Multi-method characterization of DOM from the Turia river (Spain)     

Sergio Navalon  Mercedes Alvaro  Isabel Alcaina  Hermenegildo Garcia 《Applied Geochemistry》2010

Water concentrates from Turia river (1.5 mg L⁻¹ total organic C) obtained by nanofiltration (membrane mass cut-off 90 Da) were fractioned by non-ionic Amberlite resins (DAX8 and XAD4) to afford three samples termed as hydrophobic acid (50%), transphilic acid (24%) and hydrophobic neutral (12%). If a nanofiltration membrane 270 Da mass cut-off is used then about 50% of dissolved organic matter is not retained. These three fractions were characterized by analytical and spectroscopic techniques (¹H NMR, MALDI–TOF-MS, ESI–API-MS, ESI–MS/MS). Overall, these data are compatible with the presence of oligosaccharides, oligopeptides and fatty acids as the main components of dissolved organic matter. Particularly revealing was the information from MALDI–TOF-MS and ESI–MS/MS where series of compounds differing in the number of hexose units were identified. The three fractions have many spectroscopic similarities and, particularly the hydrophobic and transphilic ones, are really almost identical. This similarity in the fraction composition shows that the conventional fractionation procedure is inefficient as a standard general method for separation of different compound types. The composition of dissolved organic matter was confirmed, and some individual organic compounds identified, by GC–MS analysis of the silylated derivatives obtained by reacting the fractions with a mixture of N,O-bis(trimethylsilyl)trifluoroacetamide with trimethylchlorosilane (10%). Thus, rather surprisingly, the dissolved organic matter of this natural raw water is predominantly composed of a relatively simple mixture of a few types of compounds with molecular weights well below 1100 Da (about six hexose units). These results, particularly the absence of detectable amounts of high molecular weight humic acids and low molecular weight phenolic compounds indicates that trihalomethanes formed in the water disinfection process by Cl₂ really derive from oligosaccharides and oligopeptides. Also, the data suggests alternative strategies to effect a more efficient fractionation of the dissolved organic matter.  相似文献   

Estimation of industrial and commercial asset values for hazard risk assessment   总被引：1，自引：0，他引：1  

Isabel Seifert  Annegret H. Thieken  Mirjam Merz  Dietmar Borst  Ute Werner 《Natural Hazards》2010,52(2):453-479

For risk analyses not only knowledge about the impact of different types of hazards, but also information about the elements and values at risk is necessary. This article introduces a methodology for a countrywide estimation of asset values for commercial and industrial properties using Germany as an example. It consists of a financial appraisal of asset values on the municipal level and a further disaggregation by means of land use data. Novelties are the distinction of 60 economic activities, the consideration of production site sizes and the application of a dasymetric mapping technique for a sector-specific estimation and disaggregation of asset values. A validation with empirical data confirms the feasibility of the calculation. The resulting maps can be used for loss estimations e.g. in the framework of cost–benefit analyses that aim to evaluate hazard mitigation measures or for portfolio analyses by banks and insurance companies. The approach can be used for other countries if the necessary data is available (mainly in industrialized countries). In any case, it reveals the critical points when estimating commercial and industrial asset values.  相似文献   

Variability of extreme events in the Colombian Pacific and Caribbean catchment basins     

Isabel Hoyos  Astrid Baquero-Bernal  Daniela Jacob  Boris A. Rodríguez 《Climate Dynamics》2013,40(7-8):1985-2003

This paper analyses the behavior of extreme events of surface precipitation and temperature inside the Pacific and Caribbean Catchment Basins in Colombia using several datasets such as observations, reconstructed data, NCEP-NCAR and ERA-40 reanalyses and data from the regional model REMO. We use an extreme value method that selects the time series excesses over a nonstationary threshold and adjusts them to a generalized Pareto distribution. The goodness of fit is evaluated through a test that includes the Cramer–von Mises, Kolmogorov–Smirnov and Anderson–Darling statistics and the p values generated by parametric bootstrap resampling. The test not only evaluates the goodness of fit but also the threshold choice. The parameters are presented in maps that allow recognition of the features of the extreme behaviour inside the catchment basins, and differences and similarities between them. Maps of return periods for the maximum extreme events are also presented. A strong influence of the El Niño–Southern oscillation on the extreme events of both temperature and precipitation is found in the two catchment basins.  相似文献   

The phase 0/A study of the ESA M3 mission candidate EChO     

Ludovic Puig  Kate Isaak  Martin Linder  Isabel Escudero  Pierre-Elie Crouzet  Roger Walker  Matthias Ehle  Jutta Hübner  Rainer Timm  Bram de Vogeleer  Pierre Drossart  Paul Hartogh  Christophe Lovis  Giusi Micela  Marc Ollivier  Ignasi Ribas  Ignas Snellen  Bruce Swinyard  Giovanna Tinetti  Paul Eccleston 《Experimental Astronomy》2015,40(2-3):393-425

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Microzooplankton feeding impact in a coastal upwelling system on the NW Iberian margin: The Ría de Vigo     

