Groundwater,Acid and Carbon Dioxide Dynamics Along a Coastal Wetland,Lake and Estuary Continuum     

Luke C. Jeffrey  Damien T. Maher  Isaac R. Santos  Ashly McMahon  Douglas R. Tait 《Estuaries and Coasts》2016,39(5):1325-1344

Coastal wetlands are hotspots for biodiversity and biological productivity, yet the hydrology and carbon cycling within these systems remains poorly understood due to their complex nature. By using a novel spatiotemporal approach, this study quantified groundwater discharge and the related inputs of acidity and CO₂ along a continuum of a modified coastal acid sulphate soil (CASS) wetland, a coastal lake and an estuary under highly contrasting hydrological conditions. To increase the resolution of spatiotemporal data and advance upon previous methodologies, we relied on automated observations from four simultaneous time-series stations to develop multiple radon mass balance models to estimate groundwater discharge and related groundwater inputs of acidity and dissolved inorganic carbon (DIC), along with surface water to atmosphere CO₂ fluxes. Spatial surveys indicated distinct acid hotspots with minimum surface water pH of 2.91 (dry conditions) and 2.67 (flood conditions) near a non-remediated (drained) CASS area. Under flood conditions, groundwater discharge accounted for ～14.5 % of surface water entering the lake. During the same period, acid discharge from the acid sulphate soil section of the continuum produced ～4.8 kg H₂SO₄?ha^?1 day^?1, a rate much higher than previous studies in similar systems. During baseflow conditions, the low pH water was rapidly buffered within the estuarine lake, with the pH increasing from 4.22 to 6.07 over a distance of ～250 m. The CO₂ evasion rates within the CASS were extremely high, averaging 2163?±?125 mmol m^?2 day^?1 in the dry period and 4061?±?259 mmol m^?2 day^?1 under flood conditions. Groundwater input of DIC could only account for 0.4 % of this evasion in the dry conditions and ～5 % during the flood conditions. We demonstrated that by utilising a spatiotemporal (multiple time-series stations) approach, the study was able to isolate distinct zones of differing hydrology and biogeochemistry, whilst providing more reasonable groundwater acid input estimates and air–water CO₂ flux estimates than some traditional sampling designs. This study highlights the notion that modified CASS wetlands can release large amounts of CO₂ to the atmosphere because of high groundwater acid inputs and extremely low surface water pH.  相似文献   

Sustainable groundwater resources exploration and management in a complex geological setting as part of a humanitarian project (Mahafaly Plateau,Madagascar)     

Simon Damien Carrière  Konstantinos Chalikakis  Chloé Ollivier  Tom Heath  Marie Mangin  Jean Kempf  Jacques Bablon Randriatsitohaina  Marina Gillon  Théodore Razakamanana  Jean Lapègue 《Environmental Earth Sciences》2018,77(21):734

Southwestern Madagascar is a semi-arid region and a hot-spot of global change. On the Mahafaly plateau, people live with quasi-permanent water stress and groundwater, the only available resource, is difficult to exploit due to a complex hydrogeological environment. A methodology (suitable for humanitarian projects; <?40 k€) was developed in four phases to assess the sustainable exploitation of the water resource: (A) regional scale exploration, (B) village scale exploration, (C) drilling campaign, and (D) hydro-climatic monitoring. This integrated hydrogeophysical approach involves geophysical measurements (262 TEM-fast soundings, 2588 Slingram measurements, 35 electrical soundings), hydrochemical analyses (112 samples), and a piezometric survey (127 measurements). Two groundwater resources were identified, one deep (below 150 m) and one shallow (<?20 m). Hydrochemical results highlighted the vulnerability of both resources: anthropic contamination for the shallower and seawater intrusion for the deeper. Therefore, subsequent geophysical surveys supported the siting of six boreholes and three wells in the shallow aquifer. This methodological approach was successful in this complex geological setting and requires testing at other sites in and outside Madagascar. The study demonstrates that geophysical results should be used in addition to drilling campaigns and to help monitor the water resource. In fact, to prevent over-exploitation, piezometric and meteorological sensors were installed to monitor the water resource. This unique hydro-climatic observatory may help (1) non-governmental organization and local institutions prevent future water shortages and (2) scientists to understand better how global change will affect this region of the world.  相似文献   

Dissolution kinetics of diopside as a function of solution saturation state: Macroscopic measurements and implications for modeling of geological storage of CO₂     

Damien Daval  Roland Hellmann  Delphine Tisserand  François Guyot 《Geochimica et cosmochimica acta》2010,74(9):2615-5525

