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161.
162.
Phase analysis of incrustations retrieved from chimney deposits of a combined heat and power plant in Malchow/Germany by X-ray powder diffraction gave evidence for the existence of a previously unknown hydrous calcium magnesium nitrate. Optical investigations of the sample showed the presence of colorless platy crystals with a maximum diameter of about 250 μm embedded in a partly polycrystalline and partly glassy matrix. Aided by EDX-analysis and Raman spectroscopy, a single-crystal diffraction study performed at ambient conditions demonstrated that the material represents a phase with composition Ca2Mg(NO3)6×12H2O. Basic crystallographic data are as follows: trigonal symmetry, space group type R \( \overline{3} \) , a?=?10.5583(5) Å, c?=?19.5351(10) Å, V?=?1885.97(16) Å3, Z?=?3, (R(|F|) = 0.0248). The magnesium ions are coordinated by water molecules to form distorted Mg(H2O)6-octahedra. The calcium atoms are surrounded by nine ligands. The resulting CaO9 tricapped trigonal prisms involve oxygen atoms from additional water moieties as well as from three different bidentate nitrate groups, respectively. Hydrogen bonds link one octahedron with two adjacent prisms into trimers. The trimers in turn are stacked in columns running parallel to [001]. Further hydrogen bonding between neighboring columns results in the formation of a three-dimensional network. To our best knowledge, Ca2Mg(NO3)6×12H2O represents a new structure type. However, column-like topologies with rods consisting of different types of polyhedra have been also observed in other trigonal hydrous nitrates. The structural relationships between these compounds are discussed. It is interesting to note that in previous phase equilibrium studies on the ternary system Ca(NO3)2-Mg(NO3)2-H2O no other hydrous double salt has been described. Finally, the results of the structure analysis allowed a qualitative and quantitative phase analysis of the crystalline part of the chimney deposit by the Rietveld method.  相似文献   
163.
The present study identified and quantified dinoflagellate cysts in surface sediments from three Mediterranean lagoons. Sediment samples were recovered from 11 stations in May 2009 at Cabras Lagoon, eight stations in May 2010 at Corru S'Ittiri Lagoon, and five stations in May 2011 at Santa Giusta Lagoon. Fifty-three dinoflagellate cyst morphotypes were identified. Sixteen species are first reports for the lagoons, and two for the Mediterranean Sea. Moreover, a new Scrippsiella species was discovered in Cabras. Seven harmful algal species were identified, primarily belonging to the potentially toxic genus Alexandrium. Total cyst abundance, number of morphotypes, and assemblages varied among lagoons, and each lagoon showed a distinct morphotype composition. A degree of heterogeneity was also detected within lagoon. Cabras and Santa Giusta cyst assemblages were characterised by morphotypes belonging to the autotrophic genus Scrippsiella, whereas Corru S'Ittiri assemblages showed dominance of heterotrophic morphotypes, including Protoperidinium cf tricingulatum. Differentiation among lagoons was also evident according to environmental conditions. Salinity proved to be a fundamental variable in determining total cyst abundance, morphotype number, and composition. This study was among the first to examine dinoflagellate cyst composition in coastal lagoons, especially from the Mediterranean region, and contributed data that increased our knowledge of cyst-producing dinoflagellates in these environments.  相似文献   
164.
165.
The reconstruction of the main structural features of the Southern Apennines (Italy), in correspondence with the focal volume of some strong earthquakes that have affected this chain, can be attempted by analysing reflection seismic lines and deep well logs in comparison with surface geology.For instance, the Calore Valley and its surroundings have been the object of intense hydrocarbon exploration, and a wealth of subsurface data is available. Moreover, this area was affected by the 1688 Sannio earthquake (macroseismic magnitude 7.1), and a new location has recently been proposed for the related causative fault system. The present work defines the structural setting of the Southern Apennine chain in correspondence with this new location, and compares it with similar cases along the Italian peninsula.The analysis was focussed on the reconstruction of deep tectonic units (formed by the buried Apulia carbonate platform succession), which generally correspond to the hypocentral depths of strong earthquakes along the axis of the Southern Apennines. The results show that the Apulia platform succession is affected by three main thrusts, locally accompanied by backthrusts. The top of this succession is relatively shallow: the maximum depth does not exceed 1.8 s TWT (i.e. about 3500 m b.s.l.), while minimum depths occur in correspondence with the ramp anticlines culminations, at 0.5 s TWT (i.e. at about 500 m b.s.l.). Moreover, data suggest that the underlying Paleozoic basement is possibly involved in thrusting.In a regional perspective, extensional seismogenic structures along the axis of the Southern Apennines seem to share some common characteristics. Indeed, they develop (i) in correspondence with an uplifted Paleozoic basement; (ii) at the rear of a set of thrusts that account for the shallow Apulia units; (iii) at the surface, in proximity to the leading edge of a surficial tectonic unit formed by the Apennine carbonate platform succession. The 1688 seismogenic fault system fits in with these common traits. In the light of this, we finally speculate that these common characteristics in the architecture of the chain could provide a key to the location of the major seismicity along the axis of the Southern Apennines and an interpretative model for the identification of possible areas of seismic gap in this part of the Italian peninsula.  相似文献   
166.
