Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS     

Kaj Sullivan  Daniel Layton‐Matthews  Matthew Leybourne  James Kidder  Zoltn Mester  Lu Yang 《Geostandards and Geoanalytical Research》2020,44(2):349-362

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.  相似文献   

Robust abnormality detection methods for spatial search of radioactive materials     

Myeong‐Hun Jeong  Clair J. Sullivan  Yizhao Gao  Shaowen Wang 《Transactions in GIS》2019,23(4):860-877

Radiological dirty bombs and improvised nuclear devices pose a significant threat to both public health and national security. Growing networks of radiation sensors have been deployed by a number of offices within the U.S. and international agencies. Detecting such threats while minimizing false alarm rates presents a considerable challenge to homeland security and public health. This research aims to achieve a higher probability of detection with a lower probability of false alarms. It focuses on the local spatial instability of radiation levels in order to detect radioactive materials based on robust outlier detection methods. Our approach includes a three‐step abnormality detection method consisting of one‐dimensional robust outlier detection for all gamma‐ray counts, a density‐based clustering analysis, and a two‐dimensional robust outlier detection method using a bagplot, based on spatial associations. The effectiveness of the method proposed is demonstrated through a case study, wherein radioactive materials are detected in urban environments, and its performance is compared with alternative methods employing a k‐sigma approach, local Getis–Ord () statistic, and the goodness of fit of the Poisson distribution.  相似文献   

Hafnium isotopic variations in East Atlantic intraplate volcanism     

Jörg Geldmacher  Kaj Hoernle  Barry B. Hanan  Janne Blichert-Toft  F. Hauff  James B. Gill  Hans-Ulrich Schmincke 《Contributions to Mineralogy and Petrology》2011,162(1):21-36

The broad belt of intraplate volcanism in the East Atlantic between 25° and 37° N is proposed to have formed by two adjacent hotspot tracks (the Madeira and Canary tracks) that possess systematically different isotopic signatures reflecting different mantle source compositions. To test this model, Hf isotope ratios from volcanic rocks from all individual islands and all major seamounts are presented in this study. In comparison with published Nd isotope variations (6 εNd units), ¹⁷⁶Hf/¹⁷⁷Hf ratios span a much larger range (14 εHf units). Samples from the proposed Madeira hotspot track have the most radiogenic Hf isotopic compositions (¹⁷⁶Hf/¹⁷⁷Hf_m up to 0.283335), extending across the entire field for central Atlantic MORB. They form a relatively narrow, elongated trend on the Nd vs. Hf isotope diagram (stretching over > 10 εHf units) between a depleted N-MORB-like endmember and a moderately enriched composition located on, or slightly below, the Nd–Hf mantle array, which overlaps the proposed “C” mantle component of Hanan and Graham (1996). In contrast, all samples from the Canary hotspot track plot below the mantle array (¹⁷⁶Hf/¹⁷⁷Hf_m = 0.282943–0.283067) and form a much denser cluster with less compositional variation (~4 εHf units). The cluster falls between (1) a low Hf isotope HIMU-like endmember, (2) a more depleted composition, and (3) the moderately enriched end of the Madeira trend. The new Hf isotope data confirm the general geochemical distinction of the Canary and Madeira domains in the East Atlantic. Both domains, however, seem to share a common, moderately enriched endmember that has “C”-like isotope compositions and is believed to represent subducted, <1-Ga-old oceanic lithosphere (oceanic crust and possibly minor sediment addition). The lower ¹⁷⁶Hf/¹⁷⁷Hf ratio of the enriched, HIMU-like Canary domain endmember indicates the contribution of oceanic lithosphere with somewhat older recycling ages of ≥1 Ga.  相似文献   

Seismic performance of steel friction connections considering direct-repair costs     

T. Z. Yeow  A. Orumiyehei  T. J. Sullivan  G. A. MacRae  G. C. Clifton  K. J. Elwood 《Bulletin of Earthquake Engineering》2018,16(12):5963-5993

This study compares seismic losses considering initial construction costs and direct-repair costs for New Zealand steel moment-resisting frame buildings with friction connections and those with extended bolted-end-plate connections. A total of 12 buildings have been designed and analysed considering both connection types, two building heights (4-storey and 12-storey), and three locations around New Zealand (Auckland, Christchurch, and Wellington). It was found that buildings with friction connections required design to a higher design ductility, yet are generally stiffer due to larger beams being required to satisfy higher connection overstrength requirements. This resulted in the frames with friction connections experiencing lower interstorey drifts on most floors but similar peak total floor accelerations, and subsequently incurring lower drift-related seismic repair losses. Frames with friction connections tended to have lower expected net-present-costs within 50 years of the building being in service for shorter buildings and/or if located in regions of high seismicity. None of the frames with friction connections in Auckland showed any benefits due to the low seismicity of the region.  相似文献   

