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31.
The last decade has seen major technical and scientific improvements in the study of water transfer time through catchments. Nevertheless, it has been argued that most of these developments used conservative tracers that may disregard the oldest component of water transfer, which often has transit times greater than 5 years. Indeed, although the analytical reproducibility of tracers limits the detection of the older flow components associated with the most dampened seasonal fluctuations, this is very rarely taken into account in modelling applications. Tritium is the only environmental tracer at hand to investigate transfer times in the 5‐ to 50‐year range in surface waters, as dissolved gases are not suitable due to the degassing process. Water dating with tritium has often been difficult because of the complex history of its atmospheric concentration, but its current stabilization together with recent analytical improvements open promising perspectives. In this context, the innovative contribution of this study lies in the development of a generalized likelihood uncertainty estimation‐based approach for analysing the uncertainties associated with the modelling of transit time due to both parameter identification and tracer analytical precision issues. A coupled resampling procedure allows assessment of the statistical significance of the transfer time differences found in diverse waters. This approach was developed for tritium and the exponential‐piston model but can be implemented for virtually any tracer and model. Stream baseflow, spring and shallow aquifer waters from the Vallcebre research catchments, analysed for tritium in different years with different analytical precisions, were investigated by using this approach and taking into account other sources of uncertainty. The results showed three groups of waters of different mean transit times, with all the stream baseflow and spring waters older than the 5‐year threshold needing tritium. Low sensitivity of the results to the model structure was also demonstrated. Dual solutions were found for the waters sampled in 2013, but these results may be disambiguated when additional analyses will be made in a few years. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
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The synthesis of experimental understanding of catchment behaviour and its translation into qualitative perceptual models is an important objective of hydrological sciences. We explore this challenge by examining the cumulative understanding of the hydrology of three experimental catchments and how it evolves through the application of different investigation techniques. The case study considers the Huewelerbach, Weierbach and Wollefsbach headwater catchments of the Attert basin in Luxembourg. Subsurface investigations including bore holes and pits, analysis of soil samples and Electrical Resistivity Tomography measurements are presented and discussed. Streamflow and tracer data are used to gain further insights into the streamflow dynamics of the catchments, using end‐member mixing analysis and hydrograph separation based on dissolved silica and electrical conductivity. We show that the streamflow generating processes in all three catchments are controlled primarily by the subsolum and underlying bedrock. In the Huewelerbach, the permeable sandstone formation supports a stable groundwater component with little seasonality, which reaches the stream through a series of sources at the contact zone with the impermeable marls formation. In the Weierbach, the schist formation is relatively impermeable and supports a ‘fill and spill’‐type of flow mechanism; during wet conditions, it produces a delayed response dominated by pre‐event water. In the Wollefsbach, the impermeable marls formation is responsible for a saturation‐excess runoff generating process, producing a fast and highly seasonal response dominated by event water. The distinct streamflow generating processes of the three catchments are represented qualitatively using perceptual models. The perceptual models are in turn translated into quantitative conceptual models, which simulate the hydrological processes using networks of connected reservoirs and transfer functions. More generally, the paper illustrates the evolution of perceptual models based on experimental fieldwork data, the translation of perceptual models into conceptual models and the value of different types of data for processes understanding and model representation. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
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The paper offers an analytical determination of the hydraulic properties of an unsaturated soil with reference to its retention curve, which describes the relationship between the volumetric water content and capillarity through matric suction. The analysis combines a particulate approach focused on the physics at the pore scale, including microstructural aspects, with a probabilistic approach where the void space and grain size are considered as random variables. In the end, the soil water characteristic curve of an unsaturated granular medium along a drying path can be derived analytically based on the sole information of particle size distribution. The analysis hinges on the tessellation of a wet granular system into an assemblage of tetrahedral unit cells revealing a pore network upon which capillary physics are computed with respect to pore throat invasion by a non-wetting fluid with evolving pendular capillary bridges. The crux of the paper is to pass from particle size probability distribution to a matching void space distribution to eventually reveal key information such as void cell and solid volume statistics. Making reasonable statistically based assumptions to render calculations tractable, the water retention curve can be readily constructed. Model predictions compare quite favourably with experimental data available for actual soils, especially in the high saturation range. Having a sound scientific basis, the model can be made amenable to address a variety of soils with a wider range of particle sizes.  相似文献   