Measurements of the dissolution rate of diopside (r) were carried out as a function of the Gibbs free energy of the dissolution reaction (ΔG_r) in a continuously stirred flow-through reactor at 90 °C and pH_90 °C = 5.05. The overall relation between r and ΔG_r was determined over a free energy range of −130.9 < ΔG_r < −47.0 kJ mo1⁻¹. The data define a highly non-linear, sigmoidal relation between r and ΔG_r. At far-from-equilibrium conditions (ΔG_r ? −76.2 kJ mo1⁻¹), a rate plateau is observed. In this free energy range, the rates of dissolution are constant, independent of [Ca], [Mg] and [Si] concentrations, and independent of ΔG_r. A sharp decrease of the dissolution rate (∼1 order of magnitude) occurs in the transition ΔG_r region defined by −76.2 < ΔG_r ? −61.5 kJ mo1⁻¹. Dissolution closer to equilibrium (ΔG_r > −61.5 kJ mo1⁻¹) is characterised by a much weaker inverse dependence of the rates on ΔG_r. Modeling the experimental r-ΔG_r data with a simple classical transition state theory (TST) law as implemented in most available geochemical codes is found inappropriate. An evaluation of the consequences of the use of geochemical codes where the r-ΔG_r relation is based on basic TST was carried out and applied to carbonation reactions of diopside, which, among other reactions with Ca- and Mg-bearing minerals, are considered as a promising process for the solid state sequestration of CO₂ over long time spans. In order to take into account the actual experimental r-ΔG_r relation in the geochemical code that we used, a new module has been developed. It reveals a dramatic overestimation of the carbonation rate when using a TST-based geochemical code. This points out that simulations of water-rock-CO₂ interactions performed with classical geochemical codes should be evaluated with great caution.  相似文献   

Peak Minerals: Theoretical Foundations and Practical Application     

Daniel May  Timothy Prior  Dana Cordell  Damien Giurco 《Natural Resources Research》2012,21(1):43-60

This article reviews the theoretical foundations for the concept of peak minerals; drawing on similarities and differences with peak oil as modelled using Hubbert style curves. Whilst several studies have applied peak modelling to selected minerals, discussion of the appropriateness of using Hubbert style curves in the minerals context remains largely unexplored. Our discussion focuses on a comparison between oil and minerals, on the key variables: rates of discovery, estimates of ultimately recoverable resources and demand and production trends. With respect to minerals, there are several obstacles which complicate the application of Hubbert style curves to the prediction of future mineral production, including the lack of accurate discovery data, the effect of uncertain reserve estimates, and varying ore quality and quantity. Another notable difference is that while oil is often combusted during use, minerals are used to make metals which are inherently recyclable. Notwithstanding, by using a range of estimates of resources and/or reserves, a period of time can be identified which indicates when a peak in minerals production may occur. This information may then be used to plan for a transition from using a potentially constrained resource, to using substitutes if available, or to reducing demand for that mineral in society.  相似文献   

Textural and fluid inclusion constraints on the origin of the banded-iron-formation-hosted gold deposits at Maevatanana,central Madagascar     

Prosper Andrianjakavah  Stefano Salvi  Didier Béziat  Damien Guillaume  Michel Rakotondrazafy  Bernard Moine 《Mineralium Deposita》2007,42(4):385-398

The Maevatanana deposits consist of gold-bearing quartz–sulphide veins crosscutting banded iron formation (BIF) within a metamorphosed 2.5 Ga greenstone belt. The host rocks are dominated by a sequence of migmatites, gneisses, amphibolites, magnetite-rich quartzites and soapstones, intruded by large granitoid batholiths (e.g. the 0.8 Ga Beanana granodiorite). In the mineralised rocks, pyrite is the dominant sulphide, in addition to accessory chalcopyrite and galena. Outside the immediate ore zone, the BIF is dominated by quartz + magnetite ± hematite, accompanied by cummingtonite, albite and biotite. Gold occurs as globular grains (usually <500 μm) within quartz crystals close to the sulphides and as invisible inclusions within pyrite and chalcopyrite (up to 2,500 ppm Au content). Fluid inclusion textural and microthermometric studies indicate heterogeneous trapping of a low-salinity (∼3.6 wt.% eq. NaCl) aqueous fluid coexisting with a carbonic fluid. Evidence for fluid-phase immiscibility during ore formation includes variable L/V ratios in the inclusions and the fact that inclusions containing different phase proportions occur in the same area, growth zone, or plane. Laser Raman spectroscopy confirms that the vapour phase in these inclusions is dominated by CO₂ but shows that it may contain small amounts of CH₄ (<1 mol%), H₂S (<0.05 mol%) and traces of N₂. Fluid inclusion trapping conditions ranged from 220 to 380°C and averaged 250°C. Pressure was on the order of 1–2 kbar. The abundant CO₂ and low salinity of the inclusions suggest a metamorphic origin for the fluid. Likewise, the presence of H₂S in the fluid and pyritisation of the wall-rock indicate that gold was likely transported by sulphide complexing. Fluid immiscibility was probably triggered by the pressure released by fracturing of the quartzites during fault movements due to competence differences with the softer greenstones. Fracturing greatly enhanced fluid circulation through the BIF, allowing reaction of the sulphide-bearing fluids with the iron oxides. This caused pyrite deposition and concomitant Au precipitation, enhanced by fluid phase separation as H₂S partitioned preferentially into the carbonic phase.  相似文献   

