silica from pre-eruption levels of ~?500 μM increased by more than 200% during and post-eruption. Highest Si concentration of 2270 μM was measured from Cadacan River in August 2011. Here, we argue that the sustained general increase of dissolved silica is due to the silica-containing materials from Mt. Bulusan’s eruption and that their concentration in river waters is also a function of watershed lithology and precipitation. Increase in dissolved silica and other nutrients caused a shift to diatom domination and, possibly, termination of Pyrodinium bahamense var. compressum blooms. Silica load increase in embayments is a natural process that controls the dominance of algae. Our study also highlights the importance of Philippine rivers to the global ocean silica budget as a function of high precipitation, tectonics in general, and volcanism in particular.  相似文献   
113.
Estuaries are productive and ecologically important ecosystems, incorporating environmental drivers from watersheds, rivers, and the coastal ocean. Climate change has potential to modify the physical properties of estuaries, with impacts on resident organisms. However, projections from general circulation models (GCMs) are generally too coarse to resolve important estuarine processes. Here, we statistically downscaled near-surface air temperature and precipitation projections to the scale of the Chesapeake Bay watershed and estuary. These variables were linked to Susquehanna River streamflow using a water balance model and finally to spatially resolved Chesapeake Bay surface temperature and salinity using statistical model trees. The low computational cost of this approach allowed rapid assessment of projected changes from four GCMs spanning a range of potential futures under a high CO2 emission scenario, for four different downscaling methods. Choice of GCM contributed strongly to the spread in projections, but choice of downscaling method was also influential in the warmest models. Models projected a ~2–5.5 °C increase in surface water temperatures in the Chesapeake Bay by the end of the century. Projections of salinity were more uncertain and spatially complex. Models showing increases in winter-spring streamflow generated freshening in the Upper Bay and tributaries, while models with decreased streamflow produced salinity increases. Changes to the Chesapeake Bay environment have implications for fish and invertebrate habitats, as well as migration, spawning phenology, recruitment, and occurrence of pathogens. Our results underline a potentially expanded role of statistical downscaling to complement dynamical approaches in assessing climate change impacts in dynamically challenging estuaries.  相似文献   
114.
Given its geological and climatic conditions and its rugged orography, Asturias is one of the most landslide prone areas in the North of Spain. Most of the landslides occur during intense rainfall episodes. Thus, precipitation is considered the main triggering factor in the study area, reaching average annual values of 960 mm. Two main precipitation patterns are frequent: (i) long-lasting periods of moderate rainfall during autumn and winter and (ii) heavy short rainfall episodes during spring and early summer. In the present work, soil moisture conditions in the locations of 84 landslides are analysed during two rainfall episodes, which represent the most common precipitation patterns: October–November 2008 and June 2010. Empirical data allowed the definition of available water capacity percentages of 99–100% as critical soil moisture conditions for the landslide triggering. Intensity-duration rainfall thresholds were calculated for each episode, considering the periods with sustained high soil moisture levels before the occurrence of each analysed landslide event. For this purpose, data from daily water balance models and weather stations were used. An inverse relationship between the duration of the precipitation and its intensity, consistent with published intensity-duration thresholds, was observed, showing relevant seasonal differences.  相似文献   
115.
In this work, we consider a new model for flow in a multiporosity shale gas reservoir constructed within the framework of an upscaling procedure where hydraulic fractures are treated as (\(n-1\)) interfaces (\(n=2,3\)). Within this framework, the hydrodynamics is governed by a new pressure equation in the shale matrix which is treated as a homogenized porous medium composed of organic matter (kerogen aggregates with nanopores) and inorganic impermeable solid (clay, calcite, quartz) separated from each other by a network of interparticle pores of micrometer size. The solution of the pressure equation is strongly influenced by the constitutive response of the retardation parameter and effective hydraulic conductivity where the former incorporates gas adsorption/desorption in the nanopores of the kerogen. By focusing our analyses on this nonlinear diffusion equation in the domain occupied by the shale matrix, an optimization strategy seated on the adjoint sensitivity method is developed to minimize a cost functional related to gas production and net present value in a single hydraulic fracture. The gradient of the objective functional computed with the adjoint formulation is explored to update the controlled pressure drop aiming to optimize production in a given window of time. The combination of the direct approach and gradient-based optimization using the adjoint formulation leads to the construction of optimal production scenarios under controlled pressure decline in the well. Numerical simulations illustrate the potential of the methodology proposed herein in optimizing gas production.  相似文献   
116.
An unsupervised machine-learning workflow is proposed for estimating fractional landscape soils and vegetation components from remotely sensed hyperspectral imagery. The workflow is applied to EO-1 Hyperion satellite imagery collected near Ibirací, Minas Gerais, Brazil. The proposed workflow includes subset feature selection, learning, and estimation algorithms. Network training with landscape feature class realizations provide a hypersurface from which to estimate mixtures of soil (e.g. 0.5 exceedance for pixels: 75% clay-rich Nitisols, 15% iron-rich Latosols, and 1% quartz-rich Arenosols) and vegetation (e.g. 0.5 exceedance for pixels: 4% Aspen-like trees, 7% Blackberry-like trees, 0% live grass, and 2% dead grass). The process correctly maps forests and iron-rich Latosols as being coincident with existing drainages, and correctly classifies the clay-rich Nitisols and grasses on the intervening hills. These classifications are independently corroborated visually (Google Earth) and quantitatively (random soil samples and crossplots of field spectra). Some mapping challenges are the underestimation of forest fractions and overestimation of soil fractions where steep valley shadows exist, and the under representation of classified grass in some dry areas of the Hyperion image. These preliminary results provide impetus for future hyperspectral studies involving airborne and satellite sensors with higher signal-to-noise and smaller footprints.  相似文献   
117.
Geotechnical and Geological Engineering - Dispersive soils are susceptible to phenomena of internal and external erosion when in contact with relatively pure water due to its particle’s...  相似文献   
118.

