Defining an absolute reference frame for ‘clumped’ isotope studies of CO₂     

Kate J. Dennis  Hagit P. Affek  Daniel P. Schrag 《Geochimica et cosmochimica acta》2011,75(22):7117-7131

We present a revised approach for standardizing and reporting analyses of multiply substituted isotopologues of CO₂ (i.e., ‘clumped’ isotopic species, especially the mass-47 isotopologues). Our approach standardizes such data to an absolute reference frame based on theoretical predictions of the abundances of multiply-substituted isotopologues in gaseous CO₂ at thermodynamic equilibrium. This reference frame is preferred over an inter-laboratory calibration of carbonates because it enables all laboratories measuring mass 47 CO₂ to use a common scale that is tied directly to theoretical predictions of clumping in CO₂, regardless of the laboratory’s primary research field (carbonate thermometry or CO₂ biogeochemistry); it explicitly accounts for mass spectrometric artifacts rather than convolving (and potentially confusing) them with chemical fractionations associated with sample preparation; and it is based on a thermodynamic equilibrium that can be experimentally established in any suitably equipped laboratory using commonly available materials.By analyzing CO₂ gases that have been subjected to established laboratory procedures known to promote isotopic equilibrium (i.e., heated gases and water-equilibrated CO₂), and by reference to thermodynamic predictions of equilibrium isotopic distributions, it is possible to construct an empirical transfer function that is applicable to data with unknown clumped isotope signatures. This transfer function empirically accounts for the fragmentation and recombination reactions that occur in electron impact ionization sources and other mass spectrometric artifacts. We describe the protocol necessary to construct such a reference frame, the method for converting gases with unknown clumped isotope compositions to this reference frame, and suggest a protocol for ensuring that all reported isotopic compositions (e.g., Δ₄₇ values; [Eiler and Schauble, 2004] and [Eiler, 2007]) can be compared among different laboratories and instruments, independent of laboratory-specific analytical or methodological differences. We then discuss the use of intra-laboratory secondary reference frames (e.g., based on carbonate standards) that can be more easily used to track the evolution of each laboratory’s empirical transfer function. Finally, we show inter-laboratory reproducibility on the order of ±0.010 (1σ) for four carbonate standards, and present revised paleotemperature scales that should be used to convert carbonate clumped isotope signatures to temperature when using the absolute reference frame described here. Even when using the reference frame, small discrepancies remain between two previously published synthetic carbonate calibrations. We discuss possible reasons for these discrepancies, and highlight the need for additional low temperature (<15 °C) synthetic carbonate experiments.  相似文献   

Societal need for improved understanding of climate change, anthropogenic impacts, and geo-hazard warning drive development of ocean observatories in European Seas     

Henry A. Ruhl  Michel AndréLaura Beranzoli  M. Namik Ça?atayAna Colaço  Mathilde CannatJuanjo J. Dañobeitia  Paolo FavaliLouis Géli  Michael GilloolyJens Greinert  Per O.J. HallRobert Huber  Johannes KarstensenRichard S. Lampitt  Kate E. LarkinVasilios Lykousis  Jürgen MienertJ. Miguel Miranda  Roland PersonImants G. Priede  Ingrid PuillatLaurenz Thomsen  Christoph Waldmann 《Progress in Oceanography》2011,91(1):1-33

Society’s needs for a network of in situ ocean observing systems cross many areas of earth and marine science. Here we review the science themes that benefit from data supplied from ocean observatories. Understanding from existing studies is fragmented to the extent that it lacks the coherent long-term monitoring needed to address questions at the scales essential to understand climate change and improve geo-hazard early warning. Data sets from the deep sea are particularly rare with long-term data available from only a few locations worldwide. These science areas have impacts on societal health and well-being and our awareness of ocean function in a shifting climate.Substantial efforts are underway to realise a network of open-ocean observatories around European Seas that will operate over multiple decades. Some systems are already collecting high-resolution data from surface, water column, seafloor, and sub-seafloor sensors linked to shore by satellite or cable connection in real or near-real time, along with samples and other data collected in a delayed mode. We expect that such observatories will contribute to answering major ocean science questions including: How can monitoring of factors such as seismic activity, pore fluid chemistry and pressure, and gas hydrate stability improve seismic, slope failure, and tsunami warning? What aspects of physical oceanography, biogeochemical cycling, and ecosystems will be most sensitive to climatic and anthropogenic change? What are natural versus anthropogenic changes? Most fundamentally, how are marine processes that occur at differing scales related?The development of ocean observatories provides a substantial opportunity for ocean science to evolve in Europe. Here we also describe some basic attributes of network design. Observatory networks provide the means to coordinate and integrate the collection of standardised data capable of bridging measurement scales across a dispersed area in European Seas adding needed certainty to estimates of future oceanic conditions. Observatory data can be analysed along with other data such as those from satellites, drifting floats, autonomous underwater vehicles, model analysis, and the known distribution and abundances of marine fauna in order to address some of the questions posed above. Standardised methods for information management are also becoming established to ensure better accessibility and traceability of these data sets and ultimately to increase their use for societal benefit. The connection of ocean observatory effort into larger frameworks including the Global Earth Observation System of Systems (GEOSS) and the Global Monitoring of Environment and Security (GMES) is integral to its success. It is in a greater integrated framework that the full potential of the component systems will be realised.  相似文献   

