Nuclear stellar discs in early-type galaxies — II. Photometric properties     

Cecilia Scorza  & Frank C. van den Bosch 《Monthly notices of the Royal Astronomical Society》1998,300(2):469-478

Hubble Space Telescope images of two early-type galaxies harbouring both nuclear and outer stellar discs are studied in detail. By means of a photometric decomposition, the images of NGC 4342 and 4570 are analysed and the photometric properties of the nuclear discs investigated. We find a continuity of properties in the parameter space defined by the central surface brightness μ₀ and the scalelength R _d of discs in spirals, S0s and embedded discs in ellipticals, in the sense that the nuclear discs extend the observed disc properties even further towards smaller scalelengths and brighter central surface brightnesses. When including the nuclear discs, disc properties span more than four orders of magnitude in both scalelength and central surface brightness. The nuclear discs studied here are the smallest and brightest stellar discs known, and as such, they are as extreme in their photometric properties as Malin I, when compared with typical galactic discs that obey Freeman's law. We discuss a possible formation scenario in which the double-disc structure observed in these galaxies has been shaped by now dissolved bars. Based on the fact that the black holes known to exist in some of these galaxies have masses comparable to those of the nuclear discs, we explore a possible link between the black holes and the nuclear discs.  相似文献   

Probing the local environment of substitutional Al$$^{}$$ in goethite using X-ray absorption spectroscopy and first-principles calculations     

Manoj Ducher  Marc Blanchard  Delphine Vantelon  Ruidy Nemausat  Delphine Cabaret 《Physics and Chemistry of Minerals》2016,43(3):217-227

We present experimental and calculated Al K-edge X-ray absorption near-edge structure (XANES) spectra of aluminous goethite with 10–33 mol% of AlOOH and diaspore. Significant changes are observed experimentally in the near- and pre-edge regions with increasing Al concentration in goethite. First-principles calculations based on density functional theory (DFT) reproduce successfully the experimental trends. This permits to identify the electronic and structural parameters controlling the spectral features and to improve our knowledge of the local environment of \(\hbox {Al}^{3+}\) in the goethite–diaspore partial solid solution. In the near-edge region, the larger peak spacing in diaspore compared to Al-bearing goethite is related to the nature (Fe or Al) of the first cation neighbours around the absorbing Al atom (Al*). The intensity ratio of the two near-edge peaks, which decreases with Al concentration, is correlated with the average distance of the first cations around Al* and the distortion of the \(\hbox {AlO}_6\) octahedron. Finally, the decrease in intensity of the pre-edge features with increasing Al concentration is due to the smaller number of Fe atoms in the local environment of Al since Al atoms tend to cluster. In addition, it is found that the pre-edge features of the Al K-edge XANES spectra enable to probe indirectly empty 3d states of Fe. Energetic, structural and spectroscopic results suggest that for Al concentrations around 10 mol%, Al atoms can be considered as isolated, whereas above 25 mol%, Al clusters are more likely to occur.  相似文献   

The contribution of the young Cretaceous Caribbean Oceanic Plateau to the genesis of late Cretaceous arc magmatism in the Cordillera Occidental of Ecuador     

J. Allibon  P. Monjoie  H. Lapierre  E. Jaillard  F. Bussy  D. Bosch  F. Senebier 《Journal of South American Earth Sciences》2008,26(4):355-368

