Effect of the injection of pure oxygen into a membrane bioreactor on the elimination of bisphenol A   总被引：1，自引：1，他引：0  

N. Dorival-García  A. Zafra-Gómez  B. Oliver-Rodríguez  A. Navalón  J. González-López  J. L. Vílchez 《International Journal of Environmental Science and Technology》2014,11(1):9-20

The effect of the injection of pure oxygen instead of air in a membrane bioreactor for the elimination of bisphenol A is investigated. A dynamic experiment was developed in a pilot plant where the aerobic reactor was continuously spiked with 1 mg L^?1 of bisphenol A. Air was injected for 10 days and then pure oxygen was injected for another 10 days. The bisphenol A concentration was determined in aqueous phases and activated sludge using simple and sensitive analytical methods based on different extraction procedures and liquid chromatography tandem mass spectrometry analysis. Enzymatic activity was also determined and toxicity tests were performed to discard that the spiked bisphenol A concentration could negatively affect the microorganisms in the bioreactor and, thus, the membrane bioreactor performance. The effluent bisphenol A concentration increased up to 0.26 mg L^?1 after 4 days in the air injection treatment, and up to 0.48 mg L^?1 after only 12 h in the oxygen injection treatment. In both cases, this was followed by a decrease in concentration despite the continuous spiking of bisphenol A into the bioreactor. In presence of pure oxygen, bisphenol A concentration reached background levels (below the limit of quantification) after 5 days. In contrast, when using air a total of 10 days were required to reach background levels. The injection of pure oxygen instead of air is an important innovation in wastewater treatment, allowing permanent elimination of organic contaminants, avoiding their return to the environment and ensuring the safety of water.  相似文献   

A geochemical and 3D-geometry geophysical survey to assess artificial groundwater recharge potential in the Pacific coast of Baja California,Mexico     

L. W. Daesslé  M. A. Pérez-Flores  J. Serrano-Ortiz  L. Mendoza-Espinosa  E. Manjarrez-Masuda  K. C. Lugo-Ibarra  E. Gómez-Treviño 《Environmental Earth Sciences》2014,71(8):3477-3490

A geophysical and geochemical study was carried out in the Maneadero aquifer, Baja California, Mexico, with the aim of identifying potential recharge locations for reclaimed water (RW). This coastal aquifer shows a significant decline in water quality, both as a result of salinization and the pollution by nitrates. Total dissolved solids (TDS) in an extreme case increased from 4 g l^?1 in 2000 to 27 g l^?1 in 2011. Nitrate as N–NO₃, reaches 46 mg l^?1. Based on their geochemistry and location, four water-quality zones are identified: (a) fresh water with TDS ≈ 1 g l^?1 in the upper creeks, (b) mixture between seawater and freshwater in the coast-proximal sections, (c) water significantly enriched in nitrate below and adjacent to the town of Maneadero, and (d) brackish water with no signs of current interaction with freshwater. The 3D geophysics identifies the influence of modern recharge areas and also buried flow-paths down to at least 30 m depth. The locations best suitable for aquifer recharge are those with equal or higher TDS concentrations (>2.5 g l^?1) than RW, which are located at the brackish water zone and/or at the coastal limits of the mixing zones.  相似文献   

More accurate,calibrated bootstrap confidence intervals for estimating the correlation between two time series     

K. B. Ólafsdóttir  M. Mudelsee 《Mathematical Geosciences》2014,46(4):411-427

Estimation of Pearson’s correlation coefficient between two time series, in the evaluation of the influences of one time-dependent variable on another, is an often used statistical method in climate sciences. Data properties common to climate time series, namely non-normal distributional shape, serial correlation, and small data sizes, call for advanced, robust methods to estimate accurate confidence intervals to support the correlation point estimate. Bootstrap confidence intervals are estimated in the Fortran 90 program PearsonT (Mudelsee, Math Geol 35(6):651–665, 2003), where the main intention is to obtain accurate confidence intervals for correlation coefficients between two time series by taking the serial dependence of the data-generating process into account. However, Monte Carlo experiments show that the coverage accuracy of the confidence intervals for smaller data sizes can be substantially improved. In the present paper, the existing program is adapted into a new version, called PearsonT3, by calibrating the confidence interval to increase the coverage accuracy. Calibration is a bootstrap resampling technique that performs a second bootstrap loop (it resamples from the bootstrap resamples). It offers, like the non-calibrated bootstrap confidence intervals, robustness against the data distribution. Pairwise moving block bootstrap resampling is used to preserve the serial dependence of both time series. The calibration is applied to standard error-based bootstrap Student’s $t$ confidence intervals. The performance of the calibrated confidence interval is examined with Monte Carlo simulations and compared with the performance of confidence intervals without calibration. The coverage accuracy is evidently better for the calibrated confidence intervals where the coverage error is acceptably small already (i.e., within a few percentage points) for data sizes as small as 20.  相似文献   

The state of the environment in Mexico     

Manuel Bollo Manent  José Ramón Hernández Santana  Ana Patricia Méndez Linares 《Central European Journal of Geosciences》2014,6(2):219-228

