Influence of IHSS Standard and Reference Materials on Copper and Mercury Toxicity to Vibrio fischeri     

James J. Alberts  Monika Takcs  Mala Pattanayek 《洁净——土壤、空气、水》2001,28(7):428-435

The reduction in light emission of the marine bacterium Vibrio fischeri used in the standard Microtox^® bioassay was measured for the metals copper and mercury. The concentration at which the light emission was reduced by 50% (EC₅₀) was determined to be (3.43 ± 0.83) μmol/L for Cu²⁺ and (0.66 ± 0.01) μmol/L for Hg²⁺. The reduction of the toxicity of these metals by humic and fulvic acids were studied using IHSS Standard and Reference Materials. Copper toxicity was reduced 17...20% by the soil and peat fulvic acids and 9...20% by the aquatic fulvic acids. While there appeared to be little difference in the reduction of Cu toxicity by fulvic acids from soils, peats, or aquatic systems, Hg toxicity was reduced 3.6...7.3% by the soils and peats, while aquatic fulvic acids reduced Hg toxicity 14...16%. Soil fulvic acids appear to have significantly less capacity to reduce Hg toxicity than Cu toxicity. Humic acids had much higher reductions of Cu toxicity (44...124%) compared to the fulvic acids, with little difference between aquatic and soil or peat humic acids, 44...124% and 67...100%, respectively. However, humic and fulvic acids, regardless of origin, had approximately the same effect on Hg toxicity with 3.5...16% reduction by fulvic acids and 8...20% reduction by humic acids. Unlike the fulvic acids, no clear trend was observed relative to origin of the humic acids. There was no correlation between percent reduction of Cu or Hg toxicity by the organic compounds and copper binding capacity (CuBC), C/N ratio, or carboxyl content of the materials. Examination of natural organic matter (NOM) isolated by reverse osmosis techniques from three water sources had reductions of both Cu and Hg toxicity that were most similar to the Suwannee River and Nordic fulvic acids.  相似文献   

Editorial     

James Scourse 《第四纪科学杂志》2000,15(1):1-1

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Turbidity and suspended sediment dynamics in small catchments in the Nepal Middle Hills     

James Brasington  Keith Richards 《水文研究》2000,14(14):2559-2574

The Himalayan environment has, until recently, been perceived to be in a critical state of environmental decline, resulting from rapid population growth and associated land‐use change. Recent research, however, has emphasized the difficulty of developing an objective appraisal of the state of the environment in a region where empirical data are scarce and unstructured and where an understanding of the spatial and temporal dynamics of natural environmental processes remains highly uncertain. This paper presents results from an intensive three‐year project designed to help address the regional empirical deficit, establish detailed baseline environmental data and to gain an insight into storm period and seasonal suspended sediment dynamics. The instrumentation, calibration and analysis of high‐frequency infrared turbidimetric records from a number of small subcatchments in the Nepal Middle Hills are reported. Storm period and seasonal variation in turbidity and suspended sediment are examined and hysteresis patterns explored and explained. A variety of methods to estimate seasonal suspended sediment yield in a mixed land‐use catchment are examined, and found to vary by up to a factor of five. Despite the inherent uncertainty, all estimates of catchment sediment yield are found to be high with respect to erosion plot studies from the local area, and this suggests the importance of riparian and channel erosion as major sediment sources, a finding consistent with other regional studies. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

The use of caesium‐137 to estimate agricultural erosion on steep slopes in a tropical watershed     

Gregory N. Nagle  James P. Lassoie  Timothy J. Fahey  Sherwood C. McIntyre 《水文研究》2000,14(5):957-969