Layered organization in the coastal ocean: An introduction to planktonic thin layers and the LOCO project     

James M. Sullivan  Margaret A. McManus  Olivia M. Cheriton  Kelly J. Benoit-Bird  Louis Goodman  Zhankun Wang  John P. Ryan  Mark Stacey  D. Van Holliday  Charles Greenlaw  Mark A. Moline  Malcolm McFarland 《Continental Shelf Research》2010,30(1):1-6

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Voracious planktonic hydroids: unexpected predatory impact on a coastal marine ecosystem     

Laurence P. Madin  Stephen M. Bollens  Erich Horgan  Mari Butler  Jeffrey Runge  Barbara K. Sullivan  Grace Klein-Macphee  Edward Durbin  Ann G. Durbin  Donna Van Keuren  Stphane Plourde  Ann Bucklin  M. Elizabeth Clarke 《Deep Sea Research Part II: Topical Studies in Oceanography》1996,43(7-8)

Hydroids are typically attached, benthic cnidarians that feed on a variety of small prey. During sampling on Georges Bank in spring 1994, we found huge numbers of hydroids suspended in the plankton. They fed on young stages of copepods that are an important prey for fish, as well as on young fish themselves. Two independent methods were used to estimate feeding rates of the hydroids; both indicate that the hydroids are capable of consuming from 50% to over 100% of the daily production of young copepods. These results suggest that hydroids can have a profound effect on the population dynamics of zooplankton and young fish on Georges Bank.  相似文献   

Upstream—Downstream Shifts in Peak Recruitment of the Native Olympia Oyster in San Francisco Bay During Wet and Dry Years     

Andrew L. Chang  Lindsay J. Sullivan  Steven G. Morgan  Matthew C. Ferner 《Estuaries and Coasts》2018,41(1):65-78

Understanding the conditions that drive variation in recruitment of key estuarine species can be important for effective conservation and management of their populations. The Olympia oyster (Ostrea lurida) is native to the Pacific coast of North America and has been a target of conservation efforts, though relatively little information on larval recruitment exists across much of its range. This study examined the recruitment of Olympia oysters at biweekly to monthly intervals at four sites in northern San Francisco Bay from 2010 to 2015 (except 2013). Mean monthly temperatures warmed at all sites during the study, while winter (January–April) mean monthly salinity decreased significantly during a wet year (2011), but otherwise remained high as a result of a drought. A recurring peak in oyster recruitment was identified in mid-estuary, in conditions corresponding to a salinity range of 25–30 and >16 °C at the time of settlement (April–November). Higher average salinities and temperatures were positively correlated with greater peak recruitment. Interannual variation in the timing of favorable conditions for recruitment at each site appears to explain geographic and temporal variation in recruitment onset. Higher winter/spring salinities and warmer temperatures at the time of recruitment corresponded with earlier recruitment onset within individual sites. Across all sites, higher winter/spring salinities were also correlated with earlier onset and earlier peak recruitment. Lower winter salinities during 2011 also resulted in a downstream shift in the location of peak recruitment.  相似文献   

Spreading of Antarctic Bottom Water and its effects on the floor of the Indian Ocean inferred from bottom-water potential temperature,turbidity, and sea-floor photography     

Venkatarathnam Kolla  Lawrence Sullivan  S.Stephen Streeter  Marcus G. Langseth 《Marine Geology》1976,21(3):171-189

Data on bottom-water potential temperature, turbidity and current indications show that in the Southern Ocean west of the Kerguelen Plateau, Antarctic Bottom Water (AABW) of Weddell Sea origin spreads northwards from the Atlantic—Indian Basin in two directions: (1) AABW enters the Agulhas Basin through relatively deep areas in the Mid-Indian Ridge at 20–25°E and possibly at 35°E, and flows northwards into the Mozambique Basin as far as its northern limits; (2) a more easterly spreading path extends from the Atlantic—Indian Basin through the Crozet into the Madagascar, Mascarene, Somali and Arabian Basins. The passage in the western branch of the Indian Ridge for the AABW spreading from the Crozet into the Madagascar Basin appears to be at 29-26°S and 60–64°E.East of the Kerguelen Plateau in the South Indian Basin, the bottom water formed mainly along the Adélie Coast and Ross Sea travels west towards the Kerguelen Plateau and then parallel to it. This water finally flows eastwards hugging the Southeast Indian Ridge. Significant deviations from this general circulation pattern occur due to local topographic effects. Some AABW in the South Indian Basin exits through a passage at 120–125°E in the region of the Australian—Antarctic discordance in the Southeast Indian Ridge and enters the South Australian Basin and subsequently the Wharton Basin. This passage is clearly indicated by the northward extension of a cold, bottom-water tongue as shown by the temperature distribution in the region; the bottom-water effects in the passage are reflected in the high turbidity and current lineations on the sea floor.In the Southern Ocean basins, bottom-water turbidity is generally high, reflecting in part the strong bottom-water activity. The effects of AABW circulation on the sea floor—in the form of well-developed small- or large-scale current ripples and erosional/depositional features, manganese-nodule formations, and unconformities and reworking of sediments observed in cores — are also marked in these basins. Even though the AABW in the Wharton Basin is cold, its spreading effects on the sea floor are minimal in this basin in contrast to the basins west of the Mid-Indian Ridge at comparable latitudes.  相似文献   

