The Behavior of Mixed Ca–Mn Carbonates in Water and Seawater: Controls of Manganese Concentrations in Marine Porewaters     

Alfonso Mucci 《Aquatic Geochemistry》2004,10(1-2):139-169

The dissolution behavior of natural, ordered kutnahorite (Mn_1.14Ca_0.82Mg_0.04Fe_0.012(CO₃)₂) and a disordered, calcian rhodochrosite (Mn_1.16Ca_0.78Mg_0.06(CO₃)₂) precipitated in the laboratory was investigated in deionized distilled water and artificial seawater in both open and closed systems at 25 °C, one atmosphere total pressure, and various pCO₂s. Both solids dissolved congruently in distilled water in an open system and yielded identical long-term equilibration or extrapolated ion activity products, IAP_pkt = a_Ca ²⁺a_Mn ²⁺(a_{CO 3} ^2?)² = 1.7 (±0.12)× 10^?21 or pIAP_pkt = 20.77 (±0.03). This value is believed to be the thermodynamic solubility product of pseudokutnahorite. In contrast, the steady state ion concentration products, ICP_pkt = [Ca²⁺][Mn²⁺][CO₃ ^2?]², measured following the dissolution of both minerals in artificial seawater increase as the CO₂ partial pressure decreases and the [Mn²⁺]:[Ca²⁺] ratio increases. These observations are interpreted as resulting from the formation of phases of different stoichiometry in response to large variations of the [Mn²⁺]:[Ca²⁺] ratio in solution. These data and results of calcite-seawater equilibration experiments in the presence of various dissolved Mn(II) concentrations define the fields of stability of manganoan calcites and calcian rhodochrosites in seawater within Lippmann phase diagrams for the CaCO₃–MnCO₃–H₂O system. Results of this study reveal that the nature (i.e., mineralogy) and composition of manganese-rich carbonate phases that may form under suboxic/anoxic conditions in marine sediments are dictated by the porewater [Mn²⁺]:[Ca²⁺] ratio, the abundance of calcite surfaces and reaction kinetics.  相似文献   

Sedimentary aspects and paleoenvironmental evolution of a rift basin: Salta Group (Cretaceous–Paleogene), northwestern Argentina     

Rosa A. Marquillas  Cecilia del Papa  Ignacio F. Sabino 《International Journal of Earth Sciences》2005,94(1):94-113

The rift history of the Salta basin is related to the evolution of the Central Andes and to the activity of the Pacific margin, owing to its geographic location. Sedimentation occurred from the Neocomian to the Paleogene, with deposits reaching up to 5,000 m in thickness. Paleoenvironmental analysis reveals an evolutionary history controlled by tectonic and climatic changes. Isolated grabens characterized the early synrift stage; differential subsidence provoked distinct environments in the southern and northern subbasins. In the southern subbasins, alluvial-fan, fluvial-fan and lacustrine deposits prevail, whilst in the northern subbasins eolian and fluvial environments dominate. During the Maastrichtian, two major factors controlled the basin fill: the decrease in tectonic subsidence and a relative sea-level rise as recorded in South America. An extensive and shallow Atlantic marine ingression installed a carbonate system coincident with mainly humid conditions until the Danian. Until the Middle Eocene, the fluvial and lacustrine environmental evolution of the sag basin was controlled especially by the alternation of temperate with dry and humid periods. Paleontological records reflect these climatic changes and show their relationship to the sedimentation regime.  相似文献   

Segmentation and kinematics of the North America‐Caribbean plate boundary offshore Hispaniola          下载免费PDF全文

Sylvie Leroy  Nadine Ellouz‐Zimmermann  Jordane Corbeau  Frédérique Rolandone  Bernard Mercier de Lépinay  Bertrand Meyer  Roberte Momplaisir  José‐Luis Granja Bruña  Anne Battani  Céline Baurion  Evgueni Burov  Valérie Clouard  Rémy Deschamps  Christian Gorini  Youri Hamon  Manfred Lafosse  Jottin Leonel  Laetitia Le Pourhiet  Pilar Llanes Estrada  Nicolas Loget  Francis Lucazeau  Daniel Pillot  Jeffrey Poort  Kevin R. Tankoo  José‐Luis Cuevas  José‐Fernando Alcaide  Claude Jean Poix  Alfonso Muñoz‐Martin  Serge Mitton  Yamil Rodriguez  Julien Schmitz  Leonardo Seeber  Andres Carbo‐Gorosabel  Santiago Muñoz 《地学学报》2015,27(6):467-478

We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a^?1 has remained stable during the entire Quaternary.  相似文献   

ESEEM of industrial silica-bearing powders: reactivity of defects during wet processing in the ceramics production     

Maurizio Romanelli  Francesco Di Benedetto  Gabriele Fornaciai  Massimo Innocenti  Giordano Montegrossi  Luca A. Pardi  Alfonso Zoleo  Fabio Capacci 《Physics and Chemistry of Minerals》2015,42(5):363-372

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Dynamics of the January 2013–June 2014 explosive-effusive episode in the eruption of Volcán de Colima,México: insights from seismic and video monitoring     

Vyacheslav M. Zobin  Raúl Arámbula  Mauricio Bretón  Gabriel Reyes  Imelda Plascencia  Carlos Navarro  Armando Téllez  Arnoldo Campos  Miguel González  Zoraida León  Alejandro Martínez  Carlos Ramírez 《Bulletin of Volcanology》2015,77(4):1-13