A timewise kinematic method for satellite gradiometry: GOCE simulations   总被引:2,自引:0,他引:2  
We have defined new algorithms for the data processing of a satellite geodesy mission with gradiometer (such as the next European mission GOCE) to extract the information on the gravity field coefficients with a realistic estimate of their accuracy. The large scale data processing can be managed by a multistage decomposition. First the spacecraft position is determined, i.e., a kinematic method is normally used. Second we use a new method to perform the necessary digital calibration of the gradiometer. Third we use a multiarc approach to separately solve for the global gravity field parameters. Fourth we use an approximate resonant decomposition, that is we partition in a new way the harmonic coefficients of the gravity field. Thus the normal system is reduced to blocks of manageable size without neglecting significant correlations. Still the normal system is badly conditioned because of the polar gaps in the spatial distribution of the data. We have shown that the principal components of the uncertainty correspond to harmonic anomalies with very small signal in the region where GOCE is flying; these uncertainties cannot be removed by any data processing method. This allows a complete simulation of the GOCE mission with affordable computer resources. We show that it is possible to solve for the harmonic coefficients up to degree 200–220 with signal to error ratio ≥1, taking into account systematic measurement errors. Errors in the spacecraft orbit, as expected from state of the art satellite navigation, do not degrade the solution. Gradiometer calibration is the main problem. By including a systematic error model, we have shown that the results are sensitive to spurious gradiometer signals at frequencies close to the lower limit of the measurement band. If these spurious effects grow as the inverse of the frequency, then the actual error is larger than the formal error only by a factor ≃2, that is the results are not compromised.  相似文献   
167.
This paper analyses the behavior of extreme events of surface precipitation and temperature inside the Pacific and Caribbean Catchment Basins in Colombia using several datasets such as observations, reconstructed data, NCEP-NCAR and ERA-40 reanalyses and data from the regional model REMO. We use an extreme value method that selects the time series excesses over a nonstationary threshold and adjusts them to a generalized Pareto distribution. The goodness of fit is evaluated through a test that includes the Cramer–von Mises, Kolmogorov–Smirnov and Anderson–Darling statistics and the p values generated by parametric bootstrap resampling. The test not only evaluates the goodness of fit but also the threshold choice. The parameters are presented in maps that allow recognition of the features of the extreme behaviour inside the catchment basins, and differences and similarities between them. Maps of return periods for the maximum extreme events are also presented. A strong influence of the El Niño–Southern oscillation on the extreme events of both temperature and precipitation is found in the two catchment basins.  相似文献   
168.
It is well accepted within the scientific community that a large ensemble of different projections is required to achieve robust climate change information for a specific region. For this purpose we have compiled a state-of-the-art multi-model multi-scenario ensemble of global and regional precipitation projections. This ensemble combines several global projections from the CMIP3 and CMIP5 databases, along with some recently downscaled regional CORDEX-Africa projections. Altogether daily precipitation data from 77 different climate change projections is analysed; separated into 31 projections for a high and 46 for a low emission scenario. We find a robust indication that, independent of the underlying emission scenario, annual total precipitation amounts over the central African region are not likely to change severely in the future. However some robust changes in precipitation characteristics, like the intensification of heavy rainfall events as well as an increase in the number of dry spells during the rainy season are projected for the future. Further analysis shows that over some regions the results of the climate change assessment clearly depend on the size of the analyzed ensemble. This indicates the need of a “large-enough” ensemble of independent climate projections to allow for a reliable climate change assessment.  相似文献   
169.
Abstract

Strategies to mitigate anthropogenic climate change recognize that carbon sequestration in the terrestrial biosphere can reduce the build-up of carbon dioxide in the Earth's atmosphere. However, climate mitigation policies do not generally incorporate the effects of these changes in the land surface on the surface albedo, the fluxes of sensible and latent heat to the atmosphere, and the distribution of energy within the climate system. Changes in these components of the surface energy budget can affect the local, regional, and global climate. Given the goal of mitigating climate change, it is important to consider all of the effects of changes in terrestrial vegetation and to work toward a better understanding of the full climate system. Acknowledging the importance of land surface change as a component of climate change makes it more challenging to create a system of credits and debits wherein emission or sequestration of carbon in the biosphere is equated with emission of carbon from fossil fuels. Recognition of the complexity of human-caused changes in climate does not, however, weaken the importance of actions that would seek to minimize our disturbance of the Earth's environmental system and that would reduce societal and ecological vulnerability to environmental change and variability.

© 2003 Elsevier Science Ltd. All rights reserved.  相似文献   
170.
This study aims to evaluate soil climate quantitatively under present and projected climatic conditions across Central Europe (12.1°–18.9° E and 46.8°–51.1° N) and the U.S. Central Plains (90°–104° W and 37°–49° N), with a special focus on soil temperature, hydric regime, drought risk and potential productivity (assessed as a period suitable for crop growth). The analysis was completed for the baselines (1961–1990 for Europe and 1985–2005 for the U.S.) and time horizons of 2025, 2050 and 2100 based on the outputs of three global circulation models using two levels of climate sensitivity. The results indicate that the soil climate (soil temperature and hydric soil regimes) will change dramatically in both regions, with significant consequences for soil genesis. However, the predicted changes of the pathways are very uncertain because of the range of future climate systems predicted by climate models. Nevertheless, our findings suggest that the risk of unfavourable dry years will increase, resulting in greater risk of soil erosion and lower productivity. The projected increase in the variability of dry and wet events combined with the uncertainty (particularly in the U.S.) poses a challenge for selecting the most appropriate adaptation strategies and for setting adequate policies. The results also suggest that the soil resources are likely be under increased pressure from changes in climate.  相似文献   
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