The evolution of polycyclic aromatic hydrocarbons under simulated inner asteroid conditions     

Claudia‐Corina Giese  Inge Loes Ten Kate  Oliver Plümper  Helen E. King  Christoph Lenting  Yang Liu  Alexander G. G. M. Tielens 《Meteoritics & planetary science》2019,54(9):1930-1950

Large polycyclic aromatic hydrocarbons (PAHs) are an important component of the interstellar medium. PAHs have been identified in the soluble and insoluble matter of carbonaceous chondrites (CCs). Here, we study the evolution of PAHs under conditions relevant to the interiors of asteroids and compare our results to PAHs observed in CCs. We have performed long‐term and short‐term hydrothermal experiments, in which we exposed PAH‐mineral mixture analogs of meteorites to temperature conditions representative of those predicted for asteroids interiors. Our results show that small PAHs with melting points within the aqueous alteration temperature of CCs form carbonaceous spherules in the presence of water. In this work, we describe the microstructure and morphology of these spherules. We discuss the similarities and differences compared to globules isolated from CCs.  相似文献   

The Stubenberg meteorite—An LL6 chondrite fragmental breccia recovered soon after precise prediction of the strewn field          下载免费PDF全文

Addi Bischoff  Jean‐Alix Barrat  Kerstin Bauer  Christoph Burkhardt  Henner Busemann  Samuel Ebert  Michael Gonsior  Janina Hakenmüller  Jakub Haloda  Dennis Harries  Dieter Heinlein  Harald Hiesinger  Rupert Hochleitner  Viktor Hoffmann  Melanie Kaliwoda  Matthias Laubenstein  Colin Maden  Matthias M. M. Meier  Andreas Morlok  Andreas Pack  Alexander Ruf  Philippe Schmitt‐Kopplin  Maria Schönbächler  Robert C. J. Steele  Pavel Spurný  Karl Wimmer 《Meteoritics & planetary science》2017,52(8):1683-1703

  相似文献   

In search of the Earth‐forming reservoir: Mineralogical,chemical, and isotopic characterizations of the ungrouped achondrite NWA 5363/NWA 5400 and selected chondrites          下载免费PDF全文

Christoph Burkhardt  Nicolas Dauphas  Haolan Tang  Mario Fischer‐Gödde  Liping Qin  James H. Chen  Surya S. Rout  Andreas Pack  Philipp R. Heck  Dimitri A. Papanastassiou 《Meteoritics & planetary science》2017,52(5):807-826

High‐precision isotope data of meteorites show that the long‐standing notion of a “chondritic uniform reservoir” is not always applicable for describing the isotopic composition of the bulk Earth and other planetary bodies. To mitigate the effects of this “isotopic crisis” and to better understand the genetic relations of meteorites and the Earth‐forming reservoir, we performed a comprehensive petrographic, elemental, and multi‐isotopic (O, Ca, Ti, Cr, Ni, Mo, Ru, and W) study of the ungrouped achondrites NWA 5363 and NWA 5400, for both of which terrestrial O isotope signatures were previously reported. Also, we obtained isotope data for the chondrites Pillistfer (EL6), Allegan (H6), and Allende (CV3), and compiled available anomaly data for undifferentiated and differentiated meteorites. The chemical compositions of NWA 5363 and NWA 5400 are strikingly similar, except for fluid mobile elements tracing desert weathering. We show that NWA 5363 and NWA 5400 are paired samples from a primitive achondrite parent‐body and interpret these rocks as restite assemblages after silicate melt extraction and siderophile element addition. Hafnium‐tungsten chronology yields a model age of 2.2 ± 0.8 Myr after CAI, which probably dates both of these events within uncertainty. We confirm the terrestrial O isotope signature of NWA 5363/NWA 5400; however, the discovery of nucleosynthetic anomalies in Ca, Ti, Cr, Mo, and Ru reveals that the NWA5363/NWA 5400 parent‐body is not the “missing link” that could explain the composition of the Earth by the mixing of known meteorites. Until this “missing link” or a direct sample of the terrestrial reservoir is identified, guidelines are provided of how to use chondrites for estimating the isotopic composition of the bulk Earth.  相似文献   

