A GLUE‐based uncertainty assessment framework for tritium‐inferred transit time estimations under baseflow conditions          下载免费PDF全文

Francesc Gallart  Maria Roig‐Planasdemunt  Michael K. Stewart  Pilar Llorens  Uwe Morgenstern  Willibald Stichler  Laurent Pfister  Jérôme Latron 《水文研究》2016,30(25):4741-4760

The last decade has seen major technical and scientific improvements in the study of water transfer time through catchments. Nevertheless, it has been argued that most of these developments used conservative tracers that may disregard the oldest component of water transfer, which often has transit times greater than 5 years. Indeed, although the analytical reproducibility of tracers limits the detection of the older flow components associated with the most dampened seasonal fluctuations, this is very rarely taken into account in modelling applications. Tritium is the only environmental tracer at hand to investigate transfer times in the 5‐ to 50‐year range in surface waters, as dissolved gases are not suitable due to the degassing process. Water dating with tritium has often been difficult because of the complex history of its atmospheric concentration, but its current stabilization together with recent analytical improvements open promising perspectives. In this context, the innovative contribution of this study lies in the development of a generalized likelihood uncertainty estimation‐based approach for analysing the uncertainties associated with the modelling of transit time due to both parameter identification and tracer analytical precision issues. A coupled resampling procedure allows assessment of the statistical significance of the transfer time differences found in diverse waters. This approach was developed for tritium and the exponential‐piston model but can be implemented for virtually any tracer and model. Stream baseflow, spring and shallow aquifer waters from the Vallcebre research catchments, analysed for tritium in different years with different analytical precisions, were investigated by using this approach and taking into account other sources of uncertainty. The results showed three groups of waters of different mean transit times, with all the stream baseflow and spring waters older than the 5‐year threshold needing tritium. Low sensitivity of the results to the model structure was also demonstrated. Dual solutions were found for the waters sampled in 2013, but these results may be disambiguated when additional analyses will be made in a few years. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Quantification of karst aquifer discharge components during storm events through end-member mixing analysis using natural chemistry and stable isotopes as tracers   总被引：1，自引：1，他引：1  

Daniel H. Doctor  E. Calvin Alexander Jr  Metka Petrič  Janja Kogovšek  Janko Urbanc  Sonja Lojen  Willibald Stichler 《Hydrogeology Journal》2006,14(7):1171-1191

Karst aquifer components that contribute to the discharge of a water supply well in the Classical Karst (Kras) region (Italy/Slovenia) were quantitatively estimated during storm events. Results show that water released from storage within the epikarst may comprise as much as two-thirds of conduit flow in a karst aquifer following rainfall. Principal components analysis (PCA) and end-member mixing analysis (EMMA) were performed using major ion chemistry and the stable isotopes of water (δ¹⁸O, δ²H) and of dissolved inorganic carbon (δ¹³C_DIC) to estimate mixing proportions among three sources: (1) allogenic river recharge, (2) autogenic recharge, and (3) an anthropogenic component stored within the epikarst. The sinking river most influences the chemical composition of the water-supply well under low-flow conditions; however, this proportion changes rapidly during recharge events. Autogenic recharge water, released from shallow storage in the epikarst, displaces the river water and is observed at the well within hours after the onset of precipitation. The autogenic recharge end member is the second largest component of the well chemistry, and its contribution increases with higher flow. An anthropogenic component derived from epikarstic storage also impacts the well under conditions of elevated hydraulic head, accounting for the majority of the chemical response at the well during the wettest conditions.  相似文献   

Groundwater recharge in the Akaki catchment,central Ethiopia: evidence from environmental isotopes (δ18O, δ2H and 3H) and chloride mass balance     

Molla Demlie  Stefan Wohnlich  Birhanu Gizaw  Willibald Stichler 《水文研究》2007,21(6):807-818

