Phase equilibrium modelling of the amphibolite to granulite facies transition in metabasic rocks (Ivrea Zone,NW Italy)     

Barbara E. Kunz  Richard W. White 《Journal of Metamorphic Geology》2019,37(7):935-950

The development of thermodynamic models for tonalitic melt and the updated clinopyroxene and amphibole models now allow the use of phase equilibrium modelling to estimate P–T conditions and melt production for anatectic mafic and intermediate rock types at high‐T conditions. The Permian mid‐lower crustal section of the Ivrea Zone preserves a metamorphic field gradient from mid amphibolite facies to granulite facies, and thus records the onset of partial melting in metabasic rocks. Interlayered metabasic and metapelitic rocks allows the direct comparison of P–T estimates and partial melting between both rock types with the same metamorphic evolution. Pseudosections for metabasic compositions calculated in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (NCKFMASHTO) system are presented and compared with those of metapelitic rocks calculated with consistent end‐member data and a–x models. The results presented in this study show that P–T conditions obtained by phase equilibria modelling of both metabasic and metapelitic rocks give consistent results within uncertainties, allowing integration of results obtained for both rock types. In combination, the calculations for both metabasic and metapelitic rocks allows an updated and more precisely constrained metamorphic field gradient for Val Strona di Omegna to be defined. The new field gradient has a slightly lower dP/dT which is in better agreement with the onset of crustal thinning of the Adriatic margin during the Permian inferred in recent studies.  相似文献   

Coal mining‐derived ochres in the UK: a potential selenium trap     

Liam A. Bullock  John Parnell  Magali Perez  Joseph G.T. Armstrong 《Geology Today》2019,35(4):140-145

Thanks to the pioneering research of Paul Younger over the past 20 years, acid mine drainage in the UK has been recognized as a major environmental issue. Acid mine drainage and hydrous ferric oxide deposition are environmental hazards resulting from centuries of extensive coal mining activities across the UK. Oxidative weathering of pyrite in coal from spoil heaps and exposed bedrock can liberate trace elements, releasing them into local water systems. In addition to posing an environmental threat through water and ground contamination, ochres can also act as a remediation material, trapping elements such as selenium. Trace elements with a close association to iron oxides, such as selenium, may fix to the fine‐grained ochre materials, resulting in hyper‐enriched ochres. Selenium in coals has been known to cause an environmental issue in areas of North America but is also an important commodity for solar cells and nanotechnologies. Coal‐bearing areas of the UK, such as Northumberland, are known to contain a high selenium content, and coal‐derived ochres in these regions also contain significant selenium. The widespread occurrence of ochres in UK coal‐mining regions may therefore present a unique ‘E tech’ trace element source and prevent a toxicity problem for which they were once thought to be responsible.  相似文献   

Effects of rainfall,overland flow and their interactions on peatland interrill erosion processes          下载免费PDF全文

Changjia Li  Joseph Holden  Richard Grayson 《地球表面变化过程与地形》2018,43(7):1451-1464

Interrill erosion processes on gentle slopes are affected by mechanisms of raindrop impact, overland flow and their interaction. However, limited experimental work has been conducted to understand how important each of the mechanisms are and how they interact, in particular for peat soil. Laboratory simulation experiments were conducted on peat blocks under two slopes (2.5° and 7.5°) and three treatments: Rainfall, where rainfall with an intensity of 12 mm h^?1 was simulated; Inflow, where upslope overland flow at a rate of 12 mm h^?1 was applied; and Rainfall + Inflow which combined both Rainfall and Inflow. Overland flow, sediment loss and overland flow velocity data were collected and splash cups were used to measure the mass of sediment detached by raindrops. Raindrop impact was found to reduce overland flow by 10 to 13%, due to increased infiltration, and reduce erosion by 47% on average for both slope gradients. Raindrop impact also reduced flow velocity (80–92%) and increased roughness (72–78%). The interaction between rainfall and flow was found to significantly reduce sediment concentrations (73–85%). Slope gradient had only a minor effect on overland flow and sediment yield. Significantly higher flow velocities and sediment yields were observed under the Rainfall + Inflow treatment compared to the Rainfall treatment. On average, upslope inflow was found to increase erosion by 36%. These results indicate that overland flow and erosion processes on peat hillslopes are affected by upslope inflow. There was no significant relationship between interrill erosion and overland flow, whereas stream power had a strong relationship with erosion. These findings help improve our understanding of the importance of interrill erosion processes on peat. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

