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181.
Biomarker analyses for evaluating maturity of organic matter and depositional environments such as redox conditions, were performed in sediments across the Cenomanian–Turonian boundary (CTB) in the Saku Formation of the Yezo Group distributed along the Shumarinai‐gawa River and the Omagari‐zawa River, both in the Tomamae area, Hokkaido, Japan. Maturity indicators using steranes and hopanes, show that organic matter in sediments from the Shumarinai‐gawa and Omagari‐zawa sections are of lower maturity than those from the Hakkin‐gawa section (Oyubari area). Moreover, the ββ hopane ratios clearly show that the maturity of the Shumarinai‐gawa samples is lower than that of the Omagari‐zawa samples. These variations in the maturity of organic matter presumably reflect the difference in their burial histories. The results for the pristane/phytane (Pr/Ph) ratios suggest that the Shumarinai‐gawa samples were deposited under dysoxic to anoxic environments across the CTB, while the depositional environments of the Omagari‐zawa samples were relatively oxic. By another paleoredox indicator using C35 homohopanoids including a homohopene index (HHenI), higher values are observed in the Shumarinai‐gawa section, particularly in the horizons of the preceding period and an early stage of the first negative shift phase and the latest oceanic anoxic event 2 (OAE2) interval. These results suggest that the Shumarinai‐gawa samples record dysoxic to anoxic environments across the CTB. In contrast, the signals for the C35 homohopanoid index values show a relatively oxic condition in the Omagari‐zawa section. The trends of stratigraphic variations in redox conditions are different from those in the OAE2 interval in the proto‐Atlantic and Tethys regions as reported previously. Hence, the redox variations in the Tomamae area were basically related to a local environmental setting rather than global anoxia. However, the prominent anoxic emphasis observed in the HHenI profile of the Shumarinai‐gawa section can be a distinctive, and possibly global, event in the North‐West Pacific just before the OAE2.  相似文献   
182.
In the near future, a new generation of sample return missions (Hayabusa2, OSIRIS‐REx, MMX, etc.) will collect samples from small solar system bodies. To maximize the scientific outcome of laboratory studies and minimize the loss of precious extraterrestrial samples, an analytical sequence from less destructive to more destructive techniques needs to be established. In this work, we present a combined X‐ray and IR microtomography applied to five Itokawa particles and one fragment of the primitive carbonaceous chondrite Paris. We show that this analytical approach is able to provide a 3‐D physical and chemical characterization of individual extraterrestrial particles, using the measurement of their 3‐D structure and porosity, and the detection of mineral and organic phases, and their spatial co‐localization in 3‐D. We propose these techniques as an efficient first step in a multitechnique analytical sequence on microscopic samples collected by space missions.  相似文献   
183.
To investigate the suitability of synthetic aperture radar (SAR) polarization data to estimate the sea-ice thickness in early summer in Lutzow-Holm Bay, Antarctica, we compared in situ ice thicknesses with the corresponding backscattering co-efficient for each polarization and the VV-to-HH backscattering ratio. The VV-to-HH backscattering ratio was derived from data acquired by ENVISAT Advanced SAR (ASAR). This ratio is related to the near-surface dielectric constant of the sea ice, which is, in turn, related to the developing process of ice and, thus, its thickness via changes in the near-surface sea-ice salinity. The sea ice encountered in the study area is close first-year pack ice and fast ice. For these old and relatively rough sea-ice types, the VV-to-HH backscattering ratio can be expected to depend on salinity-driven changes in the near-surface dielectric constant rather than changes of the surface roughness. We applied the empirical relationships between the ice thickness and the VV-to-HH backscattering ratio with the linear and logarithm fits to ASAR data. The linear fit gave the reliable result, with an rms error being 0.08 m and a correlation coefficient being 0.91, when compared to in situ fast-ice thickness.  相似文献   
184.
185.