Recharge patterns, possible flow paths and the relative age of groundwater in the Akaki catchment in central Ethiopia have been investigated using stable environmental isotopes δ¹⁸O and δ²H and radioactive tritium (³H) coupled with conservative chloride measurements. Stable isotopic signatures are encoded in the groundwater solely from summer rainfall. Thus, groundwater recharge occurs predominantly in the summer months from late June to early September during the major Ethiopian rainy season. Winter recharge is lost through high evaporation–evapotranspiration within the unsaturated zone after relatively long dry periods of high accumulated soil moisture deficits. Chloride mass balance coupled with the isotope results demonstrates the presence of both preferential and piston flow groundwater recharge mechanisms. The stable and radioactive isotope measurements further revealed that groundwater in the Akaki catchment is found to be compartmentalized into zones. Groundwater mixing following the flow paths and topography is complicated by the lithologic complexity. An uncommon, highly depleted stable isotope and zero‐³H groundwater, observed in a nearly east–west stretch through the central sector of the catchment, is coincident with the Filwoha Fault zone. Here, deep circulating meteoric water has lost its isotopic content through exchange reactions with CO₂ originating at deeper sources or it has been recharged with precipitation from a different rainfall regime with a depleted isotopic content. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Statistische Untersuchungen über die tägliche Geburtenfrequenz in Wien     

Dr. Willibald Undt  Dipl.-Ing. Dr. Ernst Schuster 《Theoretical and Applied Climatology》1978,26(1):87-96

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Isotopic and geochemical characteristics of groundwater in the Senegal River delta aquifer: implication of recharge and flow regime   总被引：3，自引：3，他引：0  

Moctar Diaw  Serigne Faye  Willibald Stichler  Piotr Maloszewski 《Environmental Earth Sciences》2012,66(4):1011-1020

Groundwater and surface water samples were collected to improve understanding of the Senegal River Lower Valley and Delta system, which is prone to salinization. Inorganic ion concentrations and environmental isotopes (¹⁸O, ²H and ³H) in groundwater, river, lake and precipitation were investigated to gain insight into the functioning of the system with regard to recharge sources and process, groundwater renewability, hydraulic interconnection and geochemical evolution. The geochemical characteristics of the system display mainly cation (Ca²⁺ and/or Na⁺) bicarbonated waters, which evolve to chloride water type; this occurs during groundwater flow in the less mineralized part of the aquifer. In contrast, saline intrusion and secondary brines together with halite dissolution are likely to contaminate the groundwater to Na–Cl type. Halite, gypsum and calcite dissolution determine the major ion (Na⁺, Cl⁻, Ca²⁺, Mg²⁺, SO₄ ²⁻ and HCO₃ ⁻) chemistry, but other processes such as evaporation, salt deposition, ion exchange and reverse exchange reactions also control the groundwater chemistry. Both surface water and groundwater in the system show an evaporation effect, but high evaporated signatures in the groundwater may be due to direct evaporation from the ground, infiltration of evaporated water or enriched rainwater in this region. The stable isotopes also reveal two types of groundwater in this system, which geomorphologically are distributed in the sand dunes (depleted isotopes) and in the flood plain (enriched isotopes). Consideration of the ³H content reinforces this grouping and suggests two mechanisms of recharge: contribution of enriched surface water in recharging the flood plain groundwater and, in the sand dunes area where water table is at depth between 8 and 13 m, slow recharge process characterized the submodern to mixed water.  相似文献   

Glaciers and Climate in the Andes between the Equator and 30° S: What is Recorded under Extreme Environmental Conditions?     

U. Schotterer  M. Grosjean  W. Stichler  P. Ginot  C. Kull  H. Bonnaveira  B. Francou  H. W. Gäggeler  R. Gallaire  G. Hoffmann  B. Pouyaud  E. Ramirez  M. Schwikowski  J. D. Taupin 《Climatic change》2003,59(1-2):157-175

Sublimation and melt disturb the environmental information obtained from ice core records in the Andes. In two case studies we demonstrate to what extent these post-depositional processes may remove major parts of the accumulated snow cover. Dark ash layers from the Tungurahua eruption changed the albedo of surface snow on Chimborazo glacier (6268 m, 1°30 S,78°36 W, Ecuador) between two ice core drilling campaigns and forced substantial melt. Re-distribution and washout of the chemical constituents shifted the concentration profiles obtained in December 1999 as compared to an equivalent core drilled in December 2000. The stable isotope records showed that approximately the water equivalent (weq) of an annual layer had melted, and that the percolating melt water penetrated within the firn layer to a depth of at least 16.5 m without refreezing. In the second example, from a site on the dry axis between the tropical and extra-tropical precipitation belts, significant loss of accumulated snow layers occurred by sublimation. A surface experiment at Cerro Tapado glacier (5536 m, 30°08 S,69°55 W, Chile) revealed that losses of 2 mm weq (5 mm snow) per day occurred during the dry period following the 1997/98 El Niño. This loss generally included the entire surface layer enriched in stable isotopes, and thus caused minimal disturbance of the isotopic signature (and hence climatic information) of the net accumulation, yet chemical constituents again experienced considerable changes in concentration. From annual layer counting and direct dating it is obvious that the major part of the accumulated ice on both glaciers is younger than 100 years; however, isotopic and chemical variations at least in the basal ice from Cerro Tapado clearly point to climate conditions different from the recent centuries. This evidence is supported by mass balance considerations derived from a glacier-climate model. The possibility of a third type of disturbance aside from sublimation and melting – in this case a significant hiatus in the environmental chronology – also deserves consideration for other icecore records from this region. Potential disruptions or discontinuities need to be carefully evaluated given the profound changes in climatic and glaciological conditions since the Last Glacial Maximum throughout Holocene times.  相似文献   

