Mesoarchean island-arc association in the Central Karelian terrane, Fennoscandian shield: New Geochronological data     

S. A. Svetov  N. M. Kudryashov  Yu. L. Ronkin  H. Huhma  A. I. Svetova  T. N. Nazarova 《Doklady Earth Sciences》2006,406(1):103-106

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Formation of iron-containing colloids by the weathering of phyllite     

Harald Zänker  Gudrun Hüttig  Thuro Arnold  Heino Nitsche 《Aquatic Geochemistry》2006,12(4):299-325

The formation of colloids during the weathering of phyllite was investigated by exposing ground phyllite to Milli-Q water. Secondary mineral colloids of 10¹–10² nm were detected in significant concentrations. At pH of about 8.5, the solution concentration of these colloids reached up to 10 mg/L (however, acidification to pH 4.0 prevented the formation of the colloids). The mineralogical composition of the secondary mineral colloids is assumed to be a mixture of ferrihydrite, manganese oxyhydroxides, aluminosilicates, amorphous Al(OH)₃ and gibbsite with possible additions of iron silicates and␣iron-alumino silicates. The colloids were stable over longer periods of time (at least several weeks), even in the presence of suspended ground rock. Direct formation of iron-containing secondary mineral colloids at the rock–water interface by the weathering of rock material is an alternative to the well-known mechanism of iron colloid formation in the bulk of water bodies by mixing of different waters or by aeration of anoxic waters. This direct mechanism is of relevance for colloid production during the weathering of freshly crushed rock in the unsaturated zone as for instance crushed rock in mine waste rock piles. Colloids produced by this mechanism, too, can influence the transport of contaminants such as actinides because these colloids have a large specific surface area and a high sorption affinity.  相似文献   

The Earthquake Readiness Scale: The Development of a Valid and Reliable Unifactorial Measure     

Matthew J. Spittal  Frank H. Walkey  John McClure  Richard J. Siegert  Kimberley E. Ballantyne 《Natural Hazards》2006,39(1):15-29

Preparedness is a key dependent variable in many studies examining people’s response to disasters such as earthquakes. A feature of many studies on this issue, however, is the lack of attention given to psychometric issues when constructing measures of preparedness. With regard to earthquake preparation, for example, many studies could be greatly improved by the use of a valid and reliable measure of preparedness. This research developed such a measure that assessed both low-level preparedness, such as having an emergency kit, and high-level preparedness, such as altering home structures to mitigate damage. Studies of Wellington (New Zealand) residents using two samples totalling n=652 showed that 23 items measuring these different aspects of earthquake preparation could be combined into a reliable, valid, unifactorial scale. This brief scale should have utility in multivariate studies of earthquake preparation, either as a dependent variable, where preparation is the outcome variable of primary interest, or as one of several independent variables, where preparation and other measures predict another outcome variable.  相似文献   

Compressibility and shear strength of a residual soil     

Yahia E.-A. Mohamedzein  Mohammed H. Aboud 《Geotechnical and Geological Engineering》2006,24(5):1385-1401

A detailed study was performed to investigate the compressibility and the shear strength of a residual soil in Omdurman, Sudan. The soil resulted from weathering of sandstone and mudstone. The soil is classified as sandy clayey silt (MH-CH) and is generally partially saturated. Consolidation tests were performed to study the compressibility of the soil and UU, CIU and insitu tests (CPT and SPT) were performed to study the shear strength characteristics of the soil. The characteristics of this residual soil can generally be predicted using correlations proposed in the literature for transported soils. The soil is of low to medium compressibility and exhibits slight apparent overconsolidation behavior. The soil dilates during shear and shows no long term effective cohesion. Problems associated with open cuts in this soil are attributed to loss of strength upon saturation.  相似文献   

Mineralogical and chemical evolution of the Ernest Henry Fe oxide–Cu–Au ore system, Cloncurry district, northwest Queensland, Australia     

Geordie Mark  Nicholas H. S. Oliver  Patrick J. Williams 《Mineralium Deposita》2006,40(8):769-801

