Uranium geochemistry in groundwater from tertiary sediments     

Roy F. Spalding  A.Douglas Druliner  Lowell S. Whiteside  Arthur W. Struempler 《Geochimica et cosmochimica acta》1984,48(12):2679-2692

Dissolved U concentrations and activity ratios (ARs) of the U isotopes in the ²³⁸U decay series were measured in ground and surface waters as part of an investigation to delineate the water quality in a proposed uranium mining area of northwest Nebraska. In oxidizing groundwaters from 67 wells completed in the Tertiary sediments, increasing U concentrations in the direction of groundwater flow generally were associated with a maturation of the formation water as evidenced by evolutionary trends in major ion character. The increased U levels probably are associated with leaching as shown by the positive correlation between U concentrations and total dissolved solids (TDS) (r = +0.83). The inverse relationships between TDS and U ARs (r = ?0.73) and U levels and ARs (r = 0.72) indicate that the decay of excess U-234 is related to maturation of the formation water and to sediment leaching along the flowpath. The data are described by a model which incorporates etching, decay and recoil and suggests that aquifer residence time can be estimated from the TDS level.The levels of soluble U in a reducing uraniferous hydrogeologic unit near Crawford, Nebraska are affected by the proximity of the sample collection to ore. In groundwater samples having similar chemistries (Na-SO₄ + Cl type), similar Ehs, and collected from a close-knit pattern, U concentrations ranged from 0.01 to 2,037 μg l^?1 and ARs ranged from 0.75 to 12.6. This high variability in U levels and ARs is indicative of uranium ore in small areal studies where low ARs almost always are associated with high U concentrations.  相似文献   

Petrography of low rank coals with reference to liquefaction potential     

S. Parkash  M.P. Du Plessis  A.R. Cameron  W.D. Kalkreuth 《International Journal of Coal Geology》1984,4(3):209-234

Ten sub-bituminous coals were analyzed petrographically and chemically as part of a program by the Alberta Research Council to investigate the compositional properties of Alberta coals and relationship to liquefaction potential. In addition, four lignites, two from Saskatchewan and one each from Texas and North Dakota, were studied for comparative purposes. Liquefaction experiments were carried out on three of the Alberta coals and on density fractions of the two U.S. lignites. Petrographically the ten sub-bituminous coals could be divided into two populations; one with high huminite and liptinite contents (>90%) and one with substantially lower contents (70–75%). The two U.S. lignites showed huminite plus liptinite contents of less than 70% while the Saskatchewan coals were somewhat higher. Reflectance measurements on the sub-bituminous coals showed a range of 0.33 to 0.51 with a rough correlation to the ASTM rank designations of these coals. Reflectivities determined on the lignites were generally lower. Float-sink fractionation of the two U.S. lignites and two sub-bituminous coals showed enrichment of huminite and liptinite in the lighter fractions and inertinite and mineral matter in the heavier splits. Examination of the relationship between liquefaction yields and petrographic composition showed a rough positive correlation with huminite-liptinite content. Examination of liquefaction residues suggested total conversion of the liptinite, extensive conversion of huminite and possible partial conversion and reactivity of the semifusinite maceral of the inertinite group.  相似文献   

Robust kriging—A proposal     

Douglas M. Hawkins  Noel Cressie 《Mathematical Geosciences》1984,16(1):3-18

Geological data frequently have a heavy-tailed normal-in-the-middle distribution, which gives rise to grade distributions that appear to be normal except for the occurrence of a few outliers. This same situation also applies to log-transformed data to which lognormal kriging is to be applied. For such data, linear kriging is nonrobust in that (1)kriged estimates tend to infinity as the outliers do, and (2)it is also not minimum mean squared error. The more general nonlinear method of disjunctive kriging is even more nonrobust, computationally more laborious, and in the end need not produce better practical answers. We propose a robust kriging method for such nearly normal data based on linear kriging of an editing of the data. It is little more laborious than conventional linear kriging and, used in conjunction with a robust estimator of the variogram, provides good protection against the effects of data outliers. The method is also applicable to time series analysis.  相似文献   