New constraints on granulite facies metamorphism and melt production in the Lewisian Complex,northwest Scotland          下载免费PDF全文

Yves Feisel  Richard W. White  Richard M. Palin  Tim E. Johnson 《Journal of Metamorphic Geology》2018,36(6):799-819

In this study, we investigate the metamorphic history of the Assynt and Gruinard blocks of the Archean Lewisian Complex, northwest Scotland, which are considered by some to represent discrete crustal terranes. For samples of mafic and intermediate rocks, phase diagrams were constructed in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (NCKFMASHTO) system using whole‐rock compositions. Our results indicate that all samples equilibrated at similar peak metamorphic conditions of ~8–10 kbar and ~900–1,000°C, consistent with field evidence for in situ partial melting and the classic interpretation of the central region of the Lewisian Complex as representing a single crustal block. Melt‐reintegration modelling was employed in order to estimate probable protolith compositions. Phase equilibria calculated for these modelled undepleted precursors match well with those determined for a subsolidus amphibolite from Gairloch in the southern region of the Lewisian Complex. Both subsolidus lithologies exhibit similar phase relations and potential melt fertility, with both expected to produce orthopyroxene‐bearing hornblende granulites, with or without garnet, at the conditions inferred for the Badcallian metamorphic peak. For fully hydrated protoliths, prograde melting is predicted to first occur at ~620°C and ~9.5 kbar, with up to 45% partial melt predicted to form at peak conditions in a closed‐system environment. Partial melts calculated for both compositions between 610 and 1,050°C are mostly trondhjemitic. Although the melt‐reintegrated granulite is predicted to produce more potassic (granitic) melts at ~700–900°C, the modelled melts are consistent with the measured compositions of felsic sheets from the central region Lewisian Complex.  相似文献   

Assessment of soil erosion in a monsoon-dominated mountain river basin in India using RUSLE-SDR and AHP   总被引：1，自引：1，他引：0  

Jobin Thomas  Sabu Joseph  K. P. Thrivikramji 《水文科学杂志》2018,63(4):542-560

The long-term average annual soil loss (A) and sediment yield (SY) in a tropical monsoon-dominated river basin in the southern Western Ghats, India (Muthirapuzha River Basin, MRB; area: 271.75 km²), were predicted by coupling the Revised Universal Soil Loss Equation (RUSLE) and sediment delivery ratio (SDR) models. Moreover, the study also delineated soil erosion risk zones based on the soil erosion potential index (SEPI) using the analytic hierarchy process (AHP) technique. Mean A of the basin is 14.36 t ha^?1 year^?1, while mean SY is only 3.65 t ha^?1 year^?1. Although the land use/land cover types with human interference show relatively lower A compared to natural vegetation, their higher SDR values reflect the significance of anthropogenic activities in accelerated soil erosion. The soil erosion risk in the MRB is strongly controlled by slope, land use/land cover and relative relief, compared to geomorphology, drainage density, stream frequency and lineament frequency.  相似文献   

Character and origin of De Geer moraines in the Seacoast region of New Hampshire,USA          下载免费PDF全文

Samantha N. Sinclair  Joseph M. Licciardi  Seth W. Campbell  Brian M. Madore 《第四纪科学杂志》2018,33(2):225-237

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Near‐surface hydraulic conductivity of northern hemisphere glaciers          下载免费PDF全文

Ian T. Stevens  Tristram D.L. Irvine‐Fynn  Philip R. Porter  Joseph M. Cook  Arwyn Edwards  Martin Smart  Brian J. Moorman  Andy J. Hodson  Andrew C. Mitchell 《水文研究》2018,32(7):850-865

