排序方式： 共有80条查询结果，搜索用时 140 毫秒
1.
Farid Juillot Delphine Jouvin Philipe Telouk Philippe Ildefonse Steve Sutton Gordon E. Brown Jr. 《Geochimica et cosmochimica acta》2011,75(9):2295-2308
Zinc isotopes have been studied along two smelter-impacted soil profiles sampled near one of the largest Pb and Zn processing plants in Europe located in northern France, about 50 km south of Lille. Mean δ66Zn values along these two soil profiles range from +0.22 ± 0.17‰ (2σ) to +0.34 ± 0.17‰ (2σ) at the lowest horizons and from +0.38 ± 0.45‰ (2σ) to +0.76 ± 0.14‰ (2σ) near the surface. The δ66Zn values in the lowest horizons of the soils are interpreted as being representative of the local geochemical background (mean value +0.31 ± 0.38‰), whereas heavier δ66Zn values near the surface of the two soils are related to anthropogenic Zn. This anthropogenic Zn occurs in the form of franklinite (ZnFe2O4)-bearing slag grains originating from processing wastes at the smelter site and exhibiting δ66Zn values of +0.81 ± 0.20‰ (2σ). The presence of franklinite is indicated by EXAFS analysis of the topsoil samples from both soil profiles as well as by micro-XANES analysis of the surface horizon of a third smelter-impacted soil from a distant site. These results indicate that naturally occurring Zn and smelter-derived Zn exhibit significantly different δ66Zn values, which suggests that zinc isotopes can be used to distinguish between geogenic and anthropogenic sources of Zn in smelter-impacted soils. In addition to a possible influence of additional past sources of light Zn (likely Zn-sulfides and Zn-sulfates directly emitted by the smelter), the light δ66Zn values in the surface horizons compared to smelter-derived slag materials are interpreted as resulting mainly from fractionation processes associated with biotic and/or abiotic pedological processes (Zn-bearing mineral precipitation, Zn complexation by organic matter, and plant uptake of Zn). This conclusion emphasizes the need for additional Zn isotopic studies before being able to use Zn isotopes to trace sources and pathways of this element in surface environments. 相似文献
2.
Thibault Cavailhes Pierre Labaume Jean‐Pierre Sizun Roger Soliva Claude Gout Jean‐Luc Potdevin Martine Buatier Aurélien Gay Alain Chauvet Delphine Charpentier Anna Travé 《地学学报》2014,26(4):298-306
This study describes normal fault zones formed in foreland arkosic turbidites (the Grès d'Annot Formation, SW French Alps) under deep diagenesis conditions (~200 °C) and highlights the occurrence of two markedly different fault‐rock types: (1) the foliated fault rocks of the Moutière‐Restefond area; and (2) the dilatant fault rocks of the Estrop area. The deformation of (1) is dominated by intra‐ and transgranular fracturing, pressure solution of quartz and feldspar grains and syn‐kinematic phyllosilicate precipitation resulting from feldspar alteration. The combination of these mechanisms results in a strongly anisotropic strain with intense shortening normal to the foliation (pressure solution) and extension parallel to the foliation (quartz‐ and calcite‐sealed extension veins). This deformation implies local mass transfer that may be achieved without (or with limited) volume change. The deformation of (2) is expressed as dilatant quartz‐sealed veins and breccia textures in which the main mechanisms are transgranular fracturing and quartz precipitation. Type (2) implies fault volume increase, isotropy of deformation and mass transfer at distances larger than in type (1). This study discusses the origins of (1) and (2) and shows that the permeability of (1) is anisotropic, with higher values than the host rocks parallel to the Y main deformation axis (i.e. perpendicular to the slip vector), whereas the permeability of (2) is isotropic and equivalent to that of the host rocks. 相似文献
3.
4.