Detailed depth profiles of photosynthetic pigments in a sediment core (G-12) collected at the BDP93 site, the Buguldeika saddle, of south Lake Baikal, along with depth profiles of total organic carbon (TOC) and biogenic silica, were studied to elucidate the temporal changes of phytoplankton assemblages in the lake during the past 28 kyr. In addition to the quantification of carotenoids by high-performance liquid chromatography with photodiode-array detection (HPLC-PDA), steryl chlorin esters (SCEs) were analyzed by HPLC-PDA, HPLC-mass spectrometry (LC-MS) and sterols in SCEs by gas chromatography–mass spectrometry (GC–MS) to enrich the taxonomical information on the phytoplankton composition. Allochthonous input of organic matter from the Selenga River resulted in the higher TOC contents in core G-12 than in a previously reported core (G-6) collected at another site from the southern basin. The poorer correlation in core G-12 than in G-6 between TOC and chlorophyll-a-originating pigments, which are indicative of autochthonous production, also indicated a significant allochthonous input at the site. The abundance of lutein among the carotenoids detected, and the good correlation of total chlorophyll a and b shows that green algae represented a significant portion of the phytoplankton, accompanying the diatoms at the G-12 site, after the last glacial period. The presence of cryptomonads and cyanobacteria were confirmed from marker carotenoids in the sediment core. GC–MS analysis of sterols in SCEs detected marker sterols of diatoms, green algae, chrysophytes and dinoflagellates. The depth profiles of the measured indicators gave consistent features for temporal changes in phytoplankton assemblage at the G-12 site of Lake Baikal after the last glacial maximum. Notably, the profile of a chrysophyte-specific sterol in SCEs was consistent with the reported distribution of chrysophyte cysts during the Holocene. The presence of phytoplankton, such as green algae, diatoms and chrysophytes, in Lake Baikal during the late last glacial period was indicated by the analysis of sterols in SCEs. Sedimentary carotenoids and sterols in SCEs were found to give complementary information about phytoplankton composition. These molecular indicators allow us to reconstruct past lake phytoplankton assemblages responding to environmental changes with a time resolution as high as age–depth relationship in sediments attainable at present.  相似文献   
186.
In situ X-ray observations of the phase transition from ilmenite to perovskite structure in MnGeO3 were carried out in a Kawai-type high-pressure apparatus interfaced with synchrotron radiation. The phase boundary between the ilmenite and perovskite structures in the temperature range of 700–1,400°C was determined to be P (GPa) = 16.5(±0.6) − 0.0034(±0.0006)T (°C) based on Anderson’s gold pressure scale. The Clapeyron slope, dP/dT, determined in this study is consistent with that for the transition boundary between the ilmenite and the perovskite structure in MgSiO3.  相似文献   
187.
Takeshi  Tsuji  Yasuyuki  Nakamura  Hidekazu  Tokuyama  Millard F.  Coffin  Keita  Koda 《Island Arc》2007,16(3):361-373
Abstract   To show the structure of oceanic crust and Moho around the eastern Ogasawara Plateau, we have analyzed industry-standard two-dimensional multichannel seismic reflection data. To obtain improved velocity models, phase information of seismic signals was used for velocity analysis and velocity models for oceanic crust above Moho were determined. We apply this velocity analysis technique to seismic reflection data around the eastern Ogasawara Plateau, with the result of clear images of structures within oceanic crust and Moho. South of the Ogasawara Plateau, Moho deepens proximal to the Plateau. Moho distal to the Plateau is ca 7 km below sea floor (bsf), whereas it is ca 10 km bsf near the Plateau. The characters of oceanic crust and Moho differ significantly north and south of the Plateau. To the north, the structure of oceanic crust is ambiguous, the sea floor is shallower and less smooth, and Moho is discontinuous. To the south, structures within oceanic crust and Moho are imaged clearly, and the sea floor is deeper. A strong Moho reflection south of the Plateau might represent a sharp boundary between layered gabbro and peridotite. However, discontinuous Moho reflections north of the Plateau might represent rough topography because of intensive magmatism or a gradual downward increase in velocity within a thick Moho transition zone. A fracture zone north of the Plateau also appears to separate oceanic crust and Moho of different characters, suggesting vigorous magmatism between the Plateau and the fracture zone, and that the Ogasawara Plateau and the fracture zone influenced the genesis of oceanic crust and upper mantle. Differences in acoustic characteristics to the north and south of the Plateau are apparent in profiles illuminated by seismic attributes.  相似文献   
188.