The eastern part of the Cordillera Occidental of Ecuador comprises thick buoyant oceanic plateaus associated with island-arc tholeiites and subduction-related calc-alkaline series, accreted to the Ecuadorian Continental Margin from Late Cretaceous to Eocene times. One of these plateau sequences, the Guaranda Oceanic Plateau is considered as remnant of the Caribbean–Colombian Oceanic Province (CCOP) accreted to the Ecuadorian Margin in the Maastrichtien.Samples studied in this paper were taken from four cross-sections through two arc-sequences in the northern part of the Cordillera Occidental of Ecuador, dated as (Río Cala) or ascribed to (Macuchi) the Late Cretaceous and one arc-like sequence in the Chogòn-Colonche Cordillera (Las Orquídeas). These three island-arcs can clearly be identified and rest conformably on the CCOP.In all four localities, basalts with abundant large clinopyroxene phenocrysts can be found, mimicking a picritic or ankaramitic facies. This mineralogical particularity, although not uncommon in island arc lavas, hints at a contribution of the CCOP in the genesis of these island arc rocks.The complete petrological and geochemical study of these rocks reveals that some have a primitive island-arc nature (MgO values range from 6 to 11 wt.%). Studied samples display marked Nb, Ta and Ti negative anomalies relative to the adjacent elements in the spidergrams characteristic of subduction-related magmatism. These rocks are LREE-enriched and their clinopyroxenes show a tholeiitic affinity (FeO_T–TiO₂ enrichment and CaO depletion from core to rim within a single crystal).The four sampled cross-sections through the island-arc sequences display homogeneous initial Nd, and Pb isotope ratios that suggest a unique mantellic source for these rocks resulting from the mixing of three components: an East-Pacific MORB end-member, an enriched pelagic sediment component, and a HIMU component carried by the CCOP. Indeed, the ankaramite and Mg-basalt sequences that form part of the Caribbean-Colombian Oceanic Plateau are radiogenically enriched in ²⁰⁶Pb/²⁰⁴Pb and ²⁰⁷Pb/²⁰⁴Pb and contain a HIMU component similar to that observed in the Gorgona basalts and Galápagos lavas. The subduction zone that generated the Late Cretaceous arcs occurred far from the continental margin, in an oceanic environment. This implies that no terrigenous detrital sediments interacted with the source at this period. Thus, the enriched component can only result from the melting of subducted pelagic sediments.We have thus defined the East-Pacific MORB, enriched (cherts, pelagic sediments) and HIMU components in an attempt to constrain and model the genesis of the studied island-arc magmatism, using a compilation of carefully selected isotopic data from literature according to rock age and paleogeographic location at the time of arc edification.Tripolar mixing models reveal that proportions of 12–15 wt.% of the HIMU component, 7–15 wt.% of the pelagic sediment end-member and 70–75 wt.% of an East-pacific MORB end-member are needed to explain the measured isotope ratios. These surprisingly high proportions of the HIMU/CCOP component could be explained by the young age of the oceanic plateau (5–15 Ma) during the Late Cretaceous arc emplacement. The CCOP, basement of these arc sequences, was probably still hot and easily assimilated at the island-arc lava source.  相似文献   

Contribution of long-term hydrothermal experiments for understanding the smectite-to-chlorite conversion in geological environments     

Régine?Mosser-RuckEmail author  Isabella?Pignatelli  Franck?Bourdelle  Mustapha?Abdelmoula  Odile?Barres  Damien?Guillaume  Delphine?Charpentier  Davy?Rousset  Michel?Cathelineau  Nicolas?Michau 《Contributions to Mineralogy and Petrology》2016,171(11):97

The smectite-to-chlorite conversion is investigated through long-duration experiments (up to 9 years) conducted at 300 °C. The starting products were the Wyoming bentonite MX80 (79 % smectite), metallic iron and magnetite in contact with a Na–Ca chloride solution. The predominant minerals in the run products were an iron-rich chlorite (chamosite like) and interstratified clays interpreted to be chlorite/smectite and/or corrensite/smectite, accompanied by euhedral crystals of quartz, albite and zeolite. The formation of pure corrensite was not observed in the long-duration experiments. The conversion of smectite into chlorite over time appears to take place in several steps and through several successive mechanisms: a solid-state transformation, significant dissolution of the smectite and direct precipitation from the solution, which is over-saturated with respect to chlorite, allowing the formation of a chamosite-like mineral. The reaction mechanisms are confirmed by X-ray patterns and data obtained on the experimental solutions (pH, contents of Si, Mg, Na and Ca). Because of the availability of some nutrients in the solution, total dissolution of the starting smectite does not lead to 100 % crystallization of chlorite but to a mixture of two dominant clays: chamosite and interstratified chlorite/smectite and/or corrensite/smectite poor in smectite. The role of Fe/(Fe + Mg) in the experimental medium is highlighted by chemical data obtained on newly formed clay particles alongside previously published data. The newly formed iron-rich chlorite has the same composition as that predicted by the geothermometer for diagenetic to low-grade metamorphic conditions, and the quartz + Fe-chlorite + albite experimental assemblage in the 9-year experiment is close to that fixed by water–rock equilibrium.  相似文献   