Partial amorphization of experimentally shocked plagioclase: A spectroscopic study     

Lidia Pittarello  Joerg Fritz  Julia Roszjar  Christoph Lenz  Chutimun Chanmuang N.  Christian Koeberl 《Meteoritics & planetary science》2020,55(3):669-678

Shock amorphization of plagioclase, from partial to complete, has been used to evaluate the degree of shock in meteorites. Important information on the shock amplitude can be derived from the measurement of the refractive index in plagioclase, either from mineral separates or in petrographic thin sections. However, this technique is time‐consuming, and associated sample preparations are considered destructive and are not always possible for precious and rare meteorite samples. In addition, plagioclase amorphization is commonly inhomogeneous at the sample scale and a statistically meaningful number of grains must be considered. Here, we apply several nondestructive spectroscopic techniques, such as Raman spectroscopy, photoluminescence, and cathodoluminescence, to plagioclase experimentally shocked at 28 GPa, and thus in the transition regime between crystalline plagioclase and fully amorphous material. Most of the plagioclase was transformed into diaplectic glass at 28 GPa, yet some grains exhibit heterogeneously distributed crystalline domains. This confirms that intrinsic and extrinsic factors lead to local variations in the intensity of the shock pressure within individual plagioclase crystals of homogeneous composition. The amorphization of plagioclase can qualitatively (and potentially also quantitatively) be investigated by spectroscopic techniques, highlighting such local variations in the shock efficiency.  相似文献   

Vegetation impacts soil water content patterns by shaping canopy water fluxes and soil properties          下载免费PDF全文

Johanna Clara Metzger  Thomas Wutzler  Nicolas Dalla Valle  Janett Filipzik  Christoph Grauer  Robert Lehmann  Martin Roggenbuck  Danny Schelhorn  Josef Weckmüller  Kirsten Küsel  Kai Uwe Totsche  Susan Trumbore  Anke Hildebrandt 《水文研究》2017,31(22):3783-3795

Soil water content is a key variable for biogeochemical and atmospheric coupled processes. Its small‐scale heterogeneity impacts the partitioning of precipitation (e.g., deep percolation or transpiration) by triggering threshold processes and connecting flow paths. Forest hydrologists frequently hypothesized that throughfall and stemflow patterns induce soil water content heterogeneity, yet experimental validation is limited. Here, we pursued a pattern‐oriented approach to explore the relationship between net precipitation and soil water content. Both were measured in independent high‐resolution stratified random designs on a 1‐ha temperate mixed beech forest plot in Germany. We recorded throughfall (350 locations) and stemflow (65 trees) for 16 precipitation events in 2015. Soil water content was measured continuously in topsoil and subsoil (210 profiles). Soil wetting was only weakly related to net precipitation patterns. The precipitation‐induced pattern quickly dissipates and returns to a basic pattern, which is temporally stable. Instead, soil hydraulic properties (by the proxy of field capacity) were significantly correlated with this stable soil water content pattern, indicating that soil structure more than net precipitation drives soil water content heterogeneity. Also, both field capacity and soil water content were lower in the immediate vicinity of tree stems compared to further away at all times, including winter, despite stemflow occurrence. Thus, soil structure varies systematically according to vegetation in our site. We conclude that enhanced macroporosity increases gravity‐driven flow in stem proximal areas. Therefore, although soil water content patterns are little affected by net precipitation, the resulting soil water fluxes may strongly be affected. Specifically, this may further enhance the channelling of stemflow to greater depth and beyond the rooting zone.  相似文献   

Turbidites deposited on Southern Central Chilean seamounts: Evidence for energetic turbidity currents   总被引：2，自引：0，他引：2  

David Vlker  Thomas Reichel  Michael Wiedicke  Christoph Heubeck 《Marine Geology》2008,251(1-2):15-31