The extended Canadian Middle Atmosphere Model (extended CMAM) is a general circulation model, which extends from the surface to about 210 km. Spatial complex spectral analysis is applied to horizontal winds simulated by the extended CMAM to obtain semidiurnal tidal amplitudes and phases (from e5 to w5) in the mesosphere and lower thermosphere (MLT) region. The dominant w2 migrating component and the presence of eight nonmigrating tides (w3, w4, w5, e1, e2, e3, e4 and e5) in the mid-latitudes are identified. Components w1 and s0, which tend to maximize at high latitudes, will be discussed separately in a later paper. The migrating semidiurnal tide (w2) has amplitudes reaching over 20 m s−1 for both zonal and meridional winds in the mid-latitude region. Its form compares well to the published results. The amplitudes of nonmigrating semidiurnal tides are non-negligible compared with the migrating semidiurnal tides. The amplitudes for w3 and e2 exceed 12 and 8 m s−1, respectively.Comparisons are made with four nonmigrating semidiurnal components (w3, w4, e1 and e2) derived from the TIMED Doppler interferometer (TIDI) wind measurements between 85 and 105 km altitude and between 45°S and 45°N latitude. Overall, the basic CMAM and TIDI latitudinal structures of the amplitudes agree well and the agreement between the annual mean amplitudes varies with component. Relative to the TIDI results, the CMAM seasonal variations of w4 are in good agreement, of e2 are in reasonable agreement, of w3 are in partial agreement and of e1 are in poor agreement.The 11 semidiurnal components from the model are superimposed to generate the total semidiurnal winds at Jakarta (6°S, 106°E) and Kototabang (0°, 100°E) and are compared with measurements from two equatorial meteor radar stations at these sites. The relative contributions of components to the reconstructed amplitude vary from month to month. The CMAM reconstructions are generally larger than the radar results by a factor varying between one and two. The phases in the radar data are typically stationary with respect to height, whereas they generally decrease with height in the CMAM reconstruction.  相似文献   
189.
Summary In August 2002, many parts of central Europe were affected by heavy precipitation and flooding caused by a cut-off cyclone. This study shows that this cyclone developed as a result of the propagation of a Rossby wave packet. The wave-packet propagation along the relatively weak subtropical jet was accompanied by wave-breaking and re-emission in the subtropics. In particular, there was an interaction between the Rossby wave packet and a precipitation band along the east coast of North America associated with tropical storm Cristobal. This interaction had a significant influence upon the formation of the European cut-off low. Results from numerical simulations from two different initial conditions are investigated to study this interaction. Downstream influences from tropical storm Cristobal upon the development of this cyclone and associated flooding precipitation are confirmed by sensitivity analysis using ensemble forecasts. It is concluded from analysis and simulations that poor forecast skills of tropical storm Cristobal affected the predictability of the European cut-off low.  相似文献   
190.
We conducted melting experiments on a low-alkali tholeiite (SiO2 ~52 wt%, MgO ~6.5 wt%, CaO/Na2O~4.4, Al2O3/SiO2 ~0.33) under both H2O-undersaturated and H2O-saturated conditions to investigate the effect of H2O on the Ca–Na partitioning between plagioclase and melt. Experiments were performed in the temperature and pressure ranges of 1,000–1,300°C and 1–5 kbar, respectively, with varying H2O contents of 0–12wt%. Redox condition was 0–2 log unit above NNO (nickel–nickel oxide) buffer. Temperature-bulk H2O diagrams for the low-alkali tholeiite are constructed at 1, 2, and 5 kbar, and compositions of near-liquidus plagioclase and coexisting melt are determined. To exclude the effect of melt composition (CaO/Na2O and Al2O3/SiO2 ratios) on plagioclase composition and to reveal the effect of H2O on An (=100×Ca/(Ca+Na)) content and (=(Ca/Na)pl/(Ca/Na)melt), we focused on the composition of near-liquidus plagioclases which crystallized from melts with nearly constant CaO/Na2O and Al2O3/SiO2 ratios. Our experimental results show that, at each experimental pressure, An content of the near-liquidus plagioclase and the KDCa-Na almost linearly increases as H2O content in melt increases. Each of the An content and the variations in a low-alkali tholeiitic system (CaO/Na2O~4.0–4.5, Al2O3/SiO2 ~0.27–0.33) can be described by one equation using temperature, pressure, and melt H2O content as parameters. An content and of liquidus plagioclase increases with increasing melt H2O and with decreasing pressure, elucidating that nearly H2O-saturated conditions of 2–3 kbar is optimal for the crystallization of the most An-rich plagioclase (>An88). We suggest this pressure condition of 2–3 kbar, corresponding to depth of 7–11 km, plays an important role for the origin of An-rich plagioclase in H2O-rich low-alkali tholeiite. At pressures more than ca. 4 kbar, crystallization of liquidus Ca-rich clinopyroxene decreases the CaO/Na2O ratio of liquid, thus prohibiting the crystallization of high-An plagioclase from hydrous tholeiite.  相似文献   
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