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1.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

2.
On June 5, 2009, a catastrophic rockslide-debris flow occurred at the crest of the Jiweishan Mountain in Wulong, Chongqing, China. Approximately five million cubic meters of limestone blocks slid along a weak interlayer of bituminous and carbonaceous shale. The source mass descended from the upper part of the slope rapidly, crossing a 200-m wide and 50-m deep creek in front of it. Blocked by the opposite steep creek wall, the sliding mass changed its direction and traveled a further 2.2 km along the creek in debris-flow mode, finally forming a large accumulation zone with an average depth of 30 m. This is one of the most catastrophic rockslide events in recent years in China. It buried 12 houses and the entrance of an iron mining tunnel where some 27 miners were working inside. Ten people died, 64 missing, and eight wounded. Immediately after this disaster happened, the government organized an expert team to assist the rescue work. As one of the geological experts, the author did a lot of field investigations and collected first-hand information. Multi-methods including the remote sensing, 3D laser scanning, geophysical exploration, and numerical modeling were used for analyzing the characteristics and the triggering mechanism of the Wulong rockslide. The preliminary investigation results reveal that this rockslide with poor geological conditions was mainly induced by the gravitation and the karst effect and also affected by the previous mining activities. The research in this paper is meaningful and useful for further research on such kind of rockslides that are geologically similar to the Wulong rockslide.  相似文献   

3.
The textural relationships and structural states of optically isotropic labradorite from the Manicouagan, Quebec, impact structure have been examined by light (optical) and transmission electron (TEM) microscopy. Two distinct diaplectic glasses have been recognized based on their contrasting morphology, timing and the inferred modes of formation. The earliest isotropic bands and grain-scale isotropism (maskelynite) optically exhibit a gradational,in situ transformation from crystalline plagioclase with preservation of relict textures (twins, grain boundaries). The same transformation from crystalline to amorphous structure is observed in TEM to occur heterogeneously at scales on the order of the unit cell. The progressive transformation of optical properties reflects an increase in the volume fraction and eventual coalescence of these amorphous units. This maskelynite-type diaplectic glass is interpreted to form in the solid-state directly from crystalline material during the compressional phase of the shock wave. The other isotropic material occurs in spatially discrete tensiongashes and planar deformation features (PDFs) that overprint the maskelynite-type glass. This second type of diaplectic glass (PDF-type) is developed homogeneously within a given glass band and exhibits sharp crystal-glass boundaries, in contrast to the gradational boundaries of the maskelynite-type glass. PDF-type glass is interpreted to form by melting in tensional release zones during passage of the rarefaction wave. These observations emphasize the ability of naturally shocked rocks to preserve subtle evidence of variations in the shock process from highly transient events.  相似文献   

4.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

5.
Brick-tea-type fluorosis is a peculiar endemic disease in China, which had been discovered in minority areas of western China since 1980, and distributed mainly in Tibet, Inner Mongolia, Gansu, Xinjiang, Qinghai and parts of Sichuan Province. The prevalence rate of fluorosis in Tibetan and Mongolian nationality people was higher. Epidemiological investigation showed that fluorosis morbidity and degrees were different in different brick-tea drinking areas, and it was probably caused by drinking various kinds of brick tea from different regions. Therefore, we collected 33 samples of brick tea from six provinces where minority nationalities were accustomed to drinking a large quantity of brick tea. F concentrations were determined by the combustion hydrolysis-ion selective electrode method. The results showed that among the brick teas, the F concentrations ranged from the minimum 74.1 mg/kg in Yunnan Province to the maximum 991.2 mg/kg in Sichuan Province. Besides, there was a great difference among the various kinds of brick tea, and F concentrations decreased in the order of Kang brick tea, Green brick tea, Black brick tea, Mi brick tea, Fu brick tea, Chitsu ping tea, Puerh tea, and Tuo tea. The average F concentration in brick teas was 431.92 mg/kg.  相似文献   