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This article contributes to the understanding of how to proceed with the development of index-insurance in order to reach extended population coverage with the insurance. The approach is applied to an example from a region in Tanzania. One of the main coping strategies that resource-poor households rely on to manage risks related to fluctuations in income flows is risk-sharing in informal networks. An informal network is an ideal way of managing idiosyncratic shocks, but once such shocks become covariate and affect whole communities, as is the case with most climate change impacts, informal networks become insufficient since the majority of risk-sharers will be affected by the shock at the same time. This paper proposes a collective approach to index-insurance in which the members of an informal network will be insured as one insurance taker. The paper raises a conceptual argument that targeting households through existing informal networks will remove a number of prevailing barriers to the take-up of insurance and consequently the approach has the potential to increase households’ resilience to climate change impacts. The policy implications of the conclusions are significant since the number of covariate shocks is predicted to increase with climate change.  相似文献   
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Complex interactions of climate and volcanic activity have shaped the environment of Iceland during the Holocene. Palaeoecological records from Iceland offer a unique look at a Holocene environment that was uninhabited by humans and free of mammal herbivores until about AD 870. We present a new reconstruction of Holocene vegetation and landscape dynamics from a small lake, Barðalækjartjörn, located near the highland margin in Northwest Iceland. A multi‐proxy approach was used to reconstruct vegetation based on pollen and plant macrofossil analysis and landscape stability based on lithological proxies. The record covers the period c. 10 300–200 cal. a BP. For the first two millennia aeolian processes probably played a part in vegetation development. This period is characterized by high input of minerogenic material into the lake and a vegetation assemblage in which plants tolerant of aeolian deposition are prominent. Betula pubescens woodland reached a maximum between c. 7400 and 6500 cal. a BP. Betula nana‐dominated dwarf shrub heath replaced woodland after c. 4000 cal. a BP, following the onset of Neoglaciation. Land use following human settlement caused an environmental shift at the highland margin. Betula pubescens probably disappeared from the vicinity of the lake soon thereafter. Large‐scale soil erosion began at c. 1000 cal. a BP in the wake of human activities, such as introduction of grazing livestock and woodcutting. This study offers an important long‐term perspective of the development of the highland ecosystem under both wholly natural and human‐influenced conditions.  相似文献   
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The 1750-m-diameter, bowl-shaped Talemzane impact structure in Algeria is emplaced in Senonian or Eocene flint-bearing limestones. Field studies reveal a thin layer of light-colored polymict breccia with rounded, dark inclusions beneath a limestone megablock zone located at the top of the crater rim. The matrix of the rounded, dark inclusions consists of Si-rich glass and microcrystalline calcite. The latter is characterized by high contents of Si and Al suggesting rapid crystallization of the calcite from a melt. Backscattered electron imagery shows textural evidence for liquid immiscibility between the CaCO3-rich and Si-rich glass of the matrix in the form of intermingling of calcite with Si-rich glass, coalesced blebs within silicate glass, individual calcite blebs within Si-rich glass, carbonate spherical globules in fresh Si-rich-glass, and sharp menisci between silicate and calcite blebs. These features are interpreted as evidence of impact melting of limestone and flint. The low totals of the Si-Al-Mg-rich glasses suggest that they contain significant amounts of volatiles. X-ray diffraction analyses indicate partial alteration of the Si-Mg-Al-rich glass to phyllosilicates.  相似文献   
39.
Human activities have progressively increased in recent years. Consequently, significant environment deterioration resulted. Soils have a particularly varied vulnerability to heavy metal pollution, especially in the vicinity of industrial areas. Heavy metal contamination of soil may induce risks and hazards to humans and the ecosystem, while toxic metals in soil can severely inhibit the biodegradation of organic contaminants. This paper is focused on human health risk assessment from extremely contaminated soil with heavy metals, mainly with carcinogenic elements. The study refers to an agricultural area in the vicinity of an old metallurgical processing industrial facility. The contaminants evaluated in the present paper are beryllium (Be), cadmium (Cd), chromium (Cr), nickel (Ni) and lead (Pb). Contamination level is pointed out through laboratory analysis results of soil samples taken from 0–0.2 m, 0.2–0.4 m soil layers and up to 2.1 m soil depth. Some heavy metal concentrations (Cd, Cr and Pb) exceed the intervention thresholds for sensitive areas, as they are stipulated in the national regulation in Romania. The identified average concentration levels of Cd, CrVI and Pb in the first layer of the investigated land are 23.83, 7.71 and 704.22 mg/kgd.w, respectively. The results show that the potential risk of human health is relevant (higher than the acceptable one after World Health Organization) and a possible solution for the remediation should become a major concern for the investigated area.  相似文献   
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