Cooling history of lunar Mg-suite gabbronorite 76255, troctolite 76535 and Stillwater pyroxenite SC-936: The record in exsolution and ordering in pyroxenes     

I. Stewart McCallum  M. Chiara Domeneghetti  Jeffrey M. Schwartz  Emily K. Mullen  Michele Zema  Fernando Cmara  Catherine McCammon  Jibamitra Ganguly 《Geochimica et cosmochimica acta》2006,70(24):6068-6078

We have determined cooling rates of orthopyroxene crystals from two Mg-suite lunar samples (gabbronorite 76255 and troctolite 76535) and one terrestrial sample (orthopyroxenite SC-936 from the Stillwater Complex), on the basis of their Fe–Mg ordering states. In addition, a cooling rate of 76255 was determined by modeling the formation of exsolution lamellae in pyroxenes. The M1–M2 site occupancies of the orthopyroxene crystals were determined by single crystal X-ray diffraction and the rate constant for the ordering reaction was used along with calibrations of the equilibrium intracrystalline fractionation of Fe and Mg as a function of temperature to calculate cooling rates. The closure temperatures (T_C) of cation ordering are 525 °C for 76255, 500 °C for 76535 and 350 °C for SC-936 corresponding to cooling rates of 4 × 10⁻² °C/year at the closure temperature for the lunar samples and 10⁻⁶ °C/year for the Stillwater sample. A cooling rate for 76255, determined by simulating the exsolution process, is 1.7 × 10⁻² °C/year at a closure temperature for exsolution of 700 °C. The Fe–Mg ordering cooling rate determined for 76535 reflects a complex thermal history superimposed on the initial plutonic provenance established for this sample [McCallum, I.S., Schwartz, J.M., 2001. Lunar Mg suite: thermobarometry and petrogenesis of parental magmas. J. Geophys. Res. 106, 27969–27983]. The preservation of a crystallization age of 4.51 Ga and a metamorphic age of 4.25 Ga for 76535 is consistent with a model in which excavation of this sample from the lower lunar crust took place while the sample was at a temperature above the closure temperatures for the Sm–Nd, U–Pb and Ar–Ar isotopic systems. Temperatures in excess of the isotopic closure temperatures (i.e., >600 °C) in the lower lunar crust were maintained by heat diffusing from concentrations of U- and Th-rich KREEP material at the base of the crust. On the other hand, 76255 formed at a much shallower depth in the lunar crust (2 km) and was well below its isotopic closure temperatures at the time of excavation, most likely during the Serenitatis basin-forming impact event. Both lunar samples were reheated during transport to the surface and deposition in hot ejecta blankets. The reheating was short lived but apparently sufficient to redistribute Fe and Mg in M sites in orthopyroxenes. For the lunar samples, the cooling rates based on Fe–Mg ordering represent final stage cooling within an ejecta blanket.  相似文献   

Thermodynamics of the oxygen isotope fractionation involving plagioclase     

Jibamitra Ganguly 《Earth and Planetary Science Letters》1982,61(1):123-126

The thermodynamic relationship between the oxygen isotope fractionation properties of plagioclase and its composition has been derived by treating plagioclase as a “reciprocal solution” consisting of independent cationic and anionic substitutions, namely (NaAl)⁵⁺?(CaSi)⁵⁺and¹⁸O?¹⁶O. The results show that the logarithm of the oxygen isotope fractionation factor, α, between plagioclase and a coexisting phase varies linearly with the anorthite content of plagioclase. The proportionality constant is given by the oxygen isotope fractionation factor between albite and anorthite, and has been derived from the experimental data of two groups of workers, O'Neil and Taylor [2] and Matsuhisa et al. [3], on the isotopic fractionation between each plagioclase end-member and aqueous solutions. It is found that O'Neil and Taylor's data on isotopic exchange of plagioclase end-members with only 2–3 M chloride solution, rather than with both pure water and the chloride solution, lead essentially to zero intercept of the ln α(Ab-An) vs. 1/T² relation, in accord with Bottinga and Javoy's [10] conclusion about the oxygen isotope fractionation between two anhydrous silicates at T<500°C.  相似文献   

A Subwaveform-Based Retracker for Multipeak Waveforms: A Case Study over Ukai Dam/Reservoir     

Debojyoti Ganguly  Shard Chander  Shruti Desai  Prakash Chauhan 《Marine Geodesy》2015,38(3):581-596

Retracking altimeter waveforms over inland water bodies is a challenging task as a wide range of waveform is encountered while the retracking algorithms are available only for a handful of echo shapes. One such waveform shape widely encountered in lakes and reservoirs is the multipeak echo. These echoes are produced when the interacting surface in the altimeter footprint is not homogeneous and a number of different types of surfaces contribute to the resulting waveform. The widely used conventional retrackers, namely the Brown, Beta-5, Ice-2, OCOG, and threshold, can retrack a number of different waveform shapes such as the Brown like waveforms, specular waveforms, and rectangular waveforms but may not perform well for multipeak waveforms. In this article, a technique has been demonstrated to identify the different subwaveforms within a multipeak waveform and identify the subwaveform corresponding to the target at nadir. The subwaveform that is reflected from the nadir surface is identified from apriory information about the surface topography of the area. The subwaveform is then retracked using the 50% threshold to find the correct retracked range and water height. This technique has been tested for nine cycles of SARAL SIGDR data on Ukai reservoir, Gujarat, India, and found to perform much better than the other retrackers, particularly for multipeak waveforms.  相似文献   

Analytical solutions for transient temperature distribution in a geothermal reservoir due to cold water injection     

Sayantan Ganguly  M. S. Mohan Kumar 《Hydrogeology Journal》2014,22(2):351-369

An analytical solution to describe the transient temperature distribution in a geothermal reservoir in response to injection of cold water is presented. The reservoir is composed of a confined aquifer, sandwiched between rocks of different thermo-geological properties. The heat transport processes considered are advection, longitudinal conduction in the geothermal aquifer, and the conductive heat transfer to the underlying and overlying rocks of different geological properties. The one-dimensional heat transfer equation has been solved using the Laplace transform with the assumption of constant density and thermal properties of both rock and fluid. Two simple solutions are derived afterwards, first neglecting the longitudinal conductive heat transport and then heat transport to confining rocks. Results show that heat loss to the confining rock layers plays a vital role in slowing down the cooling of the reservoir. The influence of some parameters, e.g. the volumetric injection rate, the longitudinal thermal conductivity and the porosity of the porous media, on the transient heat transport phenomenon is judged by observing the variation of the transient temperature distribution with different values of the parameters. The effects of injection rate and thermal conductivity have been found to be profound on the results.  相似文献