6.
We derived Sr, Y, Zr, and Ce abundances for a sample of 74 cool dwarfs and subgiants with iron abundances, [Fe/H], between 0.25 and ?2.43. These estimates were obtained using synthetic spectra, assuming local thermodynamic equilibrium (LTE) for Y, Zr, and Ce, allowing for non-LTE conditions for Sr. We used high-resolution (λ/Δλ?40 000 and 60 000) spectra with signal-to-noise ratios between 50 and 200. We find that the Zr/Y, Sr/Y, and Sr/Zr ratios for the halo stars are the same in a wide metallicity range (?2.43 ≤ [Fe/H] ≤ ?0.90), within the errors, indicating a common origin for these elements at the epoch of halo formation. The Zr/Y ratios for thick-disk stars quickly decrease with increasing Ba abundance, indicating a lower rate of production of Zr compared to Y during active thick-disk formation. The thick-disk and halo stars display an increase in the [Zr/Ba] ratio with decreasing Ba abundance and a correlation of the Zr and Eu overabundances relative to Ba. The evolutionary behavior of the abundance ratios found for the thick-disk and halo stars does not agree with current models for the Galaxy’s chemical evolution. The abundance ratios of Y and Zr to Fe and Ba for thin-disk stars, as well as the abundance ratios within each group, are, on average, solar, though we note a slight decrease of Zr/Ba and Zr/Y with increasing Ba abundance. These results provide evidence for a dominance of asymptotic-giant-branch stars in the enrichment of the interstellar medium in heavy elements during the thin-disk epoch, in agreement with the predictions of the nucleosynthesis theory for the main s-process component.  相似文献   

7.
Arsenic concentrations of less than 5 ppb to as large as 1,260 ppb in stream waters and from 5 ppm to 4,000 ppm in stream sediments were found in the Pedro Dome-Cleary Summit area, Alaska. Waters from three of 20 wells sampled had arsenic concentrations exceeding the U.S. Public Health Service recommended limit of 50 ppb. The high arsenic levels are a consequence of arsenic enrichment in the rocks of the area. Placer and lode-gold mining may increase the arsenic content of the waters by exposing arsenic-containing rocks to surface waters and by increasing the load of arsenic-rich sediments in the streams. Finding these disturbingly large concentrations of arsenic in the waters of the Fairbanks area was the major result of this work, inasmuch as a subsequent study (to be published) revealed arsenic concentrations as large as 10 ppm in domestic wells and prompted an extensive study by Federal and State agencies of the health hazard posed by these arsenic-rich waters.  相似文献   

8.
湖北宜昌王家湾五峰组顶部Chondrites的发现及其环境意义   总被引:1,自引:0,他引:1  
本文报道了湖北宜昌王家湾剖面五峰组笔石页岩段观音桥层发现的遗迹化石Chondrites的分布及其生态特点。结合生物相和同期上扬子海盆相对海平面的变化,分析了盆地水体底域在缺氧一富氧转折时期的古氧相变化特征:指出五峰组笔石页岩段上部地层沉积底域为典型的缺氧环境,在其与上覆观音桥段之间的沉积转换面附近发生了从无氧到有氧的转变,观音桥段中Hirnantia动物群繁盛于富氧的海底环境。  相似文献   

9.
Natural Hazards - Despite the application of various methods to calculate uncertainty in flood vulnerability assessments, the challenge of uncertainty remains. The main purpose of this study was to...  相似文献   

10.
通过介绍普者黑地区的岩溶地貌特征,借鉴石林和桂林的研究模式,对普者黑的岩溶地貌形成机理进行了深入研究,并针对普者黑独特的亚热带高原岩溶地貌的特征,阐述了其研究的科学价值。  相似文献   

11.
日本北海道音调津的球状石墨   总被引:1,自引:0,他引:1  
本文利用光学显微镜、X射线衍射仪、透射电镜等手段对日本北海道音调津球状石墨的成因、结构等进行研究,认为日本北海道音调津球状石墨中除了石墨外,还存在镍黄铁矿﹑黄铜矿﹑磁黄铁矿等金属硫化物矿物。通过透射电子显微镜观察发现音调津石墨中大部分是椭圆状石墨颗粒,高分辨晶格条纹主要是非晶态结构,但是同时也发现了结晶良好的石墨。高结晶度石墨的存在可能是在硫化物Fe-Ni-Cu的触媒作用下形成的。天然球状石墨的微结构和性状研究对天然石墨的形成和开发应用有重要意义,对新型碳材料的制备技术有重要科学意义。  相似文献   