Isabel G. Teixeira  Francisco G. Figueiras  Bibiana G. CrespoSílvia Piedracoba 《Estuarine, Coastal and Shelf Science》2011

The dilution technique, combined with identification and enumeration of pico-, nano- and micro-plankton by microscopy, was used to estimate microzooplankton impact on the microbial community in surface waters of a coastal embayment on the NW Iberian upwelling system. Microzooplankton were important consumers of autotrophic and heterotrophic plankton in this system, feeding up to 93% of standing stock and more than 100% of production of several groups. Heterotrophic bacteria and heterotrophic picoflagellates experienced the highest and constant impact, with 75–84% of their standing stocks and 85–102% of their production being channelled through the microbial food web. Pico- and nano-phytoplankton were also consumed, although maximum grazing occurred on diatoms during upwelling events, coinciding with highest primary production. Predation on pico-nano-heterotrophs was especially relevant under downwelling conditions, when consumption of total carbon and particularly autotrophic carbon was considerably lower than during upwelling. The results suggest that the existence of a multivorous food web, extending from the microbial loop to the herbivorous food web, could be a major feature in this coastal upwelling system. The microbial loop, which occurs as a permanent background in the system, would contribute to sustain the microbial food web during downwelling, whereas the herbivorous food web could coexist with a microbial food web based on large diatoms during upwelling. The multivorous food web would partially divert diatoms from sinking and hence favour the retention of organic matter in the water column. This could enhance the energy transfer to higher pelagic trophic levels in coastal upwelling systems.  相似文献   

Palaeoenvironmental evolution and sea‐level fluctuations along the southeastern Pampa grasslands coast of Argentina during the Holocene     

Isabel Vilanova  Aldo R. Prieto  Marcela Espinosa 《第四纪科学杂志》2006,21(3):227-242

Holocene pollen and diatom analyses and complementary data from δ¹⁸O and δ¹³C, malacology and sedimentology have provided a detailed record of vegetation history and palaeoenvironmental change at arroyo Las Brusquitas, on the southeastern coast of the pampas of Argentina especially in relation to past sea levels. Holocene palaeosalinity trends were estimated by Detrended Correspondence Analysis and by salinity indexes based on pollen and diatom data. As a consequence of sea‐level rise from the postglacial an extensive wave‐cut platform formed over which Holocene infilling sequences were deposited unconformably. In these sequences, variation in pollen and diatom assemblages occurred in agreement with changes in mollusc diversity and abundance, isotope values, and sediment deposits. Between ca. 6700 and 6190 ¹⁴C yr BP (6279–6998 cal. yr BP) saline conditions predominated in an environment highly influenced by tides and salt water during the Holocene sea‐level highstand. Between ca. 6200 and 3900 ¹⁴C yr BP (4235–4608 cal. yr BP) shallow brackish water bodies formed surrounded by saltmarsh vegetation that became more widespread from 5180 ¹⁴C yr BP (5830–6173 cal. yr BP) to 3900 ¹⁴C yr BP in relation to a sea‐level stabilisation period within the regression phase. Less saline conditions marked by frequent variations in salinity predominated between ca. 3900 and 2040 yr ¹⁴C BP (1830–2160 cal. yr BP). The intertidal saltmarsh environment changed into a brackish marsh dominated by freshwater conditions and sporadic tidal influence. Halophytic vegetation increased towards ca. 2000¹⁴C yr BP indicating that saline conditions may be due to either desiccation or an unusually high tide range with rare frequency. After ca. 2000 ¹⁴C yr BP the sedimentary sequences were buried by aeolian sand dunes. Changes in Holocene vegetation and environments in Las Brusquitas area are in agreement with data obtained from various southeastern coastal sites of the Pampa grasslands. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Chemical availability of arsenic and heavy metals in sediments from abandoned cinnabar mine tailings   总被引：1，自引：1，他引：0  

Raquel Larios  Rodolfo Fernández-Martínez  Verónica Silva  Isabel Rucandio 《Environmental Earth Sciences》2013,68(2):535-546

The understanding of the solid-phase speciation of arsenic in soils and sediments is important in the evaluations of its potential mobility and availability in the environment. The spoil heaps of abandoned mercury mines contain waste materials with high arsenic and heavy metals concentrations. The weathering of these tailings can cause their mobilization to the surroundings. In this work, the mobility and availability of arsenic and some heavy metals were evaluated in sediments from two heavily polluted mercury mining districts in Asturias (NW Spain). For this purpose, a slightly modified version of the Bureau Community of Reference sequential extraction scheme was applied to sediments. The total contents in the operationally defined fractions were analysed by inductively coupled plasma-atomic emission spectrometry. Extremely high total arsenic concentrations were found in all sediments ranging from 4,000 to 24,800 mg kg^?1. High easily mobilizable arsenic contents were found in the first mining area, related to the solubilization of Ca-bearing phases, supported by extracts analyses, X-ray diffraction results and the positive correlation found among the As and Ca fractionations. Ni and Zn were the most mobile among heavy metals, being Cr the least mobile, suggesting an anthropogenic origin due to the metallurgical processes, transport or dispersion generated from neighbour spoil heaps. In the second mining area, the bulk of As was concentrated in the residual phase, as well as Cr, Cu, Fe, Pb, Ti, indicating a mineralogical origin and the low availability of these elements. The strong correlations established between As and Fe and Ti distributions support the hypothesis that As is mainly associated to structural mineral phases in these sediments.  相似文献   