Gravity cores obtained from isolated seamounts located within, and rising up to 300 m from the sediment-filled Peru–Chile Trench off Southern Central Chile (36°S–39°S) contain numerous turbidite layers which are much coarser than the hemipelagic background sedimentation. The mineralogical composition of some of the beds indicates a mixed origin from various source terrains while the faunal assemblage of benthic foraminifera in one of the turbidite layers shows a mixed origin from upper shelfal to middle-lower bathyal depths which could indicate a multi-source origin and therefore indicate an earthquake triggering of the causing turbidity currents. The bathymetric setting and the grain size distribution of the sampled layers, together with swath echosounder and sediment echosounder data which monitor the distribution of turbidites on the elevated Nazca Plate allow some estimates on the flow direction, flow velocity and height of the causing turbidity currents. We discuss two alternative models of deposition, both of which imply high (175–450 m) turbidity currents and we suggest a channelized transport process as the general mode of turbidite deposition. Whether these turbidites are suspension fallout products of thick turbiditic flows or bedload deposits from sheet-like turbidity currents overwhelming elevated structures cannot be decided upon using our sedimentological data, but the specific morphology of the seamounts rather argues for the first option. Oxygen isotope stratigraphy of one of the cores indicates that the turbiditic sequences were deposited during the last Glacial period and during the following transition period and turbiditic deposition stopped during the Holocene. This climatic coupling seems to be dominant, while the occurrence of megathrust earthquakes provides a trigger mechanism. This seismic triggering takes effect only during times of very high sediment supply to the shelf and slope.  相似文献   

Numerical studies of gas hydrate systems: sensitivity to porosity-permeability models     

Jakob Hauschildt  Vikram Unnithan  Joachim Vogt 《Geo-Marine Letters》2010,30(3-4):305-312

The formation of sub-seafloor gas hydrates in marine environments can be described as a coupled transport and thermodynamic process inside a host sediment matrix undergoing structural evolution. The transport processes are driven by the sedimentary load and induced overpressure gradients, controlled by sediment permeability. In order to accurately model the resulting fluid flow profile, the decrease of sediment permeability during hydrate precipitation has to be taken into account, which affects both the transport of solutes and sediment compaction. In this paper, we investigate how total hydrate abundance is affected by regions of low permeability which deflect the flow field in their vicinity. For this purpose, a two-dimensional numerical hydrate system model was set up which permits to quantify this effect in scenarios where changes in water depth cause lateral variations of the thickness of the hydrate stability field, as well as of hydrate saturation and sediment permeability. The microscopic structure of gas hydrate crystals in the host sediment matrix defines the evolution of the permeability reduction during hydrate formation. Grain-coating precipitates have a stronger tendency to clog flow paths through pore throats than do pore-filling precipitates. Our results clearly show that these pore-scale processes affect the large-scale flow field and hydrate abundance. The sensitivity depends on the model geometry and, for a 5° slope of the seafloor, 4.1% relative difference is predicted for the hydrate saturation according to different porosity-permeability relationships.  相似文献   

Physical laboratory analyses of intergravel flow through brown trout redds (Salmo trutta fario) in response to coarse sand infiltration          下载免费PDF全文

Wolfgang Obruca  Christoph Hauer 《地球表面变化过程与地形》2017,42(4):670-680

In the spawning environment of salmonids, the quality of the intergravel flow is an essential abiotic requirement for the survival success of incubated embryos. As one of the most frequently investigated anthropogenic environmental impacts, the enhanced mobilization of fine sediments (<1 mm) and their entry into riverine ecosystems is considered as a major cause for the degradation of a variety of biological processes and habitats, including the spawning habitats of salmonids. In catchments draining crystalline bedrock, however, like the Bohemian Massif in the northern part of Austria, the excessive loading of river channels with coarse sand and fine gravel sediments (D = 1–10 mm) and less cohesive than fines is common as a consequence of altered catchment land use. Here, far less understanding exists of the mechanism and the possible implications of coarse sand infiltration on the functioning of the intergravel flow in salmonid redds. To investigate the intergravel flow hydraulics in response to coarse sand infiltration (D₅₀ = 2 mm) in brown trout spawning redds (Salmo trutta fario ) under controlled conditions, a laboratory flume experiment with three infiltration scenarios was conducted: (1) no infiltration; (2) segmental infiltration; and (3) full section infiltration. A more than two times drop in the average intergravel flow velocity was documented from scenario 1 (5.85 cms^?1) to scenario 2 (2.53 cms^?1) and another clear reduction was seen from scenario 2 (2.53 cms^?1) to scenario 3 (1.61 cms^?1). Moreover, in scenario 3, a clear reduction of the intergravel flow distance traveled was observed. Based on the findings we conclude that future considerations regarding the sustainable catchment management of salmonid fisheries should include programs to reduce not only the excessive entry of fines, but, in the relevant catchments, also the entry of excessive coarse sand into the riverine ecosystem. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Sediment budgeting of short-term backfilling processes: The erosional collapse of a Carolingian canal construction     