Funding low carbon cities: local perspectives on opportunities and risks     

Rory Sullivan  Andy Gouldson  Phil Webber 《Climate Policy》2013,13(4):514-529

There are compelling reasons for policy makers to be interested in the low-carbon agenda. More than half of the world's population lives in, and more than half of the world's economic output comes from, cities. Up to 70% of global carbon emissions can also be attributed to consumption that takes place in cities. Recent research has shown that cost-effective investments in low-carbon options could deliver a 40% reduction in GHG emissions from cities by 2020, while also providing wider economic benefits such as enhanced competitiveness and increased employment. As yet, however, investments in low-carbon cities have not been made at scale due mainly to the scale of the finance required, local government budgetary constraints, and perceptions about their costs and benefits. With a focus on the UK, a contemporary account is provided of what local authorities see as the major financial risks associated with funding low-carbon cities. Practical proposals – which also have more general relevance to the future financing of low-carbon cities around the world – are offered on how local authorities, in conjunction with central government, the private sector, and institutional investors, can effectively manage these risks.

Policy relevance

Cities house more than half of the world's population, generate more than half of the world's economic output, and produce between 40% and 70% of all anthropogenic GHG emissions. In the UK, 70% of such emissions are under the influence of its local authorities. Thus, one of the key public policy challenges for the low-carbon transition is how it should be financed. There are several obstacles and related risks to this transition, including financial and legal obstacles and the differing views and perceptions of stakeholders. These can be attenuated, somewhat, by national government support at scale, local authority leadership, and cooperation between other authorities and the private sector, and the development of tools and guidance to reduce transaction costs.  相似文献   

Contrasting compositional trends of rocks and olivine-hosted melt inclusions from Cerro Negro volcano (Central America): implications for decompression-driven fractionation of hydrous magmas     

Maxim V. Portnyagin  Kaj Hoernle  Nikita L. Mironov 《International Journal of Earth Sciences》2014,103(7):1963-1982

Melt inclusions in olivine Fo_83–72 from tephras of 1867, 1971 and 1992 eruptions of Cerro Negro volcano represent a series of basaltic to andesitic melts of narrow range of MgO (5.6–8 wt %) formed by ~46 wt % fractional crystallization of olivine (~6 wt %), plagioclase (~27 wt %), pyroxene (~13 wt %) and magnetite (<1 wt %) from primitive basaltic melt (average SiO₂ = 49 wt %, MgO = 7.6 wt %, H₂O = 6 wt %) as it ascended to the surface from the depth of about 14 km. The crystallization occurred at increasing liquidus temperature from 1,050 to 1,090 °C in the pressure range from 400 to 50 MPa and was induced by release of mixed H₂O–CO₂ fluid from the melt at decreasing pressure. Matrix glass compositions fall at the high-Si end of the melt inclusion trend and represent the final stage of melt crystallization during and after eruption. The bulk compositions of erupted Cerro Negro magmas (tephras and lavas) range from high- to low-MgO (3–10 wt %) basalts, which form a compositional array crossing the trend of melt inclusions so that virtually no rock from Cerro Negro has composition akin to true melt represented by the inclusions. The variations of the bulk magma (rocks) and melt (melt inclusions) compositions can be generated in a dyke connecting a deep primitive magma reservoir with the Cerro Negro edifice. While the melt inclusions represent the compositional trend of instantaneous melts along the magma pathway at decreasing pressure and H₂O content, occurrence of low-Mg to high-Mg basalts reflects the process of phenocryst re-distribution in progressively evolving melt. The crystallization scenario is anticipated to operate everywhere in dykes feeding basaltic volcanoes and can explain the predominance of plagioclase-rich high-Al basalts in island arc as well as typical compositional variations of magmas during single eruptions.  相似文献