The present work evaluates the state of the environment in Mexico based on indicators of the present status of the country’s natural resource management, social and economical conditions and anthropogenic modifications. The Mexican environment is interpreted as a spatially open system having a historical character that is essentially determined by the continual interaction between nature, society and economy. The landscape approach is followed, considering as units of territorial analysis each one of the 145 biophysical environmental units included in the national physiographic regionalization. The assessment of 16 indicators for each biophysical environmental unit was made considering their regional environmental integrity problems, the degree of disarticulation of their structure and function, and the alteration of their territorial structure, all of which determine whether or not they accomplish their environmental functions and achieve environmental stability. The classification of the state of the environment included 5 categories in 8 combinations represented in the map of the state of the environment in Mexico for the year 2008. The map shows that nearly 47.10% of the country’s surface has an environmental status ranging between unstable and critical, the problematic areas being mostly concentrated in the southeast and center of the national territory.  相似文献   

Dispersion modeling of air pollutants in the atmosphere: a review     

Ádám Leelőssy  Ferenc Molnár Jr.  Ferenc Izsák  Ágnes Havasi  István Lagzi  Róbert Mészáros 《Central European Journal of Geosciences》2014,6(3):257-278

Modeling of dispersion of air pollutants in the atmosphere is one of the most important and challenging scientific problems. There are several natural and anthropogenic events where passive or chemically active compounds are emitted into the atmosphere. The effect of these chemical species can have serious impacts on our environment and human health. Modeling the dispersion of air pollutants can predict this effect. Therefore, development of various model strategies is a key element for the governmental and scientific communities. We provide here a brief review on the mathematical modeling of the dispersion of air pollutants in the atmosphere. We discuss the advantages and drawbacks of several model tools and strategies, namely Gaussian, Lagrangian, Eulerian and CFD models. We especially focus on several recent advances in this multidisciplinary research field, like parallel computing using graphical processing units, or adaptive mesh refinement.  相似文献   

GIS application for regional assessment of seismically induced slope failures in the Sierra Nevada Range,South Spain,along the Padul Fault     

M. J. Rodríguez-Peces  J. García-Mayordomo  J. M. Azañón  A. Jabaloy 《Environmental Earth Sciences》2014,72(7):2423-2435

Complete rupture of the Padul Fault represents one of the largest plausible earthquakes in the Sierra Nevada Range, one of the most seismically active regions of Spain. We performed a regional assessment of earthquake-triggered slope instabilities in the western part of the range to determine the most likely types of failures from such an earthquake in the region and suggest where such failures have a higher likelihood of occurring. These results are broadly useful for management of regional life-lines and future development. First, a slope-instability inventory of the Sierra Nevada was produced to identify the most common instability types. Subsequently, the Newmark’s sliding rigid-block methodology, implemented in a geographic information system, was used to obtain the distribution of Newmark displacements in the area considering a M _w 6.6 earthquake on the Padul Fault. The Newmark displacements were then compared to the distribution of the inventoried slope instabilities to identify the areas where seismicity could reactivate old slope instabilities or generate new ones, and to identify the involved landslide typology. The most likely seismically induced slope instabilities in the Sierra Nevada are rock falls and rock slides. These types of instabilities could be triggered by Newmark displacements of 2 cm or less.  相似文献   

Archean to Recent aeolian sand systems and their sedimentary record: Current understanding and future prospects     

Juan Pedro Rodríguez‐López  Lars B. Clemmensen  Nick Lancaster  Nigel P. Mountney  Gonzalo D. Veiga 《Sedimentology》2014,61(6):1487-1534

The sedimentary record of aeolian sand systems extends from the Archean to the Quaternary, yet current understanding of aeolian sedimentary processes and product remains limited. Most preserved aeolian successions represent inland sand‐sea or dunefield (erg) deposits, whereas coastal systems are primarily known from the Cenozoic. The complexity of aeolian sedimentary processes and facies variability are under‐represented and excessively simplified in current facies models, which are not sufficiently refined to reliably account for the complexity inherent in bedform morphology and migratory behaviour, and therefore cannot be used to consistently account for and predict the nature of the preserved sedimentary record in terms of formative processes. Archean and Neoproterozoic aeolian successions remain poorly constrained. Palaeozoic ergs developed and accumulated in relation to the palaeogeographical location of land masses and desert belts. During the Triassic, widespread desert conditions prevailed across much of Europe. During the Jurassic, extensive ergs developed in North America and gave rise to anomalously thick aeolian successions. Cretaceous aeolian successions are widespread in South America, Africa, Asia, and locally in Europe (Spain) and the USA. Several Eocene to Pliocene successions represent the direct precursors to the present‐day systems. Quaternary systems include major sand seas (ergs) in low‐lattitude and mid‐latitude arid regions, Pleistocene carbonate and Holocene–Modern siliciclastic coastal systems. The sedimentary record of most modern aeolian systems remains largely unknown. The majority of palaeoenvironmental reconstructions of aeolian systems envisage transverse dunes, whereas successions representing linear and star dunes remain under‐recognized. Research questions that remain to be answered include: (i) what factors control the preservation potential of different types of aeolian bedforms and what are the characteristics of the deposits of different bedform types that can be used for effective reconstruction of original bedform morphology; (ii) what specific set of controlling conditions allow for sustained bedform climb versus episodic sequence accumulation and preservation; (iii) can sophisticated four‐dimensional models be developed for complex patterns of spatial and temporal transition between different mechanisms of accumulation and preservation; and (iv) is it reasonable to assume that the deposits of preserved aeolian successions necessarily represent an unbiased record of the conditions that prevailed during episodes of Earth history when large‐scale aeolian systems were active, or has the evidence to support the existence of other major desert basins been lost for many periods throughout Earth history?  相似文献   