Different levels of macroalgal sampling resolution for pollution assessment     

Isabel Díez  Alberto Santolaria  José María Gorostiaga 《Marine pollution bulletin》2010,60(10):1779-1789

The effects of using reduced sampling resolutions to study macroalgal vegetation patterns have not been studied sufficiently. Here, we test the influence of taxonomic resolution level, removal of occasional species, aggregation of species abundances into functional groups and data transformation in the detection of a long-term recovery process by phytobenthic intertidal assemblages. Results indicate that the aggregation of species data into the genus level has very little influence. Likewise, almost any significant information is lost when occasional algae are removed. Analyses at the level of families and orders still clearly detect differences between highly degraded and reference vegetation. By contrast, analyses based on class and functional group abundances capture quite different information. The effect of transformation is similar at the different taxonomic levels. Most surrogate measures properly reflect changes in diversity. It is concluded that genus level is the most appropriate surrogate approach for detecting the recovery process.  相似文献   

Variation in transparent exopolymer particles in relation to biological and chemical factors in two contrasting lake districts     

Inmaculada de Vicente  Eva Ortega-Retuerta  Ignacio P. Mazuecos  Michael L. Pace  Jonathan J. Cole  Isabel Reche 《Aquatic Sciences - Research Across Boundaries》2010,72(4):443-453

In inland waters, transparent exopolymer particles (TEP) can affect carbon export and sequestration in sediments with consequences for lake C budgets. We measured TEP concentration in 32 lakes from two contrasting lake districts covering wide ranges in biological and chemical characteristics. North temperate lakes, located in a wet region, have low to moderate ionic strength and low to high dissolved organic carbon with corresponding variation in color (light absorbance). Mediterranean lakes located in a semiarid region were characterized by high ionic strength and high concentrations of dissolved organic carbon but low color. TEP concentrations were large relative to the living portion of the particulate organic carbon pool in both Mediterranean (36%) and north temperate (33%) lakes. TEP concentrations ranged from 36 to 1,462 μg [as Gum Xanthan equivalents (GX eq)] L⁻¹ in north temperate lakes. In the Mediterranean lakes, concentrations were higher that previously reported for other systems and ranged from 66 to 9,038 μg GX eq L⁻¹. TEP concentration was positive and significantly related to chlorophyll a (chl a) in north temperate lakes and in the entire data set. Although a significant and positive relationship between TEP and chl a was also detected in the Mediterranean lakes, bacterial abundance was most strongly related to TEP. In contrast with the positive influence of phytoplankton and bacteria on TEP, there were weaker relationships between TEP and the chemical variables tested. We observed a significant and positive relationship between pH and TEP (for all lakes) but this relationship was indirectly driven by a co-variation of pH with phytoplankton biomass based on multiple regression analysis. For the Mediterranean lakes, the negative (but not significant) trends between TEP and both conductivity and divalent cations suggest thresholds above which TEP will likely be destabilized. Under these conditions, TEP may flocculate or disperse in the water column.  相似文献   

Implications of flow intermittency on sediment nitrogen availability and processing rates in a Mediterranean headwater stream     

María Isabel Arce  María del Mar Sánchez-Montoya  María Rosario Vidal-Abarca  María Luisa Suárez  Rosa Gómez 《Aquatic Sciences - Research Across Boundaries》2014,76(2):173-186

Most streams draining to the Mediterranean basin are temporary. As a result of their hydrological regime, temporary streams are affected by drying and rewetting periods. Drying can alter in-stream nitrogen (N) availability and reduce N processing rates and subsequent retention after re-wetting. We sought to determine if hydrologic drying modifies reach-scale sediment chemical properties and constrains the response of N processing to rewetting. We compared different abiotic characteristics of sediments and nitrification and denitrification rates between a perennial and intermittent reach in the same stream over a wet period, when surface water flowed in both reaches, and a dry period, when the intermittent reach dried up. We analyzed N processing rates by incubating sediments with stream water, thereby simulating a rewetting when sediments from the intermittent reach were dry. We found that drying increased the sediment nitrate (NO₃ ^?) content. Conversely, drying did not reduce the recovery of N processing rates to pre-dry levels after simulated flooding conditions. Our results suggest that dry reaches may act as a potential NO₃ ^? source by releasing downstream NO₃ ^? pulses after stream flow recovery. Given the European Water Framework Directive requirements to assess stream ecological status, these N pulses following rewetting should be considered when designing management plans in temporary streams. Our study highlights the rapid response of in-stream N processing to rewetting period following a drought. This high resilience to process N should be seen as a vital ecosystem service provided by temporary streams despite annual dry periods.  相似文献