Mineralogical and isotopic properties of inorganic nanocrystalline magnetites     

Damien Faivre  Pierre Agrinier  Pierpaolo Zuddas  Katavut Pachana  Jean-Yves Laval 《Geochimica et cosmochimica acta》2004,68(21):4395-4403

Inorganic magnetite nanocrystals were synthesized in an aqueous medium at 25°C, atmospheric pressure, ionic strength of 0.1 M, oxygen fugacity close to 0, and under controlled chemical affinity, which was maintained constant during an experiment and varied between different experiments. The total concentration of iron in the initial solutions, with Fe(III)/Fe(II) ratios of 2, was varied in order to measure the role of this parameter on the reaction rate, particle morphology, and oxygen isotopic composition. The reaction rates were followed by a pHstat apparatus. The nature and morphology of particles were studied by transmission electron microscopy and electron energy loss spectroscopy. Fractionation factors of oxygen isotopes were determined by mass spectrometry after oxygen extraction from the solid on BrF₅ lines. At low total iron concentrations, goethite and poorly crystalline iron oxides were observed coexisting with magnetite. At higher concentrations, euhedral single crystals of pure magnetite with an average characteristic size of 10 nm were formed, based on a first-order rate law with respect to total iron concentration. These results confirm that, under high supersaturation conditions, low-temperature inorganic processes can lead to the formation of well-crystallized nanometric magnetite crystals with narrow size distribution. The observed oxygen isotope fractionation factor between magnetite crystals and water was of 0-1‰, similar to the fractionation factor associated with bacterially produced magnetite. We suggest that the solution chemistry used in this study for inorganic precipitation is relevant to better understanding of magnetite precipitation in bacterial magnetosomes, which might thus be characterized by high saturation states and pH.  相似文献   

Intercomparison of Boron Isotope and Concentration Measurements. Part II: Evaluation of Results   总被引：3，自引：1，他引：3  

Roberto Gonfiantini  Sonia Tonarini  Manfred Grning  Alessandra Adorni‐Braccesi  Assad S. Al‐Ammar  Marcus Astner  Sebastien Bchler  Ramon M. Barnes  Randy L. Bassett  Alain Cocherie  Annette Deyhle  Andrea Dini  Giorgio Ferrara  Jrme Gaillardet  Judith Grimm  Catherine Guerrot  Urs Krhenbühl  Graham Layne  Damien Lemarchand  Anette Meixner  D. Jack Northington  Maddalena Pennisi  Eva Reitznerov  Ilia Rodushkin  Naoji Sugiura  Regina Surberg  Sabine Tonn  Michael Wiedenbeck  Samuel Wunderli  Yingkai Xiao  Thomas Zack 《Geostandards and Geoanalytical Research》2003,27(1):41-57

The Istituto di Geoscienze e Georisorse (IGG), on behalf and with the support of the International Atomic Energy Agency (IAEA), prepared eight geological materials (three natural waters and five rocks and minerals), intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials were distributed to twenty seven laboratories - virtually all those performing geochemical boron isotope analyses in the world -which agreed to participate in the intercomparison exercise. Only fifteen laboratories, however, ultimately submitted the isotopic and/or concentration results they obtained on the intercomparison materials. The results demonstrate that interlaboratory reproducibility is not well reflected by the precision values reported by the individual laboratories and this observation holds true for both boron concentration and isotopic composition. The reasons for the discrepancies include fractionations due to the chemical matrix of materials, relative shift of the zero position on the δ¹¹B scale and a lack of well characterized materials for calibrating absolute boron content measurements. The intercomparison materials are now available at the IAEA (solid materials) and IGG (waters) for future distribution.  相似文献   

