Stability of methane clathrate hydrates under pressure: Influence on outgassing processes of methane on Titan     

Mathieu Choukroun  Olivier Grasset 《Icarus》2010,205(2):581-10437

We have conducted high-pressure experiments in the H₂O-CH₄ and H₂O-CH₄-NH₃ systems in order to investigate the stability of methane clathrate hydrates, with an optical sapphire-anvil cell coupled to a Raman spectrometer for sample characterization. The results obtained confirm that three factors determine the stability of methane clathrate hydrates: (1) the bulk methane content of the samples; (2) the presence of additional gas compounds such as nitrogen; (3) the concentration of ammonia in the aqueous solution. We show that ammonia has a strong effect on the stability of methane clathrates. For example, a 10 wt.% NH₃ solution decreases the dissociation temperature of methane clathrates by 14-25 K at pressures above 5 MPa. Then, we apply these new results to Titan’s conditions. Dissociation of methane clathrate hydrates and subsequent outgassing can only occur in Titan’s icy crust, in presence of locally large amounts of ammonia and in a warm context. We propose a model of cryomagma chamber within the crust that provides the required conditions for methane outgassing: emplacement of an ice plume triggers the melting (if solid) or heating (if liquid) of large ammonia-water pockets trapped at shallow depth, and the generated cryomagmas dissociate surrounding methane clathrate hydrates. We show that this model may allow for the outgassing of significant amounts of methane, which would be sufficient to maintain the presence of methane in Titan’s atmosphere for several tens of thousands of years after a large cryovolcanic event.  相似文献   

Integrated stratigraphy and ⁴⁰Ar/³⁹Ar chronology of the early to middle Miocene Upper Freshwater Molasse in western Bavaria (Germany)     

Hayfaa Abdul Aziz  Madelaine B?hme  Alexander Rocholl  Jerome Prieto  Jan R. Wijbrans  Valerian Bachtadse  Albert Ulbig 《International Journal of Earth Sciences》2010,99(8):1859-1886

A detailed integrated stratigraphic study (biostratigraphy and magnetostratigraphy) was carried out on five sections from the western part of the Bavarian Upper Freshwater Molasse of the North Alpine Foreland Basin (NAFB), greatly improving the chronostratigraphy of these sediments. The sections belong to the lithostratigraphic units Limnische Untere Serie (UL) and Fluviatile Untere Serie (UF) and contain 19 (mostly new) small-mammal bearing levels, significantly refining the local biostratigraphy. Radiometric ages obtained from glass shards from tuff horizons are used together with the biostratigraphic information for constructing and confirming the magnetostratigraphic correlation of the studied sections to the Astronomical Tuned Time Scale (ANTS04; Lourens et al. in Geologic Time Scale 2004, Cambridge University Press, 2004). This correlation implies that the UL lithostratigraphic unit corresponds to the latest Ottnangian and the Early Karpatian, whereas the UF corresponds to the Karpatian and the Early Badenian. This indicates that the Brackish- to Freshwater Molasse transition already occurred during the late Ottnangian. The pre-Riesian hiatus occurred in the latest Karpatian and lower Early Badenian in Eastern Bavaria and Bohemia and in the Late Karpatian and earliest Badenian in Western Bavaria. The geochemical and Ar–Ar data of volcanic ashes suggest that highly evolved silicic magmas from a single volcano or volcanic center, characterized by a uniform Nd isotopic composition, erupted repetitively over the course of at least 1.6 Myr. Three phases of eruptive activity were identified at 16.1 ± 0.2 Ma (Zahling-2), 15.6 ± 0.4 Ma (Krumbad), and 14.5 ± 0.2 Ma (Heilsberg, Hegau). The correlation of the local biostratigraphic zonation to the ANTS04 enables further the characterization of both the Ottnangian–Karpatian and Karpatian–Badenian boundaries in the NAFB by small-mammal biostratigraphy. According to these results the Ottnangian–Karpatian boundary is contemporaneous with the first appearance datum of Megacricetodon bavaricus (in the size of the type population) and the first common occurrence of Keramidomys thaleri, whereas Ligerimys florancei, Melissiodon dominans and Prodeinotherium aff. bavaricum have been already disappeared during the late Ottnangian. The Karpatian–Badenian boundary is characterized by a significant size increase of the large Megacricetodon lineage and possibly a (re-)immigration of Prodeinotherium bavaricum.  相似文献   

Improving the simulation of fine-resolution landscape changes by coupling top-down and bottom-up land use and cover changes rules     

Thomas Houet  Noémie Schaller  Mathieu Castets  Cédric Gaucherel 《International journal of geographical information science》2014,28(9):1848-1876

