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161.
The karst environment is one of the most challenging in terms of groundwater, engineering and environmental issues. Geophysical methods can provide useful subsurface information in karst regions concerning, for instance, hazard estimation or groundwater exploration and vulnerability assessment. However, a karst area remains a very difficult environment for any geophysical exploration; selection of the best-suited geophysical method is not always straightforward, due to the highly variable and unpredictable target characteristics. The state of the art is presented, in terms of the contributions made by geophysical methods to karst-system exploration, based on extensive analysis of the published scientific results. This report is an overview and should be used as a preliminary methodological approach, rather than a guideline.  相似文献   
162.
163.
Xenotime overgrowths on detrital zircon in siliciclastic sediments have been reported in numerous studies. However, in natural samples, solid solution of zircon and xenotime is limited to near-end-member compositions. In order to characterize the interface region between both minerals and to draw inferences on the growth mechanisms of authigenic xenotime, we studied xenotime overgrowths on detrital zircon grains from two Phanerozoic sandstone samples with contrasting post-depositional histories. In one sample, the small (≤10 μm), pyramidal xenotime overgrowths are of diagenetic origin and grew without major discontinuity on the detrital zircon grain. The second sample shows up to >50-μm-wide, porous and inclusion-rich, hydrothermal xenotime overgrowths on detrital zircon, whereas the transition zone between both minerals is accompanied by large pore volume. Chemical compositions of the xenotime precipitates from the two samples differ particularly in Y, REE, Th and Sc concentrations, whereas high MREE availability in the diagenetic sample and the presence of Sc in the hydrothermal sample, respectively, appear to have promoted xenotime growth. Transmission electron microscopy on electron-transparent foils cut from the interface region shows that both the diagenetic xenotime and the hydrothermal xenotime are crystalline and grew in optical and crystallographic continuity to their detrital zircon substrata. Only a narrow transition zone (≤90 nm—diagenetic sample, 200–300 nm—hydrothermal sample) between zircon and xenotime is in part made up of nanometre-scale crystalline domains that are slightly distorted and may have formed from dissolution–re-precipitation processes at the zircon rim along with precipitation from the respective fluid.  相似文献   
164.
Sensitive high-resolution ion microprobe zircon U–Pb dating and geochemical data of igneous rocks from the composite K?odzko–Z?oty Stok (KZS) Granite Pluton, Sudetic Block, indicate that the granitoids represent an Early Carboniferous Viséan phase of Variscan metaluminous, high-K, I-type, syn-collisional granite magmatism within the Saxothuringian Zone of the Central European Variscides. Igneous zircon records hypabyssal magmatism that produced various granitoids and lamprophyre (spessartite) emplaced from ca. 340 to 331 Ma. The KZS granitoids have compositions ranging from granodiorite to monzonite, low A/CNK ratios (<1), and are associated with abundant mafic members. Most of them are alkaline, highly potassic, and moderately evolved. The major and trace element contents of the KZS granitoids suggest geochemical heterogeneity, and the hybrid nature of magmas derived from a range of sources in the middle crust, with a strong input of material from the upper mantle. Mixing of magmas of mantle origin with high-K material from partly melted continental crust was probably a more important factor than fractional crystallization, in controlling the evolution of the magmas. The mean Pb–U ages of the main population of igneous zircon from a quartz monzodiorite (?elazno) and hornblende monzonite (Droszków) are 340.2 ± 2.5 Ma and 339.5 ± 3.1 Ma, respectively. A slightly younger biotite-hornblende granodiorite from Chwalis?aw, 336.7 ± 2.5 Ma, was cut by a spessartite dyke at 333.1 ± 3.1 Ma. This indicates that mafic magmas were immediately intruded into fractured, probably incompletely solidified, granodiorites. The lamprophyric dyke also contains igneous zircon of Neoproterozoic age, 566.3 ± 6.4 Ma, typical of the crust in the Saxothuringian Zone. Tonalite from Ptasznik Hill near Droszków is of similar age to the spessartite, 331.5 ± 2.6 Ma. High REE contents in the tonalite and its igneous zircon indicate advanced differentiation of granitic magma, producing a more leucocratic melt associated with post-magmatic activity including abundant late crosscutting pegmatites and quartz veins, and contact metasomatic mineralization. The KZS granitoids have rather similar petrographic and geochemical characteristics to granitoids from other parts of the Central European Variscides, where a thickened orogenic root caused a substantial rise in crustal temperatures, producing granitoid magmas closely correlated with regional tectonic activity between the Saxothuringian and Brunovistulia Terranes at the NE margin of the Bohemian Massif.  相似文献   
165.