Subpixel fractional cloud cover and inhomogeneity effects on microwave beam-filling error     

Damien Lafont  Bernard Guillemet 《Atmospheric Research》2004,72(1-4):149

Using synthetic geometrical clouds and radiative microwave model, we examine the possibility to correct the estimations of liquid water path (LWP) or rain rate with cloud cover measurement. This information may be gotten by co-localized measurements of microwave and infrared/visible measurements on new satellites (TRMM, ADEOS 2, …). In a first step, the effects of fractional cloud cover on microwave brightness temperatures (TB) are investigated in three typical cases of nonprecipitating and precipitating (stratiform and convective) clouds. The beam-filling error (BFE) on brightness temperatures may be analyzed with the known spatial variability using 1D or 3D radiative transfer model. Relationships between BFE and subpixel cloud fraction (CF) are discussed according to the cloud type. We tested several parameters that characterize the horizontal cloud inhomogeneity within a radiometer field of view. BFE was found very sensitive to cloud type and inhomogeneity and is maximum for raining cloud with open spatial structure. In order to account for the uncertainty introduced by the spatial distribution, dependence of BFE on textural-based parameters is also discussed using homogeneity, entropy and an indicator of CF horizontal gradient.  相似文献   

Mapping the functional dimension of vegetation series in the Mediterranean region using multitemporal MODIS data     

Sébastien Rapinel  Clémence Rozo  Pauline Delbosc  Damien Arvor  Alban Thomas  Jan-Bernard Bouzillé 《地理信息系统科学与遥感》2020,57(1):60-73

ABSTRACT

Monitoring the structural and functional dimensions of natural vegetation is a critical issue to ensure effective management of biodiversity. While coarse-resolution satellite image time-series have been used extensively to monitor vegetation physiognomies, their potential to describe plant species composition remains understudied. The objective of this study is to assess the potential of annual time-series of MODIS images to discriminate combinations of plant communities, called “vegetation series,” and characterize their structural and functional dimensions at the landscape scale. Twelve vegetation series were mapped in a 16 574 ha study area in a Mediterranean context located in Corsica (France). First, the structural dimension of vegetation series was examined using a random forest (RF) model calibrated with a reference field map to (i) measure the importance of each MODIS image in discriminating vegetation series; (ii) quantify the influence of the number of dates on model accuracy; and (iii) map the vegetation series with the optimal subset of MODIS images. Second, the functional dimension of vegetation series was analyzed by ordinating three functional indices through principal component analysis. These indices were the annual sum of normalized difference vegetation index (NDVI), the annual amplitude of NDVI, and the date of maximum NDVI, considered as a proxy for annual primary production, seasonality of carbon fluxes, and vegetation phenology, respectively. Results showed that (i) vegetation series were mapped accurately (median Kappa index 0.70, median overall accuracy 0.76), preferably using images acquired from February to August; (ii) at least 10 MODIS images were required to achieve sufficient accuracy; and (iii) a functional gradient was detected, ranging from high annual net primary production with low seasonality of carbon fluxes and early phenology in Mediterranean vegetation series to low annual net primary production with high seasonality of carbon fluxes and late phenology in alpine vegetation series.  相似文献   

Salt karst and tectonics: sinkholes development along tension cracks between parallel strike‐slip faults,Dead Sea,Jordan     

Damien Closson  Najib Abou Karaki 《地球表面变化过程与地形》2009,34(10):1408-1421

This work deals with the tectonic interpretation of an alignment of more than 300 sinkholes stretching along the Jordanian coast of the Dead Sea, Ghor Al Haditha area. Its dimensions are 6 km long with a width of 600 m. Sinkholes appeared during the last decades as a consequence of the very rapid lowering of the lake level. The linear shape was inferred from ground collapse inventories carried out between 1991 and 2008. The lineament is replaced and analyzed in its structural setting at regional and local scales. Its direction (N 24° E) is sub‐parallel to the ones displayed by many focal mechanisms, especially the one associated with the earthquake of the 23 April, 1979 (mb = 5·1; N 20° E ± 5°), which is representative of all focal mechanisms calculated on a fault plane compatible with the general direction of the Jordan‐Dead Sea Transform fault system for the east coast of the Dead Sea area. The alignment of sinkholes is constituted by 13 minor linear segments separated by as many empty spaces. Four minor linear units present an en‐echelon arrangement from which one can deduce the presence of a local extensional stress field. In this context, the sinkhole locations provide information of subsurface discontinuities interpreted as hidden fractures. In a close future, such results could support the work of decision‐makers and engineers in the projected development of the area. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献