Modelling land use and cover changes (LUCC) at local and landscape scales simultaneously, in terms of composition and configuration, remains today highly challenging. Agricultural landscapes offer an illustrative context for this purpose. This article presents a modelling platform (DYPAL) able to simulate LUCC at both local (agricultural parcel, farm) and landscape levels by combining LUCC processes with an optimization algorithm. The efficiency of this approach is assessed by comparing it with an approach applying the same LUCC processes without optimization. Simulations have been developed for two representative case studies of temperate intensive agricultural mosaics: (1) neutral landscapes with simple and theoretical rules and (2) observed landscapes with realistic crop successions rules. Results show that this modelling platform improves the simulation of LUCC achieved at fine resolution, although not systematically. Improvements are observed when compared to theoretical farming practices. But, when compared with an observed landscape, it is true for one type of (arable) farms only. Several hypotheses are discussed, such as the fact that farmers possibly do not follow optimized rules. Finally, this study illustrates that the use of several indices is crucial to assess whether a simulated landscape is realistic or not, because it does not rely to the assessment of the predictive power of the model.  相似文献   

Simulation of the annual and diurnal cycles of rainfall over South Africa by a regional climate model     

Benjamin Pohl  Mathieu Rouault  Shouraseni Sen Roy 《Climate Dynamics》2014,43(7-8):2207-2226

The capability of a current state-of-the-art regional climate model for simulating the diurnal and annual cycles of rainfall over a complex subtropical region is documented here. Hourly rainfall is simulated over Southern Africa for 1998–2006 by the non-hydrostatic model weather research and forecasting (WRF), and compared to a network of 103 stations covering South Africa. We used five simulations, four of which consist of different parameterizations for atmospheric convection at a 0.5 × 0.5° resolution, performed to test the physic-dependency of the results. The fifth experiment uses explicit convection over tropical South Africa at a 1/30° resolution. WRF simulates realistic mean rainfall fields, albeit wet biases over tropical Africa. The model mean biases are strongly modulated by the convective scheme used for the simulations. The annual cycle of rainfall is well simulated over South Africa, mostly influenced by tropical summer rainfall except in the Western Cape region experiencing winter rainfall. The diurnal cycle shows a timing bias, with atmospheric convection occurring too early in the afternoon, and causing too abundant rainfall. This result, particularly true in summer over the northeastern part of the country, is weakly physic-dependent. Cloud-resolving simulations do not clearly reduce the diurnal cycle biases. In the end, the rainfall overestimations appear to be mostly imputable to the afternoon hours of the austral summer rainy season, i.e., the periods during which convective activity is intense over the region.  相似文献   

The challenge of dating early pleistocene fossil teeth by the combined uranium series–electron spin resonance method: the Venta Micena palaeontological site (Orce,Spain)     

Mathieu Duval  Christophe Falguères  Jean‐Jacques Bahain  Rainer Grün  Qingfeng Shao  Maxime Aubert  John Hellstrom  Jean‐Michel Dolo  Jordi Agusti  Bienvenido Martínez‐Navarro  Paul Palmqvist  Isidro Toro‐Moyano 《第四纪科学杂志》2011,26(6):603-615

The palaeontological site of Venta Micena (Orce, Andalusia, Spain) lies in the eastern sector of the Guadix–Baza basin, one of the best documented areas in Europe for Plio‐Pleistocene biostratigraphy. The combination of biochronological and palaeomagnetic results, combined with the radiometric data obtained for Atapuerca Sima del Elefante, indicated that the Venta Micena stratum was formed between the Jaramillo and Olduvai palaeomagnetic events, most likely between 1.22 and 1.77 Ma. Five fossil teeth from two outcrops (sites A and B) were selected to assess the potential of combined uranium series–electron spin resonance (US‐ESR) dating of Early Pleistocene sites. Although the US‐ESR results of the first outcrop showed a large scatter between the three teeth, the mean age of 1.37 ± 0.24 Ma can be considered a reasonable age estimate for Venta Micena. The mean ESR age of 0.62 ± 0.03 Ma obtained for site B seems to be a severe underestimation when compared with the independent age control. This underestimation is attributed to a relative recent U‐mobilization event that led to some U‐leaching. The results show that any ESR age calculations of old samples are extremely sensitive to variations in the measured ²³⁰Th/²³⁴U ratios in dental tissues. Although the results demonstrate that ESR can in principle be applied to Early Pleistocene sites, they also reveal the complexity of dating such old teeth. It is necessary to continue research in several directions, such as study of the behaviour of ESR signals in old teeth and understanding recent U‐mobilization processes, to improve the reliability of the combined US‐ESR dating method applied to Early Pleistocene times, a period for which the number of available numerical dating techniques is very limited. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Analyzing seismic imagery in the time–amplitude and time–frequency domains to determine fluid nature and migration pathways: A case study from the Queen Charlotte Basin,offshore British Columbia     

Mathieu J. Duchesne  E. Julie Halliday  J. Vaughn Barrie 《Journal of Applied Geophysics》2011,73(2):111-120