12.
《四川地质学报》2022,(2):234-237
紫云县地处贵州省南西部,区域上无岩浆活动,地表无温泉地热流体露头和无明显的其他地热显示,增加了地热勘查的难度。燕山期自东往西的构造应力作用下,产生了近南北向、北东向断层和近南北向褶皱的主体构造,以及碳酸盐岩—碎屑岩沉积建造为区内地热资源的产生提供了前提条件;采用基础地质结合物探方法研究优选出了层状热储较好的牛场坡背斜和带状热储F4小桥断裂结合的有利部位,施工了地热钻孔,取得了良好的地热水找矿成果。  相似文献   

13.
捕虏体麻粒岩是了解下地壳形成和演化的重要样品。汉诺坝新生代玄武岩中的二辉麻粒岩捕虏体样品中富含各种硫化物相,主要类型有:①孤立产出的球状出溶硫化物;②矿物颗粒之间或颗粒内的粗晶硫化物;③次生硫化物包裹体群;④裂隙充填硫化物。电子探针分析表明,硫化物的矿物成分均为贫镍磁黄铁矿,(Ni+Co+Cu)/Fe(原子比)远小于0.2;(Fe+Cu+Co+Ni)/S(原子比)比地幔岩的磁黄铁矿小,多小于0.875,反映了一种S过饱和环境。各种产状的磁黄铁矿中Au、Ag都有一定的含量,其平均值分别为0.19%~0.22%(Au)、0.01%~0.02%(Ag),反映下地壳的麻粒岩化与金矿化的成因联系。磁黄铁矿的Ni、Co、Cu含量与S正相关,说明微量重金属元素与S具有同源的关系,由于地幔去气伴随S而进入下地壳。  相似文献   

14.
Pillow structures developed in serpentinite is described from the Nuggehalli schist belt, Karnataka. Chemistry of the rock reveals that the serpentinite is a direct representation of mantle material.  相似文献   

15.
Summary The Middle Proterozoic Faraday Metagabbro in the Bancroft area of eastern Ontario has been subjected to syn-orogenic textural and mineralogical modifications resulting in the formation of scapolite-bearing metagabbro and gabbroic blastomylonite assemblages. The elemental flux during cryptic and overt scapolitization has been calculated usingGresens general metasomatic equation which applies corrections for density and volume changes during alteration. Metasomatic variation diagrams using analyses from two primary gabbros and six altered rocks indicate that Na, K, Cl, Li, Rb, and Ba are the principal introduced elements and that Cu and S were removed. These changes are very similar to those involved in the formation of metasomatic nepheline-bearing rocks elsewhere in the district and, furthermore, nephelinization and scapolitization were broadly coincident in time and space. It is concluded that the nephelin- and scapolite-bearing rocks and their cryptic facies are different manifestations of the same metasomatic agent and that the source of the fluids was a possible horizon of evaporitic sediments within the country rocks in which the gabbro was emplaced.
Metasomatose im Faraday-Metagabbro, Bancroft, Ontario, Kanada
Zusammenfassung Der Mittel-proterozoische Faraday-Gabbro in der Umgebung von Bancroft (Ost-Ontario) erfuhr synorogene Veränderungen in Textur und Mineralogie, die zur Bildung skapolit-haltiger Metagabbros und gabbroider Blastomylonite führten. Die während kryptischer und offener Skapolitisierung stattfindende Elementtransport wurde mit Hilfe der vonGresens entwickelten generellen metasomatischen Gleichung errechnet; Korrekturen für Varänderungen in spezifischer Dichte und Volumen wurden angebracht. Metasomatische Variationsdiagramme basierend auf Analysen an zwei primären Gabbros und sechs modifizierten Gesteinen zeigen, daß Na, K, Cl, Li, Rb und Ba die hauptsächlich zugeführten Elemente darstellen, und daß Cu-und S-Konzentrationen abgebaut wurden. Diese Veränderungen sind vergleichbar mit solchen, wie sie bei der Bildung metasomatischer, Nephelin-haltiger Gesteine erkannt wurden. Außerdem fallen Nephelinisierung und Skapolitisierung zeitlich und räumlich in etwa zusammen. Daraus kann geschlossen werden, daß Nephelin- und Skapolit-haltige Gesteine und deren kryptische Phasen durch den gleichen metasomatischen Prozeß entstanden sind, und daß die Herkunft der umwandelnden Lösungen möglicherweise in evaporitischen Sedimenten zu suchen ist, in die der Gabbro intrudierte.