The estimation of erosion and sediment delivery rates in tropical mountain watersheds is difficult and most of the methods widely used for estimating soil erosion over large areas have serious limitations. The ¹³⁷Cs approach has potential for quantifying soil erosion because it can provide retrospective estimates of long‐term (since 1963) net sediment redistribution relatively quickly. Despite its great potential, ¹³⁷Cs has not yet been used in an extensive, reconnaissance level survey of erosion in complex tropical mountain environments. The objective of this study was to examine the applicability of the ¹³⁷Cs method to estimate erosion on steep tropical agricultural lands (23 to 80% slopes) in the Nizao watershed, a humid, tropical mountain area of the Dominican Republic. In this study we (i) examine the variation of ¹³⁷Cs in ten reference sites—eight coffee groves and two forested sites—and (ii) estimate erosion from 14 cultivated fields. The soil pool of ¹³⁷Cs ranged from to 150 to 192 mBq cm⁻² on reference sites with minimal erosion. Variability among reference sites was less than expected for such complex mountain terrain. The variability within coffee and forested reference (average CV=28%) sites was similar to the variability found on grassland and forested reference sites in the temperate zone. The estimated annual soil loss from 14 sampled fields ranged from 6 to 61 t ha⁻¹ year⁻¹ with an overall mean of 26 t ha⁻¹ year⁻¹. Overall, the soil erosion estimates found using the ¹³⁷Cs method were much lower than those often assumed for such steep tropical hillsides. These erosion estimates account for soil loss since 1963 only and it seems likely that soil losses may have been much higher in earlier decades immediately after initial forest clearing earlier in the 20th century. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

Geochemistry of the Springfield Plateau aquifer of the Ozark Plateaus Province in Arkansas,Kansas, Missouri and Oklahoma,USA     

James C. Adamski 《水文研究》2000,14(5):849-866

Geochemical data indicate that the Springfield Plateau aquifer, a carbonate aquifer of the Ozark Plateaus Province in central USA, has two distinct hydrochemical zones. Within each hydrochemical zone, water from springs is geochemically and isotopically different than water from wells. Geochemical data indicate that spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Water type throughout most of the aquifer was calcium bicarbonate, indicating that carbonate‐rock dissolution is the primary geochemical process occurring in the aquifer. Concentrations of calcium, bicarbonate, dissolved oxygen and tritium indicate that most ground water in the aquifer recharged rapidly and is relatively young (less than 40 years). In general, field‐measured properties, concentrations of many chemical constituents, and calcite saturation indices were greater in samples from the northern part of the aquifer (hydrochemical zone A) than in samples from the southern part of the aquifer (hydrochemical zone B). Factors affecting differences in the geochemical composition of ground water between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zone A than in zone B. In addition, specific conductance, pH, alkalinity, concentrations of many chemical constituents and calcite saturation indices were greater in samples from wells than in samples from springs in each hydrochemical zone. In contrast, concentrations of dissolved oxygen, nitrite plus nitrate, and chloride generally were greater in samples from springs than in samples from wells. Water from springs generally flows rapidly through large conduits with minimum water–rock interactions. Water from wells flow through small fractures, which restrict flow and increase water–rock interactions. As a result, springs tend to be more susceptible to surface contamination than wells. The results of this study have important implications for the geochemical and hydrogeological processes of similar carbonate aquifers in other geographical locations. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

Evidence for variations in cryogenic extraction deuterium biases of plant xylem water across foundational northeastern US trees     

Matthew Sobota  Kevin Li  Michael Hren  James Knighton 《水文研究》2024,38(2):e15079

Measurements of oxygen and hydrogen isotopes in plant xylem water (²H, ¹⁸O) have helped to redefine conceptual and numerical models of the hydrological cycle and understand how plants compete for subsurface water. Recent experiments have shown that Cryogenic Vacuum Extraction (CVE) of plant xylem water can result in a δ²H bias. We tested if CVE δ²H-biases varied significantly across seven foundational northeastern US forest trees with a series of tree core rehydration experiments. Our analysis demonstrated that CVE δ²H-biases were well predicted by sample gravimetric water content and varied significantly with tree species identity. We show that species-level δ²H-bias corrections can result in substantially different understandings of plant water uptake and transpiration versus uncorrected data or generic bias corrections. This research demonstrates an urgent need for the critical evaluation of CVE for plant water extraction. In the absence of a stronger understanding of CVE δ²H-biases, we recommend that xylem water δ²H observations should not be used in plant water uptake studies.  相似文献   