Combining time–amplitude and time–frequency information from seismic reflection data sets of different resolutions allows the analysis of anomalous reflections from very-shallow to great subsurface depths. Thus, it can enhance the imaging of subsurface features which have a frequency-dependent reflectivity such as gas. Analysing seismic data of different resolution in the time–amplitude and time–frequency domains is a powerful method to determine hydrocarbon migration pathways from deep reservoirs to the seafloor. This interpretation method has been applied to the formerly-glaciated offshore Queen Charlotte Basin hosting several seafloor pockmarks and mounds associated with the leakage of underlying hydrocarbon reservoirs. Low-frequency shadows observed in the time–frequency domain provide evidence of different resolutions that several anomalous reflection amplitudes may be attributed to the occurrence of gas. The seismic imagery shows that gas uses a fault to migrate from deep reservoirs included in Upper Mesozoic strata towards secondary reservoirs located along the fault plane into Neogene layers. Once gas reaches a porous cut-and-fill succession, migration changes from structurally- to stratigraphically-controlled before gas leaks through unconsolidated Quaternary sediments forming the shallow subsurface to eventually seep at the seafloor where pockmarks and carbonate mounds are formed.  相似文献   

A theory of pressure sensor performance in snow     

Jerome B. Johnson 《水文研究》2004,18(1):53-64

A theory of pressure sensor response in snow is derived and used to examine the sources of measurement errors in snow water equivalent (SWE) pressure sensors. Measurement errors in SWE are caused by differences in the compressibility of the pressure sensor and the adjacent snow layer, which produces a shear stress along the perimeter of the sensor. When the temperature at the base of the snow cover equals 0 °C, differences in the snowmelt rate between the snow–SWE sensor interface and the adjacent snow–soil interface may also produce a shear stress along the sensor's perimeter. This shear stress perturbs the pressure field over the sensor, producing SWE measurement errors. Snow creep acts to reduce shear stresses along the SWE sensor's perimeter at a rate that is inversely proportional to the snow viscosity. For sustained periods of differential snowmelt, a difference in the mass of snow over the sensor compared with the surrounding soil will develop, producing additional permanent errors in SWE measurements. The theory indicates that SWE pressure sensor performance can be improved by designing a sensor with a high Young's modulus (low compressibility), low aspect ratio, large diameter and thermal properties that match those of the surrounding soil. Simulations of SWE pressure sensor errors using the theory are in close agreement with observed errors and may provide a means to correct historical SWE measurements for use in hydrological hindcast or climate studies. Published in 2003 by John Wiley & Sons, Ltd.  相似文献   

4456071 Oil collector for subsea blowouts     

Jerome H Milgram 《Marine pollution bulletin》1985,16(1):iii

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Correction to: Estimating rockfall release frequency from blocks deposited in protection barriers,growth disturbances in trees,and trajectory simulations     

Farvacque  Manon  Corona  Christophe  Lopez-Saez  Jerome  Mainieri  Robin  Stoffel  Markus  Bourrier  Franck  Eckert  Nicolas  Toe  David 《Landslides》2022,19(1):263-264

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Climate variability and trends in downscaled high-resolution simulations and projections over Metropolitan France   总被引：2，自引：1，他引：1  

Robert Vautard  Thomas Noël  Laurent Li  Mathieu Vrac  Eric Martin  Philippe Dandin  Julien Cattiaux  Sylvie Joussaume 《Climate Dynamics》2013,41(5-6):1419-1437

In order to fulfill the society demand for climate information at the spatial scale allowing impact studies, long-term high-resolution climate simulations are produced, over an area covering metropolitan France. One of the major goals of this article is to investigate whether such simulations appropriately simulate the spatial and temporal variability of the current climate, using two simulation chains. These start from the global IPSL-CM4 climate model, using two regional models (LMDz and MM5) at moderate resolution (15–20 km), followed with a statistical downscaling method in order to reach a target resolution of 8 km. The statistical downscaling technique includes a non-parametric method that corrects the distribution by using high-resolution analyses over France. First the uncorrected simulations are evaluated against a set of high-resolution analyses, with a focus on temperature and precipitation. Uncorrected downscaled temperatures suffer from a cold bias that is present in the global model as well. Precipitations biases have a season- and model-dependent behavior. Dynamical models overestimate rainfall but with different patterns and amplitude, but both have underestimations in the South-Eastern area (Cevennes mountains) in winter. A variance decomposition shows that uncorrected simulations fairly well capture observed variances from inter-annual to high-frequency intra-seasonal time scales. After correction, distributions match with analyses by construction, but it is shown that spatial coherence, persistence properties of warm, cold and dry episodes also match to a certain extent. Another aim of the article is to describe the changes for future climate obtained using these simulations under Scenario A1B. Results are presented on the changes between current and mid-term future (2021–2050) averages and variability over France. Interestingly, even though the same global climate model is used at the boundaries, regional climate change responses from the two models significantly differ.  相似文献