Tectonostratigraphic evolution of the Labrador margin, Atlantic Canada     

Kate Dickie  Charlotte E. KeenGraham L. Williams  Sonya A. Dehler 《Marine and Petroleum Geology》2011,28(9):1663-1675

The Labrador continental margin provides a rich source of data with which to study the relationships between stratigraphy, tectonics and paleoenvironment. We have completed a regional seismic interpretation and integrated this with new biostratigraphic data, based on analyses of palynomorphs from wells in the Hopedale and Saglek Basins which occur on this margin. Our results are summarized in a tectonostratigraphic chart, which displays new and consistent age control for the major lithostratigraphic units and provides more precise evaluation of their depositional and paleoenvironmental history. We have identified and dated six regional unconformities in the wells and we can recognize several others on the seismic data. The older unconformities (Cretaceous) are related to the tectonics of rifting and seafloor spreading, and may delineate the onset of different stages of the rift process. In the Paleocene-Early Eocene, unconformity development was influenced by episodic volcanism due to the passage of the proto-Iceland hotspot to the north and to a major change in spreading direction in the Labrador Sea. Many of these unconformities are also identified in offshore southwest Greenland and the Grand Banks, suggesting widespread controlling mechanisms. During the post-seafloor spreading stage the effects of mass wasting and slumping, and of paleoenvironmental controls on the stratigraphy, were more pronounced. We discuss the petroleum potential of the Hopedale Basin in terms of the structures we see on the seismic data, and highlight the Bjarni Formation, which likely contains the most prospective source and reservoir rocks in this Basin.  相似文献   

Ecosystem-based marine spatial management: Review of concepts, policies, tools, and critical issues   总被引：1，自引：0，他引：1  

Stelios Katsanevakis  Vanessa Stelzenmüller  Andy South  Thomas Kirk Sørensen  Peter J.S. Jones  Sandy Kerr  Fabio Badalamenti  Christos Anagnostou  Patricia Breen  Guillem Chust  Giovanni D’Anna  Mike Duijn  Tatiana Filatova  Fabio Fiorentino  Helena Hulsman  Kate Johnson  Aristomenis P. Karageorgis  Ingrid Kröncke  Simone Mirto  Carlo Pipitone  Susan Portelli  Wanfei Qiu  Henning Reiss  Dimitris Sakellariou  Maria Salomidi  Luc van Hoof  Vassiliki Vassilopoulou  Tomás Vega Fernández  Sandra Vöge  Anke Weber  Argyro Zenetos  Remment ter Hofstede 《Ocean & Coastal Management》2011,54(11):807-820

Conventional sectoral management and piecemeal governance are considered less and less appropriate in pursuit of sustainable development. Ecosystem based marine spatial management (EB-MSM) is an approach that recognizes the full array of interactions within an ecosystem, including human uses, rather than considering single issues, species, or ecosystem services in isolation. Marine spatial planning and ocean zoning are emerging concepts that can support EB-MSM. EB-MSM is driven by high-level goals that managers aim to achieve through the implementation of measures. High-level goals and objectives need to be translated into more operational objectives before specific targets, limits and measures can be elaborated.Monitoring, evaluation and adaptation are necessary to ensure that marine management measures are both effective and efficient. Solid monitoring frameworks are the foundation of adaptive management, as they provide the necessary information to evaluate performance and the effectiveness of management actions. Marine protected areas (MPAs) - possibly set up in networks - constitute a key component in EB-MSM policies and practises and have been applied as a cornerstone in conservation of marine biodiversity, management of fish populations, development of coastal tourism, etc. Moreover, MPA experiences have provided methods and concepts (such as zoning) to a wider EB-MSM context. The assignment of values to biophysical features of the marine environment allows the direct assessment of related management choices and may assist EB-MSM.A range of monetary valuation techniques have been proposed to reduce attributes of goods and services to a single metric. However, in the marine environment such an approach is often over simplistic, and thus less reductive techniques may be necessary. Rather than producing a single metric, the results of non-monetary assessments guide policy allowing weight to be given as necessary to potential areas of conflict and consensus.Strategies to take into account climate change effects and geohazard risks in EB-MSM have been applied or proposed worldwide. EB-MSM regimes must be alert to such risks and flexible to account for changes.  相似文献   

The extragalactic submillimetre population: predictions for the SCUBA Half-Degree Extragalactic Survey (SHADES)     