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Effect of rainfall uncertainty on the performance of physically based rainfall–runoff models     

Ignacio Fraga  Luis Cea  Jernimo Puertas 《水文研究》2019,33(1):160-173

This paper analyses the effect of rain data uncertainty on the performance of two hydrological models with different spatial structures: a semidistributed and a fully distributed model. The study is performed on a small catchment of 19.6 km² located in the north‐west of Spain, where the arrival of low pressure fronts from the Atlantic Ocean causes highly variable rainfall events. The rainfall fields in this catchment during a series of storm events are estimated using rainfall point measurements. The uncertainty of the estimated fields is quantified using a conditional simulation technique. Discharge and rain data, including the uncertainty of the estimated rainfall fields, are then used to calibrate and validate both hydrological models following the generalized likelihood uncertainty estimation (GLUE) methodology. In the storm events analysed, the two models show similar performance. In all cases, results show that the calibrated distribution of the input parameters narrows when the rain uncertainty is included in the analysis. Otherwise, when rain uncertainty is not considered, the calibration of the input parameters must account for all uncertainty in the rainfall–runoff transformation process. Also, in both models, the uncertainty of the predicted discharges increase in similar magnitude when the uncertainty of rainfall input increase.  相似文献   

A multi-tracer approach to delineate groundwater dynamics in the Rio Actopan Basin,Veracruz State,Mexico     

Juan Pérez Quezadas  Victor M. Heilweil  Alejandra Cortés Silva  Luis Araguas  María del Rocío Salas Ortega 《Hydrogeology Journal》2016,24(8):1953-1966

Geochemistry and environmental tracers were used to understand groundwater resources, recharge processes, and potential sources of contamination in the Rio Actopan Basin, Veracruz State, Mexico. Total dissolved solids are lower in wells and springs located in the basin uplands compared with those closer to the coast, likely associated with rock/water interaction. Geochemical results also indicate some saltwater intrusion near the coast and increased nitrate near urban centers. Stable isotopes show that precipitation is the source of recharge to the groundwater system. Interestingly, some high-elevation springs are more isotopically enriched than average annual precipitation at higher elevations, indicating preferential recharge during the drier but cooler winter months when evapotranspiration is reduced. In contrast, groundwater below 1,200 m elevation is more isotopically depleted than average precipitation, indicating recharge occurring at much higher elevation than the sampling site. Relatively cool recharge temperatures, derived from noble gas measurements at four sites (11–20 °C), also suggest higher elevation recharge. Environmental tracers indicate that groundwater residence time in the basin ranges from 12,000 years to modern. While this large range shows varying groundwater flowpaths and travel times, ages using different tracer methods (¹⁴C, ³H/³He, CFCs) were generally consistent. Comparing multiple tracers such as CFC-12 with CFC-113 indicates piston-flow to some discharge points, yet binary mixing of young and older groundwater at other points. In summary, groundwater within the Rio Actopan Basin watershed is relatively young (Holocene) and the majority of recharge occurs in the basin uplands and moves towards the coast.  相似文献   

Linear discriminant analysis to describe the relationship between rainfall and landslides in Bogotá, Colombia   总被引：1，自引：0，他引：1  

Alfonso Mariano Ramos-Cañón  Luis Felipe Prada-Sarmiento  Mario Germán Trujillo-Vela  Juan Pablo Macías  Ana Carolina Santos-R 《Landslides》2016,13(4):671-681

Bogotá is located in the central Andean region of Colombia, which is frequently affected by landslide processes. These processes are mostly triggered during the rainy season in the city. This fact remarks the importance of determining what rain-derived parameters (e.g. intensity, antecedent rain, daily rain) are better related with the occurrence of landslides. For this purpose, the linear discriminant analysis (LDA), a technique derived from multivariate statistics, was used. The application of this type of analysis led to obtain simple mathematical functions that represent the probability of occurrence of landslides in Bogotá. The functions also allow to identify the most relevant variables derived from records of rainfall linked to the generation of landslides. A proof of concept using the proposed methodology was done using historic rainfall data from a 9-km² area of homogenous climatology and geomorphology in the south part of Bogotá. Landslides needed to be grouped for the LDA. Each one of these grouping categories represents landslides that occurred in similar geomorphologic conditions. Another set of events with no landslides was generated synthetically. Results of the proof of concept show that rainfall parameters such as normalized rainfall intensity I _MAP, normalized daily rainfall R _MAP and rainy-days normal RDN have the best statistical correlation with the landslides observed in the zone of analysis.  相似文献   

Spatial characterization of the seawater upconing process in a coastal Mediterranean aquifer (Plana de Castellón,Spain): evolution and controls     

Olga García-Menéndez  Ignacio Morell  Bruno J. Ballesteros  Arianna Renau-Pruñonosa  Alejandra Renau-Llorens  Mª Vicenta Esteller 《Environmental Earth Sciences》2016,75(9):728

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Deep seismic exploration of the Iberian Microplate     

Juvenal Andres  David Marti  Ignacio Marzan  Imma Palomeras  Puy Ayarz  Fernando Simancas  DavidMartinez-Poyatos  Antonio Azor  Francisco Gonzalez-Lodeiro?  Jordi Diaz  Ramon Carbonel 《《地质学报》英文版》2018,92(Z1):11-11

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