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161.
Peridotite xenoliths from the Bereya alkali picrite tuff in the Vitim volcanic province of Transbaikalia consist of garnet lherzolite, garnet–spinel lherzolite and spinel lherzolite varieties. The volcanism is related to the Cenozoic Baikal Rift. All peridotites come from pressures of 20–23 kbar close to the garnet to spinel peridotite transition depth, and the presence of garnet can be attributed to cooling of spinel peridotites, probably during formation of the lithosphere. The peridotites show petrographic and mineral chemical evidence for infiltration by an alkaline silicate melt shortly before their transport to the Earth's surface. The melt infiltration event is indicated petrographically by clinopyroxenes which mimic melt morphologies, and post-dates outer kelyphitic rims on garnets which are attributed to an isochemical heating event within the mantle before transport to the Earth's surface. Single-mineral thermometry gives reasonable temperature estimates of 1050±50°C, whereas two-mineral methods involving clinopyroxene are falsified by secondary components in clinopyroxene introduced during the melt infiltration event. Excimer Laser–ICP-MS analysis has been performed for an extensive palette of both incompatible and compatible trace elements, and manifests the most thorough dataset available for this rock type. Orthopyroxene and garnet show only partial equilibration of trace elements with the infiltrating melt, whereas clinopyroxene and amphibole are close to equilibration with the melt and with each other. The incompatible element composition of the infiltrating melt calculated from the clinopyroxene and amphibole analyses via experimental mineral/melt partition coefficients is similar to the host alkali picrite, and probably represents a low melt fraction from a similar source during rift propagation. The chemistry and chronology of the events recorded in the xenoliths delineates the series of events expected during the influence of an expanding rift region in the upper mantle, namely the progressive erosion of the lithosphere and the episodic upward and outward propagation of melts, resulting in the evolution of the Vitim volcanic field.  相似文献   
162.
Petrographic observations on quartz crystals from the Mole Granite (Australia) and other localities shed new light on the mechanisms of post-entrapment modification of fluid inclusions. These modifications include migration away from pseudosecondary trails, changes in fluid salinity and density, shape distortion and the formation of “sweat-haloes” around strongly deformed inclusions. Increases in fluid salinity, which usually are associated with inclusion migration, indicate water-losses of up to 50%. However, LA-ICP-MS-analysis of unmobilized and mobilized inclusions of the same trail reveals basically unchanged ratios of major – and trace element cations, with the exception of Li, which seems to be incorporated into the crystal lattice during migration. Despite the fact that all these modifications are closely related to deformation processes, they occur not only in mechanically deformed quartz, but also in free-standing crystals. In the latter samples, stress has been generated internally as a result of brazil-twinned growth and compositional zonation. These observations and their interpretation leads to a list of practical criteria that should help in differentiating between reliable and suspect fluid inclusions in other samples. Received: 17 November 1998 / Accepted: 16 April 1999  相似文献   
163.
Besides providing an estimate of the changing ocean state, an important result of the dynamically consistent estimating the circulation and climate of the ocean (ECCO) state estimate approach is the provision of a posterior model–data residuals which contain important information about elements in the assimilated observations that are inconsistent with the model dynamics or with the information present in other ocean data sets that are being used as constraints in the assimilation procedure. Based on decreased GECCO2 model–data residuals, upon using the altimeter data through the ESA climate change initiative (cci) sea-level (SL) project, we show here that the recently reprocessed ESA SL_cci altimeter data set (SL1) has been improved relative to the earlier AVISO altimetry data set and is now more consistent with the GECCO2 estimate and with the information about the changing ocean state embedded in other ocean data sets. The improvement can be shown to exist separately for both TOPEX/POSEIDON and ERS data sets. The study reveals that especially in regions characterized by small sea surface height (SSH) variability and small signal-to-noise ratio in the SSH data, improvements can be on the order of 30% of previously existing model–data residuals. However, in some regions we can find degradations, particulary in those where GECCO2 has little skill in representing the altimeter data and where evaluation of the products with GECCO2 is thus not advisable. Upon the assimilation of the new SL1 data set, the GECCO2 synthesis was further improved. However, adding the sea surface temperature (SST) from the SST_cci project as additional constrain, no further impact can be identified.  相似文献   
164.
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