Eelco van Kampen  Will J. Percival  Miller Crawford  James S. Dunlop  Susie E. Scott  Neil Bevis  Seb Oliver  Frazer Pearce  Scott T. Kay  Enrique Gaztañaga  David H. Hughes  Itziar Aretxaga 《Monthly notices of the Royal Astronomical Society》2005,359(2):469-480

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A survey of molecular hydrogen in the central galaxies of cooling flows     

A. C. Edge  R. J. Wilman  R. M. Johnstone  C. S. Crawford  A. C. Fabian  S. W. Allen 《Monthly notices of the Royal Astronomical Society》2002,337(1):49-62

We present a large sample of H - and K -band spectra of 32 optically line-luminous central cluster galaxies. We find significant rovibrational H₂ emission in 23 of these galaxies as well as H recombination and/or [Fe  ii ] emission in another five. This represents a fourfold increase in the number of molecular line detections known. A number of the detections are of extended emission (5–20 kpc). In several objects we find significant [Si  vi ] emission that appears to correlate with the strength of high ionization lines in the optical (e.g. [O  iii ]). This comprehensive sample builds on previous work and confirms that warm (1000–2500 K) molecular hydrogen is present wherever there is ionized material in the cores of cooling flows and in most cases it also coincides with CO molecular line emission.  相似文献   

A wave-mechanical approach to cosmic structure formation     

Peter Coles  Kate Spencer 《Monthly notices of the Royal Astronomical Society》2003,342(1):176-184

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Ultra-high-resolution observations of CH in Southern Molecular Cloud envelopes     

B-G. Andersson  P. G. Wannier  I. A. Crawford 《Monthly notices of the Royal Astronomical Society》2002,334(2):327-337

We present a mini-survey of ultrahigh-resolution spectroscopy (UHRS) of CH towards three southern molecular cloud envelopes. The sightlines are selected to probe physically similar gas in different Galactic environments. With a velocity resolution of ∼0.5 km s⁻¹  ( R =575 000)  these observations resolve most kinematic components of the absorption lines. We do, however, detect one line component in the Lupus region, which is not resolved and for which an upper limit of   b <0.3 km s^-1  is found. We find a correlation between distance of the absorbing gas from the Galactic mid-plane and the fractional abundance of CH. We show that this correlation can be explained as being a result of a fall-off in the ultraviolet radiation field intensity and propose that CH observations in carefully selected sightlines might allow a mapping of the variations in the interstellar radiation field.  相似文献   

The missing soft X-ray luminosity in cluster cooling flows     

A. C. Fabian  S. W. Allen  C. S. Crawford  R. M. Johnstone  R. G. Morris  J. S. Sanders  R. W. Schmidt 《Monthly notices of the Royal Astronomical Society》2002,332(3):L50-L54

The gas temperature in the cores of many clusters of galaxies drops inward by about a factor of 3 or more within the central 100-kpc radius. The radiative cooling time drops over the same region from 5 or more Gyr down to below a few 10⁸ yr. Although this indicates that cooling flows are taking place, XMM-Newton spectra show no evidence for strong mass cooling rates of gas below  1–2 keV  . The soft X-ray luminosity expected from steady cooling flows is missing. Here we outline and test the energetics of a cold mixing model in which gas below  1–2 keV  falls from the flow and is rapidly cooled by mixing with cold gas. The missing X-ray luminosity can emerge in the ultraviolet, optical and infrared bands, where strong emission nebulosities are commonly seen. We explore further the requirements for any heat sources that balance the radiative cooling in cluster cores.  相似文献   

Analysis and survival of amino acids in Martian regolith analogs     

James R. C. Garry  Inge Loes ten Kate  Zita Martins  Per Nrnberg  Pascale Ehrenfreund 《Meteoritics & planetary science》2006,41(3):391-405

Abstract— We have investigated the native amino acid composition of two analogs of Martian soil, JSC Mars‐1 and Salten Skov. A Mars simulation chamber has been built and used to expose samples of these analogs to temperature and lighting conditions similar to those found at low latitudes on the Martian surface. The effects of the simulated conditions have been examined using high‐performance liquid chromatography (HPLC). Exposure to energetic ultraviolet (UV) light in vacuum appears to cause a modest increase in the concentration of certain amino acids within the materials, which is interpreted as resulting from the degradation of microorganisms. The influence of low temperatures shows that the accretion of condensed water on the soils leads to the destruction of amino acids, supporting the idea that reactive chemical processes involving H₂O are at work within the Martian soil. We discuss the influence of UV radiation, low temperatures, and gaseous CO₂ on the intrinsic amino acid composition of Martian soil analogs and describe, with the help of a simple model, how these studies fit within the framework of life detection on Mars and the practical tasks of choosing and using Martian regolith analogs in planetary research.  相似文献