Towards Improved Remedial Outcomes in Categorical Aquifers with an Iterative Ensemble Smoother     

Prashanth Khambhammettu  Philippe Renard  John Doherty  Jeremy White  Marc Killingstad  Michael Kladias 《Ground water》2024,62(1):60-74

Categorical parameter distributions consisting of geologic facies with distinct properties, for example, high-permeability channels embedded in a low-permeability matrix, are common at contaminated sites. At these sites, low-permeability facies store solute mass, acting as secondary sources to higher-permeability facies, sustaining concentrations for decades while increasing risk and cleanup costs. Parameter estimation is difficult in such systems because the discontinuities in the parameter space hinder the inverse problem. This paper presents a novel approach based on Traveling Pilot Points (TRIPS) and an iterative ensemble smoother (IES) to solve the categorical inverse problem. Groundwater flow and solute transport in a hypothetical aquifer with a categorical parameter distribution are simulated using MODFLOW 6. Heads and concentrations are recorded at multiple monitoring locations. IES is used to generate posterior ensembles assuming a TRIPS prior and an approximate multi-Gaussian prior. The ensembles are used to predict solute concentrations and mass into the future. The evaluation also includes an assessment of how the number of measurements and the choice of the geological prior determine the characteristics of the posterior ensemble and the resulting predictions. The results indicate that IES was able to efficiently sample the posterior distribution and showed that even with an approximate geological prior, a high degree of parameterization and history matching could lead to parameter ensembles that can be useful for making certain types of predictions (heads, concentrations). However, the approximate geological prior was insufficient for predicting mass. The analysis demonstrates how decision-makers can quantify uncertainty and make informed decisions with an ensemble-based approach.  相似文献   

The emergence of pottery: Technology and innovation in ancient societies     

James B. Stoltman 《Geoarchaeology》1997,12(7):809-811

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Floodplain sedimentation and sensitivity: summer 1993 flood,Upper Mississippi River Valley     

Basil Gomez  J. D. Phillips  F. J. Magilligan  L. A. James 《地球表面变化过程与地形》1997,22(10):923-936

Patterns of overbank sedimentation in the vicinity of, and far removed from, levee breaks that occurred in response to the >100 year, summer 1993 flood in the upper Mississippi River valley are elucidated. Two suites of overbank deposits were associated with the failure of artificial levees within a 70 km long study reach. Circumjacent sand deposits are a component of the levee break complex that develops in the immediate vicinity of a break site. As epitomized by the levee break complex at Sny Island, these features consist of an erosional, scoured and/or stripped zone, together with a horseshoe-shaped, depositional zone. At locales farther removed from the break site, the impact of flooding was exclusively depositional and was attributed to the settling of suspended sediment from the water column. The overall picture was one of modest scour at break sites and minimal suspended deposition (<4 mm) at locales farther removed from the breach. Downriver from the confluence with the Missouri River, suspended sediment deposition was of a similar magnitude to that observed within the study reach and levee break complexes exhibited a similar morphology, but scour at break sites was greatly enhanced and the excavated sand formed extensive deposits on the floodplain surface. The different erosional response was probably engendered by the higher sand content and reduced aggregate cohesion of the floodplain soils downriver from the confluence with the Missouri River. A qualitative comparison serves to highlight the influence that the resistance threshold may have on the sensitivity of floodplains bordering large low-gradient rivers to high magnitude floods. © 1997 John Wiley & Sons, Ltd.  相似文献   

Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS     

Kaj Sullivan  Daniel Layton‐Matthews  Matthew Leybourne  James Kidder  Zoltn Mester  Lu Yang 《Geostandards and Geoanalytical Research》2020,44(2):349-362

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.  相似文献