The COVID-19 pandemic and global environmental change: Emerging research needs     

Robert Barouki  Manolis Kogevinas  Karine Audouze  Kristine Belesova  Ake Bergman  Linda Birnbaum  Sandra Boekhold  Sebastien Denys  Celine Desseille  Elina Drakvik  Howard Frumkin  Jeanne Garric  Delphine Destoumieux-Garzon  Andrew Haines  Anke Huss  Genon Jensen  Spyros Karakitsios  Jana Klanova  Paolo Vineis 《Chemie der Erde / Geochemistry》2012

The outbreak of COVID-19 raised numerous questions on the interactions between the occurrence of new infections, the environment, climate and health. The European Union requested the H2020 HERA project which aims at setting priorities in research on environment, climate and health, to identify relevant research needs regarding Covid-19. The emergence and spread of SARS-CoV-2 appears to be related to urbanization, habitat destruction, live animal trade, intensive livestock farming and global travel. The contribution of climate and air pollution requires additional studies. Importantly, the severity of COVID-19 depends on the interactions between the viral infection, ageing and chronic diseases such as metabolic, respiratory and cardiovascular diseases and obesity which are themselves influenced by environmental stressors. The mechanisms of these interactions deserve additional scrutiny. Both the pandemic and the social response to the disease have elicited an array of behavioural and societal changes that may remain long after the pandemic and that may have long term health effects including on mental health. Recovery plans are currently being discussed or implemented and the environmental and health impacts of those plans are not clearly foreseen. Clearly, COVID-19 will have a long-lasting impact on the environmental health field and will open new research perspectives and policy needs.  相似文献   

Formation of phyllosilicates in a fault zone affecting deeply buried arkosic sandstones: their influence on petrophysic properties (Annot sandstones, French external Alps)     

Henri Leclère  Martine Buatier  Delphine Charpentier  Jean-Pierre Sizun  Pierre Labaume  Thibault Cavailhes 《Swiss Journal of Geoscience》2012,105(2):299-312

The Restefond fault, located in the Late Eocene-Early Oligocene Alpine foreland basin, affects the well lithified and low porosity Grès d??Annot. The fault core zone is characterized by the occurrence of highly deformed sandstone lenses. Deformation inside the lenses corresponds to mm to sub-mm-spaced cleavage planes rich in phyllosilicates and up to cm-thick and dm-long quartz-calcite pure extensional veins. The cleavages are mostly composed of newly-formed synkinematic white mica and chlorite. By using thermodynamic thermometers based on the chemical composition of chlorite, a temperature of 200?±?20?°C of fault activity was computed. This temperature shows that the Restefond fault was active at burial conditions comprised between 6.5 and 8?km, assuming a mean geothermal gradient between 25 and 30?°Ckm^?1. The petrophysic properties of sandstones from the core zone and in the hanging and foot wall of the fault were determined on drilled plugs following three spacial directions. The permeability of the highly deformed sandstone from the core zone is about one order of magnitude higher than in the host rock. This increase in permeability occurs in the direction parallel to the S?CC structures and is explained by the occurrence of well-connected micropores localized between platy phyllosilicates. This study shows that the fault petrophysic properties are mostly controlled by the precipitation of synkinematic phyllosilicates under deep burial conditions.  相似文献   

Main issues of an evacuation in case of volcanic crisis: social stakes in Guadeloupe (Lesser Antilles Arc)     

Marie Chenet  Delphine Grancher  Marie Redon 《Natural Hazards》2014,73(3):2127-2147

The last major eruption of La Soufrière volcano in Guadeloupe (Lesser Antilles) in 1976–1977 caused the mass evacuation of part of the population, whereby a total of 76,000 people were displaced for a period of 3–6 months. This evacuation has left a bitter memory among the inhabitants who believed that the political authorities of the time had not anticipated the possibility of an eruption crisis and that decisions were taken in haste. La Soufrière remains active, and future eruptions could once again lead to partial or even total evacuation of the population if there were a major Plinian eruption. This article offers an investigation of future evacuation procedures, questioning different aspects of Guadeloupe’s current territorial and social challenges (the multi-risk context, the reporting to the scientists and to the authorities, the importance of local solidarity). In order to do so, we used the Focus Group Discussion method, making it possible to identify resources and gaps in crisis management on the basis of previous event history.  相似文献   

Effect of phosphate, silicate, and Ca on Fe(III)-precipitates formed in aerated Fe(II)- and As(III)-containing water studied by X-ray absorption spectroscopy     