Martine D. Buatier Brice Lacroix Pierre Labaume Virginie Moutarlier Delphine Charpentier Jean Pierre Sizun Anna Travé 《Swiss Journal of Geoscience》2012,105(2):313-324
Thrusting fault zone in foreland basins are characterized by highly foliated zones generally enriched in phyllosilicates which can play a major role on the mechanical behaviour of the fault. In this context, investigations of synkinematic clay minerals permit to determine the origin of the fluid from which they precipitated as well as the mechanisms of deformation. Our study is focused on clay mineral assemblages (illite and chlorite) in a major thrust fault located in the Monte Perdido massif (southern Pyrenees), a shallow thrust that affects upper cretaceous-paleocene platform carbonates and lower Eocene marls and turbidites. It implied 3?km of displacement of the Monte Perdido thrust unit with respect to the underlying Gavarnie unit. In this area the cleavage development by pressure-solution is linked to the Monte Perdido and Gavarnie thrust activity. The core zone of the fault, about 6?m thick, consists of an interval of intensely deformed clay-bearing rocks bounded by major shear surfaces. The deformed sediment is markedly darker than the protolith. Calcite-quartz shear veins along the shear planes are abundant. Detailed SEM and TEM observations of highly deformed fault zone samples indicate that clay mineral enrichment in the core zone of the fault is not only related to passive increase by pressure-solution mechanism but that dissolution?Crecrystallization of phyllosilicates occurs during deformation. A mineral segregation is observed in the highly deformed zone. Newly formed 2M 1 muscovite is present along the cleavage whereas IIb chlorite crystals fill SV2 shear veins suggesting syntectonic growth of phyllosilicates in the presence of fluids in low-grade metamorphic conditions. These mineralogical reactions act as weakening processes and would favour Monte Perdido fault creeping. 相似文献
5.
Komatiites are fascinating volcanic rocks. They are among the most ancient lavas of the Earth following the 3.8 Ga pillow basalts at Isua and they represent some of the oldest ultramafic magmatic rocks preserved in the Earth’s crust at 3.5 Ga. This fact, linked to their particular features (high magnesium content, high melting temperatures, low dynamic viscosities, etc.), has attracted the community of geoscientists since their discovery in the early sixties, who have tried to determine their origin and understand their meaning in the context of terrestrial mantle evolution. In addition, it has been proposed that komatiites are not restricted to our planet, but they could be found in other extraterrestrial settings in our Solar System (particularly on Mars and Io). It is important to note that komatiites may be extremely significant in the study of the origins and evolution of Life on Earth. They not only preserve essential geochemical clues of the interaction between the pristine Earth rocks and atmosphere, but also may have been potential suitable sites for biological processes to develop. Thus, besides reviewing the main geodynamic, petrological and geochemical characteristics of komatiites, this paper also aims to widen their investigation beyond the classical geological prospect, calling attention to them as attractive rocks for research in Planetology and Astrobiology. 相似文献
6.
Nathalie Fagel Sebastien Bertrand Nadine Mattielli Delphine Gilson Luis Chirinos Gilles Lepoint Roberto Urrutia 《第四纪科学杂志》2010,25(7):1100-1112
In this paper, we compare the elemental and isotopic (C, N, Pb) geochemistry of lake sediments from two contrasted environments in south‐central Chile. The first lake, Laguna Chica de San Pedro (LCSP), is situated in the urbanised area of the Biobio Region (36°S). The second lake, Lago Puyehue (40° S), is located 400 km to the southeast of LCSP and within an Andean national park. Our aim is to identify environmental impacts associated with increasing industrial activities and land degradation during the last 150 a. In LCSP, shifts in C/N atomic ratios, δ13C and δ15N from 1915–1937 to the late 1980s are attributed to successive land degradation episodes in the lake watershed. Based on a Pb isotopic mixing model, we estimate that up to 20% of lead in LCSP sediments is supplied from urban atmospheric pollution. By contrast, human impact in the watershed of Lago Puyehue is very limited. We observe no change in organic geochemistry during the last 150 a and lead contamination remains lower than 5%, even during the last decades. Although contamination levels are much higher in LCSP than in Lago Puyehue, a peak in anthropogenic Pb is recorded during the same period (1974–1976) at both sites. This maximum contamination level is consistent with increased industrial activity in the vicinity of Concepción. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
7.