With 3 Figures  相似文献   

16.
夏季长江河口潮间带反硝化作用和N2O的排放与吸收   总被引:15,自引:1,他引:15  
采用培养箱乙炔抑制和现场静态箱法,于夏季(7月)在长江河口潮滩潮间带进行了采样,研究表明,长江河口潮滩水体自身N2O产生速率很低,在潮汐淹没期沉积物是上覆水体N2O的来源,其来自沉积物中反硝化、硝化等氮素循环的多个反应过程,沉积物中N2O自然产生速率在0.10~8.50μmol/(m2·h)之间,反硝化速率在21.91~35.87μmol/(m2·h)之间。退潮出露期中潮滩是大气N2O的排放源犤交换速率在-11.03~13.17μmol/(m2·h)之间犦,5~10cm地温是影响N2O排放速率的显著性因素;低潮滩-大气界面N2O排放、吸收速率在-5.75~0.49μmol/(m2·h)之间。总体上看,中潮滩是大气N2O的排放源;而低潮滩对大气N2O有明显的吸收作用。潮滩植被(海三棱草和底栖藻类)的光合作用明显抑制了N2O的排放并可能导致吸收,而其呼吸作用则增加了N2O的排放,潮间带-大气界面N2O的排放和吸收与CO2的排放、吸收有显著的正相关关系。  相似文献   

17.
The occurrence of fluoride in ground water is the focus of the public and has attracted the attention of many scientists all over the world due to its importance in public health. Deficiency or increase of fluoride uptake is considered a public health problem due to the narrow permissible limit which should not exceed 1.5 mg/l according to the World Health Organization (WHO). The range of fluoride tolerance and toxicity is narrow. Deviation from the optimal levels therefore results in dental health effects such as caries and fluorosis. Many studies have found fluorosis to be invariably associated with high concentrations of fluoride in drinking water. Fluorosis is a considerable health problem in many areas of the world including Brazil, China, East Africa, Ghana, India, Kenya, Korea, Malawi, Mexico, Pakistan, South Africa, southeastern Korea, Spain, Sri Lanka, Sudan, Taiwan, Tanzania, and Turkey. Fluoride in groundwater of Quaternary aquifer of the Nile Valley, Egypt, does not gain the attention of the authors in the Nile Valley which makes the public health status of fluoride is not certain. The present work aims at investigating the fluoride concentration of Quaternary groundwater aquifer at Luxor as a representative area of the Nile Valley to be a base line for subsequent studies and criteria for public health. Ground water samples were collected from Quaternary groundwater aquifer at Luxor area, Egypt and analyzed for the purpose of investigating fluoride content. The results showed that fluoride concentration in the study area ranges between 0.113 and 0.452 with an average of 0.242 mg/l. Sources of fluoride in the study area can result from the natural dissolution from fluoride-rich minerals, fertilizers and from groundwater recharge. It is worth mentioning that low fluoride content in the study area is considered a public health threat specially limited growth, fertility, and dental caries. Corrective measures should be taken to avoid the public health impacts of fluoride deficiency at Luxor area as well as similar areas in the Nile Valley. A public health program should be initiated to account for the deficiency of fluoride in groundwater and deal with the other supplementary fluoride sources in food or fluoridation of drinking water supplies.  相似文献   