Practical Application of Theoretical Models to Magnetometer Surveys on Hazardous Waste Disposal Sites — A Case History     

Robert H. Gilkeson  Paul C. Heigold  Douglas E. Laymon 《Ground Water Monitoring & Remediation》1986,6(1):54-61

Wastes were to be exhumed and removed from a hazardous and chemical waste disposal site. The major disposal practice was shallow burial of wastes in metal drums in parallel trenches. The actual boundaries of the trenches beneath the landscaped cover were not accurately known.
Theoretical two-dimensional models were used to evaluate the application of magnetic methods to define trench boundaries on the disposal site. The models predicted that both the total field and the vertical component anomalies were diagnostic; however, the vertical component anomaly was more focused on the trench boundaries.
A survey with a vertical component fluxgate magnetometer was successful in defining trench boundaries. Observations made along traverses that trended perpendicular to the long axis of the parallel trenches indicated vertical magnetic intensity values with a cyclical pattern of large positive values over trenches and large negative values over intertrench corridors. Vertical magnetic intensity values determined with theoretical two-dimensional models compared favorably to the observed vertical magnetic values. The models were used to constrain the interpretation of the field observations to define trench boundaries; the magnetic survey defined trench boundaries with an accuracy within ± 2 feet.  相似文献   

Plate tectonics,palaeoenvironments and limestone geomorphology in West-Central Britain     

Ian Douglas 《地球表面变化过程与地形》1987,12(5):481-495

The variety of active, exhumed, and buried limestone landforms of northern England, North Wales, and the Isle of Man arises in part from the way in which Dinantian (Lower Carboniferous) sedimentation was affected by a tilt-block basement structure evolved during the closure of the Iapetus Ocean suture to the north, and partly to subsequent plate tectonic movements associated with the closure of the proto-Tethys ocean, the opening of the Atlantic Ocean and the Alpine orogeny. Landforms created during the Dinantian now form important exhumed and buried landscape features. The Permian half-graben structures of the eastern Irish Sea-Cheshire-Worcester Basins account for many of the contrasts between the upland karsts of the Pennines and the lowland karsts of coastal areas.  相似文献   

Strontium-calcium ratios in Cenozoic planktonic foraminifera     

David W. Graham  Michael L. Bender  Douglas F. Williams  Lloyd D. Keigwin 《Geochimica et cosmochimica acta》1982,46(7):1281-1292

The $\text{Sr}\text{Ca}$ ratio and other parameters have been measured in fossil planktonic foraminifera from the Atlantic and Pacific Ocean basins in order to evaluate the $\text{Sr}\text{Ca}$ ratio of seawater during the last 75 million years. Results on well-preserved samples indicate that the ratio has increased to its present value by 10–15% during the Cenozoic, and that minima occurred between 55-45 Ma and 10-5 Ma, when the ratio was 15–25% less than at present. The long-term increase may reflect either decreasing deposition of aragonite with a high $\text{Sr}\text{Ca}$ ratio in shallow seas, or decreasing seafloor spreading rates and consequently decreasing hydrothermal supply of Ca during the Cenozoic. Other geologic evidence suggests that the Eocene minimum (near 50 Ma) may have resulted from increased aragonite sedimentation, while the Late Miocene minimum (between 10-5 Ma) may have been caused by an increased rate of seawater-basalt exchange when seafloor spreading rates increased on the East Pacific Rise near 10 Ma.  相似文献   

Migration and retention of elements at the Oklo natural reactor     

Douglas G. Brookins 《Environmental Geology》1982,4(3-4):201-208

The Oklo natural reactor, Gabon, permits study of fission-produced elemental behavior in a natural geologic environment. The uranium ore that sustained fission reactions formed about 2 billion years before present (BYBP), and the reactor was operative for about 5 × 10⁵ yrs between about 1.95 to 2 BYBP. The many tons of fission products can, for the most part, be studied for their abundance and distribution today. Since reactor shutdown, many fissiogenic elements have not migrated from host pitchblende, and several others have migrated only a few tens of meters from the reactor ore. Only Xe and Kr have apparently been largely removed from the reactor zones. An element by element assessment of the Oklo rocks' ability to retain the fission products, and actinides and radiogenic Pb and Bi as well, leads to the conclusion that no widespread migration of the elements occurred. This suggests that rocks with more favorable geologic characteristics are indeed well suited for consideration for the storage of radioactive waste.  相似文献   