Most ground-penetrating radar (GPR) measurements are performed on nearly flat areas. If strongly dipping reflections and/or diffractions are present in the GPR data, a classical migration-processing step is needed in order to determine the geometries of shallow structures. Nevertheless, a standard migration routine is not suitable for GPR data collected on areas showing a variable and large topographic relief. To take into account topographic variations, the GPR data are, in general, corrected by applying static shifts instead of using an appropriate topographic migration that would place the reflectors at their correct locations with the right dip angle. In this article, we present an overview of Kirchhoff's migration and show the importance of topographic migration in the case where the depth of the target structures is of the same order as the relief variations. Examples of synthetic and real GPR data are shown to illustrate the efficiency of the topographic migration.  相似文献   
166.
The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.  相似文献   
167.
Enhanced oil recovery based on CO2 injection is expected to increase recovery from Croatian oil fields. Large quantities of CO2 are generated during hydrocarbon processing produced from gas and gas condensate fields situated in the north-western part of Croatia. First CO2 injection project will be implemented on the Ivani? Oil Field. Numerical modelling based on Upper Miocene sandstone core samples testing results have shown the decrease of oil viscosity during CO2 injection. Some of the characteristics of the testing samples are porosity 21.5–23.6 %, permeability 14–80 × 10?15 m2 and initial water saturation 28–38.5 %. Water alternating foam (WAF) and water alternating gas (WAG) simulations have provided satisfactory results. The WAF injection process has provided better results, but due to the process sensitivity and costs WAG is recommended for future application. During the pilot project 16 × 106 m3 CO2 and 5 × 104 m3 of water were injected. Additional amounts of hydrocarbons (4,440 m3 of oil and 2.26 × 106 m3 of gas) were produced which confirmed injection of CO2 as a successful tertiary oil recovery mechanism in Upper Miocene sandstone reservoirs in the Croatian part of the Pannonian Basin System.  相似文献   
168.
A palaeomagnetic study is reported from the lavas of Eocene, Miocene and Pliocene age cropping out immediately to the north of the North Anatolian Fault Zone (NAFZ) in the Re?adiye–Mesudiye region of central-eastern Anatolia. Rock magnetic investigations identify a high percentage of multi-domained magnetite as the dominant ferromagnet in these rocks and this probably accounts for a relatively poor response to alternating field and thermal demagnetisation. Thirty of 37 units yielded acceptable groupings of characteristic magnetisation directions. An earlier study indicated small anticlockwise crustal block rotation in this region since Upper Cretaceous times (D/I?=?347/50°), and our study indicates that this was overtaken by clockwise rotation in Eocene times (D/I?=?40/47°), although sample size control from the Palaeogene is poor. Results from later Miocene (D/I?=?2/62°) and Pliocene (D/I?=?0/53°) volcanic rocks indicate that no significant tectonic rotation has occurred in the north of the NAFZ in Neogene times. This contrasts with rotations in the weaker crust comprising the Anatolian collage south of the NAFZ, where differential and sometimes large anticlockwise rotations occurred during the latter part of the Neogene.  相似文献   
169.
The paper describes a new method of gravity modelling of the density cross section along a DSS profile. We propose a systematic procedure of gravity interpretation using structural information contained both in the velocity distribution of the seismic model and the geometry of its layers. The procedure is based on the optimisation of the density parameters of the model. The values of the parameters are limited by relationships between the seismic velocity and the density (optimisation with inequalities). The formulation of the method allows for discussion of the presence of isostasy and the distribution of compensating masses. The discussion is very important for the considered crust-lithosphere system. The presented calculations are done for one Carpathian profile (CEL01). The analysis of the properties of the fitting procedure provides the characteristic depth of subcrustal compensating density structures, the position of crucial tectonic boundaries along the profiles, locations of the crustal areas having exceptional lithology, the regional density differences of subcrustal matter and the estimation of regional deviations from the isostatic equilibrium.  相似文献   
170.
Source parameters estimated in the frequency domain for 100 selected seismic events from the Rudna copper mine, with moment magnitude ranging from 1.4 to 3.6, were collected to study their scaling relations and to compare them with the parameters estimated in the time domain. The apparent stress and static stress drop, corrected for the limited bandwidth recording, increase slightly in a similar manner with increasing seismic moment. The ratio of apparent stress to static stress drop, a measure of radiation efficiency, is practically constant and its mean value is close to 0.1. For 37 seismic events, with moment magnitude between 1.9 and 3.4, source parameters were estimated in the time domain from relative source time functions, that displayed unilateral rupture propagation, and their rupture velocity could be estimated. It ranges from 0.23 to 0.80 of shear wave velocity and is almost independent of seismic moment. The fault length, estimated from the average source pulse width and rupture velocity, is clearly dependent on seismic moment and is smaller than the source radius estimated from the corner frequency on the average by about 25 percent. There is no correlation between the values of static stress drop estimated in the frequency and time domains, but the time domain stress drop is in general similar to that estimated in the frequency domain. The apparent stress increases with increasing rupture velocity, and the ratio of apparent stress to static stress drop seems also to depend on rupture velocity.  相似文献   
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