The hydrology of near‐surface glacier ice remains a neglected aspect of glacier hydrology despite its role in modulating meltwater delivery to downstream environments. To elucidate the hydrological characteristics of this near‐surface glacial weathering crust, we describe the design and operation of a capacitance‐based piezometer that enables rapid, economical deployment across multiple sites and provides an accurate, high‐resolution record of near‐surface water‐level fluctuations. Piezometers were employed at 10 northern hemisphere glaciers, and through the application of standard bail–recharge techniques, we derive hydraulic conductivity (K) values from 0.003 to 3.519 m day^?1, with a mean of 0.185 ± 0.019 m day^?1. These results are comparable to those obtained in other discrete studies of glacier near‐surface ice, and for firn, and indicate that the weathering crust represents a hydrologically inefficient aquifer. Hydraulic conductivity correlated positively with water table height but negatively with altitude and cumulative short‐wave radiation since the last synoptic period of either negative air temperatures or turbulent energy flux dominance. The large range of K observed suggests complex interactions between meteorological influences and differences arising from variability in ice structure and crystallography. Our data demonstrate a greater complexity of near‐surface ice hydrology than hitherto appreciated and support the notion that the weathering crust can regulate the supraglacial discharge response to melt production. The conductivities reported here, coupled with typical supraglacial channel spacing, suggest that meltwater can be retained within the weathering crust for at least several days. Not only does this have implications for the accuracy of predictive meltwater run‐off models, but we also argue for biogeochemical processes and transfers that are strongly conditioned by water residence time and the efficacy of the cascade of sediments, impurities, microbes, and nutrients to downstream ecosystems. Because continued atmospheric warming will incur rising snowline elevations and glacier thinning, the supraglacial hydrological system may assume greater importance in many mountainous regions, and consequently, detailing weathering crust hydraulics represents a research priority because the flow path it represents remains poorly constrained.  相似文献   

Artificial neural network simulation for prediction of suspended sediment concentration in the River Ramganga,Ganges Basin,India     

Mohd Yawar Ali Khan  Fuqiang Tian  Faisal Hasan  Govind Joseph Chakrapani 《国际泥沙研究》2019,34(2):95-107

The relation between the water discharge (Q) and suspended sediment concentration (SSC) of the River Ramganga at Bareilly, Uttar Pradesh, in the Himalayas, has been modeled using Artificial Neural Networks (ANNs). The current study validates the practical capability and usefulness of this tool for simulating complex nonlinear, real world, river system processes in the Himalayan scenario. The modeling approach is based on the time series data collected from January to December (2008–2010) for Q and SSC. Three ANNs (T1-T3) with different network configurations have been developed and trained using the Levenberg Marquardt Back Propagation Algorithm in the Matlab routines. Networks were optimized using the enumeration technique, and, finally, the best network is used to predict the SSC values for the year 2011. The values thus obtained through the ANN model are compared with the observed values of SSC. The coefficient of determination (R²), for the optimal network was found to be 0.99. The study not only provides insight into ANN modeling in the Himalayan river scenario, but it also focuses on the importance of understanding a river basin and the factors that affect the SSC, before attempting to model it. Despite the temporal variations in the study area, it is possible to model and successfully predict the SSC values with very simplistic ANN models.  相似文献   

Soil erosion rates assessed by RUSLE and PESERA for a Chinese Loess Plateau catchment under land-cover changes     

Pengfei Li  Yuzhe Zang  Doudou Ma  Wanqiang Yao  Joseph Holden  Brian Irvine  Guangju Zhao 《地球表面变化过程与地形》2020,45(3):707-722

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Compartmentalisation and groundwater–surface water interactions in a prospective shale gas basin: Assessment using variance analysis and multivariate statistics on water quality data     

Miles P. Wilson  Fred Worrall  Sarah A. Clancy  Chris J. Ottley  Alwyn Hart  Richard J. Davies 《水文研究》2020,34(15):3271-3294

An environmental concern with hydraulic fracturing for shale gas is the risk of groundwater and surface water contamination. Assessing this risk partly involves the identification and understanding of groundwater–surface water interactions because potentially contaminating fluids could move from one water body to the other along hydraulic pathways. In this study, we use water quality data from a prospective shale gas basin to determine: if surface water sampling could identify groundwater compartmentalisation by low-permeability faults; and if surface waters interact with groundwater in underlying bedrock formations, thereby indicating hydraulic pathways. Variance analysis showed that bedrock geology was a significant factor influencing surface water quality, indicating regional-scale groundwater–surface water interactions despite the presence of an overlying region-wide layer of superficial deposits averaging 30–40 m thickness. We propose that surface waters interact with a weathered bedrock layer through the complex distribution of glaciofluvial sands and gravels. Principal component analysis showed that surface water compositions were constrained within groundwater end-member compositions. Surface water quality data showed no relationship with groundwater compartmentalisation known to be caused by a major basin fault. Therefore, there was no chemical evidence to suggest that deeper groundwater in this particular area of the prospective basin was reaching the surface in response to compartmentalisation. Consequently, in this case compartmentalisation does not appear to increase the risk of fracking-related contaminants reaching surface waters, although this may differ under different hydrogeological scenarios.  相似文献