The Ernest Henry Cu–Au deposit was formed within a zoned, post-peak metamorphic hydrothermal system that overprinted metamorphosed dacite, andesite and diorite (ca 1740–1660 Ma). The Ernest Henry hydrothermal system was formed by two cycles of sodic and potassic alteration where biotite–magnetite alteration produced in the first cycle formed ca 1514±24 Ma, whereas paragenetically later Na–Ca veining formed ca 1529 +11/−8 Ma. These new U–Pb_titanite age dates support textural evidence for incursion of hydrothermal fluids after the metamorphic peak, and overlap with earlier estimates for the timing of Cu–Au mineralization (ca 1540–1500 Ma). A distal to proximal potassic alteration zone correlates with a large (up to 1.5 km) K–Fe–Mn–Ba enriched alteration zone that overprints earlier sodic alteration. Mass balance analysis indicates that K–Fe–Mn–Ba alteration—largely produced during pre-ore biotite- and magnetite-rich alteration—is associated with K–Rb–Cl–Ba–Fe–Mn and As enrichment and Na, Ca and Sr depletion. The aforementioned chemical exchange almost precisely counterbalances the mass changes associated with regional Na–Ca alteration. This initial transition from sodic to potassic alteration may have been formed during the evolution of a single fluid that evolved via alkali exchange during progressive fluid-rock interaction. Cu–Au ore, dominated by co-precipitated magnetite, minor specular hematite, and chalcopyrite as breccia matrix, forms a pipe-like body at the core of a proximal alteration zone dominated by K-feldspar alteration. Both the core and K-feldspar alteration overprint Na–Ca alteration and biotite–magnetite (K–Fe) alteration. Ore was associated with the concentration of a diverse range of elements (e.g. Cu, Au, Fe, Mo, U, Sb, W, Sn, Bi, Ag, F, REE, K, S, As, Co, Ba and Ca). Mineralization also involved the deposition of significant barite, K(–Ba)–feldspar, calcite, fluorite and complexly zoned pyrite. The complexly zoned pyrite and variable K–(Ba)–feldspar versus barite associations are interpreted to indicate fluctuating sulphur and/or barium supply. Together with the alteration zonation geochemistry and overprinting criteria, these data are interpreted to indicate that Cu–Au mineralization occurred as a result of fluid mixing during dilation and brecciation, in the location of the most intense initial potassic alteration. A link between early alteration (Na–Ca and K–Fe) and the later K-feldspathization and the Cu–Au ore is possible. However, the ore-related enrichments in particular elements (especially Ba, Mn, As, Mo, Ag, U, Sb and Bi) are so extreme compared with earlier alteration that another fluid, possibly magmatic in origin, contributed the diverse element suite geochemically independently of the earlier stages. Structural focussing of successive stages produced the distinctive alteration zoning, providing a basis both for exploration for similar deposits, and for an understanding of ore genesis.  相似文献   

Quantification of karst aquifer discharge components during storm events through end-member mixing analysis using natural chemistry and stable isotopes as tracers   总被引：1，自引：1，他引：1  

Daniel H. Doctor  E. Calvin Alexander Jr  Metka Petrič  Janja Kogovšek  Janko Urbanc  Sonja Lojen  Willibald Stichler 《Hydrogeology Journal》2006,14(7):1171-1191

Karst aquifer components that contribute to the discharge of a water supply well in the Classical Karst (Kras) region (Italy/Slovenia) were quantitatively estimated during storm events. Results show that water released from storage within the epikarst may comprise as much as two-thirds of conduit flow in a karst aquifer following rainfall. Principal components analysis (PCA) and end-member mixing analysis (EMMA) were performed using major ion chemistry and the stable isotopes of water (δ¹⁸O, δ²H) and of dissolved inorganic carbon (δ¹³C_DIC) to estimate mixing proportions among three sources: (1) allogenic river recharge, (2) autogenic recharge, and (3) an anthropogenic component stored within the epikarst. The sinking river most influences the chemical composition of the water-supply well under low-flow conditions; however, this proportion changes rapidly during recharge events. Autogenic recharge water, released from shallow storage in the epikarst, displaces the river water and is observed at the well within hours after the onset of precipitation. The autogenic recharge end member is the second largest component of the well chemistry, and its contribution increases with higher flow. An anthropogenic component derived from epikarstic storage also impacts the well under conditions of elevated hydraulic head, accounting for the majority of the chemical response at the well during the wettest conditions.  相似文献   