Johannes Schmidt  Lukas Werther  Johannes Rabiger-Völlmer  Franz Herzig  Birgit Schneider  Ulrike Werban  Peter Dietrich  Stefanie Berg  Sven Linzen  Peter Ettel  Christoph Zielhofer 《地球表面变化过程与地形》2020,45(14):3449-3462

Sediment budgeting concepts serve as quantification tools to decipher the erosion and accumulation processes within a catchment and help to understand these relocation processes through time. While sediment budgets are widely used in geomorphological catchment-based studies, such quantification approaches are rarely applied in geoarchaeological studies. The case of Charlemagne's summit canal (also known as Fossa Carolina) and its erosional collapse provides an example for which we can use this geomorphological concept and understand the abandonment of the Carolingian construction site. The Fossa Carolina is one of the largest hydro-engineering projects in Medieval Europe. It is situated in Southern Franconia (48.9876°N, 10.9267°E; Bavaria, southern Germany) between the Altmühl and Swabian Rezat rivers. It should have bridged the Central European watershed and connected the Rhine–Main and Danube river systems. According to our dendrochronological analyses and historical sources, the excavation and construction of the Carolingian canal took place in AD 792 and 793. Contemporary written sources describe an intense backfill of excavated sediment in autumn AD 793. This short-term erosion event has been proposed as the principal reason for the collapse and abandonment of the hydro-engineering project. We use subsurface data (drillings, archaeological excavations, and direct-push sensing) and geospatial data (a LiDAR digital terrain model (DTM), a pre-modern DTM, and a 3D model of the Fossa Carolina] for the identification and sediment budgeting of the backfills. Dendrochronological findings and radiocarbon ages of macro remains within the backfills give clear evidence for the erosional collapse of the canal project during or directly after the construction period. Moreover, our quantification approach allows the detection of the major sedimentary collapse zone. The exceedance of the manpower tipping point may have caused the abandonment of the entire construction site. The spatial distribution of the dendrochronological results indicates a north–south direction of the early medieval construction progress. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   

Arctic margin gravity highs: Deeper meaning for sediment depocenters?     

Vogt  Peter R.  Jung  Woo-Yeol  Brozena  John 《Marine Geophysical Researches》1998,20(5):459-477

Morphologic, gravity, and seismic reflection/refraction data from ca. 10,000 km of Arctic passive continental margins suggest that the numerous oval free-air gravity anomalies, their +50–150 mGal extrema typically located just landward of shelf breaks, are caused by combinations of rapidly deposited Plio-Pleistocene glacial marine sediment loads, older post-breakup sediments, and perhaps causally related density anomalies (mascons) in the underlying oceanic crust. Dispersed seismicity associated with some gravity highs may reflect ongoing brittle, flexural adjustment to the loads. Multi-channel-seismic-controlled depocenter models for several prominent highs (including the Hornsund gravity high re-examined here) suggest that sediments alone do not suffice to explain the gravity highs, unless depocenter seismic velocities have been significantly underestimated. A flexural backstripping model for the Hornsund anomaly only roughly replicates observed gravity. Subjacent 'mascons', if present below some depocenters, may be caused by (1) anomalous subsidence of initially formed dense/thin crust; (2) depocenter blanketing of early-formed crust, mitigating hydrothermal fracturing and related density reduction; or (3) metastable phase transitions, converting basalt/gabbro to denser phases (Neugebauer–Spohn hypothesis), while cracks close or fill under the increased pressures and temperatures.  相似文献