Antal?Embey-IsztinEmail author Gábor?Dobosi Jean-Louis?Bodinier Delphine?Bosch G.?A.?Jenner Simone?Pourtales Olivier?Bruguier 《Contributions to Mineralogy and Petrology》2014,168(3):1054
Peridotite xenoliths erupted by alkali basaltic volcanoes in the western Pannonian Basin can be divided into two fundamentally contrasting groups. Geochemical characteristics of the abundant protogranular, porphyroclastic and equigranular nodules suggest that these samples originate from an old consolidated and moderately depleted lithospheric mantle domain. In contrast, the geochemical features of the worldwide rare, but in the Pannonian Basin relatively abundant, poikilitic xenoliths attest to a more complex evolution. It has been argued that the origin of the peculiar texture and chemistry may be intimately linked to melt/rock reactions at successively decreasing liquid volumes in a porous melt flow system. The most likely site where such reactions can take place is the asthenosphere–lithosphere boundary. In this context, poikilitic xenoliths may provide petrological and geochemical evidence for reactions between magmatic liquids issued from the uprising asthenosphere and the solid mantle rocks of the lithosphere. These reactions are important agents of the thermal erosion of the lithosphere; thus, they could have considerably contributed to the thinning of the lithosphere in the Pannonian region. We suggest that in the Pannonian Basin, there could be a strong relation between the unusual abundance of poikilitic mantle xenoliths and the strongly eroded lithosphere. 相似文献
8.
Nicolas Hawie Remy Deschamps Fadi H. Nader Christian Gorini Carla Müller Delphine Desmares Ahmed Hoteit Didier Granjeon Lucien Montadert François Baudin 《Arabian Journal of Geosciences》2014,7(4):1323-1349
This paper presents an updated review of the Upper Mesozoic and Cenozoic sedimentological and stratigraphic evolution of the Levant margin with a focus on the northern Lebanon. Facies and microfacies analysis of outcrop sections and onshore well cores (i.e., Kousba and Chekka) supported by nannofossil and planktonic foraminifers biostratigraphy, allowed to constrain the depositional environments prevailing in the Turonian to Late Miocene. The “Senonian” (a historical term used to define the Coniacian to Maastrichtian) source rock interval was subdivided into four sub-units with related outer-shelfal facies: (1) Upper Santonian, (2) Lower, (3) Upper Campanian, and (4) Lower Maastrichtian. This Upper Cretaceous rock unit marks the major drowning of the former Turonian rudist platform. This paper confirms the Late Lutetian to Late Burdigalian hiatus, which appears to be a direct consequence of major geodynamic events affecting the Levant region (i.e., the continued collision of Afro-Arabia with Eurasia), potentially enhanced by regressional cycles (e.g., Rupelian lowstand). The distribution of Late Burdigalian–Serravallian rhodalgal banks identified in northern Lebanon was controlled by pre-existing structures inherited from the pulsating onshore deformation. Reef barriers facies occur around the Qalhat anticline, separating an eastern, restricted back-reef setting from a western, coastal to open marine one. The acme of Mount Lebanon’s uplift and exposure is dated back to the Middle–Late Miocene; it led to important erosion of carbonates that were subsequently deposited in paleo-topographic lows. The Late Cretaceous to Cenozoic facies variations and hiatuses show that the northern Lebanon was in a higher structural position compared to the south since at least the Late Cretaceous. 相似文献
9.
J. Pritchard J. B. Marquette Patrick Tisserand J. P. Beaulieu E. Lesquoy A. Milsztajn 《Astrophysics and Space Science》2006,304(1-4):227-229
More than 10 years of microlensing survey observations by the EROS Collaboration have monitored several million stars, amongst them several thousand eclipsing binary stars. In this poster we present some of the difficulties and rewards of the study of this immense database.Based on observations made at ESO by the EROS collaboration 相似文献
10.
A. van Geen K. Radloff Z. Aziz Z. Cheng M.R. Huq K.M. Ahmed B. Weinman S. Goodbred H.B. Jung Y. Zheng M. Berg P.T.K. Trang L. Charlet J. Metral D. Tisserand S. Guillot S. Chakraborty A.P. Gajurel B.N. Upreti 《Applied Geochemistry》2008
One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored. 相似文献