Geochronological constraints on the Legs Lake shear zone with implications for regional exhumation of lower continental crust, western Churchill Province, Canadian Shield     

K. H. Mahan  M. L. Williams  R. M. Flowers  M. J. Jercinovic  J. A. Baldwin  S. A. Bowring 《Contributions to Mineralogy and Petrology》2006,152(2):223-242

The Legs Lake shear zone marks the southeastern boundary of an extensive region (>20,000 km²) of high-pressure (0.8–1.5+ GPa) granulite-facies rocks in the western Churchill Province, Canada. The shear zone is one of the largest exhumation-related structures in the Canadian Shield and coincides with the central segment of the ∼2,800 km long Snowbird tectonic zone. The movement history of this shear zone is critical for the development of models for the exhumation history of the high-pressure region. We used electron microprobe U–Th–Pb dating of monazite with supplemental ID-TIMS U–Pb geochronology to place constraints on the timing of shear zone activity. Combining these and other data, we suggest that regional exhumation occurred during at least three distinct phases over an ∼150 million year period. The first phase involved high temperature decompression from ∼1.0 to 0.8–0.7 GPa shortly following 1.9 Ga peak metamorphism, possibly under an extensional regime. The second phase involved rock uplift and decompression of the hanging wall to 0.5–0.4 GPa during east-vergent thrusting across the Legs Lake shear zone at ca. 1.85 Ga. This phase was likely driven by early collision-related convergence in the Trans-Hudson orogen. The final phase of regional exhumation, involving the removal of 15–20 km of overburden from both footwall and hanging wall, likely occurred after ∼1.78 Ga and may have been related to regional extensional faulting.Electronic Supplementary Material Supplementary material is available to authorised users in the online version of this article at .  相似文献   

Petrology, geochemistry and the mechanisms determining the distribution of platinum-group element and base metal sulphide mineralisation in the Platreef at Overysel, northern Bushveld Complex, South Africa     

David A. Holwell  Iain McDonald 《Mineralium Deposita》2006,41(6):575-598

Platinum-group element (PGE) mineralisation within the Platreef at Overysel is controlled by the presence of base metal sulphides (BMS). The floor rocks at Overysel are Archean basement gneisses, and unlike other localities along the strike of the Platreef where the floor is comprised of Transvaal Supergroup sediments, the intimate PGE–BMS relationship holds strong into the footwall rocks. Decoupling of PGE from BMS is rare and the BMS and platinum-group mineral assemblages in the Platreef and the footwall are almost identical. There is minimal overprinting by hydrothermal fluids; therefore, the mineralisation style present at Overysel may represent the most ‘primary’ style of Platreef mineralisation preserved anywhere along the strike. Chondrite-normalised PGE profiles reveal a progressive fractionation of the PGE with depth into the footwall, with Ir, Ru and Rh dramatically depleted with depth compared to Pt, Pd and Au. This feature is not observed at Sandsloot and Zwartfontein, to the south of Overysel, where the footwall rocks are carbonates. There is evidence from rare earth element abundances and the amount of interstitial quartz towards the base of the Platreef pyroxenites that contamination by a felsic melt derived from partial melting of the gneissic footwall has taken place. Textural evidence in the gneisses suggests that a sulphide liquid percolated down into the footwall through a permeable, inter-granular network that was produced by partial melting around grain boundaries in the gneisses that was induced by the intrusion of the Platreef magma. PGE were originally concentrated within a sulphide liquid in the Platreef magma, and the crystallisation of monosulphide solid solution from the sulphide liquid removed the majority of the IPGE and Rh from it whilst still within the mafic Platreef. Transport of PGE into the gneisses, via downward migration of the residual sulphide liquid, fractionated out the remaining IPGE and Rh in the upper parts of the gneisses leaving a ‘slick’ of disseminated sulphides in the gneiss, with the residual liquid becoming progressively more depleted in these elements relative to Pt, Pd and Au. Highly sulphide-rich zones with massive sulphides formed where ponding of the sulphide liquid occurred due to permeability contrasts in the footwall. This study highlights the fact that there is a fundamental floor rock control on the mechanism of distribution of PGE from the Platreef into the footwall rocks. Where the floor rocks are sediments, fluid activity related to metamorphism, assimilation and later serpentinisation has decoupled PGE from BMS in places, and transport of PGE into the footwall is via hydrothermal fluids. In contrast, where the floor is comprised of anhydrous gneiss, such as at Overysel, there is limited fluid activity and PGE behaviour is controlled by the behaviour of sulphide liquids, producing an intimate PGE–BMS association. Xenoliths and irregular bands of chromitite within the Platreef are described in detail for the first time. These are rich in the IPGE and Rh, and evidence from laurite inclusions indicates they must have crystallised from a PGE-saturated magma. The disturbed and xenolithic nature of the chromitites would suggest they are rip-up clasts, either disturbed by later pulses of Platreef magma in a multi-phase emplacement or transported into the Platreef from a pre-existing source in a deeper staging chamber or conduit.  相似文献   