Andreas Voegelin  Ralf Kaegi  Delphine Vantelon 《Geochimica et cosmochimica acta》2010,74(1):164-186

We studied the local coordination and structure of Fe(III)-precipitates formed in aerated Fe(II)- and As(III)-containing water (buffered to pH 7 by 8 mM bicarbonate) using synchrotron-based X-ray absorption spectroscopy (XAS) at the K-edges of Fe, P, Ca, and As. Dissolved phosphate, silicate, and Ca at different ratios relative to each other and to Fe affect the forming Fe(III)-phases in a complex manner. The high affinity of phosphate for Fe(III) results in the predominant precipitation of Fe(III)-phosphate as long as dissolved phosphate is present, with Fe(III) polymerization limited to small oligomers. In Ca-containing solution, Ca uptake by Fe(III)-Ca-phosphate involves the linkage and coagulation of negatively charged Fe(III)-phosphate oligomers via Ca-O-P bonds. In the absence of phosphate, dissolved silicate at Si/Fe ratios above ∼0.5 results in the formation of hydrous ferric oxide (HFO) with mainly edge-sharing Fe-Fe linkage. At lower Si/Fe ratios of ∼0.5-0.1, mainly 2-line ferrihydrite (2L-Fh) with both edge- and corner-sharing Fe-Fe linkage forms. Only in the absence of phosphate at low Si/Fe ratio, lepidocrocite (Lp) forms. In solutions containing sufficient Fe(II), aeration results in the sequential precipitation of Fe(III)-(Ca-)phosphate, HFO or 2L-Fh (depending on solution Si/Fe), and finally Lp. The amount and oxidation state of As co-precipitated with Fe(III) are controlled by the co-oxidation of As(III) with Fe(II), which increases with initial Fe/As ratio, and the competitive uptake of phosphate, As(V) and less strongly sorbing silicate and As(III). This study demonstrates that the diversity and sequence of short-range-ordered Fe(III)-precipitates forming by Fe(II) oxidation in near-neutral natural waters depend on water chemistry. Because differences in the colloidal stability and biogeochemical reactivity of these phases will affect the fate of associated major and trace elements, the different Fe(III)-precipitates and their specific biogeochemical properties must be taken into account when addressing nutrient and contaminant dynamics at redox boundaries in natural and engineered systems.  相似文献   

Dissolution kinetics as a function of the Gibbs free energy of reaction: An experimental study based on albite feldspar   总被引：1，自引：0，他引：1  

Roland Hellmann  Delphine Tisserand 《Geochimica et cosmochimica acta》2006,70(2):364-383

Here we report on an experimental investigation of the relation between the dissolution rate of albite feldspar and the Gibbs free energy of reaction, ΔG_r. The experiments were carried out in a continuously stirred flow-through reactor at 150 °C and pH_(150 °C) 9.2. The dissolution rates R are based on steady-state Si and Al concentrations and sample mass loss. The overall relation between ΔG_r and R was determined over a free energy range of −150 < ΔG_r < −15.6 kJ mol⁻¹. The data define a continuous and highly non-linear, sigmoidal relation between R and ΔG_r that is characterized by three distinct free energy regions. The region furthest from equilibrium, delimited by −150 < ΔG_r < −70 kJ mol⁻¹, represents an extensive dissolution rate plateau with an average rate . In this free energy range the rates of dissolution are constant and independent of ΔG_r, as well as [Si] and [Al]. The free energy range delimited by −70 ? ΔG_r ? −25 kJ mol⁻¹, referred to as the ‘transition equilibrium’ region, is characterized by a sharp decrease in dissolution rates with increasing ΔG_r, indicating a very strong inverse dependence of the rates on free energy. Dissolution nearest equilibrium, defined by ΔG_r > −25 kJ mol⁻¹, represents the ‘near equilibrium’ region where the rates decrease as chemical equilibrium is approached, but with a much weaker dependence on ΔG_r. The lowest rate measured in this study, R = 6.2 × 10⁻¹¹ mol m⁻² s⁻¹ at ΔG_r = −16.3 kJ mol⁻¹, is more than two orders of magnitude slower than the plateau rate. The data have been fitted to a rate equation (adapted from Burch et al. [Burch, T. E., Nagy, K. L., Lasaga, A. C., 1993. Free energy dependence of albite dissolution kinetics at 80 °C and pH 8.8. Chem. Geol.105, 137-162]) that represents the sum of two parallel reactions