Operational forecasting of daily summer maximum and minimum temperatures in the Valencia Region     

I. Gómez  M. J. Estrela  V. Caselles 《Natural Hazards》2014,70(2):1055-1076

Extreme-temperature events have a great impact on human society. Thus, knowledge of summer temperatures can be very useful both for the general public and for organizations whose workers operate in the open. An accurate forecasting of summer maximum and minimum temperatures could help to predict heatwave conditions and permit the implementation of strategies aimed at minimizing the negative effects that high temperatures have on human health. The objective of this work is to evaluate the skill of the regional atmospheric and modelling system (RAMS) model in determining daily summer maximum and minimum temperatures in the Valencia Region. For this, we have used the real-time configuration of this model currently running at the Centro de Estudios Ambientales de Mediterráneo Foundation. This operational system is run twice a day, and both runs have a 3-day forecast range. To carry out the verification of the model in this work, the information generated by the system has been broken into individual simulation days for a specific daily run of the model. Moreover, we have analysed the summer forecast period from 1 June to 31 August for 2007, 2008, 2009 and 2010. The results indicate good agreement between observed and simulated maximum temperatures, with RMSE in general near 2 °C both for coastal and inland stations. For this parameter, the model shows a negative bias around ?1.5 °C in the coast, while the opposite trend is observed inland. In addition, RAMS also shows good results in forecasting minimum temperatures for coastal locations, with bias lower than 1 °C and RMSE below 2 °C. However, the model presents some difficulties for this parameter inland, where bias higher than 3 °C and RMSE of about 4 °C have been found. Besides, there is little difference in both temperatures forecasted within the two daily RAMS cycles and that RAMS is very stable in maintaining the forecast performance at least for three forecast days.  相似文献   

Natural Variability of Shear Strength in a Granite Residual Soil from Porto     

Luís Pinheiro Branco  António Topa Gomes  António Silva Cardoso  Carla Santos Pereira 《Geotechnical and Geological Engineering》2014,32(4):911-922

The renewal imposed by the Eurocodes regarding the methodologies of safety evaluation requires a statistical analysis of the variability of ground geotechnical parameters. However, the studies published in the reviewed literature do not cover the typical materials from the northeast region of Portugal—residual soils from granite—to which a strong heterogeneity is associated. Hence, a statistical characterization of the natural variability of a granite residual soil from Porto has been made through a significant amount of experimental tests, focusing on its geomechanical properties. In order to provide a database for probabilistic analysis of problems involving this type of soils, an appropriate statistical law has been used to model its variability, which has been quantified by means of coefficients of variation and scales of fluctuation.  相似文献   

FTIR spectroscopy of Ti-chondrodite,Ti-clinohumite,and olivine in deeply subducted serpentinites and implications for the deep water cycle   总被引：1，自引：0，他引：1  

Tingting Shen  Jőrg Hermann  Lifei Zhang  José Alberto Padrón-Navarta  Jing Chen 《Contributions to Mineralogy and Petrology》2014,167(4):1-15

Separated olivine grains from a deeply subducted serpentinized wehrlite (Changawuzi in the western Tianshan ultrahigh-pressure belt, China) were analysed with unpolarized transmission FTIR and the Ti contents were determined using LA-ICP-MS. The major bands in the olivine spectra display striking similarities to Ti-clinohumite and are interpreted as OH in lamellae. The quantification of the water content in lamellae requires calibration of the IR-absorption for such bands. We have obtained a new absorption coefficient for Ti-clinohumite of 0.125+/?0.017 ppm cm² based on polarized FTIR measurements on three orthogonal sections through a large single crystal of Ti-clinohumite from Val Malenco, which has a known water content of 1.53 wt%. The resulting water content in olivine using this calibration factor ranges from 440 to 2,600 ppm and correlates positively with the Ti content that ranges from 130 to 1,400 ppm. For the quantification of the water content in Ti-chondrodite and Ti-clinohumite that are associated with olivine, we developed a new method using attenuated total reflectance FTIR spectroscopy. Ti-chondrodite and Ti-clinohumite display similar IR bands at ~3,562, 3,525 and ~3,583–3,586 cm^?1. As in olivine, the water content and Ti content correlate in both Ti-clinohumite and Ti-chondrodite, indicating an intergrowth of these minerals, which has been confirmed by TEM analyses. Our results confirm previous suggestions that there is a strong correlation between the Ti content of ultramafic rocks and their capacity to transport water to the deeper mantle in subduction zones beyond conditions where hydrous phases are stable.  相似文献