Energy transfer among Pb, Ce and Mn in fluorescent calcite from Kuerle, Xinjiang, China     

Aierken Sidike  X.-M. Wang  Alifu Sawuti  H.-J. Zhu  I. Kusachi  N. Yamashita 《Physics and Chemistry of Minerals》2006,33(8-9):559-566

Natural calcite from Kuerle, Xinjiang, China, shows orange-red fluorescence when exposed to short-wave ultraviolet (UV) light (Hg 253.7 nm). Photoluminescence (PL) emission and excitation spectra of the calcite are observed at room temperature in detail. The PL emission spectrum under 208 nm excitation consists of three bands: two UV bands at 325 and 355 nm and an orange-red band at 620 nm. The three bands are ascribed to Pb²⁺, Ce³⁺ and Mn²⁺, respectively, as activators. The Pb²⁺ excitation band is observed at 243 nm, and the Ce³⁺ excitation band at 295 nm. The Pb²⁺ excitation band is also observed by monitoring the Ce³⁺ fluorescence, and the Pb²⁺ and Ce³⁺ excitation bands, in addition to six Mn²⁺ excitation bands, are also observed by monitoring the Mn²⁺ fluorescence. These indicate that four types of the energy transfer can occur in calcite through the following processes: (1) Pb²⁺ → Ce³⁺, (2) Pb²⁺ → Mn²⁺, (3) Ce³⁺ → Mn²⁺ and (4) Pb²⁺ → Ce³⁺ → Mn²⁺.  相似文献   

Zr-in-rutile thermometry in blueschists from Sifnos, Greece   总被引：1，自引：0，他引：1  

Frank S. Spear  David A. Wark  John T. Cheney  John C. Schumacher  E. Bruce Watson 《Contributions to Mineralogy and Petrology》2006,152(3):375-385

Zr-in-rutile thermometry on samples of blueschist from Sifnos, Greece, yields temperatures that reflect progressive crystallization of rutile from ca. 445 to 505°C with an analytical precision of + 18/−27 and ± 10°C using the electron microprobe and ± 1.5–3.5°C using the ion microprobe. Individual grains are generally homogeneous within analytical uncertainty. Different grains within a single sample record temperature differences as large 55°, although in most samples the range of temperatures is on the order of 25°. In several samples, Zr-in-rutile temperatures from grains within garnet are lower than temperatures from matrix grains, reflecting growth of rutile with increasing temperature of metamorphism. Although the specific rutile-producing reactions have not been identified, it is inferred that rutile grows from either continuous reaction involving the breakdown of lower grade phases (possibly ilmenite), or from pseudomorph reactions involving the breakdown of relic igneous precursors at blueschist-facies conditions. No systematic variation in rutile temperatures was observed across the blueschist belt of northern Sifnos, consistent with the belt having behaved as a coherent block during subduction.  相似文献