The site characterization of unsaturated soils is well stablished based on laboratory tests, which are expensive and time-consuming. In-situ testing methods, such as the flat dilatometer test (DMT), are an alternative to the traditional approach of drilling, sampling, and laboratory testing. The literature on DMT interpretation is well established on saturated and well-behaved soils. Only few studies deal with DMT interpretation in unusual soils, and little is known about the influence of soil suction on this test. This paper presents and discusses the influence of soil suction on four DMT campaigns carried out in an unsaturated tropical soil site, also incorporating the soil suction influence on the DMT interpretation. Soil suction was estimated by the soil–water characteristic curve (SWCC) and water content profiles. The water content profiles range from 11.3 to 19.7% which corresponds to a suction range estimated by SWCCs mostly between 6 and 200 kPa. Soil suction significantly influenced DMT data up to 5 m depth at the studied site (the unsaturated active zone) increasing the intermediate DMT parameters. The average horizontal stress index (KD) was equal to about 1.7 and the average dilatometer modulus (ED) was about 4.7 MPa in the active zone and practically doubled their values due to in situ soil suction. The estimated peak friction angle (?) was 20–30% higher due to soil suction influence on DMT assuming the soil behaves as a sand like material. Soil suction must be considered to assess the behavior of the investigated soil by the DMT. The suction influence should be incorporated in the effective stress and this approach considerably improved the site characterization of the studied site.

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119.
Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km2), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands.  相似文献   
120.

The volcanic rocks of the Colíder and Roosevelt formations are extensively exposed in the south-central portion of the Amazonian Craton where effusive and pyroclastic rocks have been mapped. Both units, topped by chemical sediments and oceanic facies as rhyolite and andesite lavas, rhyodacite, and porphyritic dacite, with frequent intercalations of pyroclastic and epiclastic deposits. Whole-rock geochemistry for 55 samples of rhyolitic to andesitic composition suggests the involvement of fertile mantle-derived components with E-MORB to OIB compositions. The analyzed rocks display calc-alkaline to shoshonitic affinity consistent with generation related to an active continental margin. The whole-rock Sm-Nd isotope data from selected felsic volcanic rocks of the Colíder and Roosevelt formations yield negative initial εNd values between –3 and –9, indicating the predominantly crustal nature of the parental magmas with early Archean to late Paleoproterozoic (ca. 2.5–2.0 Ga) depleted mantle model ages.

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