Overview of tritium records from precipitation and surface waters in Germany     

Axel Schmidt  Gabriele Frank  Willibald Stichler  Lars Duester  Thomas Steinkopff  Christine Stumpp 《水文研究》2020,34(6):1489-1493

Tritium is one of the most important environmental tracers in isotope hydrology for understanding the dynamics of groundwater and connected surface water and has been used in a wide range of applications at different scales. A key requirement for using tritium as a tracer is the knowledge of its spatial and temporal distribution in different water types. As a fundamental input, quantity long-term time series of tritium in precipitation are of particular importance. In this paper, the authors present an overview of tritium data sets of the Federal Institute of Hydrology (BfG), the Helmholtz Zentrum München (HMGU) and the German Weather Service (DWD). Since the 1970s, all three institutions have monitored the tritium concentration at 53 surface water and 37 precipitation stations on a monthly basis. The primary purpose of the data set was to provide baseline information for different water types all over Germany as an integral part of the German radiation protection monitoring system. Additionally, as geochemically inert tracer, tritium provides a unique tool to different user groups in a wide range of research questions and applications.  相似文献   

Preferential percolation quantified by large water content sensors with artifactual macroporous envelopes          下载免费PDF全文

Ilse Kogelbauer  Kamila Bát'ková  František Doležal  Svatopluk Matula  Willibald Loiskandl 《水文研究》2015,29(19):4325-4338

For many scientific and practical tasks, it is important to estimate the soil–water percolation fluxes. This paper builds on measurements with large horizontal time‐domain reflectometry water content sensors in a loamy Mollisol. The sensors were installed into pre‐drilled holes and the gaps between them, and the soil was filled with a slurry of local soil with water. This gave rise to envelopes around them that contained artificial macropores. The sensors reacted to intensive rains by a rapid increase of their readings, often above the native soil's porosity, followed by an almost equally rapid decrease. The paper explores the feasibility of quantifying the rapid percolation, based on these anomalous water content peaks, and demonstrates that this is possible in principle, if the processes are simulated by a suitable model. A two‐dimensional dual porosity non‐equilibrium (mobile‐immobile) model was tried. The envelope around the sensor was modelled as an annulus with higher porosity and hydraulic conductivity, which attracts preferential flow and amplifies the percolation signal. With the model at hand, the flux hydrographs can be derived from model simulations and measured precipitation. For contrast, the Durner equilibrium dual porosity model was tried but was found little suitable. However, even the mobile‐immobile model did not perform perfectly. Simulated water contents were similar to the measured ones at some depths but not in the others, and the percolation fluxes were overestimated, compared to cumulative soil–water balance. Efforts to improve model performance were not successful. Hence, the model structure needs to be improved. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Towards using pedotransfer functions for estimating infiltration parameters     

Shoja Ghorbani-Dashtaki  Mehdi Homaee  Willibald Loiskandl 《水文科学杂志》2013,58(8):1477-1488

ABSTRACT

Water infiltration into soils is an important component of hydrological processes. Direct measurement of infiltration is time consuming, expensive and often involves large spatial and temporal variability. The objective of this study was to develop and verify parametric pedotransfer functions (PTFs) to predict infiltration parameters. Consequently, 119 double-ring infiltration data were collected. The parameters of Philip, Kostiakov, Kostiakov-Lewis and Horton models were obtained, using the sum of squares error optimization method. Some parametric PTFs were then derived to predict the parameters of the infiltration models, using stepwise regression analysis. The results indicated a reasonable estimation of infiltration parameters by the derived PTFs. These results were more accurate when the land use of the studied area was considered. Overall results of this study suggest infiltration-based PTFs could be established as a reasonable indirect method for estimating infiltration parameters.