Slow subduction of old lithosphere in the lesser antilles     

Seth Stein  Joseph F. Engeln  Douglas A. Wiens  Robert C. Speed  Kazuya Fujita 《Tectonophysics》1983,99(2-4)

The Lesser Antilles subduction zone is an extreme case of the subduction of old (~ 90 m.y.) lithosphere at a slow (~ 2 cm/y) convergence rate. Focal mechanisms of the largest earthquakes in the area have been obtained using body and surface wave data. During the time period (1950–1978) studied the subduction seismicity appears to represent primarily intraplate rather than interplate deformation. All three large (magnitude seven) earthquakes were from intraplate normal faults; no large thrust faulting earthquakes and few small ones occurred. These observations suggest that the plate boundary is largely decoupled, that subduction is at least partially aseismic, and that the downgoing slab is in a state of extension.  相似文献   

Additive versus multiplicative models in ecologic regression     

W. Douglas Thompson  Daniel Wartenberg 《Stochastic Environmental Research and Risk Assessment (SERRA)》2007,21(5):635-646

Much research in environmental epidemiology relies on aggregate-level information on exposure to potentially toxic substances and on relevant covariates. We compare the use of additive (linear) and multiplicative (log-linear) regression models for the analysis of such data. We illustrate how both additive and multiplicative models can be fit to aggregate-level data sets in which disease incidence is the dependent variable, and contrast these results with similar models fitted to individual-level data. We find (1) that for aggregate-level data, multiplicative models are more likely than additive models to introduce bias into the estimation of rates, an effect not found with individual-level data; and (2) that under many circumstances multiplicative models reduce the precision of the estimates, an effect also not found in individual-level models. For both additive and multiplicative models of aggregate-level data, we find that, in the presence of covariates, narrow confidence interval are obtained only when two or more antecedent factors are strongly related to the measured covariate and/or the exposure of primary substantive interest. We conclude that the equivalency of fitting additive versus multiplicative models in studies with individual-level binary data does not carry over to studies that analyze aggregate-level information. For aggregate data, we strongly recommend use of additive models. Supported by Grant #1 U19 EH000102 from the National Center for Environmental Health, Centers for Disease Control and Prevention, Atlanta, GA.  相似文献   

Inferred ground motions on Guadeloupe during the 2004 Les Saintes earthquake     

John Douglas 《Bulletin of Earthquake Engineering》2007,5(3):363-376

Accurate estimates of the ground motions that occurred during damaging earthquakes are a vital part of many aspects of earthquake engineering, such as the study of the size and cause of the uncertainties within earthquake risk assessments. This article compares a number of methods to estimate the ground shaking that occurred on Guadeloupe (French Antilles) during the 21st November 2004 (M _w 6.3) Les Saintes earthquake, with the aim of providing more accurate shaking estimates for the investigation of the sources of uncertainties within loss evaluations, based on damage data from this event. The various techniques make differing use of the available ground-motion recordings of this earthquake and by consequence the estimates obtained by the different approaches are associated with differing uncertainties. Ground motions on the French Antilles are affected by strong local site effects, which have been extensively investigated in previous studies. In this article, use is made of these studies in order to improve the shaking estimates. It is shown that the simple methods neglecting the spatial correlation of earthquake shaking lead to uncertainties similar to those predicted by empirical ground-motion models and that these are uniform across the whole of Guadeloupe. In contrast, methods (such as the ShakeMap approach) that take account of the spatial correlation in motions demonstrate that shaking within roughly 10 km of a recording station (covering a significant portion of the investigated area) can be defined with reasonable accuracy but that motions at more distant points are not well constrained.  相似文献