18.
Summary Crystallization temperatures of the oceanic carbonatites of Fuerteventura, Canary Islands, have been determined from oxygen isotope fractionations between calcite, silicate minerals (feldspar, pyroxene, biotite, and zircon) and magnetite. The measured fractionations have been interpreted in the light of late stage interactions with meteoric and/or magmatic water. Cathodoluminescence characteristics were investigated for the carbonatite minerals in order to determine the extent of alteration and to select unaltered samples. Oxygen isotope fractionations of minerals of unaltered samples yield crystallization temperatures between 450 and 960°C (average 710°C). The highest temperature is obtained from pyroxene–calcite pairs. The above range is in agreement with other carbonatite thermometric studies.This is the first study that provides oxygen isotope data coupled with a CL study on carbonatite-related zircon. The CL pictures revealed that the zircon is broken and altered in the carbonatites and in associated syenites. Regarding geological field evidences of syenite–carbonatite relationship and the close agreement of published zircon U/Pb and whole rock and biotite K/Ar and Ar–Ar age data, the most probable process is early zircon crystallization from the syenite magma and late-stage reworking during magma evolution and carbonatite segregation. The oxygen isotope fractionations between zircon and other carbonatite minerals (calcite and pyroxene) support the assumption that the zircon would correspond to the early crystallization of syenite–carbonatite magmas.  相似文献   

19.
捕虏体麻粒岩是了解下地壳形成和演化的重要样品。汉诺坝新生代玄武岩中的二辉麻粒岩捕虏体样品中富含各种硫化物相,主要类型有:①孤立产出的球状出溶硫化物;②矿物颗粒之间或颗粒内的粗晶硫化物;③次生硫化物包裹体群;④裂隙充填硫化物。电子探针分析表明,硫化物的矿物成分均为贫镍磁黄铁矿,(Ni+Co+Cu)/Fe(原子比)远小于0.2;(Fe+Cu+Co+Ni)/S(原子比)比地幔岩的磁黄铁矿小,多小于0.875,反映了一种S过饱和环境。各种产状的磁黄铁矿中Au、Ag都有一定的含量,其平均值分别为0.19%~0.22%(Au)、0.01%~0.02%(Ag),反映下地壳的麻粒岩化与金矿化的成因联系。磁黄铁矿的Ni、Co、Cu含量与S正相关,说明微量重金属元素与S具有同源的关系,由于地幔去气伴随S而进入下地壳。  相似文献   

20.
Abstract The 6-km-thick Karmutsen metabasites, exposed over much of Vancouver Island, were thermally metamorphosed by intrusions of Jurassic granodiorite and granite. Observations of about 800 thin sections from the Campbell River and Buttle Lake area show that the metabasites provide a complete succession of mineral assemblages ranging from the zeolite to pyroxene hornfels facies around the intrusion. The most important observations are as follows. (1) The compositional change of Ca-amphiboles with increasing metamorphic grade is not straightforward. The tremolite component decreases from the prehnite–actinolite facies to the greenschist facies with a compensating tschermak component increase, but the tendency is not clear thereafter. Instead, the edenite component increases from the amphibolite facies to the pyroxene hornfels facies. (2) The most pargasitic Ca-amphibole occurs in high-Fe2+/Mg metabasite from the greenschist/amphibolite transition zone. (3) The reasons for such irregular compositional trends, even in the rather uniform MORB-like composition of the Karmutsen metabasites, are non-ideal solid solutions of Ca-amphibole at low temperature and the effective control by bulk rock composition in the amphibolite facies. (4) The data from this study support, but do not prove, a transition loop for the actinolite–hornblende compositional gap rather than a solvus. If the gap is a solvus, its shape is asymmetric, and is highly dependent on the other compositional parameters such as Fe3+/Al and Fe2+/Mg. (5) The XNaA/XA±XAb) ratios between Ca-amphibole and plagioclase are most useful as an indicator of metamorphic grade even within the amphibolite facies, and these change systematically from 0.2 to 0.5 from the greenschist to pyroxene hornfels facies. (6) The compositional trend of Ca-amphibole from the Karmutsen metabasites indicates a typical low-P/T metamorphic facies series on a Rbk–Gln–Tr–Ts diagram.  相似文献   

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